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Characterization of tricalcium phosphate solubilization by Stenotrophomonas maltophilia YC isolated from phosphate mines 被引量:1
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作者 肖春桥 池汝安 +1 位作者 何环 张文学 《Journal of Central South University》 SCIE EI CAS 2009年第4期581-587,共7页
The phosphate solubilizing characteristics of a strain YC, which was isolated from phosphate mines (Hubei, China), were studied in National Botanical Research Institute’s phosphate (NBRIP) growth medium containing tr... The phosphate solubilizing characteristics of a strain YC, which was isolated from phosphate mines (Hubei, China), were studied in National Botanical Research Institute’s phosphate (NBRIP) growth medium containing tricalcium phosphate (TCP) as sole phosphorus (P) source. The strain YC is identified as Stenotrophomonas maltophilia (S. maltophilia) based upon the results of morphologic, physiological and biochemical characteristics and 16S rRNA sequences analysis. The results show that the strain S. maltophilia YC can solubilize TCP and release soluble P in NBRIP growth medium. A positive correlation between concentration of soluble P and population of the isolate and a negative correlation between concentration of soluble P and pH in the culture medium are observed from statistical analysis results. Moreover, gluconic acid is detected in the culture medium by HPLC analysis. It indicates that the isolate can release gluconic acid during the solubilizing experiment, which causes acidification of the culture medium and then TCP solubilization. S. maltophilia YC has a maximal TCP solubilizing capability when using maltose as carbon source and ammonium nitrate as nitrogen source, respectively, in NBRIP growth medium. 展开更多
关键词 tricalcium phosphate (TCP) Stenotrophomonas maltophilia (S. maltophilia) phosphate mines phosphorus (P) gluconic acid
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Cyclostratigraphy Data as a Proxy for Geoelectrical Data Interpretation: Application to Phosphate Minerals Exploration in Matam (Senegal)
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作者 Mapathe Ndiaye Seydou Coulibaly +1 位作者 Winimi Saratou Zouwinaba Issa Ba 《Open Journal of Geology》 2014年第10期551-570,共20页
The vertical electrical soundings on the Matam region phosphates deposits are interpreted by inversion. To retrieve lithology from the obtained resistivities, mechanical drilling was performed to compare directly the ... The vertical electrical soundings on the Matam region phosphates deposits are interpreted by inversion. To retrieve lithology from the obtained resistivities, mechanical drilling was performed to compare directly the lithologies and the geoelectrical resistivities. The obtained relation is not simple and is not sufficient to interpret all the VES. This situation motivated the collection of supplementary information from cyclostratigraphy. Geoelectrical and cyclostratigraphic?information is combined using fuzzy logic techniques to build a fuzzy inference system. The obtained results seem to be consistent with the stratigraphy of the investigated region and allow retrieving lithological succession. Further investigations are necessary for more accurate thickness determination. 展开更多
关键词 CYCLOSTRATIGRAPHY Geoelectrical VERTICAL Electrical SOUNDING phosphate Matam Fuzzy LOGIC
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Assessment of the Heavy Metals and Natural Radioactivity in Phosphate Mines and Occupational Health Effects at Some Egyptian Regions
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作者 E. R. Atta Kh. M. Zakaria M. S. Ibrahim 《Journal of Environmental Protection》 2016年第11期1657-1669,共13页
In this work, the specific activities of natural radionuclides, namely <sup>238</sup>U series, <sup>232</sup>Th series and <sup>40</sup>K, have been measured in collected sedimentar... In this work, the specific activities of natural radionuclides, namely <sup>238</sup>U series, <sup>232</sup>Th series and <sup>40</sup>K, have been measured in collected sedimentary phosphate deposits samples from El-Hamraween, El-Quser and Safaga phosphate mines in Egypt. HPGe γ-spectrometry was used. This study was undertaken to estimate the radiation hazard indices in phosphate mining at the studied mines on their occupational workers, to establish correlation relationships between the some measured heavy metals such as As, Cd and Pb in blood workers and their concentration in phosphate rock ores and to determinate the biomarkers in the blood workers such as malondialdehyde (MDA) and superoxide dismutase (SOD). The phosphate mine sample of El-Hamrawein has the lowest activity concentration of <sup>226</sup>Ra, <sup>232</sup>Th and <sup>40</sup>K in comparison to the phosphate mine samples of El-Quseir and Safaga (El-Hamrawein kg<sup>-</sup>1</sup><sup></sup>, 122.4 to 188.3 Bq·kg<sup>-</sup>1</sup></sup> and 115.4 to 165.8 Bq·kg<sup>-</sup>1</sup></sup> for Safaga, El-Quseir and El-Hamrawein, respectively. For <sup>232</sup>Th activity concentrations varied from 135.6 to 212.3 Bq·kg<sup>-</sup>1</sup></sup>, 112.8 to 167.4 Bq·kg<sup>-</sup>1</sup></sup> and 132.8 to 188.6 Bq·kg<sup>-</sup>1</sup></sup> for Safaga, El-Quseir and El-Hamrawein, respectively. For <sup>40</sup>K activity concentrations varied from 225.2 to 312.8 Bq·kg<sup>-</sup>1</sup>, 168.7 to 268.9 Bq·kg<sup>-</sup>1</sup></sup> and 95.2 to 155.8 Bq·kg<sup>-</sup>1</sup></sup> for Safaga, El-Quseir and El-Hamrawein, respectively. The workers of old ages have higher concentration of the investigated heavy metals than those of young ages. There is a good relation between the concentration of the investigated metals in phosphate mine samples and their concentration in blood of the occupational workers in these mines. 展开更多
