Interplay of laser power and pore characteristics in selective laser melting of ZK60 magnesium alloys:A study based on in-situ monitoring and image analysis

This study offers significant insights into the multi-physics phenomena of the SLM process and the subsequent porosity characteristics of ZK60 Magnesium(Mg)alloys.High-speed in-situ monitoring was employed to visualise process signals in real-time,elucidating the dynamics of melt pools and vapour plumes under varying laser power conditions specifically between 40 W and 60 W.Detailed morphological analysis was performed using Scanning-Electron Microscopy(SEM),demonstrating a critical correlation between laser power and pore formation.Lower laser power led to increased pore coverage,whereas a denser structure was observed at higher laser power.This laser power influence on porosity was further confirmed via Optical Microscopy(OM)conducted on both top and cross-sectional surfaces of the samples.An increase in laser power resulted in a decrease in pore coverage and pore size,potentially leading to a denser printed part of Mg alloy.X-ray Computed Tomography(XCT)augmented these findings by providing a 3D volumetric representation of the sample internal structure,revealing an inverse relationship between laser power and overall pore volume.Lower laser power appeared to favour the formation of interconnected pores,while a reduction in interconnected pores and an increase in isolated pores were observed at higher power.The interplay between melt pool size,vapour plume effects,and laser power was found to significantly influence the resulting porosity,indicating a need for effective management of these factors to optimise the SLM process of Mg alloys.

High-strength and thermally stable TiB_(2)-modified Al-Mn-Mg-Er-Zr alloy fabricated via selective laser melting

To increase the processability and plasticity of the selective laser melting(SLM)fabricated Al-Mn-Mg-Er-Zr alloys,a novel TiB_(2)-modified Al-Mn-Mg-Er-Zr alloy with a mixture of Al-Mn-Mg-Er-Zr and nano-TiB_(2) powders was fabricated by SLM.The pro-cessability,microstructure,and mechanical properties of the alloy were systematically investigated by density measurement,microstruc-ture characterization,and mechanical properties testing.The alloys fabricated at 250 W displayed higher relative densities due to a uni-formly smooth top surface and appropriate laser energy input.The maximum relative density value of the alloy reached(99.7±0.1)%,demonstrating good processability.The alloy exhibited a duplex grain microstructure consisting of columnar regions primarily and equiaxed regions with TiB_(2),Al6Mn,and Al3Er phases distributed along the grain boundaries.After directly aging treatment at a high tem-perature of 400℃,the strength of the SLM-fabricated TiB_(2)/Al-Mn-Mg-Er-Zr alloy increased due to the precipitation of the secondary Al6Mn phases.The maximum yield strength and ultimate tensile strength of the aging alloy were measured to be(374±1)and(512±13)MPa,respectively.The SLM-fabricated TiB_(2)/Al-Mn-Mg-Er-Zr alloy demonstrates exceptional strength and thermal stability due to the synergistic effects of the inhibition of grain growth,the incorporation of TiB_(2) nanoparticles,and the precipitation of secondary Al6Mn nanoparticles.

Effects of processing parameters on fabrication defects,microstructure and mechanical properties of additive manufactured Mg–Nd–Zn–Zr alloy by selective laser melting process

Mg–3Nd–0.2Zn–0.4Zr(NZ30K,wt.%)alloy is a new kind of high-performance metallic biomaterial.The combination of the NZ30K Magnesium(Mg)alloy and selective laser melting(SLM)process seems to be an ideal solution to produce porous Mg degradable implants.However,the microstructure evolution and mechanical properties of the SLMed NZ30K Mg alloy were not yet studied systematically.Therefore,the fabrication defects,microstructure,and mechanical properties of the SLMed NZ30K alloy under different processing parameters were investigated.The results show that there are two types of fabrication defects in the SLMed NZ30K alloy,gas pores and unfused defects.With the increase of the laser energy density,the porosity sharply decreases to the minimum first and then slightly increases.The minimum porosity is 0.49±0.18%.While the microstructure varies from the large grains with lamellar structure inside under low laser energy density,to the large grains with lamellar structure inside&the equiaxed grains&the columnar grains under middle laser energy density,and further to the fine equiaxed grains&the columnar grains under high laser energy density.The lamellar structure in the large grain is a newly observed microstructure for the NZ30K Mg alloy.Higher laser energy density leads to finer grains,which enhance all the yield strength(YS),ultimate tensile strength(UTS)and elongation,and the best comprehensive mechanical properties obtained are YS of 266±2.1 MPa,UTS of 296±5.2 MPa,with an elongation of 4.9±0.68%.The SLMed NZ30K Mg alloy with a bimodal-grained structure consisting of fine equiaxed grains and coarser columnar grains has better elongation and a yield drop phenomenon.

