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添加剂对ABS/APP/PETA体系协同阻燃作用的研究 被引量:6
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作者 易江松 鲁成祥 +1 位作者 任显诚 蔡绪福 《高校化学工程学报》 EI CAS CSCD 北大核心 2011年第2期319-324,共6页
为了提高膨胀型阻燃体系聚磷酸胺(APP)/聚对苯二甲酰乙二胺(PETA)对苯乙烯-丁二烯-丙烯腈共聚物(ABS)的阻燃效果,并研究一些常用添加剂的协效阻燃机理,采用极限氧指数法、垂直燃烧法、热失重探讨了添加剂4A分子筛、次磷酸铝、有机蒙脱土... 为了提高膨胀型阻燃体系聚磷酸胺(APP)/聚对苯二甲酰乙二胺(PETA)对苯乙烯-丁二烯-丙烯腈共聚物(ABS)的阻燃效果,并研究一些常用添加剂的协效阻燃机理,采用极限氧指数法、垂直燃烧法、热失重探讨了添加剂4A分子筛、次磷酸铝、有机蒙脱土(OMMT)和双噁唑啉(BOZ)对ABS/APP/PETA膨胀型阻燃复合物的协效阻燃效应。结果表明,这些添加剂显著地改善了ABS/APP/PETA体系的阻燃性能。当四种添加剂分别以2%(wt)的用量加入到ABS/APP/PETA(70/25/5)体系中时,阻燃复合物的极限氧指数由未加添加剂的29分别提高到32、33、32及30,UL-94测定都能达到V-0级。热失重分析表明添加剂的加入提高了阻燃体系的热稳定性和高温残炭率。进而分析了协效阻燃机理。 展开更多
关键词 添加剂 ABS/APP/peta 膨胀型阻燃 协效阻燃机理
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PETA熔融接枝PP/LDPE共混物的研究
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作者 谭小华 金阳 +2 位作者 王庭慰 韩颖 邵赛兵 《塑料工业》 CAS CSCD 北大核心 2003年第1期8-9,19,共3页
研究了季戊四醇三丙烯酸酯熔融接枝PP/LDPE共混物体系中 ,各因素对产物熔体质量流动速率和熔体强度的影响 ,并对产物拉伸粘度和化学接枝情况等进行了测试及表征。实验结果表明 ,引发剂用量较低 ,单体用量较高时 ,产物的熔体质量流动速... 研究了季戊四醇三丙烯酸酯熔融接枝PP/LDPE共混物体系中 ,各因素对产物熔体质量流动速率和熔体强度的影响 ,并对产物拉伸粘度和化学接枝情况等进行了测试及表征。实验结果表明 ,引发剂用量较低 ,单体用量较高时 ,产物的熔体质量流动速率小、熔体强度较高、拉伸粘度较大 ,且在拉伸过程中 ,产生了应变硬化效应 ;随着单体用量的增加 。 展开更多
关键词 peta 熔融接枝 PP/LDPE共混物 研究 季戊四醇三丙烯酸酯 2 5-二甲基-2 5-二(叔丁基过氧)己烷 聚丙烯 熔体强度
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人PETA-3/CD151基因RNAi慢病毒载体的构建及沉默效应鉴定
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作者 王绍清 王俊平 +2 位作者 徐凤琳 艾中伟 刘婷 《中国老年学杂志》 CAS 北大核心 2017年第2期271-273,共3页
目的构建PETA-3/CD151shRNA慢病毒表达载体,并在人乳腺癌细胞株MCF-7细胞鉴定其转染及基因沉默效果。方法应用基因工程技术,构建4条针对PETA-3基因的RNAi靶序列,分别与慢病毒载体Pg LV3连接,构建重组慢病毒表达载体PETA-3-shRNA-1~4;将... 目的构建PETA-3/CD151shRNA慢病毒表达载体,并在人乳腺癌细胞株MCF-7细胞鉴定其转染及基因沉默效果。方法应用基因工程技术,构建4条针对PETA-3基因的RNAi靶序列,分别与慢病毒载体Pg LV3连接,构建重组慢病毒表达载体PETA-3-shRNA-1~4;将连接产物转化到Top10感受态细胞,经筛选阳性克隆、测序鉴定。应用脂质体法转染293FT细胞,进行病毒包装及滴度测定。将包装产生的4种重组慢病毒分别感染MCF-7细胞,实时定量PCR和Western印迹检测MCF-7细胞PETA-3 mRNA和蛋白的表达。根据筛选的结果,选取最有效的载体进行病毒的大量包装。结果 4个慢病毒载体PCR和测序结果与预期结果一致,感染MCF-7细胞96 h后,PETA-3-shRNA-2 mRNA和蛋白的表达量与未感染慢病毒的细胞组及空载体感染组相比均明显下降,其中mRNA表达下降85%,蛋白表达下降84%(均P<0.05)。shRNA-2病毒载体大量包装后其滴度为1×109TU/ml。结论成功构建针对PETA-3基因的慢病毒载体PETA-3-RNAi-LV3,体外感染MCF-7细胞后可有效抑制PETA-3基因和蛋白的表达。 展开更多
关键词 peta.3/CD151 RNA干扰 慢病毒 乳腺癌
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Sources of IR Radiation in the Earth’s Atmosphere in Connection with the PeTa Effect
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作者 Vitali A. Tatartchenko 《Optics and Photonics Journal》 2021年第6期152-196,共45页
The PeTa (Perelman-Tatartchenko) effect is the radiation of the energy of a first-order phase transition during the transition from a less condensed phase to a more condensed one. The effect was independently discover... The PeTa (Perelman-Tatartchenko) effect is the radiation of the energy of a first-order phase transition during the transition from a less condensed phase to a more condensed one. The effect was independently discovered by M. Perelman and the author of this paper. Six papers on the PeTa effect have been published in this journal over the past nine years. They are devoted to the development of PeTa models to explain the following phenomena: IR radiation from cold surfaces, cavitation luminescence/sonoluminescence (CL/SL), laser-induced bubble luminescence (LIBL), and vapor bubble luminescence (VBL) in underwater geysers. This paper describes the sources of PeTa radiation in the Earth’s atmosphere. These sources of infrared radiation have been investigated by numerous research groups, but their interpretation