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《资源税法》实施对资源型企业绿色技术创新的影响
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作者 周海炜 齐增睿 《工业技术经济》 北大核心 2024年第8期58-67,共10页
2020年《资源税法》正式实施,其作为我国绿色税制的重要组成将从价计征改革成果上升固化为法律制度,开启我国经济绿色发展的新篇章,因此有必要对《资源税法》的实施效果进行分析。本文基于2013~2022年中国上市资源型企业的面板数据,采... 2020年《资源税法》正式实施,其作为我国绿色税制的重要组成将从价计征改革成果上升固化为法律制度,开启我国经济绿色发展的新篇章,因此有必要对《资源税法》的实施效果进行分析。本文基于2013~2022年中国上市资源型企业的面板数据,采用双重差分模型实证分析《资源税法》实施对资源型企业绿色技术创新的影响及作用机制。研究结果表明:《资源税法》的实行,显著促进了资源型企业的绿色技术创新,机制检验表明《资源税法》的实施有助于增加资源型企业的研发创新投入,进而对资源型企业的绿色技术创新起到激励作用。异质性分析发现,《资源税法》的实施对中部和东部地区、国有资源型企业绿色技术创新的激励作用更明显;相较于绿色实用新型专利,《资源税法》的实施对资源型企业绿色发明专利的边际贡献更大。未来《资源税法》可以从增加企业绿色技术创新投入的激励性政策、促进资源税与财政税收政策协调配合、实施差异化的税收优惠等方面进行完善。 展开更多
关键词 资源税法 绿色技术创新 税收优惠 资源型企业 研发投入 资源税改革 环境规制 环境保护
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Airblast evolution initiated by Wangjiayan landslides in the M_(s)8.0 Wenchuan earthquake and its destructive capacity analysis
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作者 Yu-feng Wang Qian-gong Cheng Qi Zhu 《China Geology》 CAS CSCD 2024年第2期237-247,共11页
Airblasts,as one common phenomenon accompanied by rapid movements of landslides or rock/snow avalanches,commonly result in catastrophic damages and are attracting more and more scientific attention.To quantitatively a... Airblasts,as one common phenomenon accompanied by rapid movements of landslides or rock/snow avalanches,commonly result in catastrophic damages and are attracting more and more scientific attention.To quantitatively analyze the intensity of airblast initiated by landslides,the Wangjiayan landslide,occurred in the Wenchuan earthquake,is selected here with the landslide propagation and airblast evolution being studied using FLUENT by introducing the Voellmy rheological law.The results reveal that:(1)For the Wangjiayan landslide,its whole travelling duration is only 12 s with its maximum velocity reaching 36 m/s at t=10 s;(2)corresponding to the landslide propagation,the maximum velocity,28 m/s,of the airblast initiated by the landslide also appears at t=10 s with its maximum pressure reaching594.8 Pa,which is equivalent to violent storm;(3)under the attack of airblast,the load suffered by buildings in the airblast zone increases to 1300 Pa at t=9.4 s and sharply decreased to-7000 Pa as the rapid decrease of the velocity of the sliding mass at t=10 s,which is seriously unfavorable for buildings and might be the key reason for the destructive collapse of buildings in the airblast zone of the Wangjiayan landslide. 展开更多
关键词 LANDSLIDE Voellmy rheological law 3D FLUENT simulation Airblast Intensity Building destructive collapse Wenchuan earthquake Geological hazards survey engineering
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农业信息化对舟山市农业经济发展的影响研究
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作者 翟文晓 沈最意 《特区经济》 2024年第1期119-122,共4页
