Unexpected Twinning and Phase-Transition of the Indentation Standards, Their Transition Energies, and Scientific Dichotomy

The general use of aluminium as an indentation standard for the iteration of contact heights for the determination of ISO-14577 hardness and elastic modulus is challenged because of as yet not appreciated phase-changes in the physical force-depth standard curve that seemed to be secured by claims from 1992. The physical and mathematical analyses with closed formulas avoid the still world-wide standardized energy-law violation by not reserving 33.33% (h2 belief) (or 20% h3/2 physical law) of the loading force and thus energy for all not depth producing events but using 100% for the depth formation is a severe violation of the energy law. The not depth producing part of the indentation work cannot be done with zero energy! Both twinning and structural phase-transition onsets and normalized phase-transition energies are now calculated without iterations but with physically correct closed arithmetic equations. These are reported for Berkovich and cubecorner indentations, including their comparison on geometric grounds and an indentation standard without mechanical twinning is proposed. Characteristic data are reported. This is the first detection of the indentation twinning of aluminium at room temperature and the mechanical twinning of fused quartz is also new. Their disqualification as indentation standards is established. Also, the again found higher load phase-transitions disqualify aluminium and fused quartz as ISO-ASTM 14577 (International Standardization Organization and American Society for Testing and Materials) standards for the contact depth “hc” iterations. The incorrect and still world-wide used black-box values for H- and Er-values (the latter are still falsely called “Young’s moduli” even though they are not directional) and all mechanical properties that depend on them. They lack relation to bulk moduli from compression experiments. Experimentally obtained and so published force vs depth parabolas always follow the linear FN = kh3/2 + Fa equation, where Fa is the axis-cut before and after the phase-transition branches (never “h2” as falsely enforced and used for H, Er and giving incorrectly calculated parameters). The regression slopes k are the precise physical hardness values, which for the first time allow for precise calculation of the mechanical qualities by indentation in relation to the geometry of the indenter tip. Exactly 20% of the applied force and thus energy is not available for the indentation depth. Only these scientific k-values must be used for AI-advises at the expense of falsely iterated indentation hardness H-values. Any incorrect H-ISO-ASTM and also the iterated Er-ISO-ASTM modulus values of technical materials in artificial intelligence will be a disaster for the daily safety. The AI must be told that these are unscientific and must therefore be replaced by physical data. Iterated data (3 and 8 free parameters!) cannot be transformed into physical data. One has to start with real experimental loading curves and an absolute ZerodurR standard that must be calibrated with standard force and standard length to create absolute indentation results. .

Physical Nanoindentation: From Penetration Resistance to Phase-Transition Energies

-The ISO standard 14577 is challenged for its violation of the energy law, its wrong relation of normal force FN with impression depth h, and for its iterative treatments. The solution of this dilemma is the use of sacrosanct simplest calculation rules for the loading parabola (now FN = kh3/2) giving straight lines for cones, pyramids and wedges. They provide the physical penetration resistance hardness k with dimension [Nm-3/2] and allow for non-iterative calculations with closed formulas, using simple undeniable calculation rules. The physically correct FN versus h3/2 plot is universally valid. It separates out the most common surface effects and reveals gradients. It provides unmatched precision, including reliability checks of experimental data. Regression analysis of FN versus h3/2 plots reveals eventual unsteadiness kink phase-transition onset with the transition-energy. This is shown for all kinds of solid materials, including salts, silicon, organics, polymers, composites, and superalloys. Exothermic and endothermic single and consecutive multiple phase-transitions with their surface dependence are distinguished and the results compared in 5 Tables. The sharp phase-transition onsets and the transition energies provide unprecedented most important materials’ characteristics that are indispensable for safety reasons. ISO ASTM is thus urged to thoroughly revise ISO 14577 and to work out new standards for the mechanically (also thermally) stressed materials. For example, the constancy of the first phase-transition parameters must be controlled, and materials must only be admitted for maximal forces well below the first phase-transition onset. Such onset loads can now be easily calculated. The nevertheless repeated oppositions against the physical analysis of indentations rest on incredibly poor knowledge of basic mathematics, errors that are uncovered. The safety aspects caused by the present unphysical materials’ parameters are discussed.

