Flexible devices produced using organic materials have attracted the attention of many researchers. Important components of these flexible devices include transparent electrodes, which transmit visible light and posse...Flexible devices produced using organic materials have attracted the attention of many researchers. Important components of these flexible devices include transparent electrodes, which transmit visible light and possess conductivity. The present study improved the characteristics of a transparent conductive film that was made of poly(3, 4 ethylenedioxythiophene):poly(styrenesul-fonate) (PEDOT:PSS), an organic conductive material, and that had been prepared using ink-jet printing. To improve the resistance value and visible light transmittance of the film, the film substrate was first cleaned with ultraviolet/ozone treatment, and then the film was annealed after it was deposited on the substrate and dipped into a polar solvent. Consequently, the resistance value of the thin film decreased. However, the surface state of the film changed according to the treatment method and affected its visible light transmittance. Thus, the surface state of the film substrate, the annealing temperature after film deposition, and the dipping treatment with a polar solvent influenced the characteristics of a thin film.展开更多
Recently, a high-performance and low-priced transparent conductive film has been expected to be developed because flexible devices produced using organic materials have been actively studied. An indium tin oxide (ITO)...Recently, a high-performance and low-priced transparent conductive film has been expected to be developed because flexible devices produced using organic materials have been actively studied. An indium tin oxide (ITO) thin film, which has been generally used as a material for a transparent conductive film, has problems, such as fragility to bending stress and depletion of the resource. The present study used poly(3, 4-ethylenedioxythiophene)/poly(styrenesulfonate) (PEDOT:PSS), an organic electroconductive material, and examined the improvement in the resistance value and visible light transmittance of a transparent conductive film produced using the ink-jet method. In previous studies, we reported that, to improve the resistance value and visible light transmittance of a thin film, it was effective to clean the film substrate with ultraviolet/ozone (UV/O<sub>3</sub>) treatment, anneal the film after it was deposited on the substance, and dip the annealed film into a polar solvent. Focusing on the thin film processing between printing operations, the present study improved resistance value and visible light transmittance by examining both the application methods of a polar solvent and the annealing time between printing operations. As a result, the resistance value and visible light transmittance of a PEDOT:PSS thin film were 390.4 Ω and 86.6%, respectively. This film was obtained by applying a polar solvent and performing annealing for 30 min between printing operations. The printing was performed three times.展开更多
In this paper,the effects of four sorts of silica with the particle size range of 4～10μm on coated paper properties and printing performance were studied.The results showed that the smaller particle size silica can ...In this paper,the effects of four sorts of silica with the particle size range of 4～10μm on coated paper properties and printing performance were studied.The results showed that the smaller particle size silica can provide the coated paper with higher density and contrast, better definition and good printing performance.展开更多
Through discussing the color matching technology and its application in printing industry the conventional approaches commonly used in color matching, and the difficulties in color matching, a nonlinear color matching...Through discussing the color matching technology and its application in printing industry the conventional approaches commonly used in color matching, and the difficulties in color matching, a nonlinear color matching model based on two step learning is established by finding a linear model by learning pure color data first and then a nonlinear modification model by learning mixed color data. Nonlinear multiple regression is used to fit the parameters of the modification model. Nonlinear modification function is discovered by BACON system by learning mixture data. Experiment results indicate that nonlinear color conversion by two step learning can further improve the accuracy when it is used for straightforward conversion from RGB to CMYK. An improved separation model based on GCR concept is proposed to solve the problem of gray balance and it can be used for three to four color conversion as well. The method proposed has better learning ability and faster printing speed than other historical approaches when it is applied to four color ink jet printing.展开更多
The crystalline fullerene C60 particles were formed and immobilized on poly(dimethylsiloxane) (PDMS) substrates under the various discharge conditions by an ink-jet method, and investigated for the reactive oxygen spe...The crystalline fullerene C60 particles were formed and immobilized on poly(dimethylsiloxane) (PDMS) substrates under the various discharge conditions by an ink-jet method, and investigated for the reactive oxygen species (ROS) generation property under visible light irradiation. The particles were synthesized by discharging a toluene solution dissolved C60 and poly(methyl methacrylate) (PMMA) with the ink-jet spotting system. The ROS generation was evaluated by comparisons of the fluorescence intensities measured for the formed particles under green laser irradiation and in a dark room using fluorescent dyes, 2’,7’-dichlorofluorescein diacetate and dihydroethidium. The results of transmission electron microscope (TEM) observation showed that the formed particles consisted of crystalline C60. The optimal ink-jet discharge conditions for synthesizing the particles to generate more ROS were found. In the case of the optimal conditions, the structure in which the needle-like particles were three-dimensionally formed was confirmed. The surface area of the crystalline C60 particles was calculated using the SEM observation results, and it was suggested that when the needle-like finer particles were three-dimensionally formed under the optimal conditions, increasing the surface area lead to an increase in the ROS generation amount.展开更多
A combinatorial chemistry method was employed to screen the Ba2＋ and Fe3＋ incorporated into cordierite structure （Ba0.05Fe0.1Mg）2A14Si5018 for exploring of high infrared radiance materials. A series of square-type...A combinatorial chemistry method was employed to screen the Ba2＋ and Fe3＋ incorporated into cordierite structure （Ba0.05Fe0.1Mg）2A14Si5018 for exploring of high infrared radiance materials. A series of square-type sample array that consists of 7×7 compositions was syn- thesized by ink-jetting nitrate solutions into micro-reactor wells in a ceramic plate and then heat-treated at high temperatures. X-ray diffraction and infrared thermograph were used to analyze the effects of Ba2＋/Fe3＋ incorporating on the lattice distortion of cordierite and resultant changes in infrared radiance properties. Based on the results of X-ray phase analy- sis and radiance measurement of the scale-up prepared samples, the optimal Ba2＋ and Fe3＋ co-adding amount was determined to be 5%Ba2＋ plus 10%Fe3＋. Moreover, the infrared emissivity of the optimal composition at 100 ℃ was found to be higher than 0.8 in a wide wavelength range of 5-24μm. The research work demonstrates a promising application of Ba2＋/Fe3＋ cordierite solid solution as a kind of infrared heating materials for energy saving.展开更多
文摘Flexible devices produced using organic materials have attracted the attention of many researchers. Important components of these flexible devices include transparent electrodes, which transmit visible light and possess conductivity. The present study improved the characteristics of a transparent conductive film that was made of poly(3, 4 ethylenedioxythiophene):poly(styrenesul-fonate) (PEDOT:PSS), an organic conductive material, and that had been prepared using ink-jet printing. To improve the resistance value and visible light transmittance of the film, the film substrate was first cleaned with ultraviolet/ozone treatment, and then the film was annealed after it was deposited on the substrate and dipped into a polar solvent. Consequently, the resistance value of the thin film decreased. However, the surface state of the film changed according to the treatment method and affected its visible light transmittance. Thus, the surface state of the film substrate, the annealing temperature after film deposition, and the dipping treatment with a polar solvent influenced the characteristics of a thin film.