Crack elimination and strength enhancement mechanisms of selective laser melted Si-modified Al−Mn−Mg−Er−Zr alloy

In order to increase the processability and process window of the selective laser melting(SLM)-fabricated Al−Mn−Mg−Er−Zr alloy,a novel Si-modified Al−Mn−Mg−Er−Zr alloy was designed.The effect of Si alloying on the surface quality,processability,microstructure,and mechanical properties of the SLM-fabricated alloy was studied.The results showed that introducing Si into the Al−Mn−Mg−Er−Zr alloy prevented balling and keyhole formation,refined the grain size,and reduced the solidification temperature,which eliminated cracks and increased the processability and process window of the alloy.The maximum relative density of the SLM-fabricated Si/Al−Mn−Mg−Er−Zr alloy reached 99.6%.The yield strength and ultimate tensile strength of the alloy were(371±7)MPa and(518±6)MPa,respectively.These values were higher than those of the SLM-fabricated Al−Mn−Mg−Er−Zr and other Sc-free Al−Mg-based alloys.

Selective laser melted AZ91D magnesium alloy with superior balance of strength and ductility

In the context of global carbon neutrality, the application of lightweight magnesium alloys is becoming increasingly attractive. In this study, selective laser melting(SLM) was employed to achieve nearly full dense and crack-free AZ91D components with fine equiaxed grain structure. The formation mechanism of typical pore defects(gas pore, lack-of-fusion pore and keyhole pore) and melting modes(keyhole mode and conduction mode) were systematically studied by varying the laser power and scanning speed. The morphology and volume fraction of the pores under different processing conditions were characterized. A criterion based on the depth-to-width ratio of the melt pool was established to identify different melting modes. The strength and ductility(tensile strength up to 340 MPa and uniform elongation of 8.9%)of the as deposited AZ91D are far superior to those of the casting components and are comparable to those of its wrought counterparts.The superior balance of strength and ductility of SLMed AZ91D, as well as the negligible anisotropic properties are mainly ascribed to the extremely fine equiaxed grain structure(with average grain size of ~1.2 μm), as well as the discontinuous distribution of β-Al_(12)Mg_(17) phases. It thus provides an alternative way to fabricate high-strength magnesium alloys with complex geometry.

Towards implementation of alloy-specific thermo-fluid modelling for laser powder-bed fusion of Mg alloys

Multi-physics thermo-fluid modeling has been extensively used as an approach to understand melt pool dynamics and defect formation as well as optimizing the process-related parameters of laser powder-bed fusion(L-PBF).However,its capabilities for being implemented as a reliable tool for material design,where minor changes in material-related parameters must be accurately captured,is still in question.In the present research,first,a thermo-fluid computational fluid dynamics(CFD)model is developed and validated against experimental data.Considering the predicted material properties of the pure Mg and commercial ZK60 and WE43 Mg alloys,parametric studies are done attempting to elucidate how the difference in some of the material properties,i.e.,saturated vapor pressure,viscosity,and solidification range,can influence the melt pool dynamics.It is found that a higher saturated vapor pressure,associated with the ZK60 alloy,leads to a deeper unstable keyhole,increasing the keyhole-induced porosity and evaporation mass loss.Higher viscosity and wider solidification range can increase the non-uniformity of temperature and velocity distribution on the keyhole walls,resulting in increased keyhole instability and formation of defects.Finally,the WE43 alloy showed the best behavior in terms of defect formation and evaporation mass loss,providing theoretical support to the extensive use of this alloy in L-PBF.In summary,this study suggests an approach to investigate the effect of materials-related parameters on L-PBF melting and solidification,which can be extremely helpful for future design of new alloys suitable for L-PBF.

Microstructural evolution and dynamic recrystallization mechanisms of additively manufactured TiAl alloy with heterogeneous microstructure during hot compression

Microstructural evolution and dynamic recrystallization(DRX)mechanisms of a Ti-48Al-2Cr-2Nb(at.%)alloy prepared by selective electron beam melting(SEBM)during hot deformation at 1150℃and 0.1 s^(-1)were investigated by hot compression tests,optical microscope(OM),scanning electron microscope(SEM),electron back-scattered diffraction(EBSD)and transmission electron microscope(TEM).The results show that the initial microstructure of the as-SEBMed alloy exhibits layers of coarseγgrains and fineγ+α_(2)+(α_(2)/γ)lamellar mixture grains alternately along the building direction.During the early stage of hot deformation,deformation twins tend to form within the coarse grains,facilitating subsequent deformation,and a small number of DRX grains appear in the fine-grained regions.With the increase of strain,extensive DRX grains are formed through different DRX mechanisms in both coarse and fine-grained regions,involving discontinuous dynamic recrystallization mechanism(DDRX)in the fine-grained regions and a coexistence of DDRX and continuous dynamic recrystallization(CDRX)in the coarsegrained regions.