关键词 Superoxide Dismutase MALONDIALDEHYDE Natural Radionuclides Heavy Metals phosphate Occupational Workers Health Effects
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Purification Effect of Constructed Wetlands for Treating River Water Flowing from Phosphate Mine Areas into Fuxian Lake
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作者 WANG Lin KE Fan +2 位作者 FENG Mu-hua SUN Pei-shi ZHU Hui-xian 《Meteorological and Environmental Research》 2012年第7期38-41,共4页
[ Objective] The study aimed at discussing the purification effect of constructed wetlands for treating river water flowing from phosphate mine areas into Fuxian Lake. [Method] The running parameters of the constructe... [ Objective] The study aimed at discussing the purification effect of constructed wetlands for treating river water flowing from phosphate mine areas into Fuxian Lake. [Method] The running parameters of the constructed wetlands were investigated for one year, and the purification effect of the constructed wetlands for treating the sewage from phosphate mine areas was analyzed. [Result] With the aid of the constructed wet- land, the average removal rates of total nitrogen (TN), total phosphorus (TP) and CODcr were 52%, 32% and 54%, and the removal effects were best when the designed hydraulic load was 0.67 m3/( m2 · d). Running stably for six years, the constructed wetlands had advantages of no power, low resistance and high removal rate. [ Conclusion] The constructed wetlands reduced the load of pollutants from phosphate mine areas into Fuxian Lake effectivelv, which Dlaved important roles in the Drotection of water aualitv of Fuxian Lake. 展开更多
关键词 Fuxian Lake Dongda River phosphate removing Constructed wetlands China
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Novel interface engineering of LDH-based materials on Mg alloy for efficient photocatalytic systems considering the geometrical linearity of condensed phosphates 被引量:3
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作者 Mosab Kaseem Ananda Repycha Safira Arash Fattah-alhosseini 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2024年第1期267-280,共14页
This study presents a facile and rapid method for synthesizing novel Layered Double Hydroxide(LDH)nanoflakes,exploring their application as a photocatalyst,and investigating the influence of condensed phosphates'g... This study presents a facile and rapid method for synthesizing novel Layered Double Hydroxide(LDH)nanoflakes,exploring their application as a photocatalyst,and investigating the influence of condensed phosphates'geometric linearity on their photocatalytic properties.Herein,the Mg O film,obtained by plasma electrolysis of AZ31 Mg alloys,was modified by growing an LDH film,which was further functionalized using cyclic sodium hexametaphosphate(CP)and linear sodium tripolyphosphate(LP).CP acted as an enhancer for flake spacing within the LDH structure,while LP changed flake dispersion and orientation.Consequently,CP@LDH demonstrated exceptional efficiency in heterogeneous photocatalysis,effectively degrading organic dyes like Methylene blue(MB),Congo red(CR),and Methyl orange(MO).The unique cyclic structure of CP likely enhances surface reactions and improves the catalyst's interaction with dye molecules.Furthermore,the condensed phosphate structure contributes to a higher surface area and reactivity in CP@LDH,leading to its superior photocatalytic performance compared to LP@LDH.Specifically,LP@LDH demonstrated notable degradation efficiencies of 93.02%,92.89%,and 88.81%for MB,MO,and CR respectively,over a 40 min duration.The highest degradation efficiencies were observed in the case of the CP@LDH sample,reporting 99.99%for MB,98.88%for CR,and 99.70%for MO.This underscores the potential of CP@LDH as a highly effective photocatalyst for organic dye degradation,offering promising prospects for environmental remediation and water detoxification applications. 展开更多
关键词 Plasma electrolysis Layered Double Hydroxide Condensed phosphates Adsorption capacity Photocatalytic efficiency
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Effect of safety valve types on the gas venting behavior and thermal runaway hazard severity of large-format prismatic lithium iron phosphate batteries 被引量:2
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作者 Zhuangzhuang Jia Yuanyuan Min +5 位作者 Peng Qin Wenxin Mei Xiangdong Meng Kaiqiang Jin Jinhua Sun Qingsong Wang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第2期195-207,I0006,共14页
