Soil heavy metal pollution is one of the main environmental problems in Pearl River Delta Economic?Zone of China. Based on multi-purpose regional geochemical survey, regional eco-geochemical assessment, local eco-geoc...Soil heavy metal pollution is one of the main environmental problems in Pearl River Delta Economic?Zone of China. Based on multi-purpose regional geochemical survey, regional eco-geochemical assessment, local eco-geochemical assessment and comprehensive appraisal, the eco-geochemical survey and assessment in Pearl River Delta Economic Zone of 41,698 km2?were completed. Samples from soils were collected in accordance with the two-layer grid method. Totally 54 elements and indicators for soils were determined. Compared to deep soils, the sampled surface soils are enriched in OrgC, N, P, Cd, S,Hg, Ag, B, Au, S and poor with As, Ni, I, Co, Cr, V, MgO, Sc, Al2O3, Fe2O3?etc. The characteristics of geochemical reference value of element in soil that inherited soil parent material and regional elements combined features reflected that the elements enriched in the soil was interrelated with acid rock, sandstone and shale. The spatial distribution characteristics of element regional geochemistry were conditional by regional environmental geological conditions,and effected by human activities. The Pearl River Delta plain is a typical geochemical landscape area with regional anomaly of multiple-elements. The north, western and eastern parts of the Pearl River Delta Economic Zone are quite different in geochemical features due to regional geological background, soil parent materials, geomorphic characteristics and human activities. Environment quality evaluation results show that the grade I and grade II soil accounted for 19.9% and 57.3% of the total area. Many samples that widely distributed in the economic developed of Pearl River Delta Plain area reached the third-grade of national soil environment standard. The soil enriched in Cd, Hg, As, and the area ratio accounting for 22.8% of the total area. It is mainly controlled by the geochemical background, the Pearl River Delta formation evolution process, especially the marine transgression process lead to Cd, Cu, Zn and Pb enrichment in Pearl River Delta plain. At the same time, under the influence of higher pressure of human activities, all kinds of exogenous input material carrying heavy metal pollutants on soil environmental quality also could not to ignore.展开更多
Dongguan City, located in the Pearl River Delta economic zone of China, is famous for its rapid developing township-enterprises in the past 30 years. A total of 759 composite soil samples, including 606 surface soil s...Dongguan City, located in the Pearl River Delta economic zone of China, is famous for its rapid developing township-enterprises in the past 30 years. A total of 759 composite soil samples, including 606 surface soil samples and 153 deep soil samples, have been collected in the city. These samples have been analyzed for 13elements(Al, As, Cu, Cd, Co, Cr, Fe, Hg, Mn, Ni, Pb, Si,and Zn) and other parameters(p H values and organic matter) to evaluate the influence of anthropic activities on the soil environmental quality and to identify the spatial distribution of heavy metals and their possible sources. The results indicate that the average concentrations of heavy metals in soil were significantly lower than the threshold of the second grade of the Soil Environment Quality Standard in China(GB15618-1995) and the soil environmental quality in this area is comparatively good. But in comparison with local soil geochemical baseline values, As,Cd, Cu, Hg, Pb, and Zn have accumulated remarkably.Specifically, the average concentrations of As, Cd, Cu, and Hg in the small part samples of the west plain and central areas are higher than the national second-grade quality standard, indicating some level of contamination. Multivariate and geostatistical methods have been applied to differentiate the influences of natural processes and human activities on the concentration of heavy metals in surface soils in the study area. Cluster and factor analyses result in the grouping of Al, As, Cr, Cu, Fe, Ni, and Si into factor F1; Co, Mn, Pb, and Zn into F2; and Cd and Hg into F3.The spatial pattern of the three factors may be well demonstrated by geostatistical analysis. It is shown that the first factor could be considered as a natural source controlled by parent material. The second factor could be referred to as ‘‘industrial and traffic pollution sources' '. The source of the third factor is mainly controlled by long-term anthropic activities, including agricultural activities, fossil fuel consumption, and atmospheric deposition.展开更多