either does not exist at all, or it is erroneous. The following phenomena are specifically considered: PeTa radiation during the formation of clouds and fog;a pulse laser based on the PeTa radiation;condensation explosions as sources of PaTa radiation;measurement of the concentration of water vapor in the atmosphere using PeTa radiation;atmospheric scintillation of infrared radiation in the atmosphere due to the PeTa effect;PeTa radiation as a source of comfort for the igloo;the influence of PeTa radiation on living organisms;PeTa radiation due to characteristics of tropical storms;PeTa radiation as a possible precursor to earthquakes. The problem of global warming, which worries everyone, as it turns out, is also associated with the PeTa effect. 展开更多
关键词 peta (Perelman-Tatartchenko) Effect Sources of peta Radiation in the Earth’s Atmosphere Pulse IR Laser Condensation Explosions Atmospheric IR Scintillations Tropical Storms EARTHQUAKES Global Warming
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Sonoluminescence as the PeTa Radiation 被引量:1
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作者 Vitali A. Tatartchenko 《Optics and Photonics Journal》 2017年第2期27-55,共29页
In this paper, a model of cavitational luminescence (CL) and sonoluminescence (SL) is developed. The basis of the model is the PeTa (Perel’man-Tatartchenko) effect—a characteristic radiation under first-order phase ... In this paper, a model of cavitational luminescence (CL) and sonoluminescence (SL) is developed. The basis of the model is the PeTa (Perel’man-Tatartchenko) effect—a characteristic radiation under first-order phase transitions. The main role is given to the liquid, which is where the cavitation occurs. The evaporation of the liquid and subsequent vapor condensation inside the bubble are responsible for the CL and SL. Apparently, the dissolved gases and other impurities in the liquid are responsible for peaks that appear at the background of the main spectrum. They most likely are excited by a shock wave occurred during cavitation. The model explains the main experimental data. Thus, no mystery, no plasma, no Hollywood. 展开更多
关键词 Cavitational LUMINESCENCE (CL) SONOLUMINESCENCE (SL) peta (Perel’Man-Tatartchenko) Effect FIRST-ORDER Phase TRANSITIONS EVAPORATION CONDENSATION
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Bubble Glow at Hydrothermal Vents as the <i>PeTa</i>Radiation 被引量:1
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作者 Vitali A. Tatartchenko 《Optics and Photonics Journal》 2019年第11期189-217,共29页
The paper presents a physical model of a natural phenomenon, the glow of bubbles at hydrothermal vents formed during underwater volcanic activity. The basis of the model is characteristic non-equilibrium radiation und... The paper presents a physical model of a natural phenomenon, the glow of bubbles at hydrothermal vents formed during underwater volcanic activity. The basis of the model is characteristic non-equilibrium radiation under first order phase transitions that since 2010 has been referred to as the PeTa (Perelman-Tatartchenko) effect. This is the fourth paper in a series developing the model for similar physical phenomena: cavitational luminescence (CL), multi-bubble sonoluminescence (MBSL), single-bubble sonoluminescence (SBSL) and laser-induced bubble luminescence (LIBL). The previous three papers were published during 2017-2018 in this Journal. In the third one we have shown that above mentioned physical effects can be generalized