The safety valve is an important component to ensure the safe operation of lithium-ion batteries(LIBs).However,the effect of safety valve type on the thermal runaway(TR)and gas venting behavior of LIBs,as well as the ... The safety valve is an important component to ensure the safe operation of lithium-ion batteries(LIBs).However,the effect of safety valve type on the thermal runaway(TR)and gas venting behavior of LIBs,as well as the TR hazard severity of LIBs,are not known.In this paper,the TR and gas venting behavior of three 100 A h lithium iron phosphate(LFP)batteries with different safety valves are investigated under overheating.Compared to previous studies,the main contribution of this work is in studying and evaluating the effect of gas venting behavior and TR hazard severity of LFP batteries with three safety valve types.Two significant results are obtained:(Ⅰ)the safety valve type dominates over gas venting pressure of battery during safety venting,the maximum gas venting pressure of LFP batteries with a round safety valve is 3320 Pa,which is one order of magnitude higher than other batteries with oval or cavity safety valve;(Ⅱ)the LFP battery with oval safety valve has the lowest TR hazard as shown by the TR hazard assessment model based on gray-fuzzy analytic hierarchy process.This study reveals the effect of safety valve type on TR and gas venting,providing a clear direction for the safety valve design. 展开更多
关键词 Lithium iron phosphate battery Safety valve Thermal runaway Gas venting behavior Thermal runaway hazard severity Gray-fuzzy analytic hierarchy process
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Efficient Removal of Phosphate from Aqueous Solutions Using Corundum-hollow-spheres Supported Caclined Hydrotalcite Porous Thin Films
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作者 刘云才 ZHU Chen 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第1期44-49,共6页
Phosphate was removed from aqueous environment by corundum-hollow-spheres supported caclined hydrotalcite (cHT) thin films. Mg-Al-CO3 hydrotalcite (HT) thin films were deposited on corundumhollow-sphere substrates by ... Phosphate was removed from aqueous environment by corundum-hollow-spheres supported caclined hydrotalcite (cHT) thin films. Mg-Al-CO3 hydrotalcite (HT) thin films were deposited on corundumhollow-sphere substrates by hydrothermal homogeneous precipitation at 120℃for 30-240 min and cHT thin films were obtained by annealing of the HT thin films at 500℃for 180 min. Their crystal phase, morphology and microstructure were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM).The results show that homogeneous, well-crystallized and hierarchical flower-like thin films were deposited firmly on the surface of the corundum. The mechanism of nucleation and growth of the HT thin films was fitted well with the anion coordination polyhedron growth unit model. To determine the absorption of phosphate by this adsorbent, different bed depth (10-30 cm) and flow rate (1.0-3.0 m L/min) were examined by column experiments. The highest removal efficiency of phosphate amounted to 98.5%under optimum condition (pH=7.2). The adsorption capacity increased as the bed depth increased and decreased as the flow rate increased. 展开更多
关键词 adsorption phosphate HYDROTALCITE corundum-hollow-sphere hydrothermal homogeneous precipitation thermal anneal
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Enhancing sustainability in phosphate ore processing:Performance of frying oil as alternative flotation collector for carbonate removal
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作者 Asmae El-bahi Yassine Taha +2 位作者 Yassine Ait-Khouia Abdellatif Elghali Mostafa Benzaazoua 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2024年第4期557-571,共15页
Recycling waste frying oils for the synthesis of flotation reagents presents a promising avenue for sustainable waste management.Moreover,it offers a cost-effective solution for crafting a specialized collector design... Recycling waste frying oils for the synthesis of flotation reagents presents a promising avenue for sustainable waste management.Moreover,it offers a cost-effective solution for crafting a specialized collector designed to efficiently remove carbonates and enhance phosphate enrichment in froth flotation processes.This study focuses on the synthesis of an anionic collector using the saponification reaction of a frying oil sample,subsequently applied to the flotation of calcite and dolomite.To elucidate the adsorption mechanisms of the frying oil collector(FrOC)and sodium oleate,a reference collector,on fluorapatite,calcite,dolomite,and quartz surfaces,comprehensive experiments were conducted,including zeta potential measurements and Fourier transform infrared spectroscopy.Results revealed diverse adsorption affinities of the molecules towards these minerals.To assess the practical performance of the collector,flotation tests were conducted using a natural phosphate ore mixture,employing a BoxBehnken experimental design.Notably,under optimized conditions(pH 9,1000 g/t of FrOC,3.5 min of conditioning,and 6 min of flotation),FrOC exhibited excellent performance,with calcite and dolomite recoveries exceeding 80%,while apatite recovery in the concentrate fraction remained below 10%.This work exemplifies both circular economy practices and the distinctive approach to sustainable mineral processing. 展开更多