Magnetism and phase-transitional analysis of nano-metal gadolinium

The structures,grain sizes and magnetism were analyzed and computed for three typical samples:the stock of polycrystalline metal Gd(sample 1),the bulk nanocrystalline Gd prepared by spark plasma sintering(SPS) technique and subjected to the annealing process of 623 K for 0.5 h(sample 2) and the bulk nanocrystalline Gd prepared by the SPS technique at 573 K(sample 3).The computation results indicated that the sample 3 had the efficiency of space filling up to 99.38%.The computation results of magnetization i...

Finding Short-Range Parity-Time Phase-Transition Points with a Neural Network

The non-Hermitian PT-symmetric system can live in either unbroken or broken PT-symmetric phase. The separation point of the unbroken and broken PT-symmetric phases is called the PT-phase-transition point.Conventionally, given an arbitrary non-Hermitian PT-symmetric Hamiltonian, one has to solve the corresponding Schrodinger equation explicitly in order to determine which phase it is actually in. Here, we propose to use artificial neural network(ANN) to determine the PT-phase-transition points for non-Hermitian PT-symmetric systems with short-range potentials. The numerical results given by ANN agree well with the literature, which shows the reliability of our new method.

MEMS-actuated terahertz metamaterials driven by phase-transition materials

The non-ionizing and penetrative characteristics of terahertz(THz)radiation have recently led to its adoption across a variety of applications.To effectively utilize THz radiation,modulators with precise control are imperative.While most recent THz modulators manipulate the amplitude,frequency,or phase of incident THz radiation,considerably less progress has been made toward THz polarization modulation.Conventional methods for polarization control suffer from high driving voltages,restricted modulation depth,and narrow band capabilities,which hinder device performance and broader applications.Consequently,an ideal THz modulator that offers high modulation depth along with ease of processing and operation is required.In this paper,we propose and realize a THz metamaterial comprised of microelectromechanical systems(MEMS)actuated by the phase-transition material vanadium dioxide(VO_(2)).Simulation and experimental results of the three-dimensional metamaterials show that by leveraging the unique phase-transition attributes of VO_(2),our THz polarization modulator offers notable advancements over existing designs,including broad operation spectrum,high modulation depth,ease of fabrication,ease of operation condition,and continuous modulation capabilities.These enhanced features make the system a viable candidate for a range of THz applications,including telecommunications,imaging,and radar systems.

Dual-functional bacterial cellulose modified with phase-transitioned proteins and gold nanorods combining antifouling and photothermal bactericidal properties

Bacterial cellulose(BC)is one of the most versatile natural biopolymers with unique physical,chemical,and biological features.However,the lack of intrinsic antibacterial property of native BC limits its broad biomedical applications where such property is highly required to prevent contamination or infection caused by attached bacteria.In this work,we developed a simple and facile method to fabricate a dualfunctional BC membrane by physical incorporation of gold nanorods(GNRs)followed by deposition of a phase-transitioned bovine serum albumin(PTB)film.Due to the broad-spectrum antifouling property of the PTB film,the resulting membrane could prevent the adhesion and accumulation of bacteria.A few bacteria that broke through the protection of the PTB film could be eradicated under short-term irradiation of a near-infrared laser due to the excellent photothermal property of incorporated GNRs.The whole fabrication was conducted in a simple and environmentally friendly manner,avoiding complicated processes and toxic organic solvents.Moreover,because all the components were biocompatible,the resulting membrane showed negligible cytotoxicity in vitro and good histocompatibility in vivo.This work thus provided a reliable way to endow BC with antibacterial property,being beneficial for diverse biomedical applications.

Cellular automaton model considering headway-distance effect

This paper presents a cellular automaton model for single-lane traffic flow. On the basis of the Nagel-Schreckenberg （NS） model, it further considers the effect of headway-distance between two successive cars on the randomization of the latter one. In numerical simulations, this model shows the following characteristics. （1） With a simple structure, this model succeeds in reproducing the hysteresis effect, which is absent in the NS model. （2） Compared with the slow-tostart models, this model exhibits a local fundamental diagram which is more consistent to empirical observations. （3） This model has much higher efficiency in dissolving congestions compared with the so-called NS model with velocitydependent randomization （VDR model）. （4） This model is more robust when facing traffic obstructions. It can resist much longer shock times and has much shorter relaxation times on the other hand. To summarize, compared with the existing models, this model is quite simple in structure, but has good characteristics.

