Subdivision of petrologic type of unequilibrated ordinary chondrites from Antarctica

We report results of petrologic and mineralogical studies of 25 unequili- brated ordinary chondrites （19 Chinese Antarctic meteorites） using electron microprobe, scanning electron microscopy （SEM） and energy-dispersive X-ray spectrometry （EDS） techniques. With increasing degree of thermal metamorphism, chemical zoning of olivine was erased; plessite was transformed into intergrowths of coarsergrained kamacite and Ni-rich metal; Cr exsolved from ferroan olivine, produced needie-like crystals and coarsened into equant chromite grains; and feldspar crystallized during devitrification of glass and recrystallization of matrix. These features can help to identify different metamorphic grades. Based on the scheme by Sears et al （1982）, we subdivided type 3 Chinese Antarctic ordinary chondrites into petrologic type 3.3 to 4 （3 type 3.3, 3 type 3.4, 1 type 3.5, 2 type 3.6, 2 type 3.7, 5 type 3.8, 3 type 4 ）. This classification scheme is a quite effective way to subdivide Antarctic meteorites. Additionally, we propose to revise the chemical groups of GRV 020032 and GRV 020104 to L and H, respectively.

Response of silicate chemical composition variation on thermal metamorphism of ordinary chondrites and classification of petrologic types:the case of L chondrites from Grove Mountains,Antarctica

Analysis of the thermal metamorphism of the ordinary chondrites is a key premise for gaining insights into the accretion and heating of rocky bodies in the early solar system.Such an analysis also represents an essential condition for constraining the early thermal and evolutionary histories of asteroids and terrestrial planets.Classifying ordinary chondrites into petrologic type(type 3–6)is the criterion for studying the thermal metamorphism of their parent bodies.However,the boundary between the unequilibrated(type 3)and equilibrated(type 4–6)chondrites is ambiguous at present,thus,limiting the understanding of their thermal metamorphism.In this study,the petrology,mineralogy and chemical composition of a set of seven ordinary chondrites with different degrees of thermal metamorphism collected from Grove Mountains(Antarctica)have been studied.The results demonstrated that these chondrite samples were L3.7,L3.8,L3.9,L3.9/4,L4,L5 and L6 type meteorites,with optimal correlations of Si,Mg,Fe,Mn and Ca with equilibrium degree of the olivine and low-calcium pyroxene and petrologic type.In this respect,the multi-parameter classification standard PMD(SiO2)-PMD(MgO)-PMD(MnO)-PMD(CaO)based on the percent mean deviation(PMD)of the chemical compositions of the olivine and low-calcium pyroxene was proposed to distinguish between the unequilibrated and equilibrated meteorites.The proposed standard exhibited high“resolution”in terms of classification,thus,also deepening the understanding of the effect of the silicate mineral composition in the thermal metamorphism of chondrites.Highlights The chemical groups and petrologic types of the selected seven Antarctic chondrites were L3.7,L3.8,L3.9,L3.9/4,L4,L5 and L6.A new method for petrologic type classification is proposed to distinguish the unequilibrated and equilibrated chondrites.The above developed multi-parameter system exhibited high“resolution”in terms of classification.

Dyke Swarms Florianópolis: Petrologic and Structural Aspects Related to Rifting Supercontinent Gondwana and Formation South Atlantic in the Santa Catarina of Island, Brazil

From a point of magmatic view,the rupturing Gondwana Supercontinent is registered on the South American shelf in continental flood basalts,mafic dyke swarms,basins rift and,to a lesser extent,by intrusions alkaline.Among those

Petrological Study on the Ductile Shear Zones in the Core of the Eastern Qinling Orogenic Belt in Western Henan

A series of ductile shear zones of the overthrust and strike-slip-types and related ductile shear metamorphicrocks, including tectonic melange and mylonites. were formed in the core of the Qinling orogenic belt in thecourse of the Caledonian-Indosinian ductilc and brittle-ductile reworking. The study on their petrography. va-riations in composition and conditions of formation is conducive to revealing the metamorphism-deformationhistory of the core of the Qinling orogenic belt and further to understanding the dynamic mechanism of its evo-lution.