关键词 Frying oils recycling phosphate beneficiation Flotation separation Green surfactants SUSTAINABILITY
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Gadolinium-doped injectable magnesium-calcium phosphate bone cements for noninvasive visualization
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作者 Polina A.Krokhicheva Margarita A.Goldberg +12 位作者 Alexander S.Fomin Dinara R.Khayrutdinova Olga S.Antonova Margarita A.Sadovnikova Ivan V.Mikheev Aleksander V.Leonov Ekaterina M.Merzlyak Daria A.Kovalishina Suraya A.Akhmedova Natalia S.Sergeeva Marat R.Gafurov Sergey M.Barinov Vladimir S.Komlev 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2024年第9期3698-3716,共19页
Injectable bone cements are used in minimally invasive surgical techniques including vertebroplasty and kyphoplasty.This work is devoted to the development of magnesium-calcium phosphate cements(MCPCs)doped with gadol... Injectable bone cements are used in minimally invasive surgical techniques including vertebroplasty and kyphoplasty.This work is devoted to the development of magnesium-calcium phosphate cements(MCPCs)doped with gadolinium ions(Gd^(3+))for bone defect repair.Interaction between cement powders and a cement liquid resulted in the formation of newberyite and brushite phases,which gave mechanical strength up to 17 MPa without a thermal effect.The introduction of Gd3+into the lattice was confirmed by electron paramagnetic resonance spectroscopy;the doping increased injectivity while giving rise to antibacterial properties against Escherichia coli.Assays of the cement samples soaking in Kokubo’s simulated body fluid revealed the formation of calcium phosphate coatings on the cements’surface.The cements manifested biocompatibility with the MG-63 cell line and significantly enhanced contrast when Gd-MCPC was placed into a bone defect and examined by X-ray micro-computed tomography.For the first time,visualization of a Gd-doped cement material was achieved in a model of a bone defect analyzed by MRI. 展开更多
关键词 Magnesium-calcium phosphate cement GADOLINIUM INJECTIVITY Antibacterial properties CYTOCOMPATIBILITY
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Surface-neutralization engineered NiCo-LDH/phosphate hetero-sheets toward robust oxygen evolution reaction
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作者 Shunfa Zhou Yuxuan Liu +4 位作者 Jing Li Zhao Liu Jiawei Shi Liyuan Fan Weiwei Cai 《Green Energy & Environment》 SCIE EI CAS CSCD 2024年第7期1151-1158,共8页
Developing highly active oxygen evolution reaction(OER)electrocatalysts with robust durability is essential in producing high-purity hydrogen through water electrolysis.Layered double hydroxide(LDH)based catalysts hav... Developing highly active oxygen evolution reaction(OER)electrocatalysts with robust durability is essential in producing high-purity hydrogen through water electrolysis.Layered double hydroxide(LDH)based catalysts have demonstrated efficient catalytic performance toward the relatively sluggish OER.By considering the promotion effect of phosphate(Pi)on proton transfer,herein,a facile phosphate acid(PA)surface-neutralization strategy is developed to in-situ construct NiCo-LDH/NiCoPi hetero-sheets toward OER catalysis.OER activity of NiCoLDH is significantly boosted due to the proton promotion effect and the electronic modulation effect of NiCoPi.As a result,the facilely prepared NiCo-LDH/NiCoPi catalyst displays superior OER catalytic activity with a low overpotential of 300 mV to deliver 100 mA cm^(-2)OER and a Tafel slope of 73 mV dec^(-1).Furthermore,no visible activity decay is detected after a 200-h continuous OER operation.The present work,therefore,provides a promising strategy to exploit robust OER electrocatalysts for commercial water electrolysers. 展开更多
关键词 Oxygen evolution reaction phosphate Layered double hydroxide Hetero-sheets Stability
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In-situ construction of abundant active centers on hierarchically porous carbon electrode toward high-performance phosphate electrosorption: Synergistic effect of electric field and capture sites
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作者 Peng Zhang Fukuan Li +6 位作者 Mingming He Silu Huo Xueli Zhang Benqiang Cen Dezhi Fang Kexun Li Hao Wang 《Green Energy & Environment》 SCIE EI CAS CSCD 2024年第1期126-137,共12页