Cluster-size dependent randomization traffic flow model

In order to exhibit the meta-stable states, several slow-to-start rules have been investigated as modification to Nagel-Schreckenberg （NS） model. These models can reproduce some realistic phenomena which are absent in the original NS model. But in these models, the size of cluster is still not considered as a useful parameter. In real traffic, the slow-to-start motion of a standing vehicle often depends on the degree of congestion which can be measured by the clusters＇ size. According to this idea, we propose a cluster-size dependent slow-to-start model based on the speed- dependent slow-to-start rule （VDR） model. It gives expected results through simulations. Comparing with the VDR model, our new model has a better traffic efficiency and shows richer complex characters.

Water Gas Shift Reaction： A Monte Carlo Simulation

The water gas shift （WGS） reaction is reacts with water on a catalytic surface a process of industrial importance to form CO2 and H2. We study this In this reaction carbon monoxide reaction with thermal （Langmuir- Hinshelwood） and non-thermal （precursor and Eley-Rideal） reaction mechanisms using the techniques of Monte Carlo computer simulation. The details of surface coverages and production rates are given as a function of CO partial pressure. The diffusion of species on the surface as well as their desorption from the surface is also introduced to include temperature effects. The phase diagrams of the system have been drawn to observe the behaviour of reacting species on the surface. The study reveals that the production rates are higher for non-thermal precursor mechanism and are in agreement with the experimental finding.

Electron Transport Property of CdTe under High Pressure and Moderate Temperature by In-Situ Resistivity Measurement in Diamond Anvil Cell

In situ resistivity measurement has been performed to investigate the electron transport property of powered CdTe under high pressure and moderate temperature in a designed diamond anvil cell. Several abnormal resistivity changes can be found at room temperature when the pressure increases from ambient to 33 GPa. The abnormal resistivity changes at about 3.8 GPa and 10 GPa are caused by the structural phase transitions to the rock-salt phase and to the Cmcm phase, respectively. The other abnormal resistivity changes at about 6.5 GPa, 15.5 GPa, 22.2 GPa and about 30 GPa never observed before are due to the electronic phase transitions of CdTe. The origin of the abnormal change occurred at about 6.5 GPa is discussed. The temperature dependence of the resistivity of CdTe shows its semiconducting behaviour at least before 11.3 GPa.

Real and Fitted Spherical Indentations

Spherical indentations that rely on original date are analyzed with the physically correct mathematical formula and its integration that take into account the radius over depth changes upon penetration. Linear plots, phase-transition onsets, energies, and pressures are algebraically obtained for germanium, zinc-oxide and gallium-nitride. There are low pressure phase-transitions that correspond to, or are not resolved by hydrostatic anvil onset pressures. This enables the attribution of polymorph structures, by comparing with known structures from pulsed laser deposition or molecular beam epitaxy and twinning. The spherical indentation is the easiest way for the synthesis and further characterization of polymorphs, now available in pure form under diamond calotte and in contact with their corresponding less dense polymorph. The unprecedented results and new possibilities require loading curves from experimental data. These are now easily distinguished from data that are “fitted” to make them concur with widely used unphysical Johnson’s formula for spheres (“P = (4/3)h3/2R1/2E∗”) not taking care of the R/h variation. Its challenge is indispensable, because its use involves “fitting equations” for making the data concur. These faked reports (no “experimental” data) provide dangerous false moduli and theories. The fitted spherical indentation reports with radii ranging from 4 to 250 μm are identified for PDMS, GaAs, Al, Si, SiC, MgO, and Steel. The detailed analysis reveals characteristic features.

Undue Hardness/Modulus Ratio Claims instead of Physical Penetration Resistance and Applications with Mollusk Shells

The Nanoindentation is a precise technique for the elucidation of mechanical properties. But such elucidation requires physically based interpretation of the loading curves that is widely still not practiced. The use of indentation hardness H and indentation modulus Er is unphysical and cannot detect the most important phase-transitions under load that very often occur. The claim that H versus E plots relate linearly for all different materials is neither empirically found nor correctly deduced. It is most dangerous by producing incorrect materials properties and misleading. The use of H/E (that is also called “elasticity index”) in complicated formulas for brittle parameter, yield strength, toughness, and so-called “true hardness” is also in error. The use of H/E cannot reveal the true qualities of materials without considering phase-transitions under load that require the correct exponent 3/2 on h for the loading curves (instead of disproved 2). This is exemplified with the physical data of different mollusk shells that experience phase-transitions, a new bionics model, and different contributions for their strengthening. The data are compared to the ones of aragonite and calcite and vaterite.

