Differential Evolution of High-Pressure and Ultrahigh-Pressure Metapelites from Habutengsu, Chinese Western Tianshan: Phase Equilibria Modelling and ^(40)Ar/^(39)Ar Geochronology

Metapelite is one of the predominant rock types in the high-pressure–ultrahigh-pressure（HP–UHP） metamorphic belt of western Tianshan, NW China; however, the spatial and temporal variations of this belt during metamorphism are poorly understood. In this study, we present comparative petrological studies and 40^Ar/39 ^Ar geochronology of HP and UHP pelitic schist exposed along the Habutengsu valley. The schist mainly comprises quartz, white mica, garnet, albite and bluish amphibole. In the Mn O–Na2O–Ca O–K2O–Fe O–Mg O–Al2O3–Si O2–H2O（Mn NCKFMASH） system, P–T pseudosections were constructed using THERMOCALC 333 for two representative pelitic schists. The results demonstrate that there was a break in the peak metamorphic pressures in the Habutengsu area. The northern schist has experienced UHP metamorphism, consistent with the presence of coesite in the same section, while the southern one formed at lower pressures that stabilized the quartz. This result supports the previous finding of a metamorphic gradient through the HP–UHP metamorphic belt of the Chinese western Tianshan by the authors. Additionally, phengite in the northern schist was modelled as having a Si content of 3.55–3.70（a.p.f.u.） at the peak stage, a value much higher than that of oriented matrix phengite（Si content 3.32–3.38 a.p.f.u.）. This indicates that the phengite flakes in the UHP schist were subjected to recrystallization during exhumation, which is consistent with the presence of phengite aggregates surrounding garnet porphyroblast. The 40^Ar/39^ Ar age spectra of white mica（dominantly phengite） from the two schists exhibit similar plateau ages of ca. 315 Ma, which is interpreted as the timing of a tectonometamorphic event that occurred during the exhumation of the HP–UHP metamorphic belt of the Chinese western Tianshan.

Provenance of Precambrian Fe- and Al-rich Metapelites in the Yenisey Ridge and Kuznetsk Alatau, Siberia: Geochemical Signatures

Major, trace and rare earth element contents of Fe- and Al-rich metapelites from the Korda （Yenisey Ridge） and Amar （Kuznetsk Alatau） formations were determined to examine the nature, origin and evolution of their protoliths. Results indicate that these rocks are the redeposited and metamorphosed products of Precambrian kaolinitic weathering crusts, while the geochemical distinctions between the studied metapelites are determined by different weathering conditions in the source area and tectonic settings. The protolith of the Korda Formation metapelites was produced by erosion products of the post-Archean granitoid rocks, which accumulated under humid climate conditions in shallow-water basins along the continental margin. The geochemical characteristics of the deeper primary deposits of the Amar Formation suggest that volcanogenic material of mafic composition derived from an island-arc environment had a major role in supplying the erosion zone. These results agree with lithofacies data and with the geodynamic reconstruction of the evolution of the Yenisey Ridge and Kuznetsk Alatau during the Mesoproterozoic and Neoproterozoic, respectively. It was shown that REEs had limited mobility during contact metamorphism. The coherent mobility of REEs during collisional metamorphism may be attributed both to mineral reactions responsible for modal changes and to local chemical heterogeneity inherited from the initial protolith.

阿尔金淡水泉早古生代泥质高压麻粒岩及其P-T演化轨迹

南阿尔金构造带淡水泉一带出露的含石榴石蓝晶石黑云母片麻岩是一套典型的泥质高压麻粒岩,其峰期特征矿物组合为石榴子石+蓝晶石+钾长石+金红石+石英。根据矿物内部一致性热力学数据和Thermocalc 3.23程序计算,确定其峰期变质温压条件为T>850℃和P>11kbar。结合岩相学研究和P-T视剖面图计算,可识别出该岩石经历了4个阶段的变质演化,构成了一个早期快速等温降压,后期近等压降温的顺时针型的退变质P-T演化轨迹,为与陆壳俯冲碰撞有关的高压变质事件的产物。该岩石锆石阴极发光图像显示其内部具有明显的核-边结构,核部为残留的原岩碎屑锆石,边部则表现为面状或扇状生长的变质锆石的特征。微区原位LA-ICP-Ms微量元素分析表明,核部测点的重稀土含量较高,对应Th/U接近于0.4,具有岩浆锆石的特征;边部测点的重稀土相对亏损,重稀土配分曲线平坦,对应Th/U比值均小于0.1,显示与石榴子石平衡共生的变质锆石特征。LA-ICP-MS微区定年获得其变质年龄为486±5Ma,该年龄值与阿尔金江尕勒萨依和英格利萨依两地超高压变质岩石的变质年龄相近,进一步证明沿阿尔金构造带南缘断续存在一条早古生代的高压-超高压变质岩带。另外,本次研究在获得该泥质高压麻粒岩峰期变质时代的同时,还获得该岩石原岩的形成时代上限值约为719Ma,从而限定阿尔金构造带南缘阿尔金群的形成时代可能不属古元古代,而应属新元古代。