Phosphate removal is crucial for eutrophication control and water quality improvement.Electro-assisted adsorption,an eco-friendly elec-trosorption process,exhibited a promising potential for wastewater treatment.Howev... Phosphate removal is crucial for eutrophication control and water quality improvement.Electro-assisted adsorption,an eco-friendly elec-trosorption process,exhibited a promising potential for wastewater treatment.However,there are few works focused on phosphate electro-sorption,and reported electrodes cannot attach satisfactory removal capacities and rates.Herein,electro-assisted adsorption of phosphate via in-situ construction of La active centers on hierarchically porous carbon(LaPC)has been originally demonstrated.The resulted LaPC composite not only possessed a hierarchically porous structure with uniformly dispersed La active sites,but also provided good conductivity for interfacial electron transfer.The LaPC electrode achieved an ultrahigh phosphate electrosorption capability of 462.01 mg g^(-1) at 1 V,outperforming most existing electrodes.The superior phosphate removal performance originates from abundant active centers formed by the coupling of electricfield and capture sites.Besides,the stability and selectivity toward phosphate capture were maintained well even under comprehensive conditions.Moreover,a series of kinetics and isotherms models were employed to validate the electrosorption process.This work demonstrates a deep understanding and promotes a new level of phosphate electrosorption. 展开更多
关键词 Electro-assisted adsorption ELECTROSORPTION phosphate removal Active centers MOF-derived carbon
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Immunomodulatory activity of polycaprolactone nanoparticles with calcium phosphate salts against Leishmania infantum infection
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作者 Kübra Kelleci Adil Allahverdiyev +2 位作者 Melahat Bağırova Murat Ihlamur EmrahŞefik Abamor 《Asian Pacific Journal of Tropical Biomedicine》 SCIE CAS 2024年第8期359-368,共10页
Objective:To prepare and characterize polycaprolactone(PCL)nanoparticles loaded with sonicator fragmented(SLA)and freeze-thaw Leishmania antigens(FTLA)and to investigate the in vitro immunogenicity of antigen-encapsul... Objective:To prepare and characterize polycaprolactone(PCL)nanoparticles loaded with sonicator fragmented(SLA)and freeze-thaw Leishmania antigens(FTLA)and to investigate the in vitro immunogenicity of antigen-encapsulated nanoparticles with calcium phosphate adjuvant.Methods:The water/oil/water binary emulsion solvent evaporation method was used to synthesize antigen-loaded PCL nanoparticles.Particles were characterized by scanning electron microscopy and zeta potential measurements.Their cytotoxicity in J774 macrophages in vitro was determined by MTT analysis.In addition,the amount of nitric oxide and the level of cytokines produced by macrophages were determined by Griess reaction and ELISA method,respectively.The protective effect of the developed formulations was evaluated by determining the infection index percentage in macrophages infected with Leishmania infantum.Results:Compared to the control group,SLA PCL and FTLA PCL nanoparticles with calcium phosphate adjuvant induced a 6-and 7-fold increase in nitric oxide,respectively.Additionally,the vaccine formulations promoted the production of IFN-γand IL-12.SLA PCL and FTLA PCL nanoparticles combined with calcium phosphate adjuvant caused an approximately 13-and 11-fold reduction in infection index,respectively,compared to the control group.Conclusions:The encapsulation of antigens obtained by both sonication and freeze-thawing into PCL nanoparticles and the formulations with calcium phosphate adjuvant show strong in vitro immune stimulating properties.Therefore,PCL-based antigen delivery systems and calcium phosphate adjuvant are recommended as a potential vaccine candidate against leishmaniasis. 展开更多
关键词 LEISHMANIASIS Calcium phosphate POLYCAPROLACTONE NANOPARTICLE Antigen delivery system ADJUVANT Vaccine design
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Effect of Fluoride on the Ion-association of Calcium Phosphate and Crystallization of Hydroxyapatite
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作者 宋昊月 CAI Meng +1 位作者 袁萍 邹朝勇 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第4期831-838,共8页
Using a titration setup to accurately control the reaction conditions and in situ monitor the reaction,we showed that fluoride exhibited negligible effects on the ion association process of calcium and phosphate and t... Using a titration setup to accurately control the reaction conditions and in situ monitor the reaction,we showed that fluoride exhibited negligible effects on the ion association process of calcium and phosphate and the formation of ACP nanospheres in a buffer solution with constant ionic strength.However,the stability of ACP increased with increasing fluoride concentration,which was ascribed to the inhibitory effect of fluoride on the aggregation of ACP nanospheres and the nucleation of nanocrystals on the surface of ACP nanospheres.Furthermore,fluoride could inhibit the lateral growth of HAP nanosheets and promote the formation of rod-like crystals.These results further improve our understanding of the crystallization pathway of HAP crystals and the regulatory effects of fluoride. 展开更多
关键词 CRYSTALLIZATION amorphous calcium phosphate HYDROXYAPATITE FLUORIDE
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Preparation and interface state of phosphate tailing-based geopolymers
