For the first time,two-dimensional FeOCl(Fe_(1-x)Co_(x)OCl)doped with Co was successfully applied to the photocatalytic and photo-Fenton degradation of Rhodamine B(RhB).The photocatalytic and photo-Fenton experiments ...For the first time,two-dimensional FeOCl(Fe_(1-x)Co_(x)OCl)doped with Co was successfully applied to the photocatalytic and photo-Fenton degradation of Rhodamine B(RhB).The photocatalytic and photo-Fenton experiments showed that the degradation rates of RhB by Fe0.94Co0.06OCl are 82.6%and 98.2%within 50 min under neutral solution,room temperature and visible light.The inclusion of Co resulted in lattice imperfections on the surface of Fe OCl,which was advantageous for the photogenerated electron-hole pair separation efficiency(consistent with the density functional theory calculation).Moreover,the RhB removal rate decreased from 98%to 82%during five successive cycles,showing good structural stability.Finally,based on the radical capture experiment,a potential mechanism for RhB degradation by Fe_(1-x)Co_(x)OCl catalyst was proposed.The idea of a synergistic mechanism for Fe_(1-x)Co_(x)OCl also offers a fresh concept for catalysts used in doping modification.展开更多
In this paper,the residue from bamboo factory has been used to design photo-Fenton catalyst,which has the advantages of low cost and magnetic recycling.The photo-Fenton catalytic performance of the biocarbon-based cat...In this paper,the residue from bamboo factory has been used to design photo-Fenton catalyst,which has the advantages of low cost and magnetic recycling.The photo-Fenton catalytic performance of the biocarbon-based catalyst was excellent and its optimal preparation process was also explored by response surface methodology.First,bamboo-carbon fiber was selected as the photo-Fenton catalyst carrier.Subsequently,the surface of the car-bon fiber was modified,with which dopamine,nano-Fe_(3)O_(4) and nano-TiO_(2) were successively loaded by hydro-thermal method.After the single factor tests,four factors including dopamine concentration,ferric chloride mass,P25 titanium dioxide mass and liquid-solid ratio were selected as the characteristic values.The degradation efficiency of photo-Fenton catalyst to methylene blue(MB)solution was treated as the response value.After the analysis of the response surface optimization,it was shown that the significance sequence of the selected 4 factors in terms of the MB degradation efficiency was arranged as follows:dopamine concentration>liquid-solid ratio>P25 titanium dioxide quality>ferric chloride quality.The optimal process parameters of fiber-carbon catalyst were affirmed as follows:the 1.7 mg/mL concentration of dopamine,the 1.2 g mass of ferric chloride,the 0.2 g mass of P25 titanium dioxide and the liquid-solid ratio of 170 mL/g.The experiment-measured average MB degra-dation efficiency performed by the optimized catalyst was 99.3%,which was nearly similar to the model-predicted value of 98.9%.It showed that the prediction model and response surface model were accurate and reliable.The results from response surface optimization could provide a good reference to design bamboo-based Fenton-like catalyst with excellent catalytic performance.展开更多
Both citrate and hypophosphite in aqueous solution were degraded by advanced oxidation processes （Fe^2＋/H2O2, UV/Fe^2＋/H2O2, and electrolysis/Fe^2＋/H2O2） in this study. Comparison of these techniques in oxidation...Both citrate and hypophosphite in aqueous solution were degraded by advanced oxidation processes （Fe^2＋/H2O2, UV/Fe^2＋/H2O2, and electrolysis/Fe^2＋/H2O2） in this study. Comparison of these techniques in oxidation efficiency was undertaken. It was found that Fenton process could not completely degrade citrate in the presence of hypophosphite since it caused a series inhibition. Therefore, UV light （photo-Fenton） or electron current （electro-Fenton） was applied to improve the degradation efficiency of the Fenton process. Results showed that both photo-Fenton and electro-Fenton processes could overcome the inhibition of hypophosphite, especially the electro-Fenton.展开更多
This paper provides evidence for the degradation of organic pollutant by the photo-Fenton complex mechanism. Both the complex oxidation and HO. oxidation mechanisms were verified by p-chlorophenol degradation, UV/Vis ...This paper provides evidence for the degradation of organic pollutant by the photo-Fenton complex mechanism. Both the complex oxidation and HO. oxidation mechanisms were verified by p-chlorophenol degradation, UV/Vis spectra anaylsis, and quantum yield. The hydroxyl radical involved in the photo-Fenton process can also be generated from the decomposition of H2O2, photolysis of Fe^3＋ and degradation of hydrated Fe（Ⅵ）-complex, excepting the traditional Fenton reaction.展开更多
