We report the first nuclear magnetic resonance （NMR） study on single crystals of staircase Kagome antiferromagnet PbCu3Te07 （TN1 -36K）. A Curie constant θ -140K is obtained by a Curie Weiss fit to the high- tempe...We report the first nuclear magnetic resonance （NMR） study on single crystals of staircase Kagome antiferromagnet PbCu3Te07 （TN1 -36K）. A Curie constant θ -140K is obtained by a Curie Weiss fit to the high- temperature Knight shift of 125 Te. The hyperfine coupling constant is estimated to be 125Ahf = -67 kOe/#B, and a strong interlayer coupling among staircase Kagome planes is suggested with such a large hyperfine coupling, according to the lattice structure. The 63,65Cu NMR spectra are found by the zero-field （ZF） NMR at T = 2 K, and the internal hyperfine fields are estimated to be 10.3 T and 9.6 T, for Cu（1） and Cu（2） sites, respectively, in the lattice. A second type of ZF NMFt signal with a large rf enhancement is also seen after field-cycling through a high magnetic field.展开更多
基金Supported by the National Natural Science Foundation of China under Grant Nos 11374364 and 11222433the National Basic Research Program of China under Grant No 2011CBA00112the Scientific Research Foundation for the Returned Overseas Chinese Scholars of State Education Ministry
文摘We report the first nuclear magnetic resonance （NMR） study on single crystals of staircase Kagome antiferromagnet PbCu3Te07 （TN1 -36K）. A Curie constant θ -140K is obtained by a Curie Weiss fit to the high- temperature Knight shift of 125 Te. The hyperfine coupling constant is estimated to be 125Ahf = -67 kOe/#B, and a strong interlayer coupling among staircase Kagome planes is suggested with such a large hyperfine coupling, according to the lattice structure. The 63,65Cu NMR spectra are found by the zero-field （ZF） NMR at T = 2 K, and the internal hyperfine fields are estimated to be 10.3 T and 9.6 T, for Cu（1） and Cu（2） sites, respectively, in the lattice. A second type of ZF NMFt signal with a large rf enhancement is also seen after field-cycling through a high magnetic field.