A Petrological, Geochemical, and Geochronological Study of Shuikou Ultrabasic Rock Mass in Wuding County, Yunnan Province, China

Geotectonically, the Shuikou ultrabasic-basic rock mass is located on the western margin of the Yangtze Platform. As revealed by field geological surveys, the Shuikou rock mass intrudes into the quartz sandstones of the Sinian Chengjiang Formation (Zac). It is dominated by pyroxenites and can be roughly divided into four lithofacies zones, namely gabbros at the outermost periphery and fine-, medium-, and coarse-grained pyroxenites from margin to center. With the transition from pyroxenites to gabbros, the Shuikou rock mass features gradual enrichment in silica and alkali overall, an increase in ΣREE and (La/Yb)N ratio, and a decrease in δEu values and Eu/Sm ratio, indicating that the Shuikou rock mass was formed from the continuous differentiation and crystallization of consanguineous magma and that low-degree partial melting occurred meanwhile. According to the U-Pb baddeleyite geochronology, the crystallization age of the Shuikou rock mass is 210.7 ± 3 Ma (MSWD = 1.01). Based on this, as well as the analysis of geochemical characteristics, the Shuikou rock mass occurred in a continental intraplate tensional environment, this is closely related to the activities of the Emeishan mantle plume during the same period.

New Petrological and Sedimentary Evidences on the Late Cretaceous Uplift of the Tibetan Plateau

The India-Asia collision and uplift of the Tibetan plateau are the most important geological events in Earth＇s history; it profoundly affects our understanding of global climate change during the Cenozoic. Despite a research history over half a century, the uplifting history remains hotly controversial. The early uplifting model suggested that the Lhasa terrane attained an elevation of 3-4 km at -99 Ma due to the Lhasa-Qiangtang collision. However, the evidences are mainly from deformation of the Lhasa terrane and inconsistency with the palaeontological data.

Petrologic perspectives on tectonic evolution of a nascent basin(Okinawa Trough) behind Ryukyu Arc: A review

Okinawa Trough is a back-arc, initial marginal sea basin, located behind the Ryukyu Arc-Trench System. The formation and evolution of the Okinawa Trough is intimately related to the subduction process of the Philippine Sea Plate beneath the Eurasian Plate since the late Miocene. The tectonic evolution of the trough is similar to other active back-arcs, such as the Mariana Trough and southern Lau Basin, all of which are experiencing the initial rifting and subsequent spreading process. This study reviews all petrologic and geochemical data of mafic volcanic lavas from the Okinawa Trough, Ryukyu Arc, and Philippine Sea Plate, combined with geophysical data to indicate the relationship between the subduction sources （input） and arc or back-arc magmas （output） in the Philippine Sea Plate-Ryukyu Arc-Okinawa Trough system （PROS）. The results obtained showed that several components were variably involved in the petrogenesis of the Oki-nawa Trough lavas：sub-continental lithospheric mantle underlying the Eurasian Plate, Indian mid-oceanic ridge basalt （MORB）-type mantle, and Pacific MORB-type mantle. The addition of shallow aqueous fluids and deep hydrous melts from subducted components with the characteristics of Indian MORB-type mantle into the mantle source of lavas variably modifies the primitive mantle wedge beneath the Ryukyu and sub-continental lithospheric mantle （SCLM） beneath the Okinawa Trough. In the northeastern end of the trough and arc, instead of Indian MORB-type mantle, Pacific MORB-type mantle dominates the magma source. Along the strike of the Ryukyu Arc and Okinawa Trough, the systematic variations in trace element ratios and isotopic compositions reflect the first-order effect of variable subduction input on the magma source. In general, petrologic data, combined with geophysical data, imply that the Okinawa Trough is experiencing the＂seafloor spreading＂process in the southwest segment,＂rift propagation＂process in the middle seg-ment, and＂crustal extension＂process in the northeast segment, and a nascent ocean basin occurs in the southwest segment.