Water pollution is a global environmental issue with multi-dimensional infl uences on human life.Some strategies,such as photo-Fenton reaction,have been employed to remove recalcitrant pollutants.Two-dimensional(2D)gr...Water pollution is a global environmental issue with multi-dimensional infl uences on human life.Some strategies,such as photo-Fenton reaction,have been employed to remove recalcitrant pollutants.Two-dimensional(2D)graphene and its threedimensional(3D)confi gurations have attracted considerable attention as emerging carbon-based catalysts in photo-Fenton fi elds owing to their alluring properties in electron transfer,reactant adsorption,and light response.This review summarizes the recent developments in 2D and 3D graphene-based catalysts for photo-Fenton reactions.Their structures,characteristics,activity,and mechanisms are discussed.The conclusions and outlooks are proposed for the profound understanding of challenges and future directions.展开更多
In this work, the degradation of 2-chloro-4,6-diamino-1,3,5-triazine in aqueous solutions by photo-Fenton process has been investigated. The preliminary results have shown that the degradation of 2-chloro-4,6-diamino-...In this work, the degradation of 2-chloro-4,6-diamino-1,3,5-triazine in aqueous solutions by photo-Fenton process has been investigated. The preliminary results have shown that the degradation of 2-chloro-4,6-diamino-1,3,5-triazine by photo-Fenton process is more rapid and more effective than Fenton and UV/H2O2 processes. The effects of certain experimental parameters on kinetics and efficiency of the degradation of 2-chloro-4,6,-diamino-1,3,5-triazine by photo-Fenton process, have been evaluated. Under optimal conditions, photo-Fenton process achieved more than 90% of chloride release and about 30% of nitrate formation. The results of total organic carbon (TOC) and total Kjeldahl nitrogen (TKN) analyses have shown that no carbon dioxide and ammonia are formed during photo-Fenton treatment of aqueous solutions containing 40 mg/L triazine. These results indicate that only substituent groups of triazine ring are released;however, nitrogen atoms of triazine ring remain unaffected. A simple mechanism of degradation of 2-chloro-4,6-diamino-1,3,5-triazine has been proposed. The degradation starts by a rapid release of chlorine atoms as chloride ions to form 2-hydroxy-4,6-diamino-1,3,5-triazine. The amino groups of 2-hydroxy-4,6-diamino-1,3,5-triazine undergo are oxidized into nitro groups by hydroxyl radicals to form 2-hydroxy-4,6-dinitro-1,3,5-triazine which undergoes a slow release of nitro groups and their substitution with hydroxyl groups to form cyanuric acid and nitrate ions. The degradation of cyanuric acid by photo-Fenton process has also been investigated. The results of TOC and TKN analyzes show that no carbon dioxide is formed during the treatment.展开更多
基金the National Natural Science Foundation of China(Grant No.52268042)the Natural Science Foundation of Gansu Province+1 种基金China(Grant No.22JR5RA253)HongLiu First-Class Disciplines Development Program of Lanzhou University of Technology。
文摘For the first time,two-dimensional FeOCl(Fe_(1-x)Co_(x)OCl)doped with Co was successfully applied to the photocatalytic and photo-Fenton degradation of Rhodamine B(RhB).The photocatalytic and photo-Fenton experiments showed that the degradation rates of RhB by Fe0.94Co0.06OCl are 82.6%and 98.2%within 50 min under neutral solution,room temperature and visible light.The inclusion of Co resulted in lattice imperfections on the surface of Fe OCl,which was advantageous for the photogenerated electron-hole pair separation efficiency(consistent with the density functional theory calculation).Moreover,the RhB removal rate decreased from 98%to 82%during five successive cycles,showing good structural stability.Finally,based on the radical capture experiment,a potential mechanism for RhB degradation by Fe_(1-x)Co_(x)OCl catalyst was proposed.The idea of a synergistic mechanism for Fe_(1-x)Co_(x)OCl also offers a fresh concept for catalysts used in doping modification.
基金funding from Hunan Provincial Key Research and Development Program(2020WK2018)Hunan Provincial Forestry Technological Innovation Funds(XLK202107-3)+2 种基金Scientific Research Project of Hunan Education Department(19A505,21B0242)National Natural Science Foundation of China(No.21908251)Hunan Provincial Natural Science Foundation of China(No.2020JJ2058).