随着我国农业信息化进程的不断加快,信息技术已经渗透到了农业领域的方方面面。因此,农业经济的发展与农业信息化水平息息相关。本文采用2010-2020年期间浙江省舟山市的面板数据,运用熵权法测算出2010-2020年舟山历年的农业信息化水平,... 随着我国农业信息化进程的不断加快,信息技术已经渗透到了农业领域的方方面面。因此,农业经济的发展与农业信息化水平息息相关。本文采用2010-2020年期间浙江省舟山市的面板数据,运用熵权法测算出2010-2020年舟山历年的农业信息化水平,将农业信息化水平引为柯布—道格拉斯生产函数的第三生产要素,实证分析农业信息化水平对舟山农业经济发展的影响。从分析结果可以看出,农业信息化水平与舟山市农业经济增长之间具有正向关联性,农业信息化水平每提高1%就能促进农业经济增长0.272%。据此,可以积极采用培养农业信息化人才和加强农业信息化设施建设等措施来提升舟山市农业信息化建设水平,进而促进舟山市农业经济的健康可持续发展。 展开更多
关键词 农业信息化 农业经济 熵权法 C-D生产函数 农业信息化建设
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FORMULA OF GLOBAL SMOOTH SOLUTION FOR NON-HOMOGENEOUS M-D CONSERVATION LAW WITH UNBOUNDED INITIAL VALUE 被引量:1
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作者 曹高伟 胡凯 杨小舟 《Acta Mathematica Scientia》 SCIE CSCD 2015年第2期508-526,共19页
In this article, we prove the existence and obtain the expression of its solution formula of global smooth solution for non-homogeneous multi-dimensional(m-D) conservation law with unbounded initial value; our metho... In this article, we prove the existence and obtain the expression of its solution formula of global smooth solution for non-homogeneous multi-dimensional(m-D) conservation law with unbounded initial value; our methods are new and essentially different with the situation of bounded initial value. 展开更多
关键词 Solution formula non-homogeneous m-D conservation laws global smooth solution global implicit function
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过敏性紫癜患儿临床特点及中医证候演变规律的研究 被引量:3
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作者 陶洪 刘慧英 +3 位作者 彭昕欣 谢静 谢薇 黄婷 《湖南中医药大学学报》 CAS 2023年第5期935-939,共5页
目的观察过敏性紫癜中医证候演变规律,探讨过敏性紫癜临床特点与中医证型的相关性。方法对426例来自湖南中医药大学第一附属医院住院和门诊的过敏性紫癜(Henoch-Schonlein purpura,HSP)患儿临床资料进行回顾性分析,总结中医证候演变规律... 目的观察过敏性紫癜中医证候演变规律,探讨过敏性紫癜临床特点与中医证型的相关性。方法对426例来自湖南中医药大学第一附属医院住院和门诊的过敏性紫癜(Henoch-Schonlein purpura,HSP)患儿临床资料进行回顾性分析,总结中医证候演变规律,比较患儿的一般资料、发病季节、诱发病因、实验室指标不同水平分布情况。结果(1)HSP患儿男女发病比例相当,冬春季发病多,病程多在4周以内。(2)中医证型以风热伤络证、血热妄行证为多,其次是湿热痹阻证、阴虚火旺证、气不摄血证,发病诱因以感染多见,其中呼吸道感染最多见,统计学分析提示:不同中医证型在年龄、发病诱因上差异有统计学意义(P<0.05);实验室指标D-二聚体、白细胞介素-6(interlenkin-6,IL-6)、免疫球蛋白A(immunoglobulin A,IgA)、CD4^(+)/CD8^(+)T在不同中医证型上差异有统计学意义(P<0.05)。(3)风热伤络证易演变为气不摄血证;血热妄行证易演变为阴虚火旺证。结论(1)HSP中医证型上早期以风热伤络证、血热妄行证为主,后期常见阴虚火旺证、气阴两虚证;(2)HSP中医病机演变上,主要向虚、瘀发展。(3)D-二聚体、IL-6、IgA数值升高和CD4^(+)/CD8^(+)T数值偏低的现象主要集中在风热伤络证和血热妄行证。 展开更多
关键词 过敏性紫癜 中医证候演变规律 临床特点 D-二聚体 白细胞介素-6 免疫球蛋白A CD4^(+)/CD8^(+)T
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NEW CONSERVATION LAWS OF ENERGY AND C-D INEQUALITIES IN CONTINUA WITH MICROSTRUCTURE
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作者 DAI Tian-min(戴天民) 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2001年第2期135-143,共9页
Existing fundamental laws, balance equations and Clausius-Duhem inequalities in continua with microstructure are systematically restudied, and the incomplete formulations of conservation laws of energy and related C-D... Existing fundamental laws, balance equations and Clausius-Duhem inequalities in continua with microstructure are systematically restudied, and the incomplete formulations of conservation laws of energy and related C-D inequalities are pointed out. Some remarks on existing results are made, and new conservation laws of energy and related C-D inequalities are presented. 展开更多