Metamorphism and zircon U-Pb dating of high-pressure pelitic granulites from glacial moraines in the Grove Mountains, East Antarctica

The Grove Mountains are an inland continuation of the Prydz Belt in East Antarctica. Detailed metamorphic petrological and zircon U-Pb geochronological studies are performed on the high-pressure （HP） pelitic granulites from glacial moraines in the Grove Mountains. The metamorphic peak mineral assemblage of the HP pelitic granulites is characterized by garnet ＋ kyanite ＋ K-feldspar ＋ biotite ＋ plagioclase ＋ quartz, and the subsequent medium-pressure （MP） granulite facies retrogression is characterized by sillimanite replacing kyanite, the formation of the biolite ＋ sillimanite symplectite in the matrix. These mineral assemblages and their P-T estimates based on the P-T pseudosection constructed in MnNCKFMASHT system define a clockwise P-T path involving metamorphic peak of 11.6–13.6 kbar at 817–834°C followed by a near-isothermal decompression of 6.7–7.5 kbar at 806–828°C, comparable with those of associated HP mafic granulites from glacial moraines in the Grove Mountains. Zircon U-Pb dating, coupled with available metamorphic age data obtained for HP mafic granulites, reveals HP metamorphism occurred at 540–545 Ma. Combining the previous research results, the HP pelitic granulites and contemporary HP mafic granulites were widely distributed in glacial moraines from the Grove Mountains, suggesting at least part of the Grove Subglacial Highlands underwent Pan-Afrian HP granulite facies metamorphism, which provides new evidence for a collisional tectonic setting of the Pan-Afrian Prydz Belt.

The Metamorphism and Its Tectonic Implications of Indosinian High Pressure Granulites from the Badu Complex of the Cathaysia Block, Southwestern Zhejiang Province, South China

The Badu Complex is the oldest metamorphic rock in Cathaysia Block which experienced several episodes of metamorphism Especially indosinian metamorphic reworking in the southwestern Zhejiang Province, South China. The degree of indosinian metamorphism reaches granulite facies. However, there is still insufficient understanding of the characteristics of the Indosinian granulite metamorphism in the Cathaysia and many interpretations of its tectonic significance. Therefore, we present detailed petrology, mineral chemistry and LA-ICP-MS zircon U-Pb age in this paper from pelitic granulites of the Badu Complex, which is composed of "sillimanite + garnet + cordierite + spinel + biotite + k-feldspar" assemblage and garnet pyroxenite with garnet amphibolite which is consists of "garnet + clinopyroxene + orthopyroxene + amphibole + plagioclase". By comprehensive study we get following new findings: Pelitic granulites record four stages of metamorphic mineral assemblages, including prograde(M1), pressure peak(M2), Peak(M3) and post-peak decompressional and then cooling(M4) stages. The prograde M1 assemblage consists of garnet1(core) + staurolite + kyanite + biotite + quartz ± rutile ± chlorite;The pressure peak M2 assemblage consists of garnet1(mantle) + sudoite + rutile + kyanite + corundum + biotite + quartz;The peak M3 have garnet2(rim-mantle) + biotite + sillimanite + quartz ± K-feldspar ± plagioclase ± ilmenite assemblag;the M4 stage is consist of garnet + cordierite + biotite + sillimanite + quartz + ilmenite ± spine ± K-feldspar. The garnet pyroxenite and garnet amphibolites have experienced three stages of metamorphic evolution. Peak high-pressure granulite facies stage M2 consists of garnet + sahlite ± ilmenite ± quartz;Post-peak near isothermal decompression medium granulite facies stage M3 is characterized by typical decompression reaction textures and assemblage of orthopyroxene + plagioclase(An=90–92);amphibolites facies retrograde metamorphic stage M4 is characterized by amphibole + plagioclase(An=33–35) + ilmenite ± sahlite ± quartz mineral assemblage. By means of phase equilibrium simulation and traditional thermobarometer, P-T conditions of 785–820 ℃ and 8.9–9.9 kbar for M3 stage, 780–860 ℃ and 5.7–6.2 kbar for decompressional M4 stage, 705–720 ℃ and 4.5–4.7 kbar for cooling M4 stage in pelitic granulites were obtained. And also 11.6–12.5 kbar and 780–840 ℃ for M2 stage, 7.4–8.2 kbar and 800–880 ℃ for M3 stage, 6.6–7.5 kbar and 500–560 ℃ for M4 stage were obtained in garnet pyroxenite and garnet amphibolite. A clockwise P-T path is confirmed in the two type rocks of the Badu Complex which reflected a near-isothermal decompressional metamorphic process. The peak metamorphism can reach highpressure granulite facies. In addition, the mineral assemblage of garnet + rutile + kyanite + corundum in the peak metamorphic stage of pelitic granulite indicates that it may underwent ultra-high-pressure metamorphism, and the acidic plagioclase exsolution of clinopyroxene in garnet pyroxenite also suggests that it may be retrograded eclogites, which indicates that the deeper Cathaysian block may have eclogite metamorphism. Analyses of LA-ICP-MS zircon U-Pb dating indicate that the metamorphic age of pelitic granulite is 233.5 Ma–subduction/collision followed by rapid exhumation and cooling events. The events may relate with the amalgamation of the Indochina BlockSouth China Block North China Block in the paleo-Tethyan domain.