文摘In this paper,the residue from bamboo factory has been used to design photo-Fenton catalyst,which has the advantages of low cost and magnetic recycling.The photo-Fenton catalytic performance of the biocarbon-based catalyst was excellent and its optimal preparation process was also explored by response surface methodology.First,bamboo-carbon fiber was selected as the photo-Fenton catalyst carrier.Subsequently,the surface of the car-bon fiber was modified,with which dopamine,nano-Fe_(3)O_(4) and nano-TiO_(2) were successively loaded by hydro-thermal method.After the single factor tests,four factors including dopamine concentration,ferric chloride mass,P25 titanium dioxide mass and liquid-solid ratio were selected as the characteristic values.The degradation efficiency of photo-Fenton catalyst to methylene blue(MB)solution was treated as the response value.After the analysis of the response surface optimization,it was shown that the significance sequence of the selected 4 factors in terms of the MB degradation efficiency was arranged as follows:dopamine concentration>liquid-solid ratio>P25 titanium dioxide quality>ferric chloride quality.The optimal process parameters of fiber-carbon catalyst were affirmed as follows:the 1.7 mg/mL concentration of dopamine,the 1.2 g mass of ferric chloride,the 0.2 g mass of P25 titanium dioxide and the liquid-solid ratio of 170 mL/g.The experiment-measured average MB degra-dation efficiency performed by the optimized catalyst was 99.3%,which was nearly similar to the model-predicted value of 98.9%.It showed that the prediction model and response surface model were accurate and reliable.The results from response surface optimization could provide a good reference to design bamboo-based Fenton-like catalyst with excellent catalytic performance.
基金The authors thank the "National" Science Council, Taiwan, China for financially supporting (No. NSC95- 2211-E-006-032).
文摘Both citrate and hypophosphite in aqueous solution were degraded by advanced oxidation processes （Fe^2＋/H2O2, UV/Fe^2＋/H2O2, and electrolysis/Fe^2＋/H2O2） in this study. Comparison of these techniques in oxidation efficiency was undertaken. It was found that Fenton process could not completely degrade citrate in the presence of hypophosphite since it caused a series inhibition. Therefore, UV light （photo-Fenton） or electron current （electro-Fenton） was applied to improve the degradation efficiency of the Fenton process. Results showed that both photo-Fenton and electro-Fenton processes could overcome the inhibition of hypophosphite, especially the electro-Fenton.
文摘This paper provides evidence for the degradation of organic pollutant by the photo-Fenton complex mechanism. Both the complex oxidation and HO. oxidation mechanisms were verified by p-chlorophenol degradation, UV/Vis spectra anaylsis, and quantum yield. The hydroxyl radical involved in the photo-Fenton process can also be generated from the decomposition of H2O2, photolysis of Fe^3＋ and degradation of hydrated Fe（Ⅵ）-complex, excepting the traditional Fenton reaction.
文摘Water pollution is a global environmental issue with multi-dimensional infl uences on human life.Some strategies,such as photo-Fenton reaction,have been employed to remove recalcitrant pollutants.Two-dimensional(2D)graphene and its threedimensional(3D)confi gurations have attracted considerable attention as emerging carbon-based catalysts in photo-Fenton fi elds owing to their alluring properties in electron transfer,reactant adsorption,and light response.This review summarizes the recent developments in 2D and 3D graphene-based catalysts for photo-Fenton reactions.Their structures,characteristics,activity,and mechanisms are discussed.The conclusions and outlooks are proposed for the profound understanding of challenges and future directions.
文摘In this work, the degradation of 2-chloro-4,6-diamino-1,3,5-triazine in aqueous solutions by photo-Fenton process has been investigated. The preliminary results have shown that the degradation of 2-chloro-4,6-diamino-1,3,5-triazine by photo-Fenton process is more rapid and more effective than Fenton and UV/H2O2 processes. The effects of certain experimental parameters on kinetics and efficiency of the degradation of 2-chloro-4,6,-diamino-1,3,5-triazine by photo-Fenton process, have been evaluated. Under optimal conditions, photo-Fenton process achieved more than 90% of chloride release and about 30% of nitrate formation. The results of total organic carbon (TOC) and total Kjeldahl nitrogen (TKN) analyses have shown that no carbon dioxide and ammonia are formed during photo-Fenton treatment of aqueous solutions containing 40 mg/L triazine. These results indicate that only substituent groups of triazine ring are released;however, nitrogen atoms of triazine ring remain unaffected. A simple mechanism of degradation of 2-chloro-4,6-diamino-1,3,5-triazine has been proposed. The degradation starts by a rapid release of chlorine atoms as chloride ions to form 2-hydroxy-4,6-diamino-1,3,5-triazine. The amino groups of 2-hydroxy-4,6-diamino-1,3,5-triazine undergo are oxidized into nitro groups by hydroxyl radicals to form 2-hydroxy-4,6-dinitro-1,3,5-triazine which undergoes a slow release of nitro groups and their substitution with hydroxyl groups to form cyanuric acid and nitrate ions. The degradation of cyanuric acid by photo-Fenton process has also been investigated. The results of TOC and TKN analyzes show that no carbon dioxide is formed during the treatment.