关键词 continua with microstructure new conservation laws of energy new C-D inequalities
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Three-dimensional suboptimal guidance law for fly-over and shoot-down smart ammunition via virtual target
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作者 杨喆 吴炎烜 +1 位作者 范宁军 王正杰 《Journal of Beijing Institute of Technology》 EI CAS 2014年第4期443-451,共9页
An optimal burst height is required for the fly-over and shoot-down smart ammunition with an EFP warhead at the instant of explosion which brings a special requirement to the miss distance of the terminal guidance law... An optimal burst height is required for the fly-over and shoot-down smart ammunition with an EFP warhead at the instant of explosion which brings a special requirement to the miss distance of the terminal guidance law. In this paper, a guidance law based on the virtual target scheme is proposed. First, the practical pursuit-evasion issue between the ammunition and the target with specific miss distance is transformed into a virtuai pursuit-evasion problem with zero miss distance. Secondly, a complete three-dimensional pursuit-evasion kinematics model is established without any simplifications. And then, a suboptimal guidance law is designed based on the θ-D method which has constraints of the elevation and azimuth angular velocity of the virtual line of sight (LOS). Finally, in order to verify the performance of the proposed guidance law, three test cases are conducted. Numericai results show that under the proposed terminal guidance law, the smart ammunition not only can fly above the target with an optimal burst height but also have a smaller normal acceleration on the terminal trajectory. 展开更多
关键词 three-dimensional guidance law virtual target fly-over and shoot-down θ-D method
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NEW CONSERVATION LAWS OF ENERGY AND C-D INEQUALITIES IN CONTINUA WITHOUT MICROSTRUCTURE
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作者 DAI Tian-min(戴天民) 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2001年第2期127-134,共8页
Fundamental laws and balance equations as well as C-D inequalities in continuum mechanics are carefully restudied, incompleteness of existing balance laws of angular momentum and conservation laws of energy as well as... Fundamental laws and balance equations as well as C-D inequalities in continuum mechanics are carefully restudied, incompleteness of existing balance laws of angular momentum and conservation laws of energy as well as C-D inequalities are pointed out, and finally new and more general conservation laws of energy and corresponding balance equations of energy as well as C-D inequalities in local and nonlocal asymmetric continua are presented. 展开更多