as a phenomenon that we have titled “Vapour bubble luminescence” (VBL). VBL is very clearly represented in a non-equilibrium phase diagram. The essence of VBL is as follows: when there is a local decrease in pressure and/or an increase of temperature in a tiny volume of a liquid occurs, one or several bubbles filled with vapour will appear. Subsequently a very rapid pressure increase and/or temperature decrease in the same volume of liquid leads to supersaturation of the vapour inside the bubble. Upon reaching critical vapor density, instantaneous vapour condensation and emission of the phase transition energy that is accompanied by a flash (this is the PeTa effect) results in a sharp pressure decrease and the bubble collapses due to the pressure drop. This process is accompanied by a shock wave in the liquid. A similar effect occurs if bubbles filled with hot steam, for example from a cappuccino machine, are injected into a relatively large volume of cold water. The VBL model explains all experimental data concerning CL/MBSL/SBSL/LIBL and the relatively new natural phenomenon, the glow of bubbles at hydrothermal vents. Several model experiments demonstrate the PeTa effect under similar conditions. Additionally, we define the PeTa effect in all its manifestations on a non-equilibrium phase diagram. This clarifies which niches can contain VBL processes. We also demonstrate the window of transparency (WT) for the PeTa radiation during crystallization of a supercooled tellurium melt and propose the design of a cavity-free pulsed laser on the basis of similar crystallization processes. 展开更多
关键词 BUBBLE GLOW Hydrothermal Vents Perel’man-Tatartchenko (peta) Effect Cavitational LUMINESCENCE (CL) SONOLUMINESCENCE (SL) Vapour BUBBLE LUMINESCENCE (VBL)
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Sonoluminescence as the PeTa Radiation, Part Two 被引量:1
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作者 Vitali A. Tatartchenko 《Optics and Photonics Journal》 2017年第11期197-220,共24页
This paper is a continuation of one published in this journal nine months ago. The two papers present a model of cavitational luminescence (CL), multi-bubble sonoluminescence (MBSL), one-bubble sonoluminescence (OBSL)... This paper is a continuation of one published in this journal nine months ago. The two papers present a model of cavitational luminescence (CL), multi-bubble sonoluminescence (MBSL), one-bubble sonoluminescence (OBSL), and laser-induced bubble luminescence (LIBL). The basis of this model is the PeTa (Perel’man-Tatartchenko) effect, a nonequilibrium characteristic radiation under first-order phase transitions, especially vapour condensation. In this model, the main role is given to the liquid, where the evaporation, condensation, flash, and subsequent collapse of bubbles occur. The instantaneous vapour condensation inside the bubble is a reason for the CL/MBSL/OBSL/LIBL. Apparently, the dissolved gases and other impurities in the liquid are responsible for peaks that appear at the background of the main spectrum. They are most likely excited by a shock wave occurred during the collapse. This paper, in contrast to the previous one, presents a slightly expanded model that explains additional experimental data concerning especially the LIBL spectrum. As a result, today we are not aware of any experimental data that would contradict the PeTa model, and we continue to assert that there is no mystery to the CL/MBSL/OBSL/LIBL phenomena, as well as no reason to hope that they can be used for high-temperature chemical reactions, and even more so for a thermonuclear ones. 展开更多