Finite Element Method on Shape Memory Alloy Structure and Its Applications

It is significant to numerically investigate thermo-mechanical behaviors of shape memory alloy(SMA)structures undergoing large and uneven deformation for they are used in many engineering fields to meet special requirements To solve the problems of convergence in the numerical simulation on thermo-mechanical behaviors of SMA structures by universal finite element software.This work suppose a finite element method to simulate the super-elasticity and shape memory effect in the SMA structure undergoing large and uneven deformation.Two scalars,named by phase-transition modulus and equivalent stiffness,are defined to make it easy to establish and implement the finite element method for a SMA structure.An incremental constitutive equation is developed to formulate the relationship of stress,strain and temperature in a SMA material based on phase-transition modulus and equivalent stiffness.A phase-transition modulus equation is derived to describe the relationship of phase-transition modulus,stress and temperature in a SMA material during the processes of martensitic phase transition and martensitic inverse phase transition.A finite element equation is established to express the incremental relationship of nodal displacement,external force and temperature change in a finite element discrete structure of SMA.The incremental constitutive equation,phase-transition modulus equation and finite element equation compose the supposed finite element method which simulate the thermo-mechanical behaviors of a SMA structure.Two SMA structures,which undergo large and uneven deformation,are numerically simulated by the supposed finite element method.Results of numerical simulation show that the supposed finite element method can effectively simulate the super-elasticity and shape memory effect of a SMA structure undergoing large and uneven deformation,and is suitable to act as an effective computational tool for the wide applications based on the SMA materials.

Transition Temperature of Two-Degenerate-Flavour QCD in the Chiral Limit

We present the results for the transition temperature of quantum chromodynamics （QCD） with two degenerate flavours （Nf = 2） of Wilson quarks. On lattice 8^3 × 4 with 4 representing the temporal extent, by using the Ferrenberg-Swendsen reweighting method, we determine the critical β = 6/g^2 where the transition occurs, g is the coupling constant. On lattice 8^2 × 20 × 4, by using the axial vector Ward-Takahashi identity, we calculate the current quark mass amq, a is the lattice spacing. Assuming the O（4） scaling, the critical β in the chiral limit is determined. We calculate the p meson mass amp at zero temperature on lattice 8^3 × 20. By using the experimental p meson mass to set the scale, we obtain 194（1） MeV for the transition temperature in the chiral limit.

In-Situ Conductivity Measurement of BaF2 under High Pressure and High Temperature

We perform the in-situ conductivity measurement on BaF2 at high pressure using a microcircuit fabricated on a diamond anvil cell. The results show that BaF2 initially exhibits the electrical property of an insulator at pressure below 25 GPa, it transforms to a wide energy gap semiconductor at pressure from 25 to 30 GPa, and the conductivity increases gradually with increasing pressure from 30 GPa. However, the metallization predicted by theoretical calculation at 30-33 GPa cannot be observed. In addition, we measure the temperature dependence of the conductivity at several pressures and obtain the relationship between the energy gap and pressure. Based on the experimental data, it is predicted that BaF2 would transform to a metal at about 87 GPa and ambient temperature. The conductivity of BaF2 reaches the order of 10^-3Ω^-1 cm^-1 at 37 GPa and 2400 K, the superionic conduction is not observed during the experiments, indicating the application of pressure elevates greatly the transition temperature of the superionic conduction.

Monte Carlo Study of CO-NO Catalytic Surface Reaction Including CO-CO Repulsion

The CO-NO reaction on a catalytic surface is studied by using Langmuir-Hinshclwood thermal mechanism with Monte Carlo computer simulation. In this model, a novel concept of CO CO repulsion is introduced, which has experimental evidence due to the formation of dipoles when these molecules are chemisorbed on the surface. The system is investigated by applying two approaches of NO dissociation. In the first ca.se, NO always decomposes into N and O before adsorption on the surface, In the second case, NO adsorbs on the surface molecularly and then dissociates into N and O if a vacancy is present in its adjacent neighbourhood. The steady state reactive window （i.e. the continuous production of CO2 and N2） is obtained only with the diffusion of N-atoms on the surface, which extends with CO-CO repulsion in the first, case. Itowever, in the second case, reactive window is obtained with CO-CO repulsion alone, The reactive window width in this case is reasonably large. The first-order phase transition is eliminated in both the cases with CO-CO repulsion.