关键词 local asymmetric nonlocal asymmetric continuum mechanics conservation laws of energy balance equations of energy C-D inequalities
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基于MSER仿射变换配准的农用柔性pH芯片性能优化
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作者 张淼 王丽茹 +2 位作者 李浩榛 路逍 刘刚 《农业机械学报》 EI CAS CSCD 北大核心 2023年第5期288-294,386,共8页
针对柔性pH芯片复合结构多层打印制备过程的配准偏差严重,限制其农用pH值在线监测精度及稳定性问题,比较分析了MSER仿射变换模型对“叠层复合结构”柔性pH芯片性能的影响,分析了配准后柔性pH芯片在基质培番茄根系pH值在线监测应用中的... 针对柔性pH芯片复合结构多层打印制备过程的配准偏差严重,限制其农用pH值在线监测精度及稳定性问题,比较分析了MSER仿射变换模型对“叠层复合结构”柔性pH芯片性能的影响,分析了配准后柔性pH芯片在基质培番茄根系pH值在线监测应用中的可行性。试验结果表明:MSER仿射变换模型配准后,农用柔性芯片加工最小线宽和线间距分别为90、500μm,芯片加工平均相对误差可控制在25%以内;配准后,农用柔性pH传感器灵敏度达到了每单位pH值-61.9 mV,响应范围为2.0~10.0,与商用玻璃pH电极的测量绝对误差小于0.15,相对误差小于4.1%;基质培番茄根系pH值监测试验中,自制柔性芯片与商用pH电极的测量结果具有较好一致性,同步测定结果的绝对误差小于0.09,相对误差小于1.5%,RMSE仅为0.05。MSER仿射变换配准方法可有效提高“叠层复合结构”农用打印柔性传感芯片的制备精度及传感检测准确性。 展开更多
关键词 pH值在线监测 柔性pH芯片 最大稳定极值区域 仿射变换 3D打印多层配准
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Are Black Holes 4-D Spatial Balls Filled with Black Body Radiation? Generalization of the Stefan-Boltzmann Law and Young-Laplace Relation for Spatial Radiative Transfers
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作者 Christopher Pilot 《Journal of High Energy Physics, Gravitation and Cosmology》 2019年第3期638-682,共45页
This is the first paper in a two part series on black holes. In this work, we concern ourselves with the event horizon. A second follow-up paper will deal with its internal structure. We hypothesize that black holes a... This is the first paper in a two part series on black holes. In this work, we concern ourselves with the event horizon. A second follow-up paper will deal with its internal structure. We hypothesize that black holes are 4-dimensional spatial, steady state, self-contained spheres filled with black-body radiation. As such, the event horizon marks the boundary between two adjacent spaces, 4-D and 3-D, and there, we consider the radiative transfers involving black- body photons. We generalize the Stefan-Boltzmann law assuming that photons can transition between different dimensional spaces, and we can show how for a 3-D/4-D interface, one can only have zero, or net positive, transfer of radiative energy into the black hole. We find that we can predict the temperature just inside the event horizon, on the 4-D side, given the mass, or radius, of the black hole. For an isolated black hole with no radiative heat inflow, we will assume that the temperature, on the outside, is the CMB temperature, T2 = 2.725 K. We take into account the full complement of radiative energy, which for a black body will consist of internal energy density, radiative pressure, and entropy density. It is specifically the entropy density which is