关键词 Cavitational LUMINESCENCE (CL) SONOLUMINESCENCE (SL) Multi-Bubble SONOLUMINESCENCE (MBSL) One-Bubble SONOLUMINESCENCE (OBSL) LASER-INDUCED Bubble LUMINESCENCE (LIBL) peta (Perel’man-Tatartchenko) Effect FIRST-ORDER Phase TRANSITIONS Evapora-tion Condensation
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Sonoluminescence as the PeTa Radiation, Part Three 被引量:1
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作者 Vitali A. Tatartchenko 《Optics and Photonics Journal》 2018年第6期187-200,共14页
This paper is the third in a series published in this journal during 2017-2018. These three papers present various stages in the development of the PeTa model for phenomena of the same physical nature: cavitational lu... This paper is the third in a series published in this journal during 2017-2018. These three papers present various stages in the development of the PeTa model for phenomena of the same physical nature: cavitational luminescence (CL), multi-bubble sonoluminescence (MBSL), single-bubble sonoluminescence (SBSL), and laser-induced bubble luminescence (LIBL). The basis of this model is the PeTa (Perel’man-Tatartchenko) effect—a nonequilibrium characteristic radiation under first-order phase transitions, for instance, vapour condensation. The third iteration of this model “Vapour bubble luminescence” (VBL) is presented in this paper. The essence of this model is as follows: with a local decrease of pressure or an increase of temperature in a tiny volume of the liquid, one or several bubbles filled with vapour will appear. Subsequently, a very rapid increase in pressure or a decrease in temperature of the bubble leads to super-saturation of the vapour inside the bubble, followed by its instantaneous condensation with the emission of condensation energy (this is the PeTa effect). A sharp decrease in pressure causes the collapse of the bubble accompanied by a shock wave in the liquid. VBL model is conveniently represented on the solid-liquid-vapour phase diagram. A better understanding of the physical nature of the phenomena under consideration could help to find their useful applications. To develop this idea further, we propose a design of a cavity-free pulsed laser on the basis of CL/MBSL/SBSL. An analysis of LIBL in cryogenic liquids is also given in this paper. 展开更多
关键词 Cavitational LUMINESCENCE (CL) SONOLUMINESCENCE (SL) Multi-Bubble SONOLUMINESCENCE (MBSL) Single-Bubble SONOLUMINESCENCE (SBSL) Laser-Induced BUBBLE LUMINESCENCE (LIBL) LIBL in Cryogenic Liquids VAPOUR BUBBLE LUMINESCENCE (VBL) peta (Perel’man-Tatartchenko) Effect FIRST-ORDER Phase Transitions Evaporation Condensation Crystallization Cavity-Free Pulsed Laser
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赛灵思收购嵌入式Linux方案提供商PetaLogix
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《工业设计》 2012年第8期18-18,共1页
赛灵思公司(Xilinx,Inc)今天宣布收购嵌入式Linux解决方案提供商PetaLogix。随着Linux解决方案成为越来越多依赖赛灵思AllProgrammable技术的嵌入式应用的必备之选,收购PetaLogix及其PetaLinux技术,加强了赛灵思致力于为客户提供... 赛灵思公司(Xilinx,Inc)今天宣布收购嵌入式Linux解决方案提供商PetaLogix。随着Linux解决方案成为越来越多依赖赛灵思AllProgrammable技术的嵌入式应用的必备之选,收购PetaLogix及其PetaLinux技术,加强了赛灵思致力于为客户提供最好的Linux解决方案的能力和承诺。 展开更多
关键词 嵌入式LINUX 提供商 收购 LINUX技术 赛灵思公司 嵌入式应用 peta 客户
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日本:Peta计算机用超高速加速器
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《创新科技》 2006年第12期51-51,共1页