Effect of Nd content on electrochemical performances of nanocrystalline and amorphous (Mg_(24)Ni_(10)Cu_2)_(100-x)Nd_x(x=0-20) alloys prepared by melt spinning

The nanocrystalline and amorphous Mg2Ni-type alloys with a chemical composition of （Mg24Ni10Cu2）100-xNdx （x=0, 5, 10, 15, 20） were fabricated by melt spinning technology. The effects of spinning rate on the structure and electrochemical hydrogen storage performance of the alloys were investigated. The as-spun Nd-free alloy displays an entire nanocrystalline structure, whereas the as-spun Nd-added alloys hold a nanocrystalline and amorphous structure, suggesting that the addition of Nd facilitates the glass forming of the Mg2Ni-type alloys. Increasing the spinning rate from 0 to 40 m/s gives rise to the discharge capacity growing from 42.5 to 100.6 mA·h/g for the x=0 alloy and from 86.4 to 452.8 mA·h/g for the x=10 alloy. And the cycle stability （S20） rises from 40.2%to 41.1%for the x=0 alloy and from 53.2%to 89.7%for the x=10 alloy, respectively.

Laser surface melting AZ31B magnesium alloy with liquid nitrogen-assisted cooling

Laser surface melting（LSM） is a high-energy surface treatment that allows modification of the microstructure and surface properties of Mg alloys. In the present work, an attempt of LSM on magnesium alloy with liquid nitrogen-assisted cooling（LNSC） was carried out to get the higher cooling rate and improve the surface properties. The experimental results were compared with those of Ar gas protection at room temperature. The samples after LSM with LNSC resulted in a thinner melted layer, a highly homogeneous, refined melted microstructure and formed a lot of worm-like nanocrystals and local amorphous structures. Microhardness of the melted layer with LNAC was improved to HV 90-148 as compared to HV 65-105 of the samples with Ar gas protection. The corrosion resistance of the melted layer in a 3.5% Na Cl solution（mass fraction） was improved because of the grain refinement and redistribution of β-Mg17Al12 phases following rapid quenching associated with the process.

Electrochemical codeposition of Mg-Li-Gd alloys from LiCl-KCl-MgCl_2-Gd_2O_3 melts

Mg-Li-Gd alloys were prepared by electrochemical codeposition from LiCl-KCl-MgCl 2 -Gd 2 O 3 melts on molybdenum electrode with constant current density at 823 and 973 K. The microstructure of the Mg-Li-Gd alloys was analyzed by X-ray diffraction （XRD）, optical microscopy （OM） and scanning electron microscopy （SEM）. The results show that magnesium and gadolinium deposit mainly in the first 30 min, and the alloy obtained contains 96.53% Mg, 0.27% Li and 3.20% Gd （mass fraction）. Then, the reduction of lithium ions occurs quickly. The composition of alloy can be adjusted by controlling electrolysis time or Gd 2 O 3 concentration in LiCl-KCl melts. With the addition of Gd into Mg-Li alloys, the corrosion resistance of the alloys is enhanced. XRD results suggest that Mg 3 Gd and Mg 2 Gd can be formed in Mg-Li-Gd alloys. The distribution of Gd element in Mg-Li-Gd alloys indicates that Gd element mainly distributes at the grain boundaries of Mg-Li-Gd alloys.

Effect of melt convection on primary dendrite arm spacing in directionally solidified Pb-26%Bi hypo-peritectic alloys

Primary dendrite arm spacing（PDAS） of α phase in directionally solidified Pb-26%Bi（mass fraction） hypo-peritectic alloys was measured by considering the effect of melt convection in cylindrical samples with different diameters.The experimental results show the measured PDAS increases with increasing diameter of the sample.At the growth velocity of 5 μm/s,its value changes from 161.5 μm for the sample with 1.8 mm in diameter to 240.4 μm for the sample with 7 mm in diameter.The strong melt convection in large diameter samples causes a high bulk alloy composition and a high concentration gradient in peritectic β phase,resulting in a larger PDAS.Simultaneously,the high concentration gradient could effectively promote the peritectic transformation,enhancing the dissolution of the thin α dendrite.