Cultivated land pressure is often used to reflect the shortage of cultivated land resources. By using the methods of the Cultivated Land Pressure Index, coefficient of variation and cold-hot spot analysis, this paper ...Cultivated land pressure is often used to reflect the shortage of cultivated land resources. By using the methods of the Cultivated Land Pressure Index, coefficient of variation and cold-hot spot analysis, this paper analyzes the spatial-temporal differentiation pattern and dynamic change processes of cultivated land pressure in the counties of the Pearl River-Xijiang Economic Zone from 2008 to 2017, and measures the factors which influence cultivated land pressure by using Principal Component Analysis. The results show that the cultivated land pressure in the Pearl River-Xijiang Economic Zone has been in a “high pressure” state, and the Cultivated Land Pressure Index has been rising continuously from 2008 to 2017. The coefficient of variation of the Cultivated Land Pressure Index in the Pearl River-Xijiang Economic Zone and various prefecture-level cities is fluctuating and rising, which indicates that the overall spatial differences in the cultivated land pressure in this region are expanding and polarization is obvious. In addition, the area where the municipal district of the provincial capital city is located is the core area of urban development and also the area with the greatest cultivated land pressure. The spatial pattern of cultivated land pressure cold-hot spots in the Pearl River-Xijiang Economic Zone is obviously heterogeneous, in which the Pearl River Economic Zone is the main hot spot gathering area and the Xijiang Economic Zone is the main cold spot gathering area. Farmers’ income, investment in fixed assets, GDP, population and other socio-economic factors are the main factors driving the changes in the cultivated land pressure in the Pearl River-Xijiang Economic Zone. Furthermore, farming production factors, such as the multiple cropping index and grain yield per unit area,will also have an important impact on the changes in the cultivated land pressure.展开更多
Understanding essential for formulating the trends in PM2.5 levels is clean air plans. This paper analyzes PM2.5 data from various published sources for the years 2000 to 2010 in the Pearl River Delta Economic Zone (...Understanding essential for formulating the trends in PM2.5 levels is clean air plans. This paper analyzes PM2.5 data from various published sources for the years 2000 to 2010 in the Pearl River Delta Economic Zone (PRDEZ). The long-term variation in PM2.5 mass concentration is analyzed. Results show that PM2.5, organic carbon (OC), elemental carbon (EC), and SO24 show a similar trend, increasing before 2005 and then decreasing slightly. The annual average PM2.5 concentra- tion ranges from 49.1 μg·m-3 in 2000 to 64.3 μg·m-3 in 2010, with a peak of 84.1 μg· m3 in 2004. None of these 11 years meets the new National Ambient Air Quality standard (NAAQS) for PM2.5 (35 μg· m-3). Overall average concentrations of OC, EC, and SO2/4 are 13.0, 6.5, and 11.8μg·m-3, respectively. NO3 and NH+ respectively have concentrations of 1.5 μg·m-3 and 2.9 μg·m-3 in 2000 and 6.4 μg·m 3 and 5.3μg·m-3 in 2010, with a statistically significant average annual trend of+ 0.2 μg·m-3 ·yr-1 and + 0.1 μg· m-3. yr-1. In certain geographic regions, OC and EC contribute most of the PM2.5, while in other regions secondary water-soluble ions are more important. In general, OC and SO2/4- are the dominant components of PM2.5, contributing 20.6% and 18.6%, respectively. These results provide, for the first time, a better understanding of the long-term PM2.5 characteristics and trends, on a species-by-species basis, in the PRDEZ. The results indicate that PM2.5 abatement needs to prioritize secondary species.展开更多
文摘Soil heavy metal pollution is one of the main environmental problems in Pearl River Delta Economic?Zone of China. Based on multi-purpose regional geochemical survey, regional eco-geochemical assessment, local eco-geochemical assessment and comprehensive appraisal, the eco-geochemical survey and assessment in Pearl River Delta Economic Zone of 41,698 km2?were completed. Samples from soils were collected in accordance with the two-layer grid method. Totally 54 elements and indicators for soils were determined. Compared to deep soils, the sampled surface soils are enriched in OrgC, N, P, Cd, S,Hg, Ag, B, Au, S and poor with As, Ni, I, Co, Cr, V, MgO, Sc, Al2O3, Fe2O3?etc. The characteristics of geochemical reference value of element in soil that inherited soil parent material and regional elements combined features reflected that the elements enriched in the soil was interrelated with acid rock, sandstone and shale. The spatial distribution characteristics of element regional geochemistry were conditional by regional environmental geological conditions,and effected by human activities. The Pearl River Delta plain is a typical geochemical landscape area with regional anomaly of multiple-elements. The north, western and eastern parts of the Pearl River Delta Economic Zone are quite different in geochemical features due to regional geological background, soil parent materials, geomorphic characteristics and human activities. Environment quality evaluation results show that the grade I and grade II soil accounted for 19.9% and 57.3% of the total area. Many samples that widely distributed in the economic developed of Pearl River Delta Plain area reached the third-grade of national soil environment standard. The soil enriched in Cd, Hg, As, and the area ratio accounting for 22.8% of the total area. It is mainly controlled by the geochemical background, the Pearl River Delta formation evolution process, especially the marine transgression process lead to Cd, Cu, Zn and Pb enrichment in Pearl River Delta plain. At the same time, under the influence of higher pressure of human activities, all kinds of exogenous input material carrying heavy metal pollutants on soil environmental quality also could not to ignore.
