The interaction between a screw dislocation and an elliptical hole with two asymmetrical cracks in a one-dimensional(1 D) hexagonal quasicrystal with piezoelectric effect is considered. A general formula of the genera...The interaction between a screw dislocation and an elliptical hole with two asymmetrical cracks in a one-dimensional(1 D) hexagonal quasicrystal with piezoelectric effect is considered. A general formula of the generalized stress field, the field intensity factor, and the image force is derived, and the special cases are discussed. Several numerical examples are given to show the effects of the material properties and the dislocation position on the field intensity factors and the image forces.展开更多
An electro-elastic analysis is performed on an icosahedral quasicrystal with piezoelectric effects containing a straight dislocation. The closed-form expressions for the elastic and electric fields are obtained using ...An electro-elastic analysis is performed on an icosahedral quasicrystal with piezoelectric effects containing a straight dislocation. The closed-form expressions for the elastic and electric fields are obtained using the extended Stroh formalism. The effects of piezoelectric constant on the phonon displacement, phason displacement, and electric potential are discussed in detail.展开更多
Direct piezoelectricity of electro-active papers (EAPap) is analysed in this paper. The test setups for direct effect are designed and determined. Different ambient factors impacting the piezoelectricity of EAPap, s...Direct piezoelectricity of electro-active papers (EAPap) is analysed in this paper. The test setups for direct effect are designed and determined. Different ambient factors impacting the piezoelectricity of EAPap, such as temperature, humidity, and strain rate, are applied and analyzed. Strong piezoelectricity of EAPap is found on the basis of the test results and in comparison with polyvinylidene fluoride (PVDF) and lead zirconate titanate (PZT)-5H. The maximum piezoelectric constant is achieved to be 504 pC/N. The reason of strong piezoelectricity of EAPap is discussed in this paper. The potential of EAPap as a biomimetic actuator and sensor is also investigated.展开更多
Piezoelectric effects and electronic structures of InAs/GaAs quantum dots grown along (111) and (011) directions are investigated in this paper. The finite element method is used. Electronic energy levels are calc...Piezoelectric effects and electronic structures of InAs/GaAs quantum dots grown along (111) and (011) directions are investigated in this paper. The finite element method is used. Electronic energy levels are calculated by solving the three-dimensional effective mass Schrodinger equation including a strain modified confinement potential and piezoelectric effects. The difference in electronic structure between quantum dots grown along the (111) direction and the (011) direction are compared. The cubic and truncated pyramidal shaped quantum dots are adopted.展开更多
Quasicrystals (QCs) are sensitive to the piezoelectric (PE) effect. This paper studies static deformation of a multilayered one-dimensional (1D) hexagonal QC plate with the PE effect. The exact closed-form solut...Quasicrystals (QCs) are sensitive to the piezoelectric (PE) effect. This paper studies static deformation of a multilayered one-dimensional (1D) hexagonal QC plate with the PE effect. The exact closed-form solutions of the extended displacement and traction for a homogeneous piezoelectric quasicrystal (PQC)plate are derived from an eigensystem. The general solutions for multilayered PQC plates are then obtained using the propagator matrix method when mechanical and electrical loads are applied on the top surface of the plate. Numerical examples for several sandwich plates made up of PQC, PE, and QC materials are provided to show the effect of stacking sequence on phonon, phason, and electric fields under mechanical and electrical loads, which is useful in designing new composites for engineering structures.展开更多
Piezoelectricity is pivotal for applications in micro/nanoelectromechanical systems(MEMS/NEMS).Inducing such a property in 2D systems via the reduction of the dimensionality of their corresponding 3D bulk is here expl...Piezoelectricity is pivotal for applications in micro/nanoelectromechanical systems(MEMS/NEMS).Inducing such a property in 2D systems via the reduction of the dimensionality of their corresponding 3D bulk is here explored.Based on DFT theory and Gaussian-type-localized basis sets,the structural,electronic,mechanical,and piezoelectric properties of both 3D and 2D rare earth monochalcogenides RmX(Rm=Tm,Yb,Lu,and X=S,Se,Te)are investigated using the CRYSTAL code.Most intriguingly,the 2D LuX compounds display a buckled structure,where the Lu and X atoms protrude from the monolayer surface leading to an additional out-of-plane piezoelectric effect;(e_(31)=2104.84,1770.28,1689.79 pC/m,and d31=56.37,49.76,and 147.90 pm/V for LuS,LuSe,and LuTe,respectively).Such piezoelectric response is two orders of magnitude larger than the one of recently reported 2D ferroelectric MXenes,and is nearly thirty times larger than the commonly used AlN and GaN bulk structures.Furthermore,the reduced elastic constants obtained,when compared to other 2D materials,confirm the flexibility and softness of the considered 2D systems.展开更多