Equilibrium vs.disequilibrium melting relations in the Higher Himalayan Crystalline(HHC) pelitic migmatites,Sikkim Himalaya

Higher Himalayan Crystalline（HHC） complex of the Sikkim Himalaya predominantly consists of high-grade pelitic migmatites.In this study,reaction textures,mineral/bulk rare earth elements （REE）,trace element partition coefficients and trace element zoning profiles in garnet are used to demonstrate a complex petrogenetic process during crustal anatexis.With the help of equilibrium REE and trace element partitioning model,it is shown that strong enrichment of Effective Bulk Composition（EBC） is responsible for the zoning in garnet in these rocks.The data strongly support disequilibrium element partitioning and suggest that the anatectic melts associated with mafic selvedges are likely produced by disequilibrium melting because of fast melt segregation process.

Ultrahigh Temperature Metamorphic Record of Pelitic Granulites in the Huangtuyao Area of the Huai’an Complex,North China Craton

Pelitic granulite from the Huangtuyao area,occurrs in the Huai'an Complex,is located in the Trans-North China Orogen of the North China Craton.On the basis of petrolography,mineral component,and phase equilibrium modeling studies,the P-T conditions and mineral assemblages of pelitic granulites can be divided into four metamorphic stages:the prograde metamorphic stage M1 defined by the stable mineral assemblage of Grt1(garnet core)+Pl+Bt+Kfs+Qz+Rt,the peak pressure Pmax stage M2 indicated by Grt2(garnet mantle)+Kfs±(Ky)+Rt+Qz+Liq(melt),peak temperature Tmax stage M3 characterized by Grt3(garnet rim)+Sill+Pl+Kfs+Qz+Ilm+Liq,and retrograde stage M4 represented by Grt(in matrix)+Kfs+Sill+Bt+Pl+Qz+Ilm.By using the THERMOCALC V340,the P-T conditions are estimated at^13.8–14.1 kbar and^840–850℃at stage M2,and 7–7.2 kbar and 909–915℃for the Tmax stage M3,indicating an ultra-high temperature(UHT)metamorphic overprinting during decompression and heating process after high pressure granulite facies metamorphism.The mineral assemblages and their P-T conditions presented a clockwise P-T trajectory for the Huangtuyao pelitic granulites.The major metamorphic events at^1.95 and^1.88 Ga obtained by the zircon U-Pb dating suggest that pelitic granulites from the Huangtuyao area has undergone HP granulite metamorphism which probably occurred in the prograde metamorphism and related to the collision between the Ordos and the Yinshan blocks,and afterwards UHT metamorphism is related to crustal extension after continental-continental collision.

