Electrochemical Studies on the Photolysis of Iron-Arene Complex Photoinitiator

Iron-arene complex was first introduced by researchers in Ciba-Geigy as an effective photoinitiator for the photocuring of epoxy resin. The photolysis of these complexes has been studied by some authors. The electrochemical study reported in this note provides further evidence for the photolysis process which is crucial for the understanding of the photoinitiation mechanism.

The Fluorescence spectra of Iron-arene complex photo initiator

ＴｈｅＦｌｕｏｒｅｓｃｅｎｃｅｓｐｅｃｔｒａｏｆＩｒｏｎ－ａｒｅｎｅｃｏｍｐｌｅｘｐｈｏｔｏｉｎｉｔｉａｔｏｒＣｈｅｎＸｕｄｏｎｇ￣１；ＦｅｎｇＪｉｕｃｈａｏ￣２；ＤｅｎｇＣｈｕａｎｙｕｅ￣２１（ＤｅｐａｒｔｍｅｎｔｏｆＰｏｌｙｍｅｒａｎｄＥｎｇｉｎ...

铁－芳烃络合物光引发剂的吸收光谱研究

铁－芳烃络合物光引发剂的吸收光谱研究陈旭东，黄新华陈用烈，梁兆熙（西南师范大学化学系重庆，６３０７１５）（中山大学高分子研究所广州）关键词铁－芳烃络合物，光引发剂，吸收光谱，光解铁－芳烃络合物作为环氧化物阳离子聚合光引发剂已引起人们关注［１，２］．我...

反相高效液相色谱分离测定铁-芳烃络合物光引发剂及光解动力学研究

本文以反相高效液相色谱法（RP－HPLC）研究了铁－芳烃络合物光引发剂及光解产物的分离条件和影响因素，推导出光解动力学方程式。方法灵敏度高，引发剂的检测限为100ng／L，测定的标准偏差为0.31％～0.46％，相对标准偏差为0.82％～2.13％。在此条件下样品杂质不干扰测定。