Petrologic and REE Geochemical Characters of Burnt Rocks

The study of burnt rocks is beneficial to the discussion on the tectonic movement, paleoclimate and paleogeography that coal seams are subjected to after they were formed. In order to obtain the basic data on the features of the burnt rocks, a systematic study of petrology and REE geochemistry on burnt rocks in Shenmu, Northern Shaanxi Province has been done, using the methods of SEM, EDS, susceptibility measurements and ICP-MS. The burnt rocks are divided into two series in the section： the melted rocks and the baked rocks. SEM and EDS analyses reveal that all the minerals show burnt and melted traces, and there are no clay minerals except illite found in the burnt rocks. Susceptibility measurements reveal that the burnt rocks have abnormally high susceptibility values, whereas a geochemical analysis shows that the REE distribution pattern of burnt rocks is similar to that of sedimentary rocks （initial rocks）. In the longitudinal section, with increasing degree of burning （from baked rocks to melted rocks）, the ∑REE gradually decreases, and the total REE of melted rocks is obviously lower than that of baked rocks. Besides, the melted rocks show apparent negative Ce anomalies, while the baked rocks show no anomaly of Ce, and sometimes even show positive anomalies.

PETROLOGIC AND GEOCHRONOLOGIC STUDIES

The model of extrusion tectonics for the accommodation of the Indo\|Asian collis i on requires the presence of large\|scale strike\|slip faults with hundreds of ki lo meters of displacement. Along the western edge of the Tibetan Plateau, the Kara koram fault, extending ～900[KG*9]km from the central Pamir to western Tibet, ha s been proposed as one of these accommodating faults. At the northern terminus of the Karakoram fault lies the west\|southwest dipping Kongur Shan detachment f ault system. As the two systems have been proposed to be kinematically linked, constraining the amount of slip along the Kongur Shan detachment system helps d etermine the total displacement along the Karakoram fault system. This in turn will co nstrain the applicability of extrusion tectonics models for the Indo\|Asian coll ision. [KH*2] Detailed geologic mapping was conducted in the northern Kongur Shan region along the Gezi River and near the village of Qiake lake. Kinematic indicators f rom rocks directly below the fault, such as rotated crystals, asymmetric boundar y, and S\|C fabrics, show a normal sense of shear. The detachment fault in th e area dips between 35° to 45° to the east. A thin zone of chloritic breccias, a few meters thick, is locally exposed directly below the fault. Mylonitic gneisse s ＞2[KG*9]km thick are present in the footwall. The strike of mylonitic foliat ions c hanges systematically and, together with the domal geometry of a deformed grani tic body, define a gneiss dome in the footwall. Associated with the variation i n the strike of foliation is a systematic change in the trend of the mylonitic l ineation. Their trend is to the west directly below the fault, but changes to the northwest farther away from the fault. Rocks in the footwall of the detachm ent fault are composed of biotite and muscovite schists (quartz, plagioclase, bi otite, muscovite, +/-garnet, +/-epidote), and deformed granitite sills and sh ee t\|like bodies. Preliminary petrologic studies indicate that these rocks have ex perienced upper greenschist to lower amphibolite facies metamorphism.

Petrological geodynamics of mantle melting Ⅲ.AlphaMELTS+multiphase flow:The effect of water

