Photopromoted methoxycarbonylation of olefins with carbon monoxide can be carried out under ambient conditions with non-precious transition metal complexes (such as cobalt complexes) catalysts in DMF. The isotope expe...Photopromoted methoxycarbonylation of olefins with carbon monoxide can be carried out under ambient conditions with non-precious transition metal complexes (such as cobalt complexes) catalysts in DMF. The isotope experiments show that DMF is decomposed under irradiation and is conveniently used as a carbon monoxide source for the reaction.展开更多
文摘Photopromoted methoxycarbonylation of olefins with carbon monoxide can be carried out under ambient conditions with non-precious transition metal complexes (such as cobalt complexes) catalysts in DMF. The isotope experiments show that DMF is decomposed under irradiation and is conveniently used as a carbon monoxide source for the reaction.