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作者 ZHANG Shou-xun XIE Xian +4 位作者 XIE Rui-qi TONG Xiong WU Yu-yao LI Jia-wen LI Yue 《Journal of Central South University》 SCIE EI CAS CSCD 2024年第6期1900-1914,共15页
The long-term storage of phosphate tailings will occupy a large amount of land,pollute soil and groundwater,thus,it is crucial to achieve the harmless disposal of phosphate tailings.In this study,high-performance geop... The long-term storage of phosphate tailings will occupy a large amount of land,pollute soil and groundwater,thus,it is crucial to achieve the harmless disposal of phosphate tailings.In this study,high-performance geopolymers with compressive strength of 38.8 MPa were prepared by using phosphate tailings as the main raw material,fly ash as the active silicon-aluminum material,and water glass as the alkaline activator.The solid content of phosphate tailings and fly ash was 60% and 40%,respectively,and the water-cement ratio was 0.22.The results of XRD,FTIR,SEM-EDS and XPS show that the reactivity of phosphate tailings with alkaline activator is weak,and the silicon-aluminum material can react with alkaline activator to form zeolite and gel,and encapsulate/cover the phosphate tailings to form a dense phosphate tailings-based geopolymer.During the formation of geopolymers,part of the aluminum-oxygen tetrahedron replaced the silicon-oxygen tetrahedron,causing the polycondensation reaction between geopolymers and increasing the strength of geopolymers.The leaching toxicity test results show that the geopolymer has a good solid sealing effect on heavy metal ions.The preparation of geopolymer from phosphate tailings is an important way to alleviate the storage pressure and realize the resource utilization of phosphate tailings. 展开更多
关键词 phosphate tailing GEOPOLYMER interface state toxicity leaching
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Non-flammable long chain phosphate ester based electrolyte via competitive solventized structures for high-performance lithium metal batteries
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作者 Li Liao Zhiqiang Han +16 位作者 Xuanjie Feng Pan Luo Jialin Song Yin Shen Xiaoshuang Luo Xinpeng Li Xuanzhong Wen Bo Yu Junchen Chen Bingshu Guo Mingshan Wang Yun Huang Hongmei Zhang Mengmeng Yin Jiangtao Liu Yuanhua Lin Xing Li 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第10期156-165,I0004,共11页
Safety remains a persistent challenge for high-energy-density lithium metal batteries(LMBs).The development of safe and non-flammable electrolytes is especially important in harsh conditions such as high temperatures.... Safety remains a persistent challenge for high-energy-density lithium metal batteries(LMBs).The development of safe and non-flammable electrolytes is especially important in harsh conditions such as high temperatures.Herein,a flame-retardant,low-cost and thermally stable long chain phosphate ester based(tributyl phosphate,TBP)electrolyte is reported,which can effectively enhance the cycling stability of highly loaded high-nickel LMBs with high safety through co-solvation strategy.The interfacial compatibility between TBP and electrode is effectively improved using a short-chain ether(glycol dimethyl ether,DME),and a specially competitive solvation structure is further constructed using lithium borate difluorooxalate(LiDFOB)to form the stable and inorganic-rich electrode interphases.Benefiting from the presence of the cathode electrolyte interphase(CEI)and solid electrolyte interphase(SEI)enriched with LiF and Li_(x)PO_(y)F_(z),the electrolyte demonstrates excellent cycling stability assembled using a 50μm lithium foil anode in combination with a high loading NMC811(15.4 mg cm^(-2))cathode,with 88%capacity retention after 120 cycles.Furthermore,the electrolyte exhibits excellent high-temperature characteristics when used in a 1-Ah pouch cell(N/P=0.26),and higher thermal runaway temperature(238℃)in the ARC(accelerating rate calorimeter)demonstrating high safety.This novel electrolyte adopts long-chain phosphate as the main solvent for the first time,and would provide a new idea for the development of extremely high safety and high-temperature electrolytes. 展开更多
关键词 Non-flammable electrolyte Long chain phosphate ester Solvation structure Lithium metal batteries Battery safety
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Natural variation in ZmGRF10 regulates tolerance to phosphate deficiency in maize by modulating phosphorus remobilization
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作者 Yankai Wang Xiaohui Peng +10 位作者 Xuechun Lian Qi Yu Lingli Zhang Tingting Li Haoyu Luo Tingting Li Kaili Yu Wenli Zhang Deyi Zhong Yonghui Zhao Shengben Li 《The Crop Journal》 SCIE CSCD 2024年第5期1414-1425,共12页
