A series of CoPd/KIT-6 bimetallic catalysts with various Co:Pd molar ratios at different calcination temperatures were prepared and used for the direct synthesis of H_(2)O_(2) from H_(2) and O_(2).These catalysts were...A series of CoPd/KIT-6 bimetallic catalysts with various Co:Pd molar ratios at different calcination temperatures were prepared and used for the direct synthesis of H_(2)O_(2) from H_(2) and O_(2).These catalysts were characterized by nitrogen adsorption-desorption,low and wide-angle X-ray diffraction(XRD),X-ray photoelectron spectroscopy(XPS),transmission electron microscopy(TEM),scanning electron microscopy(SEM),elemental mapping and energy-dispersive X-ray(EDX)methods.It was found that the particle size,electronic interactions,morphology,and textural properties of these catalysts as well as their catalytic activity in the reaction of H_(2) with O_(2) were affected by Co addition and different calcination temperatures.Also,the results showed that while the H_(2)O_(2) selectivity depends on Pd^(2+) species,the H_(2) conversion is related to Pd0 active sites.Among these catalysts,CoPd/KIT-6 calcined at 350℃(CoPd/KIT-350 catalyst)showed the best catalytic activity with 50%of H_(2)O_(2) selectivity and 51%conversion of H_(2).展开更多
对于非线性电力传动对象和非线性PD反馈控制器组成的整个模糊控制系统,进行了稳定性分析,并且给出了非线性PD反馈控制器的增益参数设计,其中,非线性电力传动对象是用模糊Takagi and Sugeno模型描述的。提出了模糊系统中的状态微分反馈控...对于非线性电力传动对象和非线性PD反馈控制器组成的整个模糊控制系统,进行了稳定性分析,并且给出了非线性PD反馈控制器的增益参数设计,其中,非线性电力传动对象是用模糊Takagi and Sugeno模型描述的。提出了模糊系统中的状态微分反馈控制,并且有效地分析了整个控制系统的稳定性。设计方法最终被归结为满足所谓Y2-condition的一些参数的选择。给出了对于一个非线性质量-弹簧-阻尼器系统的应用实例。展开更多
为了解决直线电机伺服系统跟踪速度与峰化现象之间的矛盾,设计一种基于非线性扩张状态观测器的比例微分(Proportion Differentiation,PD)控制器。将直线电机伺服系统中的未建模动态和外界干扰定义为总和扰动并扩充为系统新的状态变量,...为了解决直线电机伺服系统跟踪速度与峰化现象之间的矛盾,设计一种基于非线性扩张状态观测器的比例微分(Proportion Differentiation,PD)控制器。将直线电机伺服系统中的未建模动态和外界干扰定义为总和扰动并扩充为系统新的状态变量,利用非线性扩张状态观测器(Non Linear Extended State Observer,NLESO)估计不可测量的直线电机动子速度以及总和扰动。利用NLESO和跟踪微分器TD的输出,基于动态补偿线性化思想设计了引入补偿量的PD控制器,并给出了闭环控制系统稳定性证明。在Googol公司的实验平台上,通过与两种基于LESO的PD控制器对比,验证了所设计的基于NLESO的PD控制器的可行性。实验结果表明,基于NLESO的PD控制器可使直线电机伺服系统具有跟踪速度快、跟踪精度高、峰化现象小、鲁棒性强的优点。展开更多
基金the financial support(Research Council Grant)provided by Isfahan University of Technology(Iran).
文摘A series of CoPd/KIT-6 bimetallic catalysts with various Co:Pd molar ratios at different calcination temperatures were prepared and used for the direct synthesis of H_(2)O_(2) from H_(2) and O_(2).These catalysts were characterized by nitrogen adsorption-desorption,low and wide-angle X-ray diffraction(XRD),X-ray photoelectron spectroscopy(XPS),transmission electron microscopy(TEM),scanning electron microscopy(SEM),elemental mapping and energy-dispersive X-ray(EDX)methods.It was found that the particle size,electronic interactions,morphology,and textural properties of these catalysts as well as their catalytic activity in the reaction of H_(2) with O_(2) were affected by Co addition and different calcination temperatures.Also,the results showed that while the H_(2)O_(2) selectivity depends on Pd^(2+) species,the H_(2) conversion is related to Pd0 active sites.Among these catalysts,CoPd/KIT-6 calcined at 350℃(CoPd/KIT-350 catalyst)showed the best catalytic activity with 50%of H_(2)O_(2) selectivity and 51%conversion of H_(2).
文摘对于非线性电力传动对象和非线性PD反馈控制器组成的整个模糊控制系统,进行了稳定性分析,并且给出了非线性PD反馈控制器的增益参数设计,其中,非线性电力传动对象是用模糊Takagi and Sugeno模型描述的。提出了模糊系统中的状态微分反馈控制,并且有效地分析了整个控制系统的稳定性。设计方法最终被归结为满足所谓Y2-condition的一些参数的选择。给出了对于一个非线性质量-弹簧-阻尼器系统的应用实例。
文摘为了解决直线电机伺服系统跟踪速度与峰化现象之间的矛盾,设计一种基于非线性扩张状态观测器的比例微分(Proportion Differentiation,PD)控制器。将直线电机伺服系统中的未建模动态和外界干扰定义为总和扰动并扩充为系统新的状态变量,利用非线性扩张状态观测器(Non Linear Extended State Observer,NLESO)估计不可测量的直线电机动子速度以及总和扰动。利用NLESO和跟踪微分器TD的输出,基于动态补偿线性化思想设计了引入补偿量的PD控制器,并给出了闭环控制系统稳定性证明。在Googol公司的实验平台上,通过与两种基于LESO的PD控制器对比,验证了所设计的基于NLESO的PD控制器的可行性。实验结果表明,基于NLESO的PD控制器可使直线电机伺服系统具有跟踪速度快、跟踪精度高、峰化现象小、鲁棒性强的优点。