基金supported by the China Geological Survey Project (1212010511216)Environmental Protection Special Foundation of Guangdong Provincial (Guangdong Environment [2014]126)
文摘Dongguan City, located in the Pearl River Delta economic zone of China, is famous for its rapid developing township-enterprises in the past 30 years. A total of 759 composite soil samples, including 606 surface soil samples and 153 deep soil samples, have been collected in the city. These samples have been analyzed for 13elements(Al, As, Cu, Cd, Co, Cr, Fe, Hg, Mn, Ni, Pb, Si,and Zn) and other parameters(p H values and organic matter) to evaluate the influence of anthropic activities on the soil environmental quality and to identify the spatial distribution of heavy metals and their possible sources. The results indicate that the average concentrations of heavy metals in soil were significantly lower than the threshold of the second grade of the Soil Environment Quality Standard in China(GB15618-1995) and the soil environmental quality in this area is comparatively good. But in comparison with local soil geochemical baseline values, As,Cd, Cu, Hg, Pb, and Zn have accumulated remarkably.Specifically, the average concentrations of As, Cd, Cu, and Hg in the small part samples of the west plain and central areas are higher than the national second-grade quality standard, indicating some level of contamination. Multivariate and geostatistical methods have been applied to differentiate the influences of natural processes and human activities on the concentration of heavy metals in surface soils in the study area. Cluster and factor analyses result in the grouping of Al, As, Cr, Cu, Fe, Ni, and Si into factor F1; Co, Mn, Pb, and Zn into F2; and Cd and Hg into F3.The spatial pattern of the three factors may be well demonstrated by geostatistical analysis. It is shown that the first factor could be considered as a natural source controlled by parent material. The second factor could be referred to as ‘‘industrial and traffic pollution sources' '. The source of the third factor is mainly controlled by long-term anthropic activities, including agricultural activities, fossil fuel consumption, and atmospheric deposition.
基金The Guangdong Education Science Planning Project(2019GXJK080)The Guangdong Philosophy and Social Science Planning Project(GD19YYJ03)The Guangdong Coastal Economic Belt Development Research Institute 2020 Special Project(YJY202002).
文摘Cultivated land pressure is often used to reflect the shortage of cultivated land resources. By using the methods of the Cultivated Land Pressure Index, coefficient of variation and cold-hot spot analysis, this paper analyzes the spatial-temporal differentiation pattern and dynamic change processes of cultivated land pressure in the counties of the Pearl River-Xijiang Economic Zone from 2008 to 2017, and measures the factors which influence cultivated land pressure by using Principal Component Analysis. The results show that the cultivated land pressure in the Pearl River-Xijiang Economic Zone has been in a “high pressure” state, and the Cultivated Land Pressure Index has been rising continuously from 2008 to 2017. The coefficient of variation of the Cultivated Land Pressure Index in the Pearl River-Xijiang Economic Zone and various prefecture-level cities is fluctuating and rising, which indicates that the overall spatial differences in the cultivated land pressure in this region are expanding and polarization is obvious. In addition, the area where the municipal district of the provincial capital city is located is the core area of urban development and also the area with the greatest cultivated land pressure. The spatial pattern of cultivated land pressure cold-hot spots in the Pearl River-Xijiang Economic Zone is obviously heterogeneous, in which the Pearl River Economic Zone is the main hot spot gathering area and the Xijiang Economic Zone is the main cold spot gathering area. Farmers’ income, investment in fixed assets, GDP, population and other socio-economic factors are the main factors driving the changes in the cultivated land pressure in the Pearl River-Xijiang Economic Zone. Furthermore, farming production factors, such as the multiple cropping index and grain yield per unit area,will also have an important impact on the changes in the cultivated land pressure.
基金This work was supported by the National Natural Science Foundation of Guangdong Province as key project (S201202 0011044) and Public Sector (Meteorological) Scientific Research Project (GYHY201406031). It was also partly supported by the Jiangsu Collabora- tive Innovation Center for Climate Change and Specialized Research Fund for the Doctoral Program of Higher Education in China.
文摘Understanding essential for formulating the trends in PM2.5 levels is clean air plans. This paper analyzes PM2.5 data from various published sources for the years 2000 to 2010 in the Pearl River Delta Economic Zone (PRDEZ). The long-term variation in PM2.5 mass concentration is analyzed. Results show that PM2.5, organic carbon (OC), elemental carbon (EC), and SO24 show a similar trend, increasing before 2005 and then decreasing slightly. The annual average PM2.5 concentra- tion ranges from 49.1 μg·m-3 in 2000 to 64.3 μg·m-3 in 2010, with a peak of 84.1 μg· m3 in 2004. None of these 11 years meets the new National Ambient Air Quality standard (NAAQS) for PM2.5 (35 μg· m-3). Overall average concentrations of OC, EC, and SO2/4 are 13.0, 6.5, and 11.8μg·m-3, respectively. NO3 and NH+ respectively have concentrations of 1.5 μg·m-3 and 2.9 μg·m-3 in 2000 and 6.4 μg·m 3 and 5.3μg·m-3 in 2010, with a statistically significant average annual trend of+ 0.2 μg·m-3 ·yr-1 and + 0.1 μg· m-3. yr-1. In certain geographic regions, OC and EC contribute most of the PM2.5, while in other regions secondary water-soluble ions are more important. In general, OC and SO2/4- are the dominant components of PM2.5, contributing 20.6% and 18.6%, respectively. These results provide, for the first time, a better understanding of the long-term PM2.5 characteristics and trends, on a species-by-species basis, in the PRDEZ. The results indicate that PM2.5 abatement needs to prioritize secondary species.