文摘Recently, a high-performance and low-priced transparent conductive film has been expected to be developed because flexible devices produced using organic materials have been actively studied. An indium tin oxide (ITO) thin film, which has been generally used as a material for a transparent conductive film, has problems, such as fragility to bending stress and depletion of the resource. The present study used poly(3, 4-ethylenedioxythiophene)/poly(styrenesulfonate) (PEDOT:PSS), an organic electroconductive material, and examined the improvement in the resistance value and visible light transmittance of a transparent conductive film produced using the ink-jet method. In previous studies, we reported that, to improve the resistance value and visible light transmittance of a thin film, it was effective to clean the film substrate with ultraviolet/ozone (UV/O<sub>3</sub>) treatment, anneal the film after it was deposited on the substance, and dip the annealed film into a polar solvent. Focusing on the thin film processing between printing operations, the present study improved resistance value and visible light transmittance by examining both the application methods of a polar solvent and the annealing time between printing operations. As a result, the resistance value and visible light transmittance of a PEDOT:PSS thin film were 390.4 Ω and 86.6%, respectively. This film was obtained by applying a polar solvent and performing annealing for 30 min between printing operations. The printing was performed three times.
文摘In this paper,the effects of four sorts of silica with the particle size range of 4～10μm on coated paper properties and printing performance were studied.The results showed that the smaller particle size silica can provide the coated paper with higher density and contrast, better definition and good printing performance.
文摘Through discussing the color matching technology and its application in printing industry the conventional approaches commonly used in color matching, and the difficulties in color matching, a nonlinear color matching model based on two step learning is established by finding a linear model by learning pure color data first and then a nonlinear modification model by learning mixed color data. Nonlinear multiple regression is used to fit the parameters of the modification model. Nonlinear modification function is discovered by BACON system by learning mixture data. Experiment results indicate that nonlinear color conversion by two step learning can further improve the accuracy when it is used for straightforward conversion from RGB to CMYK. An improved separation model based on GCR concept is proposed to solve the problem of gray balance and it can be used for three to four color conversion as well. The method proposed has better learning ability and faster printing speed than other historical approaches when it is applied to four color ink jet printing.
文摘The crystalline fullerene C60 particles were formed and immobilized on poly(dimethylsiloxane) (PDMS) substrates under the various discharge conditions by an ink-jet method, and investigated for the reactive oxygen species (ROS) generation property under visible light irradiation. The particles were synthesized by discharging a toluene solution dissolved C60 and poly(methyl methacrylate) (PMMA) with the ink-jet spotting system. The ROS generation was evaluated by comparisons of the fluorescence intensities measured for the formed particles under green laser irradiation and in a dark room using fluorescent dyes, 2’,7’-dichlorofluorescein diacetate and dihydroethidium. The results of transmission electron microscope (TEM) observation showed that the formed particles consisted of crystalline C60. The optimal ink-jet discharge conditions for synthesizing the particles to generate more ROS were found. In the case of the optimal conditions, the structure in which the needle-like particles were three-dimensionally formed was confirmed. The surface area of the crystalline C60 particles was calculated using the SEM observation results, and it was suggested that when the needle-like finer particles were three-dimensionally formed under the optimal conditions, increasing the surface area lead to an increase in the ROS generation amount.
文摘A combinatorial chemistry method was employed to screen the Ba2＋ and Fe3＋ incorporated into cordierite structure （Ba0.05Fe0.1Mg）2A14Si5018 for exploring of high infrared radiance materials. A series of square-type sample array that consists of 7×7 compositions was syn- thesized by ink-jetting nitrate solutions into micro-reactor wells in a ceramic plate and then heat-treated at high temperatures. X-ray diffraction and infrared thermograph were used to analyze the effects of Ba2＋/Fe3＋ incorporating on the lattice distortion of cordierite and resultant changes in infrared radiance properties. Based on the results of X-ray phase analy- sis and radiance measurement of the scale-up prepared samples, the optimal Ba2＋ and Fe3＋ co-adding amount was determined to be 5%Ba2＋ plus 10%Fe3＋. Moreover, the infrared emissivity of the optimal composition at 100 ℃ was found to be higher than 0.8 in a wide wavelength range of 5-24μm. The research work demonstrates a promising application of Ba2＋/Fe3＋ cordierite solid solution as a kind of infrared heating materials for energy saving.