The influence of water is evaluated in this last contribution of a series aiming to study the petrological and dynamic evolution of mantle melting.Water is considered to be either a chemical component in the melt or solid assemblage but it can also be present as a pure water phase in a oversaturated environment.A three-phase-flow model was developed for this purpose.Only a limited set of conditions has been applied to the 1-D upwelling mantle column.A range of fixed temperatures(1150-1450℃) and water contents in the solid mantle(0,0.02 wt.%,0.2 wt.%) have been imposed at the entry point(120 km deep) for the two melting models introduced in the previous installments,dynamic equilibrium melting(DEM) and dynamic fractional melting(DFM) model.As expected,for a given temperature at the base of the mantle column,the depth of the first melt formation increases with higher water content in the mantle.After the first melt is created,very negligible amount of melt is formed over a certain depth interval which approximately ends at the depth where the first melting of the dry mantle would take place.However melt is present as a dynamic phase thorough the entire region regardless whether the DEM or DFM model has been applied.Under a quasi-steady state regime,the melt and residual mantle compositions vary significantly over depth,depending on the conditions imposed to the model(DEM,DFM,bottom temperature and water content).Several distinctions can be made at the extraction point(top of the mantle column=15 km deep).For DEM and DFM models at this lowest depth,the most influential factor affecting the melt composition after the quasi-steady state condition has been reached is the temperature at the base of the column.In general,for a high temperature model,the input water in the mantle does not seem to play a significant role on the bulk composition of the melt(except for the water content in melt).But at low temperature water does have some noticeable influence on the variation of some chemical components in melt(SiO2,Fe2 O3,CaO,Na2 O at T=1250℃ or lower).A similar conclusion can be made also for the residual mantle composition.The presence of a dynamic free water phase is detected only in absence of melt or in coexistence with a melt phase when the mantle is relatively cold(bottom temperature≤1250℃) and the input water content at the base of the model is relatively high(0.2 wt.%).Complete output data for several numerical simulations and six animations illustrating various melting models are available following the instructions in the supplementary material.

Petrological Research of K-Rich Volcanic Rocks from Wudalianchi and Nearby Areas

A K-rich volcano zone , Wudalianchi-Erkeshan - Keluo in Heilongjiang Province of Northeastern China , is studied in this paper . Some results from the study of mantle inclusions , accumulative inclusions and megacrysts are reported here for the first time . On the petrological , experimental , and magma-dynamical study of the host rocks and their inclusions and megacrysts , it is concluded that the K-rich magma in these areas was derived from upper mantle with rich in K2O and incompatible element by partial melting of phlogopite-bearing Iherzolite. Leucite picrite magma is primary and the magma represented by leucite basalt is derivative one of both fractional crystallization and assimilation . The mantle where the magma came from had undergone both the depletion and enrichment events , and had high geotherm similar to that of mid -oceanic ridge and rift valley . Mantle metasomatism , uplift and diapirism result in the K-rich volcanic rocks . The environment of volcanism in these areas is rift tectonics within continental plate ,and the composition and distribution of volcanic rocks in these areas are controlled by mantle-reach faults , and are not directly related to the subduction of the Pacific plate .

Provenance for the Chang 6 and Chang 8 Member of the Yanchang Formation in the Xifeng area and in the periphery Ordos Basin: Evidence from petrologic geochemistry

Study indicates that the major paleocurrent and source direction for the Chang 8 Member of the Yangchang Formation, Upper Triassic in the Xifeng area of the southwestern Ordos Basin derived from the southwest direction with the southeast source as the subordinate one. While the Chang 6 Member was influenced not only by the same source as that of the Chang 8 Member from the southwest and the southeast direction, but also affected by the northeast and the east provenance around the Ordos Basin, based upon measurement of paleocurrents on outcrops located in the periphery Ordos Basin, analysis of framework grains and heavy minerals in sandstones of the Chang 6 and Chang 8 Members and their spatial distribution in the study area, combined with characteristics of trace elements and rare-earth elements of mudstones and of a small amount of sandstones in the Xifeng area and outcrops in margin of the Ordos Basin. The Yuole-Xuanma-Gucheng-Heshui-Ningxia region located in the northeastern and the eastern Xifeng area was the mixed source area where the southwest, southeast, northeast and the east sources were convergent till the Chang 6 Member was deposited. The rare earth elements of the Chang 6 and Chang 8 Members are characterized by slight light rare earth-elements (LREE) enrichment and are slightly depleted in heavy rare earth-elements (HREE) with weak to moderate negative abnormal Eu, resulting in a right inclined REE pattern, which implies that the source rocks are closely related with better differential crust material. Analysis on geochemical characteristics of the mudstones and sandstones, features of parent rocks in provenance terranes and tectonic settings shows that source rocks for the Chang 8 Member mainly came from metamorphic and sedimentary rocks in transitional continental and basement uplift terranes with a small amount of rocks including metamorphic, sedimentary and igneous rocks coming from mixed recycle orogenic belt located in the southwest margin of the Ordos basin. Rocks in the crystalline basement and the overlying sedimentary cover in a basement uplift setting in the northeast periphery of the basin also contributed a part of the sources for the Chang 6 Member, in addition to the sources deriving from transitional continental and basement uplift terranes in the southwest margin of the basin. Parent rocks of the provenance terrane in the northeast margin of the Ordos Basin are characterized by having more felsic rocks.

