Enthalpy for mixing of Cu La and Pd Sn binary systems were predicted by Miedema model. The agreement between the predicting results and the experimental data shows that such model is suitable for not only ferrous me...Enthalpy for mixing of Cu La and Pd Sn binary systems were predicted by Miedema model. The agreement between the predicting results and the experimental data shows that such model is suitable for not only ferrous metal systems, but also rare earth elements and nonferrous metals.展开更多
Developing efficient catalysts with high activity and durability via alloying strategy is essential to the energy conversion in various electro-catalytic reactions.Among the different alloy structures,intermetallic co...Developing efficient catalysts with high activity and durability via alloying strategy is essential to the energy conversion in various electro-catalytic reactions.Among the different alloy structures,intermetallic compounds(IMCs)have received much attention recently due to the special geometric and electronic effects and outstanding activity and durability,endowed by their ordered structure.Herein,A series of hollow-structured nanocrystals of Pd-Sn alloy,including face-centered cubic solid solution of Pd(Sn),IMCs of Pd_(2)Sn,and IMCs of Pd_(3)Sn2,are fabricated via a solvothermal strategy by varying the precursor ratio of Pd and Sn.The structure difference of the nanocrystals has been investigated via combined electron microscopy and spectroscopy,assisted by local elemental separation analysis and X-ray spectroscopy.Among all,Pd_(3)Sn_(2)IMCs show outstanding methanol oxidation reaction(MOR)activity in terms of mass activity(1.3 A·mgPd^(−1))and specific activity(5.03 mA·cm^(−2)).Through density functional theory(DFT)simulation calculations on three different Pd-Sn alloy models,the performance has been well understood.As compared with Pd(Sn)and Pd2Sn,the high MOR kinetics on Pd_(3)Sn_(2)is featured by its weaker CO adsorption and favorable CO–OH co-adsorption.展开更多
文摘Enthalpy for mixing of Cu La and Pd Sn binary systems were predicted by Miedema model. The agreement between the predicting results and the experimental data shows that such model is suitable for not only ferrous metal systems, but also rare earth elements and nonferrous metals.
基金support from the Natural Science Foundation of Tianjin,China(No.18JCYBJC20600)Institute of Energy,Hefei Comprehensive National Science Center(No.19KZS207).
文摘Developing efficient catalysts with high activity and durability via alloying strategy is essential to the energy conversion in various electro-catalytic reactions.Among the different alloy structures,intermetallic compounds(IMCs)have received much attention recently due to the special geometric and electronic effects and outstanding activity and durability,endowed by their ordered structure.Herein,A series of hollow-structured nanocrystals of Pd-Sn alloy,including face-centered cubic solid solution of Pd(Sn),IMCs of Pd_(2)Sn,and IMCs of Pd_(3)Sn2,are fabricated via a solvothermal strategy by varying the precursor ratio of Pd and Sn.The structure difference of the nanocrystals has been investigated via combined electron microscopy and spectroscopy,assisted by local elemental separation analysis and X-ray spectroscopy.Among all,Pd_(3)Sn_(2)IMCs show outstanding methanol oxidation reaction(MOR)activity in terms of mass activity(1.3 A·mgPd^(−1))and specific activity(5.03 mA·cm^(−2)).Through density functional theory(DFT)simulation calculations on three different Pd-Sn alloy models,the performance has been well understood.As compared with Pd(Sn)and Pd2Sn,the high MOR kinetics on Pd_(3)Sn_(2)is featured by its weaker CO adsorption and favorable CO–OH co-adsorption.