Multi-Stage Metamorphism of the UHP Pelitic Gneiss from the Southern Altyn Tagh HP/UHP Belt,Western China:Petrological and Geochronological Evidence

The kyanite-bearing garnet pelitic gneiss from the Jianggalesavi area in southern Altyn Tagh high pressure/ultra-high pressure belt was proved to have been experienced UHP metamorphism (>12 GPa) by the discovery of kyanite and spinel exsolution microstructure in quartz (precursor stishovite). In this study, three stages of retrograded metamorphism (M2-M4) after the UHP metamorphism (Ml) were identified for the UHP pelitic gneiss. The HP granulite-facies stage (M2) was characterized by the mineral assemblage of garnet+kyanite+K?feldspar+nitile+qiiartz±ilinenite, recording the P-T condition of >1.12 GPa and ?850-930℃. The granulite-facies stage (M3) was represented by the mineral assemblage of garnet rim+K-feldspar+sillimanite (SillJ+biotite (Bti)+plagioclase (Pli)+ilmenite+quartz, and confined under P-T conditions of 0.5-0.8 GPa and^770-795℃. The late cooling stage M4 was accompanied by the appearance of fine-grained Pl2, Sill2 and Bt2 in the matrix, and the P-T conditions were 0.4-0.6 GPa and <675℃. A clockvvised P-T path was obtained for the pelitic gneiss in the P-T pseudosection, which showed a deep subduction/collision processes with subsequent exhumation and cooling. Com? bined with the corresponding multistage metamorphic assemblages, the age dating results implied that the zircons from the gneiss have integrated the recording peak metamorphic (Ml,484±3 Ma) and retrograded metamorphic ages (M2 to M3, 450±2 Ma). There was about 32 Ma interval during the first exhumation from the upper mantle depth (>350 km) to the lower crust depth (-40-20 km), resulting in an average exhumation rate of 9.11-9.70 mm/yr. In the southern Altyn Tagh region, the HP and UHP rocks from different areas had identical peak metamorphic ages. Therefore, contemporary UHP and HP rocks with different metamorphic evolutions were recognized coexisting in the same orogenic belt, which can be interpreted by the model of subduction channel. The continental crustal were subducted to different depths along the direction of the subduction channels at ~500 Ma, suffered different grade metamorphism, and then returned to the surface along the subduction channel.

Cenozoic ultrahigh-temperature metamorphism in pelitic granulites from the Mogok metamorphic belt, Myanmar

Ultrahigh-temperature(UHT)metamorphism is critical for understanding the most extreme thermal evolution of continental crust.However,UHT metamorphism predominantly occurred in the Precambrian and is rarely observed in the modern Earth.Here,we report the discovery of~25 Ma UHT granulites from the Mogok metamorphic belt(MMB)in Myanmar via a combined study of petrology and geochronology.The studied pelitic granulites well preserve a peak mineral assemblage of garnet+sillimanite+plagioclase(antiperthite)+K-feldspar+quartz+Ti-rich biotite+rutile+ilmenite.Pressure(P)-temperature(T)pseudosections and conventional geothermobarometry data only constrain the P-T conditions of the peak stage to<12 kbar and 780–890°C.However,high Zr contents in the matrix rutile(3005–4308 ppm)and high Ti contents(up to 9.2 wt% TiO_(2))in the biotite demonstrate that the Mogok granulites may have experienced UHT metamorphism.The Zr-in-rutile thermometer and X_(Grs) isopleth in the pseudosections yield peak P-T conditions of~12 kbar and>900°C.In situ SIMS and LAICP-MS U-Pb dating and trace element analyses show that both metamorphic zircon cores and rims have flat heavy rare earth element(HREE)patterns with negative Eu anomalies.The metamorphic zircon rims show the lowest HREE contents and yield ^(206)Pb/^(238)U ages of 24.9±0.5 and 25.4±0.6 Ma,respectively,representing the timing of UHT metamorphism.Our results indicate that the central MMB underwent~25 Ma UHT metamorphism,which is possibly induced by continental rifting along the thinned orogenic lithosphere.Our data,as well as reported Cenozoic UHT events,further suggest that UHT metamorphism can be produced in the modern plate tectonic regime by lithospheric extension.

Sapphirine-Bearing Pelitic Granulite from Ailaoshan Orogen,West Yunnan,China: Metamorphic Conditions and Tectonic Setting