responsible for the heat flowing in. We also generalize the Young- Laplace equation for a 4-D/3-D interface. We derive an expression for the surface tension, and prove that it is necessarily positive, and finite, for a 4-D/3-D membrane. This is important as it will lead to an inherently positively curved object, which a black hole is. With this surface tension, we can determine the work needed to expand the black hole. We give two formulations, one involving the surface tension directly, and the other involving the coefficient of surface tension. Because two surfaces are expanding, the 4-D and the 3-D surfaces, there are two radiative contributions to the work done, one positive, which assists expansion. The other is negative, which will resist an increase in volume. The 4-D side promotes expansion whereas the 3-D side hinders it. At the surface itself, we also have gravity, which is the major contribution to the finite surface tension in almost all situations, which we calculate in the second paper. The surface tension depends not only on the size, or mass, of the black hole, but also on the outside surface temperature, quantities which are accessible observationally. Outside surface temperature will also determine inflow. Finally, we develop a “waterfall model” for a black hole, based on what happens at the event horizon. There we find a sharp discontinuity in temperature upon entering the event horizon, from the 3-D side. This is due to the increased surface area in 4-D space, AR(4) = 2π2R3, versus the 3-D surface area, AR(3) = 4πR2. This leads to much reduced radiative pressures, internal energy densities, and total energy densities just inside the event horizon. All quantities are explicitly calculated in terms of the outside surface temperature, and size of a black hole. Any net radiative heat inflow into the black hole, if it is non-zero, is restricted by the condition that, 0cdQ/dt FR(3), where, FR(3), is the 3-D radiative force applied to the event horizon, pushing it in. We argue throughout this paper that a 3-D/3-D interface would not have the same desirable characteristics as a 4-D/3-D interface. This includes allowing for only zero or net positive heat inflow into the black hole, an inherently positive finite radiative surface tension, much reduced temperatures just inside the event horizon, and limits on inflow. 展开更多
关键词 BLACK Holes 4-D SPATIAL BALLS BLACK Body Radiation Stefan-Boltzmann law Young-Laplace RELATION
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利用点击化学合成pH敏感型有机硅树脂
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作者 赵维 李玉红 +2 位作者 魏华 何佳 宋瑶 《化学工程师》 CAS 2023年第3期88-91,共4页
本实验以八甲基环四硅氧烷(D_(4))、γ-甲基丙烯酰氧基丙基三乙基硅烷(KH-570)、六甲基二硅氧烷(MM)、二甲基亚砜(DMSO)为原料,在KOH催化下,于80~90℃水浴加热,磁力搅拌下反应得到有机硅大分子。通过红外光谱分析表明,分子中引入双键。... 本实验以八甲基环四硅氧烷(D_(4))、γ-甲基丙烯酰氧基丙基三乙基硅烷(KH-570)、六甲基二硅氧烷(MM)、二甲基亚砜(DMSO)为原料,在KOH催化下,于80~90℃水浴加热,磁力搅拌下反应得到有机硅大分子。通过红外光谱分析表明,分子中引入双键。再利用点击化学的方法,使其与不同量的巯基乙酸通过C=C双键加成反应得到系列带羧基有机硅树脂。通过红外光谱分析表明,双键消失并且引入羧基,从而得到了目标产物。并采用了质量变化法研究了其pH敏感性能。将产物分别加入不同pH值的缓冲溶液中,测定其质量变化率随反应时间变化,结果表明,该树脂具有强的pH敏感性,且在pH值为9时,巯基乙酸加入量为3mL的产物的重量变化率最大,达到28%。 展开更多