Phosphorus is a limiting factor in agriculture due to restricted availability in soil and low utilization efficiency of crops.The identification of superior haplotypes of key genes responsible for low-phosphate(Pi)tol... Phosphorus is a limiting factor in agriculture due to restricted availability in soil and low utilization efficiency of crops.The identification of superior haplotypes of key genes responsible for low-phosphate(Pi)tolerance and their natural variation is important for molecular breeding.In this study,we conducted genome-wide association studies on low-phosphate tolerance coefficients using 152 maize inbred lines,and identified a significant association between SNPs on chromosome 7 and a low-phosphate tolerance coefficient.ZmGRF10 was identified as a candidate gene involved in adaptation of maize to Pi starvation.Expression of ZmGRF10 is induced by Pi starvation.A mutation in ZmGRF10 alleviated Pi starvation stress.RNA-seq analyses revealed significant upregulation of genes encoding various phosphatases in the zmgrf10-1 mutant,suggesting that ZmGRF10 negatively regulates expression of these genes,thereby affecting low-Pi tolerance by suppressing phosphorus remobilization.A superior haplotype with variations in the promoter region exhibited lower transcription activity of ZmGRF10.Our study unveiled a novel gene contributing to tolerance to low-Pi availability with potential to benefit molecular breeding for high Pi utilization. 展开更多
关键词 CORN phosphate utilization efficiency GWAS Phosphorus metabolism
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Excavation compensation and bolt support for a deep mine drift
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作者 Longji Guo Zhigang Tao +1 位作者 Manchao He Massimo Coli 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2024年第8期3206-3220,共15页
To overcome large deformation of deep phosphate rock roadways and pillar damage,a new type of constant-resistance large-deformation negative Poisson’s ratio(NPR)bolt that can withstand a high prestress of at least 13... To overcome large deformation of deep phosphate rock roadways and pillar damage,a new type of constant-resistance large-deformation negative Poisson’s ratio(NPR)bolt that can withstand a high prestress of at least 130 KN was developed.In the conducted tests,the amount of deformation was 200-2000 mm,the breaking force reached 350 KN,and a high constant-resistance pre-stress was maintained during the deformation process.A stress compensation theory of phosphate rock excavation based on NPR bolts is proposed together with a balance system for bolt compensation of the time-space effect and high NPR pre-stress.Traditional split-set rock bolts are unable to maintain the stability of roadway roofs and pillars.To verify the support effect of the proposed bolt,field tests were conducted using both the proposed NPR bolts and split-set rock bolts as support systems on the same mining face.In addition,the stress compensation mechanism of roadway mining was simulated using the particle flow code in three dimensions(PFC^(3D))-fast Lagrangian analysis of continua(FLAC^(3D))particle-flow coupling numerical model.On-site monitoring and numerical simulations showed that the NPR excavation compensation support scheme effectively improves the stress state of the bolts and reduces the deformation of the surrounding rock.Compared to the original support scheme,the final deformation of the surrounding rock was reduced by approximately 70%.These results significantly contribute to domestic and foreign research on phosphate-rock NPR compensation support technology,theoretical systems,and engineering practices,and further promote technological innovation in the phosphate rock mining industry. 展开更多
关键词 Deep phosphate rock NPR bolt Split-set rock bolt PFC3D-FLAC3D Compensation support
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Preparation and Reinforcement Adaptability of Jute Fiber Reinforced Magnesium Phosphate Cement Based Composite Materials
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作者 刘芯州 郭远臣 +3 位作者 WANG Rui XIANG Kai WANG Xue YE Qing 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第4期999-1009,共11页
To improve the brittleness characteristics of magnesium phosphate cement-based materials(MPC)and to promote its promotion and application in the field of structural reinforcement and repair,this study aimed to increas... To improve the brittleness characteristics of magnesium phosphate cement-based materials(MPC)and to promote its promotion and application in the field of structural reinforcement and repair,this study aimed to increase the toughness of MPC by adding jute fiber,explore the effects of different amounts of jute fiber on the working and mechanical properties of MPC,and prepare jute fiber reinforced magnesium phosphate cement-based materials(JFRMPC)to reinforce damaged beams.The improvement effect of beam performance before and after reinforcement was compared,and the strengthening and toughening mechanisms of jute fiber on MPC were explored through microscopic analysis.The experimental results show that,as the content of jute fiber(JF)increases,the fluidity and setting time of MPC decrease continuously;When the content of jute fiber is 0.8%,the compressive strength,flexural strength,and bonding strength of MPC at 28 days reach their maximum values,which are increased by 18.0%,20.5%,and 22.6%compared to those of M0,respectively.The beam strengthened with JFRMPC can withstand greater deformation,with a deflection of 2.3 times that of the unreinforced beam at failure.The strain of the steel bar is greatly reduced,and the initial crack and failure loads of the reinforced beam are increased by 192.1%and 16.1%,respectively,compared to those of the unreinforced beam.The JF added to the MPC matrix dissipates energy through tensile fracture and debonding pull-out,slowing down stress concentration and inhibiting the free development of cracks in the matrix,enabling JFRMPC to exhibit higher strength and better toughness.The JF does not cause the hydration of MPC to generate new compounds but reduces the amount of hydration products generated. 展开更多