Simulation study on non-linear effects of initial melt temperatures on microstructures during solidification process of liquid Mg_7Zn_3 alloy

The non-linear effects of different initial melt temperatures on the microstructure evolution during the solidification process of liquid Mg7Zn3 alloys were investigated by molecular dynamics simulation, The microstructure transformation mechanisms were analyzed by several methods. The system was found to be solidified into amorphous structures from different initial melt temperatures at the same cooling rate of 1×10^12 K/s, and the 1551 bond-type and the icosahedron basic cluster （12 0 12 0 ） played a key role in the microstructure transition. Different initial melt temperatures had significant effects on the final microstructures. These effects only can be clearly observed below the glass transition temperature Tg; and these effects are non-linearly related to the initial melt temperatures, and fluctuated in a certain range. However, the changes of the average atomic energy of the systems are still linearly related with the initial melt temperatures, namely, the higher the initial melt temperature is, the more stable the amorphous structure is and the stronger the glass forming ability will be.

Melting purification process and refining effect of 5083 Al-Mg alloy

To improve the poor stability of casting process of Al alloy with high Mg content, which leads to poor final product quality, the melting purification process and the influences of the refiner on the microstructure and defect of 5083 alloy were studied. The results show that the optimized process for the rotary impeller degassing of 5083 alloy is as follows： a rotary speed of 250-400 r/min; a gas flow of 1.2-2.0 L/s, a refining time of 10-15 min. This optimized process can reduce the gas content in the solid alloy to 2× 10^-3 mL/g or lower. Due to the addition of grain refiner, the cast microstructure of 5083 alloy is refined. The Al-5Ti-IB wire shows the best refining effect among all the refiners. The refining effect is improved with the increase of grain refiner addition amount. And the refinement effects become stable when Ti content reaches 0.1% or higher. The surface crinkling defect of the billet can be easily found in the alloy refined with Al-5Ti-IB wire compared with the alloys refined with other refiners.

Banding structure formation during directional solidification of Pb-Bi peritectic alloys

Directional solidification experiments on Pb-Bi peritectic alloys were carried out at very low growth rate （v=0.5 μm/s） and high temperature gradient （G=35 K/mm） in an improved Bridgman furnace. The banding structures were observed in both hypoperitectic and hyperperitectic compositions （Pb-xBi, x=26%, 28%, 30% and 34%）. Tree-like primary α phase in the center of the sample surrounded by the peritectic β phase matrix was also observed, resulting from the melt convection. The banding microstructure, however, is found to be transient after the tree-like structure and only the peritectic phase forms after a few bands. Composition variations in the banding structure are measured to determine the nucleation undercooling for both α and β phases. In a finite length sample, convection is shown to lead only to the transient formation of bands. In this transient banding regime, only a few bands with a variable width are formed, and this transient banding process can occur over a wide range of compositions inside the two-phase peritectic region.

Effects of melt overheating degree on undercooling degree and amorphous forming of Nd_9Fe_(85-x)Ti_4C_2B_x(x=10, 12) magnetic alloys

The effectsof melt overheating degree on the undercooling degree and resultant solidification structures of Nd9Fe85-xTi4C2Bx（x=10, 12） glass-forming alloyswerestudied by differential thermal analysis combining with solidification structure analysis. The results indicate that the undercooling degree of Nd9Fe85-xTi4C2Bx（x=10, 12） alloys significantly increaseswith the rise of melt overheating degree, and two overheating degree thresholds corresponding to the drastic increase of the mean undercooling degree are found for each of the alloys. The existence of two turning points of the mean undercooling degreescan be linked to the structure transitions inside the overheated melts, which result in the evident increase of volume fraction of amorphous phasein the solidified structures.

Microstructural evolution and mechanical properties of laser melting deposited Ti-6.5Al-3.5Mo-1.5Zr-0.3Si titanium alloy

A rectangular plate of Ti-6.5A1-3.5Mo-I.5Zr-0.3Si titanium alloy was fabricated by laser melting deposition （LMD） technology. Macrostructure and microstructure were characterized by optical microscope （OM） and scanning electron microscope （SEM）. Room temperature tensile properties were evaluated. Results indicate that the macro-morphology is dominated by large columnar grains traversing multiple deposited layers. Two kinds of bands, named the wide bands and the narrow bands, are observed. The wide band consists of crab-like a lath and Widmanstatten a colony. The narrow band consists of a lath and transformed ft. The formation mechanism of the two bands was explored. The influence of heat effect caused by subsequent deposition layers on microstructural evolution during deposition process was discussed. The room temperature tensile test demonstrates that the strength of laser deposited Ti-6.5A1-3.5Mo-I.5Zr-0.3Si is comparable to that of wrought bars.