关键词 D4 PH敏感性 点击化学
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热处理工艺对黏结剂喷射3D打印17−4PH不锈钢微观组织与性能的影响
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作者 林海涛 陈凌 +1 位作者 付志强 陈维平 《精密成形工程》 北大核心 2023年第3期120-127,共8页
目的探究热处理工艺对黏结剂喷射3D打印17−4PH不锈钢样品微观组织、力学性能及电化学腐蚀性能的影响规律,为BJ3DP技术制备综合性能良好的17−4PH不锈钢零件提供参考。方法基于黏结剂喷射3D打印技术制备17−4PH不锈钢生坯,并将其固化、脱... 目的探究热处理工艺对黏结剂喷射3D打印17−4PH不锈钢样品微观组织、力学性能及电化学腐蚀性能的影响规律,为BJ3DP技术制备综合性能良好的17−4PH不锈钢零件提供参考。方法基于黏结剂喷射3D打印技术制备17−4PH不锈钢生坯,并将其固化、脱脂、烧结,得到烧结态样品,然后对烧结态样品进行热处理,热处理工艺为在1040℃固溶热处理2 h,随后分别在410、480、550℃下热处理3 h后空冷至室温。对烧结态和热处理态样品进行金相试验、单向拉伸试验以及电化学腐蚀试验。结果经热处理后,试样在480℃时效热处理3 h时力学性能提升最为显著,其屈服强度由608 MPa提升至806 MPa,抗拉强度由1159 MPa提升至1245 MPa,伸长率由3.6%提升至13.6%。当时效热处理温度提升至550℃时,由于沉淀相的粗化,其力学性能有所下降;同时,电化学腐蚀性能中腐蚀电流密度(Jcorr)减小,腐蚀电位(Ecorr)增大,电荷转移电阻(Rct)增大,出现明显的钝化区。结论黏结剂喷射3D打印17−4PH不锈钢经热处理后力学性能得到提升,试样在480℃时效热处理3 h时力学性能提升最为显著,优于商用热轧17−4PH不锈钢,电化学腐蚀性能与商用热轧17−4PH不锈钢电化学腐蚀性能水平相当。 展开更多
关键词 黏结剂喷射3D打印 17−4PH不锈钢 热处理工艺 力学性能 电化学腐蚀性能
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长期服役长隧洞衬砌裂缝分布规律与仿真分析
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作者 李翔宇 李军 +3 位作者 王海军 张继勋 汤雷 王倩 《水利水电技术(中英文)》 北大核心 2023年第1期108-118,共11页
【目的】由于已建输调水隧洞工程均埋于地下,盲运时间较长,随着服役时间的增长,隧洞衬砌产生裂缝病害,严重影响运行安全,因此研究衬砌裂缝发生的规律极为重要。【方法】对某运行20 a的隧洞素混凝土衬砌裂缝进行现状调查和现场检测,基于... 【目的】由于已建输调水隧洞工程均埋于地下,盲运时间较长,随着服役时间的增长,隧洞衬砌产生裂缝病害,严重影响运行安全,因此研究衬砌裂缝发生的规律极为重要。【方法】对某运行20 a的隧洞素混凝土衬砌裂缝进行现状调查和现场检测,基于现场检测数据分析,揭示该素混凝土衬砌病害发生的部位、类型、裂纹密集程度等规律,并进行初步成因分析。为进一步揭示该隧洞裂缝病害的成因和主控因素,基于Flac3D软件,开展典型洞段衬砌结构的三维数值仿真分析,得到了初始地应力、衬砌厚度、外水压力等对衬砌工作性态的影响,揭示了裂缝密集程度的主控因素。【结果】结果显示:(1)裂缝是该素混凝土隧洞衬砌中最为广泛的病害;(2)单位隧洞长度下的裂缝密集程度从高到低,依次为Ⅱ、Ⅲ、Ⅳ、Ⅴ类围岩洞段;(3)衬砌厚度、地应力、外水压力是影响单位隧洞长度下的裂缝密集程度不同的主要因素。【结论】数值模拟计算结果反映了衬砌裂缝密度差异的原因与现场检测结果一致。研究结果为水工隧洞建设与长效运维提供了参考。 展开更多
关键词 引水隧洞 长期服役 素混凝土衬砌 裂缝分布规律 三维数值仿真
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利用光谱分析技术检测氢离子浓度
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作者 肖婷 丁文卿 +4 位作者 廖育城 陈虹宇 张箫扬 肖昊瑾 廖浩翔 《物理实验》 2023年第11期14-18,共5页
利用光谱分析技术可对无色水溶液pH值进行测定,该方法能够快速便捷地检测溶液中氢离子浓度.首先通过酸碱指示剂对待测溶液进行显色处理,再利用光谱仪对其各波长吸光度进行测量.在指示剂变色范围内,吸收光谱曲线将出现多个吸收峰,通过测... 利用光谱分析技术可对无色水溶液pH值进行测定,该方法能够快速便捷地检测溶液中氢离子浓度.首先通过酸碱指示剂对待测溶液进行显色处理,再利用光谱仪对其各波长吸光度进行测量.在指示剂变色范围内,吸收光谱曲线将出现多个吸收峰,通过测量各吸收峰峰值,并计算其比值,结合朗伯-比尔定律代入由定标溶液确定的比值函数曲线,得到待测溶液的pH值.由于采用比值计算,该方法操作简便易行,无须要求每次滴入指示剂的量相同,可在实验室中对溶液样本快速地进行pH值测量,且结果误差小于0.05. 展开更多
关键词 氢离子浓度 光谱分析 PH值 朗伯-比尔定律
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博士研究生多元奖助体系探索与实践——以西南交通大学为例
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作者 陈志伟 周先礼 +1 位作者 黄亚楠 田杨 《科教导刊》 2023年第1期38-40,共3页
在研究生教育全面收费的背景下,奖助体系是博士研究生获得学习生活保障、激发其科研积极性的重要措施,也是博士研究生培养工作的重要组成部分。本研究首先对研究生奖助体系进行梳理,以西南交通大学为例,通过引入双因素理论将博士研究生... 在研究生教育全面收费的背景下,奖助体系是博士研究生获得学习生活保障、激发其科研积极性的重要措施,也是博士研究生培养工作的重要组成部分。本研究首先对研究生奖助体系进行梳理,以西南交通大学为例,通过引入双因素理论将博士研究生奖助体系分为为博士研究生提供生活保障的“支撑因素”和提高博士研究生科研积极性的“激励因素”。最后,探讨了现有奖助体系各组成部分与博士研究生培养之间的内在联系,并根据分析为博士研究生多元奖助体系的优化提供思路。 展开更多