Genesis and tectonic setting of Early Jurassic granitic rocks in Huashan Town,Xingcheng,western Liaoning

There are a large number of Mesozoic intrusive and volcanic rocks in western Liaoning of China,which is an ideal place to study the Mesozoic Paleo-Pacific subduction processes,and lithospheric destruc-tion of North China Craton.Detailed petrographic,zircon U-Pb dating and geochemical studies of the Early Jurassic granites in Huashan pluton,Xingcheng,western Liaoning,indicate that the Early Jurassic granites were formed at 184-174 Ma,mainly composed of syenite and monzogranite.The geochemical characteristics show high contents of SiO_(2),Al_(2)O_(3)and Na_(2)O+K_(2)O,low contents of Fe_(2)O_(3)and MgO,enrichment in LREEs and LILEs,and depletion in HREEs and HFSEs,and have a high content of Sr and low contents of Y and Yb,with weak negative Eu anomalies and slightly negative anomalies of Ce,indicating that they are a set of intermediate-acidic adakitic granites in high-K calc-alkaline series.All the facts significantly suggest that the Early Jurassic adakitic granites were formed at the active continental margin in the context of Paleo-Pacific plate subduction.

Magma underplating and Hannuoba present crust-mantle transitional zone composition: Xenolith petrological and geochemical evidence

On the basis of mineral assemblage, mineralogy, petrology, and major, trace ele-mental and isotopic geochemistry of the underplated granulite- and eclogite-facies accumulate, peridotite and pyroxenite xenoliths entrained in Hannuoba Cenozoic basalts, this work con-strained the petrological constituents for the crust-mantle transitional zone, which is supported by the results of high-temperature and pressure velocity experiments on rocks and geophysics deep survey. Present lower part of lower crust is mainly composed of granulite-facies mafic accumu-lates (dominantly plagioclase websterite) and crust-mantle transitional zone dominantly com-posed of eclogite-facies pyroxenites with or without garnet and spinel lherzolites; Archaean ter-rain granulite is only nominally early lower crust. Magma underplating in the crust-mantle boundary led to the crustal vertical accretion and the formation of the crust-mantle transitional zone, which is a significant mechanism for the chemical adjustment of the crust-mantle boundary since the Phanerozoic.

Metamorphic P-T Path Differences between the Two UHP Terranes of Sulu Orogen, Eastern China: Petrologic Comparison between Eclogites from Donghai and Rongcheng

The Sulu Orogen constitutes the eastern part of the Sulu-Dabie Orogen formed by Triassic collision between the Sino-Korean and Yangtze plates. An HP Slice Ⅰ and two UHP slices Ⅱ and Ⅲ with contrasting subduction and exhumation histories within the Sulu Orogen were postulated. This study presents the metamorphic P-T paths of eclogites from the two UHP belts constructed by petrog- raphy, mineral chemistry and Perple_X P-T pseudosection modeling in the MnC（K）NFMASHO system. Eclogites from Slice Ⅲ mainly consist of omphacite, garnet and quartz, with minor rutile, ilmenite, amphibole and phengite. Eclogites from Slice Ⅱ show a porphyroblastic texture with epidote porphyroblasts and garnet, omphacite, phengite, quartz and rutile in matrix. Pseudosection modeling reveals that eclogites from Slice Ⅱ witness a peak metamorphism of eclogite-facies under conditions of 3.1-3.3 GPa and 660-690 ℃, and a retrograde cooling decompression process. The eclogites from Slice Ⅲ record a heating decompressive P-T path with a peak-P stage of 3.2 GPa and 840℃ and a peak-T stage of 2.4 GPa and 950 ℃, suggesting an apparent granulite-facies metamorphism overprint during exhumation. Both eclogites recorded clockwise P-T paths with peak P-T conditions suggesting a subduction beneath the Sino-Korean Plate to -100-105 km depth. Combined with tectonic scenarios from previous studies, it is concluded that the two UHP crustal slices in the Sulu terrane have a similar geodynamic evolution, but the UHP rocks in Slice Ⅱ exhumed after the eclogitic peak-pressure conditions earlier than that of Slice Ⅲ. The existence of Slice Ⅱ diminished the buoyancy force on Slice Ⅲ, resulting in a granulite-facies overprint on Slice Ⅲ. The Sulu orogenic belt is made up of different crustal slices that underwent different subduction and exhumation histories, rather than a single unit.