日本东京大学和日立国立天文台开发出了单精度时运算速度达512GFLOPS、双精度时达384GFLOPS的加速器“GRAPEDR”.其运算性能达到了由索尼集团、东芝和IBM共同开发的微处理器“Cell”的2倍以上,与通用微处理器配合使用,能够起到提高... 日本东京大学和日立国立天文台开发出了单精度时运算速度达512GFLOPS、双精度时达384GFLOPS的加速器“GRAPEDR”.其运算性能达到了由索尼集团、东芝和IBM共同开发的微处理器“Cell”的2倍以上,与通用微处理器配合使用,能够起到提高系统运算速度的作用,其电力效率高,每个加速器最大功耗为60W。 展开更多
关键词 日本东京大学 加速器 peta 超高速 通用微处理器 机用 计算 运算速度
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4A分子筛对EVA/APP/PETA复合材料阻燃性能的影响 被引量:1
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作者 徐淳 蔡绪福 《塑料工业》 CAS CSCD 北大核心 2014年第9期92-95,共4页
以聚磷酸铵(APP)和聚对苯二甲酰乙二胺(PETA)复配制备了无卤阻燃乙烯-醋酸乙烯共聚物(EVA)/膨胀型阻燃体系(IFR)复合材料,通过极限氧指数仪、热失重分析仪(TG)和扫描电镜(SEM)分析了4A分子筛对复合材料的阻燃性能、热稳定性能和复合材... 以聚磷酸铵(APP)和聚对苯二甲酰乙二胺(PETA)复配制备了无卤阻燃乙烯-醋酸乙烯共聚物(EVA)/膨胀型阻燃体系(IFR)复合材料,通过极限氧指数仪、热失重分析仪(TG)和扫描电镜(SEM)分析了4A分子筛对复合材料的阻燃性能、热稳定性能和复合材料残炭表面形貌的影响。结果表明,当4A分子筛添加量为2%时,复合材料的极限氧指数达39%,比未添加4A分子筛的提高了4%,垂直燃烧达到V-0级。SEM表明,4A分子筛的加入提高了样品残炭表面致密度。 展开更多
关键词 乙烯-醋酸乙烯共聚物 4A分子筛 阻燃 聚对苯二甲酰乙二胺 聚磷酸铵
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Programming for scientific computing on peta-scale heterogeneous parallel systems 被引量:1
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作者 杨灿群 吴强 +2 位作者 唐滔 王锋 薛京灵 《Journal of Central South University》 SCIE EI CAS 2013年第5期1189-1203,共15页
Peta-scale high-perfomlance computing systems are increasingly built with heterogeneous CPU and GPU nodes to achieve higher power efficiency and computation throughput. While providing unprecedented capabilities to co... Peta-scale high-perfomlance computing systems are increasingly built with heterogeneous CPU and GPU nodes to achieve higher power efficiency and computation throughput. While providing unprecedented capabilities to conduct computational experiments of historic significance, these systems are presently difficult to program. The users, who are domain experts rather than computer experts, prefer to use programming models closer to their domains (e.g., physics and biology) rather than MPI and OpenME This has led the development of domain-specific programming that provides domain-specific programming interfaces but abstracts away some performance-critical architecture details. Based on experience in designing large-scale computing systems, a hybrid programming framework for scientific computing on heterogeneous architectures is proposed in this work. Its design philosophy is to provide a collaborative mechanism for domain experts and computer experts so that both domain-specific knowledge and performance-critical architecture details can be adequately exploited. Two real-world scientific applications have been evaluated on TH-IA, a peta-scale CPU-GPU heterogeneous system that is currently the 5th fastest supercomputer in the world. The experimental results show that the proposed framework is well suited for developing large-scale scientific computing applications on peta-scale heterogeneous CPU/GPU systems. 展开更多
关键词 heterogeneous parallel system programming framework scientific computing GPU computing molecular dynamic
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PETA与生物玻璃复合及其性能研究 被引量:2
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作者 汤爱明 吴琳莉 +1 位作者 陈纯 陈继兰 《化学与粘合》 CAS 2003年第2期61-62,85,共3页
这种材料是由具有PETA(四丙烯酸香戊四醇酯)液相树脂和生物玻璃复合而成。该材料含有硅氧烷—磷酸钙生物玻璃。本文论述了它们的复合及性能。
关键词 peta 生物玻璃 复合 性能
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多官能度单体PETA合成及其在牙科中的应用 被引量:1
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作者 蒋继英 唐立辉 谢贺明 《化学与粘合》 CAS 1994年第3期152-153,166,共3页
本文介绍了由季戊四醇和丙烯酸合成PETA的方法.讨沦了影响合成反应的诸因素.PETA是一种多官能单体混合物,将其宜接用作牙科复合树脂可明显提高机械强度和耐磨性.可满足后牙修复要求.