关键词 博士研究生 奖助体系 科研动力 双因素理论
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基于3D打印和丝网印刷制作的电化学微流控反应器及其在DNA四面体上的应用
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作者 张武凯 谢瑶 +6 位作者 靳聪 刘沛川 高月 姜丁瑞 张栩源 李茜 陈翔 《微纳电子技术》 CAS 北大核心 2023年第7期1139-1148,共10页
为了能够实现快速、低成本的制作电化学微流控反应器,并将其用于电化学合成DNA四面体,利用纳米材料结合丝网印刷技术构建低成本的pH敏感电极,利用3D打印技术制作牺牲层管道以及框架结构用于快速构建带有盐桥的微反应池,并开发了微型恒... 为了能够实现快速、低成本的制作电化学微流控反应器,并将其用于电化学合成DNA四面体,利用纳米材料结合丝网印刷技术构建低成本的pH敏感电极,利用3D打印技术制作牺牲层管道以及框架结构用于快速构建带有盐桥的微反应池,并开发了微型恒电位控制电路。实验结果表明,基于TiO2与Co3O4的丝网印刷pH敏感电极可以对2~12的pH值进行敏感测量,并且可以通过在其与Ag/AgCl电极之间施加恒电位逆向调控溶液的pH值。将基于3D打印结合丝网印刷制作的电化学微流控反应器搭配微型恒电位控制电路用于电化学合成DNA四面体。实验结果表明,该系统可合成不同碱基长度20 bp、26 bp、37 bp的DNA四面体,时间为6 min,相比于传统热法合成DNA四面体需要30 min,时间大为缩短。该种制作工艺可应用于电化学合成DNA四面体,并具有微型化、集成化、低成本制作电化学微流控反应器的发展潜力。 展开更多
关键词 3D打印 丝网印刷 电化学微流控反应器 DNA四面体 纳米材料 pH敏感电极
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A Numerical Simulation of Air Flow in the Human Respiratory System Based on Lung Model
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作者 Md. Kamrul Hasan Mahtab U. Ahmmed Md. Samsul Arefin 《Journal of Applied Mathematics and Physics》 2023年第8期2205-2215,共11页
The lung is an important organ that takes part in the gas exchange process. In the study of gas transport and exchange in the human respiratory system, the complicated process of advection and diffusion (AD) in airway... The lung is an important organ that takes part in the gas exchange process. In the study of gas transport and exchange in the human respiratory system, the complicated process of advection and diffusion (AD) in airways of human lungs is considered. The basis of a lumped parameter model or a transport equation is modeled during the inspiration process, when oxygen enters into the human lung channel. The quantitative measurements of oxygen are detached and the model equation is solved numerically by explicit finite difference schemes. Numerical simulations were made for natural breathing conditions or normal breathing conditions. The respiratory flow results for the resting conditions are found strongly dependent on the AD effect with some contribution of the unsteadiness effect. The contour of the flow rate region is labeled and AD effects are compared with the variation of small intervals of time for a constant velocity when breathing is interrupted for a negligible moment. 展开更多
关键词 Lumped Model Lumped Model Channel Mass Flow Rate Ideal law of Gas 2D Advection Diffusion Equation Finite Difference Scheme
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Scaling laws governing the elastic properties of 3D graphenes
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作者 LI Ming LU Guo +2 位作者 YU HaoDong LI MengLei ZHENG FaWei 《Science China(Technological Sciences)》 SCIE EI CAS CSCD 2024年第6期1748-1756,共9页