Low cycle fatigue behavior of laser melting deposited TC18 titanium alloy

Low cycle fatigue （LCF） behavior of laser melting deposited （LMD） TC18 titanium alloy was studied at room temperature. Microstructure consisting of fine lamella-like primary α phase and transformed β matrix was obtained by double annealed treatment, and inhomogeneous grain boundaryαphase was detected. Fatigue fracture surfaces and longitudinal sections of LCF specimens were examined by optical microscopy and scanning electron microscopy. Results indicate that more than one crack initiation site can be detected on the LCF fracture surface. The fracture morphology of the secondary crack initiation site is different from that of the primary crack initiation site. When the crack grows along the grain boundaryαphase, continuous grain boundaryαphase leads to a straight propagating manner while discontinuous grain boundaryαphase gives rise to flexural propagating mode.

Effects of low melting point metals(Ga,In,Sn) on hydrolysis properties of aluminum alloys

Low melting point metals（Ga, In, Sn） as alloy elements were used to prepare Al-In-Sn and Al-Ga-In-Sn alloys through mechanical ball milling method. The effects of mass ratio of In to Sn and Ga content on the hydrolysis properties of aluminum alloys were investigated. X-ray diffraction（XRD） and scanning electron microscopy（SEM） with energy disperse spectroscopy（EDS） were used to analyze the compositions and morphologies of the obtained Al alloys. The results show that the phase compositions of Al-In-Sn ternary alloys are Al and two intermetallic compounds, In3 Sn and In Sn4. All Al-In-Sn ternary alloys exhibit poor hydrolysis activity at room temperature. Al-In-Sn alloy with the mass ratio of In to Sn equaling 1：4 has the highest hydrogen yield. After Ga is introduced to the ternary alloys, the hydrolysis activity of aluminum alloys at room temperature is greatly improved. It is speculated that the addition of Ga element promotes the formation of defects inside the Al alloys and Ga-In3Sn-In Sn4 eutectic alloys on the alloys surface. Al atoms can be dissolved in this eutectic phase and become the active spots during the hydrolysis process. The small size and uniform distribution of this eutectic phase may be responsible for the enhancement of hydrolysis activity.

Effect of Rare Earth on Microstructure of Vacuum Melting Ni-Based Self-Fluxing Alloy Coatings

The Ni-based self-fluxing alloy coating containing RE was acquired by the technique of vacuum melting on the hypoeutectoid steel (Fe-0.45%C) matrix. By X-ray diffraction, SEM and EDX, the microstructure and phase structure of section of coating and the microstructure near the interface between coating and matrix were investigated, and the effect of RE on microstructure of coating was also discussed. The results show that the microstructure of the NiCrBSi alloy coating is composed of Ni-based solid solution and a lot of massive, globular and needle secondary phases CrB, Ni_3B, Cr_7C_3, Cr_(23)C_6 among the solid solution. The metallurgical binding between steel matrix and coating is realized. RE makes needle phase of alloy coating vanish. New phases of NiB and Cr_(6.5)Ni_(2.5)Si are precipitated from alloy coating, and secondary phases of alloy coating are sphericized. Consequently, RE also hinders the diffusion of Ni, Cr and Si atoms from coating to matrix and Fe atoms from matrix to coating, holds back the dilution of Fe for NiCrBSi alloy coating, and assures the chemical composition of the alloy coating.

Effects of rare earth La on the microstructure and melting property of(Ag-Cu_(28))-30Sn alloys prepared by mechanical alloying

To obtain novel intermediate temperature alloy solders with a melting temperature of 400-600°C,nominal（Ag-Cu28）-30Sn alloys without or with a trace addition（0.5 or 1.0 wt.%） of rare earth（RE） element La were prepared by mechanical alloying.The aim of this research is to investigate the effects of the addition of La on the microstructures,alloying process and melting properties of（Ag-Cu28）-30Sn alloys.The results show that the addition of La produces no new phase.A trace amount of La addition can effectively refine the grain size,but the excessive addition of 1.0 wt.% La inhibits the alloying process.The influence of La on the melting temperatures of solder alloys is negligible.However,the trace addition of 0.5 wt.% La can distinctly reduce the fusion zone and improve the melting property of（Ag-Cu28）-30Sn alloys.