关键词 多官能单体 peta 合成 牙科
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时空派对 摄影师Peta的异想世界
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作者 李琼 《宠物世界(猫迷)》 2013年第9期12-13,共2页
穿越虫洞,遇到另一个时空的自己,参加一个只有自己参加的狂欢派对。这个怪异的约会对两只住在罗马的猫来说,一点儿也不难。因为,它们有一个充满想象力的摄影师主人Peta。
关键词 peta 虫洞 娱乐精神 澳大利亚人
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芒果AP1同源基因的克隆及其生物信息学分析 被引量:17
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作者 罗聪 何新华 +3 位作者 陈虎 蒋雅琴 高美萍 李杨瑞 《基因组学与应用生物学》 CAS CSCD 北大核心 2009年第5期851-858,共8页
我们采用RT-PCR方法克隆了2个A州同源基因全长cDNA,分别命名为MAPl—1(GenBankac—cession No.FJ529206)和MAPl—2(GenBankaccession No.FJ529207)。MAPl—1编码247个氨基酸,开放阅读框长度为741bp,蛋白质分子量为28.54kD,... 我们采用RT-PCR方法克隆了2个A州同源基因全长cDNA,分别命名为MAPl—1(GenBankac—cession No.FJ529206)和MAPl—2(GenBankaccession No.FJ529207)。MAPl—1编码247个氨基酸,开放阅读框长度为741bp,蛋白质分子量为28.54kD,等电点为8.31;MAPl—2编码248个氨基酸,开放阅读框长度为744bp,蛋白质分子量为28.78kD,等电点为8.70。同源性分析表明,它们的核苷酸序列与其它木本植物A纠同源基因的一致性为72%~81%。实验分析表明,MAPl—1和MAPl—2第1至第61个氨基酸含有一个MADS盒结构域,第88至第178个为K盒结构域;两个基因均定位于细胞核,且功能位点分布存在着不同,推测这两个基因在花器官发育过程中的功能存在差异。蛋白二级结构预测显示,MAPl—1蛋白有12个α-螺旋,4个8折叠区,14个β-转角;而MAP1—2蛋白有11个α-螺旋,5个B折叠区,15个β-转角;其大多数氨基酸具有亲水性。本研究有助于进一步了解芒果的开花分子机理及成花的生物学发育阶段。 展开更多
关键词 芒果 AP1(ApetaLA1)基因 克隆 生物信息学分析
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胡椒属植物DNA条形码初步研究 被引量:3
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作者 郝朝运 邬华松 +4 位作者 范睿 杨建峰 吴刚 马腾飞 秦晓威 《热带作物学报》 CSCD 北大核心 2013年第5期870-874,共5页
为筛选胡椒属DNA条形码最佳片段,研究了ITS、rbcL、psbJ-petA和matK基因片段的有效使用性、种内种间变异和barcoding gap,并评估了序列鉴定效率。结果显示:ITS和matK的barcoding gap图相对较好,matK物种水平鉴定成功率高,ITS种间变异较... 为筛选胡椒属DNA条形码最佳片段,研究了ITS、rbcL、psbJ-petA和matK基因片段的有效使用性、种内种间变异和barcoding gap,并评估了序列鉴定效率。结果显示:ITS和matK的barcoding gap图相对较好,matK物种水平鉴定成功率高,ITS种间变异较大,而其他2个候选序列不能进行有效鉴定。为此,推荐matK和ITS作为胡椒属植物潜在的DNA条形码序列,并依此探索建立该属的DNA条形码鉴定方法。 展开更多