Genesis and Geodynamic Significance of Chromitites from the Fuchuan Ophiolite,Southern China,as Evidenced by Trace Element Fingerprints of Chromite,Olivine and Pyroxene

The Fuchuan ophiolite is located in the northeasternmost segment of the Neoproterozoic Jiangnan orogen and consists mainly of harzburgites,with minor dunites,pyroxenite and gabbro veins and dykes.In order to investigate the genesis and tectonic setting of the Fuchuan ophiolite and chromitites,in situ analyses of unaltered chromites and silicates were carried out.Trace element analyses of unaltered chromites from the Fuchuan chromitites indicate the parental magma is of mid-ocean ridge basalt(MORB)-like origin,with the Ti/Fe^(3+#)–Ga/Fe^(3+#)diagram of chromites showing that the chromitites are a result of melt/rock interaction of MORB melts with mantle peridotites,and that the Fuchuan harzburgites present the dual features of MORB and supra-subduction zone peridotites(SSZP).Trace and rare earth element(REE)analyses of olivines and orthopyroxenes from the Fuchuan harzburgites hint at the possibility of mantle metasomatism influenced by SSZ-subducted fluids.Finally,integrating with previous study,the Fuchuan ophiolite and chromitites might have been formed in a back-arc spreading ridge between the Yangtze and Cathaysia blocks during the Neoproterozoic.

Coal petrology,sedimentology and depositional environment of the Parvadeh coais in the Upper Triassic,Tabas Block of Central-East Iran

Peat forming environment strongly influences the economic value of any coal seam and coal-bearing strata.Hence,pal-aeoenvironmental studies provide important information for coal resource exploration.In this context,detailed studies on selected coals from the Parvadeh Area,Iran,were conducted using sedimentology,coal petrology,X-ray diffraction(XRD),scanning electron microscopy-energy dispersive X-ray analyzer(SEM-EDX),and proximate analysis.The sedi-mentary facies above and below the coal seams are mainly marine or marine-influenced facies,supporting that the coal-forming mires in the Parvadeh Area developed in a paralic environment,where the base level must be closely related to sea level.Sulfur contents are moderate to high and mark the influence of brackish/marine water,especially during transgres-sion after peat growth in a lower delta plain environment.The peat-forming mires extended on coastal/delta plain lobes.The lower delta plain/coastal plain coals are characterized by lateral continuity and substantial thickness,whereas few coals possibly representing the upper delta plain are thin and more discontinuous.The detrital nature and composition of the numerous partings and the overall high ash yield in the coal seams indicate an active tectonic area with high rates of creation of accommodation space over peat growth.Coal petrology and coal facies analysis exhibits a permanently high water table within a forest swamp and mostly rheotrophic conditions,sometimes with connection to the seawater.Accord-ing to paleoenvironmental reconstructions,it seems that coal layers may be thicker,with less sulfur(pyrite),but more clastic minerals and partings toward the western part of the area.Although these coal seams presently have low economic potential for the mining operation,partly due to great depth,this humic,high-volatile to medium-volatile bituminous coal may be suitable for exploration of coal bed methane resources.

