The recent discovery of deep and ultra-deep gas reservoirs in the Permian Changxing Formation reefs, northeastern Sichuan Basin is a significant development in marine carbonate oil ＆ gas exploration in China. Reef do...The recent discovery of deep and ultra-deep gas reservoirs in the Permian Changxing Formation reefs, northeastern Sichuan Basin is a significant development in marine carbonate oil ＆ gas exploration in China. Reef dolomites and their origins have been major research topics for sedimentologists and oil ＆ gas geologists. The petrography, trace element and isotope geochemistry of the reef dolomites indicated that the dolomites are characterized by low Sr and Mn contents, relatively low Fe contents, very similar δ13C and 6180 values and very different 87Sr/86Sr ratios. Although the calculated results of the fluid mixing suggested that a mixture with 85%-95% meteoric water and 50/o- 15% seawater seemed to be the dolomitizing fluids of the reef dolomites, the low Mn contents, relatively low Fe contents, high δ13c values and high homogenization temperatures of the dolomites did not support that there were large proportions of meteoric water in the dolomitization process, and the 87Sr/86Sr ratios which were close to coeval seawater also did not support the possibility of the mixture of deep-burial circulated fluids from clastic rocks. High temperature deep-burial circulated seawater with low Mn and Fe contents, high Sr content and high δ13C values from the dissolution of widely distributed Triassic evaporites during the burial diagenetic processes （including dehydration of water-bearing evaporites） could have been the dolomitizing fluids of the reef dolomites.展开更多
基金supported by the National Natural Science Foundation (41172099,40839908)Research Fund for the Doctoral Program of Higher Education of China(20050616005)
文摘The recent discovery of deep and ultra-deep gas reservoirs in the Permian Changxing Formation reefs, northeastern Sichuan Basin is a significant development in marine carbonate oil ＆ gas exploration in China. Reef dolomites and their origins have been major research topics for sedimentologists and oil ＆ gas geologists. The petrography, trace element and isotope geochemistry of the reef dolomites indicated that the dolomites are characterized by low Sr and Mn contents, relatively low Fe contents, very similar δ13C and 6180 values and very different 87Sr/86Sr ratios. Although the calculated results of the fluid mixing suggested that a mixture with 85%-95% meteoric water and 50/o- 15% seawater seemed to be the dolomitizing fluids of the reef dolomites, the low Mn contents, relatively low Fe contents, high δ13c values and high homogenization temperatures of the dolomites did not support that there were large proportions of meteoric water in the dolomitization process, and the 87Sr/86Sr ratios which were close to coeval seawater also did not support the possibility of the mixture of deep-burial circulated fluids from clastic rocks. High temperature deep-burial circulated seawater with low Mn and Fe contents, high Sr content and high δ13C values from the dissolution of widely distributed Triassic evaporites during the burial diagenetic processes （including dehydration of water-bearing evaporites） could have been the dolomitizing fluids of the reef dolomites.