关键词 胡椒属 DNA条形码 ITS psbJ-peta MATK RBCL
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油酸钠/水/十六烷/三丙烯酸季戊四醇酯体系层状液晶的聚合 被引量:3
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作者 郭荣 傅清红 张晓红 《化学学报》 SCIE CAS CSCD 北大核心 2000年第10期1196-1201,共6页
将十六烷增溶于油酸钠(NaOL)/水体系层状液晶的油层,共聚单体三丙烯酸季戊四醇酯(PETA)增溶于油酸钠/水体系层状液晶的两亲双层.72℃下,以增溶于油层中的十六烷作为阻隔.在层状液晶同一两亲双层内的两亲分子油酸钠与共聚单体PETA之间进... 将十六烷增溶于油酸钠(NaOL)/水体系层状液晶的油层,共聚单体三丙烯酸季戊四醇酯(PETA)增溶于油酸钠/水体系层状液晶的两亲双层.72℃下,以增溶于油层中的十六烷作为阻隔.在层状液晶同一两亲双层内的两亲分子油酸钠与共聚单体PETA之间进行共聚,得到了具有层状结构、并具有较好表面活性的共聚物. 展开更多
关键词 层状液晶 共聚合 油聚钠 十六烷 peta
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医药包装用互穿网络结构水性聚氨酯的制备 被引量:4
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作者 项尚林 刘超 +1 位作者 张冉 吴新上 《粘接》 CAS 2015年第4期38-41,共4页
采用异佛尔酮二异氰酸酯(IPDI)、聚己二酸丁二醇酯(PBA)、二羟甲基丙酸(DMPA)、丙烯酸羟乙酯(HEA)、三乙胺(TEA)、乙二胺(EDA)、甲基丙烯酸甲酯(MMA)、过硫酸钾(KPS)、季戊四醇三丙烯酸酯(PETA)等原料制备了水性聚氨酯丙烯酸酯乳液(PUA)... 采用异佛尔酮二异氰酸酯(IPDI)、聚己二酸丁二醇酯(PBA)、二羟甲基丙酸(DMPA)、丙烯酸羟乙酯(HEA)、三乙胺(TEA)、乙二胺(EDA)、甲基丙烯酸甲酯(MMA)、过硫酸钾(KPS)、季戊四醇三丙烯酸酯(PETA)等原料制备了水性聚氨酯丙烯酸酯乳液(PUA),考查了PETA用量对其性能的影响。结果表明,随着PETA的加入,PUA粒子形成互穿网络结构;乳液黏度先降低后增大;聚氨酯胶膜的拉伸强度和复合薄膜的T型剥离强度均先上升后下降,且在PETA用量为1.5%时达到最大值;PUA胶膜的断裂伸长率则呈下降趋势;复合薄膜的易氧化物指标、有机溶剂残留指标符合药品包装容器标准,表明合成的PUA适合用于医药包装。 展开更多
关键词 水性聚氨酯(WPU) peta 胶粘剂 性能
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季戊四醇三丙烯酸酯的合成 被引量:5
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作者 夏泽斌 谢保国 《化学世界》 CAS CSCD 1995年第10期528-530,共3页
季戊四醇三丙烯酸酯(PETA)不饱和度高,固化速度快,所形成的固化膜耐溶剂性优,是辐射固化领域广泛应用的多官能丙烯酸酯活性稀释剂。本文叙述用酸醇直接酯化法合成PETA,以丙烯酸和季戊四醇为原料,试验了不同催化剂、阻聚... 季戊四醇三丙烯酸酯(PETA)不饱和度高,固化速度快,所形成的固化膜耐溶剂性优,是辐射固化领域广泛应用的多官能丙烯酸酯活性稀释剂。本文叙述用酸醇直接酯化法合成PETA,以丙烯酸和季戊四醇为原料,试验了不同催化剂、阻聚剂、酸/醇比、反应物浓度诸因素对反应的影响,重点讨论了反应中的阻聚问题。 展开更多
关键词 季戊四醇 三丙烯酸酯 peta 合成
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