Effects of Spin Transition and Cation Substitution on the Optical Properties and Iron Partitioning in Carbonate Minerals

The high-pressure behavior of deep carbonate dictates the state and dynamics of oxidized carbon in the Earth's mantle,playing a vital role in the global carbon cycle and potentially influencing long-term climate change.Optical absorption and Raman spectroscopic measurements were carried out on two natural carbonate samples in diamond-anvil cells up to 60 GPa.Mg-substitution in high-spin siderite FeCO_(3)increases the crystal field absorption band position by approximately 1000 cm^(-1),but such an effect is marginal at>40 GPa when entering the low-spin state.The crystal field absorption band of dolomite cannot be recognized upon compression to 45.8 GPa at room temperature but,in contrast,the high-pressure polymorph of dolomite exhibits a strong absorption band at frequencies higher than(Mg,Fe)CO_(3)in the lowspin state by 2000–2500 cm^(-1).Additionally,these carbonate minerals show more complicated features for the absorption edge,decreasing with pressure and undergoing a dramatic change through the spin crossover.The optical and vibrational properties of carbonate minerals are highly correlated with iron content and spin transition,indicating that iron is preferentially partitioned into low-spin carbonates.These results shed new light on how carbonate minerals evolve in the mantle,which is crucial to decode the deep carbon cycle.

Organic geochemical and petrographic characteristics of the Cambrian-Ordovician organic-rich marine shales in Scandinavia

This work used organic geochemistry and organic petrology to study the depositional environment,organic matter characteristics,and thermal maturity of the Cambrian-Ordovician organic-rich marine shales in the Baltic Basin.The main macerals in Cambrian samples include alginite,bituminite and solid bitumen,while zooclastic macerals become the major proportion of organic matter in the Ordovician samples.As the maturity increase,solid bitumen becomes abundant and dispersed.Semifusinite-like maceral was observed only in Furongian of well DBH15/73,which probably indicates the local intrusion of Permo-Carboniferous dolerite dikes.The programmed pyrolysis results show that immature,early mature,and over-mature samples are developed.However,the data of high-uranium Furongian samples were greatly altered by igneous intrusives from local dikes.HIo calculation model is simulated based on pyrolysis data and fitted according to the least-square fitting method.The simulated fitting HIo:400mg HC/g TOC(369.5 mg HC/g TOC,430.5 mg HC/g TOC as 95%confidence bounds)is within the worldwide marine shale HI_(o)and indicates a marine anoxia and transgressive sea with shallow water column(organofacies B).

Geochemical and mineralogical evaluations of coal,shale,and mine waste overburden from Makum coalfield of the Northeast India

The Cenozoic-age Makum coal from northeastern India offers numerous research opportunities because of its diverse geochemical and geological characteristics.Due to its high sulfur content,the coal has been found to be less useful for industrial purposes.It can,however,serve as a hub for ongoing research on coal-based derivative products.The aim of this research work is to investigate the mineralogical and geochemical compositions of the coal,mine overburden(MOB)and shale samples taken from the Makum coal field and also on establishing a mutual relationship between them.To characterize the geochemical controlling factors of the Makum coal field,the study employs coal petrography,FTIR,mineralogical,and geochemical analysis.According to X-ray diffraction analysis,the major minerals like quartz,kaolinite,haematite,illite,pyrite,and calcite are present in coal and MOB.Pyrite is observed by SEM-EDS analysis as cubic-shaped particles that are smaller than a fewμm in size.The presence of sulfide minerals represents a phase of pyrite mineralization.The petrography study was used to better understand the environment that existed during the formation of the plant material,which aids us in determining the quantity of detrital mineral sediment contained in the coal.According to the ICP-MS analysis,the samples indicate significant levels of rare earth elements including yttrium.The present study reveals higher concentrations of poten-tial hazardous elements in the coal samples,with V,Cr,Ni,Cu,and Zn content in coal being considerably enriched compared to world-average concentrations.The correlation analysis reveals that the potential hazardous elements like Co,Ni,As,and Cu are associated with pyrite as they have strong affinity towards pyrite.Thus,numerous minerals and rare earth elements(REEs)exist,opening up a fresh avenue for more research in the area.This study also assists researchers in understanding the significance of Makum coal and provides numerous ideas for coal characterization.