Block Entanglement in the Single-Hole Hubbard Model

We investigate the distribution of the entanglement of the one-dimensional single-hole Hubbard model （HM） and study the relationship between the entanglement and quantum phase transition in the model. The von Neumann entropy of a block with neighbouring spins L for a single-hole HM is calculated using the densitymatrix renormalization group. The distributions of the entanglement entropy in the ground state, as a function of block length, show a dramatic effect, i.e. effectively decoupling with the centres, no matter how the Coulomb interaction u 〉0 or u 〈0. Contrarily, for the Coulomb interaction u = 0 or close to zero, the entanglement entropy in the single-hole model reaches a saturation value for a certain block size. For a fixed size L = 40, the ground state entanglement entropy measure, as a function of u1 shows a peak corresponding to the critical quantum phase transition.

Ultralow fouling electrochemical detection of uric acid directly in serum based on phase-transited bovine serum albumin and conducting polymer

Electrochemistry with antifouling sensing interfaces that effectively resist the adsorption of nonspecific biomolecules provides a powerful mean for the accurate and sensitive detection of disease biomarkers tive dete in complex biofluids.However.there are few strategies to acquire a stable and solid antifouling coat-ing on any substrate by a simple way.Herein,a simple one-step assembly methød has been adopted to construct phase-transited bovine serum albumin(PTB)antifouling Layers.Prior to construction of the an-tifouling layers.the poly(3,4-ethylenedioxythiophene)(PEDOT)doped with 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide(ionic liquid,IL)were firstly electrodeposited on bare electrodes,en-dowing good conductiviry and catalytic capability for the developed sensor.Subsequently.with the assist of tris(2-carboxyethyl)phosphine(TCEP)the disulfide bonds of bovine serum albumin(BSA)were re-Im alb duced to form PTB,which can be coated on the PEDOT-It modified electrode to construct an antifouling electrochemical senor(PTB/PEDOT-ILCCE)for the detection of uric acid(UA)in human serum.The UA sensor demonstrated a good linear range from 1.11 umol/L to 798.9 umol/L with a high sensltivity of0,556 jA umolL^(-1)cm^(-2).The combination of conducting polymers with one-step assembly of PTB offers a universal and rellable method før the modification of various electrodes to determine target molecules in complex human body fluids.

Highly selective adsorption of rhenium by amyloid-like protein material

Rhenium separation from molybdenum in molybdenite minerals and waste leachate has become an emerging challenge.Addressing this challenge,we prepared a set of protein-based alkylamine/alkylammonium salts complexes as extractants for selective uptake of rhenium from molybdenum,where the protein component turned into the insoluble amyloid-like structure when its internal disulfide bonds were reduced,namely phase-transition process.Among them,the phase-transited lysozyme and methyletrioctyleammonium chloride complex(PTL-N263)exhibited the most efficient adsorption at the alkaline condition for the electrostatic interaction between negatively charged metal ions with positively charged center(R_(4)N^(+))in N263,where negatively charged protein residues hindered the ion exchange of Cl^(-)in N263 for larger size Mo species(Mo_(7)O_(24)^(6-))than smaller size Re species(ReO^(4-)).The adsorption follows the Freundlich model and pseudo-second-order kinetics,which exhibits toplevel adsorption performance with a maximum adsorption capacity of 124 mg/g and a separation factor(β_(Re/Mo))of 2.78×10^(3)for Re.The adsorption capacity per unit area(57.2 mg/(g m^(2)))is 1.6–41 times higher than previously reported adsorbents,and the cost for adsorbing 1 g of Re(VII)is$1.07,indicating its industrial capability.This adsorption strategy can be applied to separating Re from Mo in binary solutions and industrial wastewater with other competing ions.

In-situ and one-step preparation of protein film in capillary column for open tubular capillary electrochromatography enantioseparation

In this wo rk,the phase-transitioned BSA(PTB)film using the mild and fast fabrication process adhered to the capillary inner wall uniformly,and the fabricated PTB film-coated capillary column was applied to realize open tubular capillary electrochromatography(OT-CEC)enantioseparation.The enantioseparation ability of PTB film-coated capillary was evaluated with eight pairs of chiral analytes including drugs and neurotransmitters,all achieving good resolution and symmetrical peak shape.For three consecutive runs,the relative standard deviations(RSD)of migration time for intra-day,inter-day,and column-tocolumn repeatability were in the range of 0.3%-3.5%,0.2%-4.9%and 2.1%-7.7%,respectively.Moreover,the PTB film-coated capillary column ran continuously over 300 times with high separation efficiency.Therefore,the coating method based on BSA self-assembly supramolecular film can be extended to the preparation of other proteinaceous capillary columns.