关键词 magnesium phosphate cement jute fiber reinforcement of damaged beam flexural behavior
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Fluid-Related Performances and Compressive Strength of Clinker-Free Cementitious Backfill Material Based on Phosphate Tailings
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作者 Jin Yang Senye Liu +3 位作者 Xingyang He Ying Su Jingyi Zeng Bohumír Strnadel 《Fluid Dynamics & Materials Processing》 EI 2024年第9期2077-2090,共14页
Phosphate tailings are usually used as backfill material in order to recycle tailings resources.This study considers the effect of the mix proportions of clinker-free binders on the fluidity,compressive strength and o... Phosphate tailings are usually used as backfill material in order to recycle tailings resources.This study considers the effect of the mix proportions of clinker-free binders on the fluidity,compressive strength and other key performances of cementitious backfill materials based on phosphate tailings.In particular,three solid wastes,phosphogypsum(PG),semi-aqueous phosphogypsum(HPG)and calcium carbide slag(CS),were selected to activate wet ground granulated blast furnace slag(WGGBS)and three different phosphate tailings backfill materials were prepared.Fluidity,rheology,settling ratio,compressive strength,water resistance and ion leaching behavior of backfill materials were determined.According to the results,when either PG or HPG is used as the sole activator,the fluidity properties of the materials are enhanced.Phosphate tailings backfill material activated with PG present the largest fluidity and the lowest yield stress.Furthermore,the backfill material’s compressive strength is considerably increased to 2.9 MPa at 28 days after WGGBS activation using a mix of HPG and CS,all with a settling ratio of only 1.15 percent.Additionally,all the three ratios of binder have obvious solidification effects on heavy metal ions Cu and Zn,and P in phosphate tailings. 展开更多
关键词 FLUIDITY RHEOLOGY compressive strength phosphate tailing backfill material
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Differential roles of C-3 and C-6 phosphate monoesters in affecting potato starch properties
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作者 Li Ding Andreas Blennow Yuyue Zhong 《Grain & Oil Science and Technology》 CAS 2024年第2期79-86,共8页
The effects of starch phosphate monoester content(SPC),namely C-3(C3P)and C-6 phosphate monoesters(C6P),on the starch properties were investigated using four potato starches with varied SPC/C3P/C6P and two nonphosphor... The effects of starch phosphate monoester content(SPC),namely C-3(C3P)and C-6 phosphate monoesters(C6P),on the starch properties were investigated using four potato starches with varied SPC/C3P/C6P and two nonphosphorylated maize starches with a similar range of amylose content(AC)as controls.The starch property results showed that a higher SPC is associated with lower turbidity,storage and loss modulus after storage,and water solubility,but higher swelling power(SP)and pasting viscosities.These findings suggested that SPC inhibited molecular rearrangement during storage and starch leaching during heating,and enhanced swelling and viscosities due to increased hydration and water uptake caused by the repulsion effect of phosphate groups and a less ordered crystalline structure.Increased SPC also resulted in lower resistant starch(RS)content in a native granular state but higher RS after retrogradation.Pearson correlations further indicated that SPC/C3P/C6P were positively correlated with peak(r^(2)=0.925,0.873 and 0.930,respectively),trough(r^(2)=0.994,0.968 and 0.988,respectively),and final viscosities(r^(2)=0.981,0.968 and 0.971,respectively).Notably,SPC,mainly C3P,exhibited a significantly positive correlation with SP(r^(2)=0.859)and setback viscosity(r^(2)=0.867),whereas SPC,mainly C6P,showed a weak positive correlation with RS after retrogradation(r^(2)=0.746).However,SPC had no significant correlations with water solubility,turbidity and rheology properties,which were more correlated with AC.These findings are helpful for the food industry to select potato starches with desired properties based on their contents of SPC,C3P,or C6P. 展开更多
关键词 Starch phosphate monoesters C-3 phosphate monoesters C-6 phosphate monoesters Physicochemical properties In vitro digestibility
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