To reveal the petrological characteristics, metamorphic evolution histon and tectonic setting of the pelitic granulites from Ailaoshan Orogen, Uest Yunnan, China, a comprehensive study in mineral chemistry, petrogeochemistry and geochronology studies is presented in this paper. Two metamorphic stages of the granulites can be established:(1) the peak metamorphism recorded by the mineral assemblage of garnet, kyanite, K-feidspar and rutile, and the initial retrograde metamorphism shown by the mineral assemblage of garnet, sillimanite, sapphirine, spinel, K-feldspar, plagioclase and biotite;(2) the superim-posed metamorphism recorded by the mineral assemblage of biotite, muscovite, plagioclase, quartz and ilmenite. Zircon LA-ICP-MS U-Pb dating indicates that the protolith of the granulite was deposited after 337 Ma. The initial retrograde metamorphism occurred at P-T conditions of 8.6-12 kbar at 850-920℃ estimated by mineral assemblages, the low pressure limit of kyanite stability and GBPQ geothermobarometer in Indosinian (about 235 Ma), and the late superimposed metamorphism occurred at the P-T condition of 3.5-3.9 kbar at 572-576℃ estimated by GBPQ geothermobarometer since 33Ma. The first stage was related to the amalgamation of the South China and Indochina blocks during the Triassic, and the second stage was possibly related with the large scale sinistral slip-shearing since the Oligocene. It is inferred that the upper continental crust was suhducted/underthrusted to the lower continental crust (deeper than 30 km) and underwent granulite-facies metamorphism and then quickly exhumed to the middle-upper crust (10-12 km) and initial retrograde metamorphism occurred due to the collision of the Indochina and South China blocks during Indosinian, which was followed by superimposition of the second stage of metamorphism since the Oligocene.

Monazite recorded Paleoproterozoic granulite-facies metamorphism and Triassic fluid modification of the Weihai pelitic granulite,Sulu orogen

Monazite is an important accessory mineral in the pelitic granulites(Weihai area,Sulu orogen),and is also a powerful monitor for understanding the metamorphic evolution of the granulites.The pelitic granulites incongruously occur as lenses in granitic gneisses.The lithologies of the lenses gradually change from core to margin:The undeformed coarse-grained granulite,the foliated fine-grained granulite,the garnet-biotite-gneiss,and the migmatized granulite.The lens cores mostly preserve a peak granulite-facies metamorphic mineral assemblage of garnet+plagioclase(antiperthite)+quartz+sillimanite+biotite with accessory minerals of rutile,zircon,and monazite.The lens margins display a fluid-induced retrogression.In order to decipher the metamorphic processes of the pelitic granulites,a combined study of BSE imaging,U-Pb dating,and trace element composition for the monazites from the metapelitic lens were conducted.Monazites from the undeformed coarse-grained granulite only record a Paleoproterozoic age(1832±7 Ma,n=40).Monazites from the other lithologies yield the inherited Paleoproterozoic age and Triassic overgrowth age.For example,monazites from the migmatite yield intercept ages of 1818±10 and 211±22 Ma(n=56)with Triassic concordant age of 223.8±2.9 Ma.The Paleoproterozoic monazites are characterized by remarkable depletion in HREE and Y with obviously negative Eu anomalies,indicating their formation equilibrated with garnet and feldspar under granulite-facies conditions.During Triassic fluid modification,the monazite bright rims assimilated Th and Si but released U,HREE,Y,and P.This process resulted in that the Triassic overgrowth monazites have higher HREE and Y contents,and lower Th and U contents with relatively low Th/U ratios.Thus,the monazites in the pelitic granulites recorded a Paleoproterozoic metamorphic event and Triassic fluid modification.The Weihai pelitic granulites might have a tectonic affinity with the North China Craton.Therefore,the Paleoproterozoic pelitic granulites were mechanically drawn into the orogen during the Triassic continental collision,and subsequently were remoulded by the fluids during its exhumation.

Effect of Temperature upon Fe-Mg Composition of Garnet in Pelitic System

Garnet is an essential phase in a wide range of metamorphic grades. Ratios of Fe and Mg concentrations in garnet have been widely used as a geothermometer for the crystallization, cooling rate and tectonic uplift rate because garnets in natural rocks always show a variety of Fe-Mg compositional partition. Normally, Fe-Mg concentrations of natural garnets vary widely and the Fe-Mg exchange reactions usually occur in a complex chemical system. Effect of pressure and temperature on Fe-Mg compositions of garnet in natural pelitic system was studied experimentally at temperatures of 700 to 780 ℃ and pressures from 21 to 29.4 kbar. The concentrations of FeO and MgO of garnet in the run products showed a linear relation with experimental temperatures. The result provided experimental evidence of Fe-Mg partition trend with temperature in a complex natural rock and therefore improved our understanding in the determinations of metamorphic temperature calculated by garnet geothermometer. Although the accurate geological application of our results requires the knowledge of the effects of other components upon [D(Mg)] and [D(Fe)] which is largely unknown currently, the data provided in this study are useful to build the relation between FeO-MgO contents and temperature, which is useful in the metamorphic temperatures determine of rocks with pelitic composition.