In this study,we comprehensively investigated the scaling law for elastic properties of three-dimensional honeycomb-like graphenes(3D graphenes)using hybrid neural network potential-based molecular dynamics simulation... In this study,we comprehensively investigated the scaling law for elastic properties of three-dimensional honeycomb-like graphenes(3D graphenes)using hybrid neural network potential-based molecular dynamics simulations and theoretical analyses.The elastic constants were obtained as functions of honeycomb hole size,denoted by the graphene wall length L.All five independent elastic constants in the large-L limit are proportional to L^(-1).The associated coefficients are combinations of elastic constants of two-dimensional graphene.High-order terms including L^(-2)and L^(-3)emerge for finite L values.They have three origins,the distorted areas close to the joint lines of 3D graphenes,the variation in solid angles between graphene plates,and the bending distortion of graphene plates.Significantly,the chirality becomes essential with decreasing L because the joint line structures are different between the armchair and zigzag-type 3D graphenes.Our findings provide insights into the elastic properties of graphene-based superstructures and can be used for further studies on graphene-based materials. 展开更多
关键词 scaling law neural network elastic properties 3D graphene
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木聚糖酶XYNB的N46D突变、表达及酶学性质变化 被引量:12
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作者 杨浩萌 柏映国 +5 位作者 李江 罗会颖 王亚茹 伍宁丰 范云六 姚斌 《中国生物化学与分子生物学报》 CAS CSCD 北大核心 2006年第3期204-211,共8页
对来源于Streptomyces olivaceoviridis的高比活木聚糖酶XYNB进行同源建模和同源序列比较,发现第11族木聚糖酶的催化结构域在β折叠股A3和B3之间存的一个保守的氨基酸位点,该位点与木聚糖酶的pH特性有关.据此设计了XYNB的N46D定点突变.... 对来源于Streptomyces olivaceoviridis的高比活木聚糖酶XYNB进行同源建模和同源序列比较,发现第11族木聚糖酶的催化结构域在β折叠股A3和B3之间存的一个保守的氨基酸位点,该位点与木聚糖酶的pH特性有关.据此设计了XYNB的N46D定点突变.将突变酶XYNBN46D在毕赤酵母中表达,表达的XYNBN46D经纯化后与原酶XYNB(同样经毕赤酵母表达后纯化)进行酶学性质比较,结果表明,XYNBN46D的最适pH值由5·2下降到4·2,pH稳定性也向酸性pH偏移,同时,热稳定性和最适温度也有一定的提高,但酶的比活性显著下降.结果证实,木聚糖酶XYNB的第46位Asn与其最适pH值相关.对导致酶学性质改变的可能因素进行了分析,结果为进一步的结构与功能研究提供了资料. 展开更多
关键词 木聚糖酶 XYNBN46D 定点突变 pH特性
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D2EHPA萃取回收Cr(Ⅲ)的研究 被引量:9
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作者 霍小平 秦炜 +1 位作者 孙晓玮 戴猷元 《高校化学工程学报》 EI CAS CSCD 北大核心 2007年第5期849-852,共4页
以回收废水中Cr(Ⅲ)为目的,选择2-乙基己基磷酸(D2EHPA)为萃取剂,煤油为稀释剂,进行了萃取回收Cr(Ⅲ)的实验研究。考察了皂化剂种类、溶液pH值、助溶剂种类、萃取剂浓度等因素对于萃取平衡影响以及三种无机酸、两种有机酸对于负载Cr(Ⅲ)... 以回收废水中Cr(Ⅲ)为目的,选择2-乙基己基磷酸(D2EHPA)为萃取剂,煤油为稀释剂,进行了萃取回收Cr(Ⅲ)的实验研究。考察了皂化剂种类、溶液pH值、助溶剂种类、萃取剂浓度等因素对于萃取平衡影响以及三种无机酸、两种有机酸对于负载Cr(Ⅲ)的D2EHPA反萃效果的影响。结果表明,pH值是影响D2EHPA/煤油萃取Cr(Ⅲ)的重要因素,在pH<2时,D2EHPA几乎不萃取Cr(Ⅲ),通过萃取剂的皂化,提高水相pH值,可以实现D2EHPA萃取Cr(Ⅲ)。随平衡水相pH值的升高,D2EHPA显示出良好的萃取效果。NaOH溶液作为皂化剂比氨水的分相效果好。加入助溶剂后萃取效率提高,其中10%~20%正辛醇是适宜的助溶剂选择。D2EHPA/正辛醇/煤油萃取Cr(Ⅲ)后立即用无机酸或有机酸反萃,其中硫酸、盐酸或草酸的反萃率能够达到90%以上。 展开更多
关键词 D2EHPA 皂化 PH值 正辛醇
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