The development of two-dimensional(2D)semiconductors has attracted widespread attentions in the scientific community and industry due to their ultra-thin thickness,unique structure,excellent optoelectronic properties ...The development of two-dimensional(2D)semiconductors has attracted widespread attentions in the scientific community and industry due to their ultra-thin thickness,unique structure,excellent optoelectronic properties and novel physics.The excellent flexibility and outstanding mechanical strength of 2D semiconductors provide opportunities for fabricated strain-sensitive devices and utilized strain tuning their electronic and optic–electric performance.The strain-engineered one-dimensional materials have been well investigated,while there is a long way to go for 2D semiconductors.In this review,starting with the fundamental theories of piezoelectric and piezoresistive effect resulted by strain,following we reviewed the recent simulation works of strain engineering in novel 2D semiconductors,such as Janus 2D and 2D-Xene structures.Moreover,recent advances in experimental observation of strain tuning PL spectra and transport behavior of 2D semiconductors are summarized.Furthermore,the applications of strain-engineered 2D semiconductors in sensors,photodetectors and nanogenerators are also highlighted.At last,we in-depth discussed future research directions of strain-engineered 2D semiconductor and related electronics and optoelectronics device applications.展开更多
In this work, novel ZnO/SnS nanocomposites were successfully synthesized via a hydrothermal approach, which is developed for piezoelectric catalytic reduction of hexavalent chromium(Cr(VI)) in an aqueous solution. The...In this work, novel ZnO/SnS nanocomposites were successfully synthesized via a hydrothermal approach, which is developed for piezoelectric catalytic reduction of hexavalent chromium(Cr(VI)) in an aqueous solution. The constructed ZnO/SnS nanocomposites exhibited higher catalytic efficiency for Cr(VI) reduction under a mechanical force(e.g., ultrasonic vibration) compared to pristine ZnO and SnS. In particular, the ZnO/SnS(with 30 wt.% of SnS) heterojunctions revealed an optimal degradation activity among all the prepared samples, which completely removed the Cr(VI)(20 mg/L) solution within 35 min. Moreover, the piezoelectric catalytic activity of ZnO/SnS remained stable after four consecutive cycling experiments. The results of the morphology observations indicated that the SnS nanoparticles adhere to the surface of the ZnO nanorods. The improved piezoelectric catalytic performance of the ZnO/SnS heterojunctions can be attributed to the formation of an intimate interfacial between ZnO and SnS, which effectively inhibits the electron-hole recombination and speeds up the rate of charge transfer. The study reveals a new design of ZnO/SnS heterojunctions as a high-performance and eco-friendly piezoelectric catalyst and provides a promising strategy for addressing environmental problems and energy crises.展开更多
Piezoelectric superlattice is a potential component for nanoelectromechanical systems. Due to the strong nonlocal effect such as flexoelectric effect at interfaces, classical piezoelectric theory is unable to accurate...Piezoelectric superlattice is a potential component for nanoelectromechanical systems. Due to the strong nonlocal effect such as flexoelectric effect at interfaces, classical piezoelectric theory is unable to accurately describe the electromechanical response of piezoelectric superlattice at nanoscale scale. Based on the previous nonlocal thermodynamics theory with flexoelectric effect Liu et al. (2016), the size- dependent electromechanical properties of piezoelectric superlattices made of BaTiO3 (BTO) and PbTiO3 (PRO) layers are investigated systematically in the present work. Giant strain gradient is found near the interface between BTO and PTO layers, which leads to the significant enhancement of polarization in the superlattice due to the flexoelectric effect. For the piezoelectric BTO-PTO superlattices with different unit- cell sizes, the thickness of interface with nontrivial strain gradient is almost constant. The influence of strain gradient at the interface becomes significant when the size of superlattice decreases, As a result, a strong size dependence of electromechanical properties is predicted for the piezoelectric BTO-PTO superlattices, In particular, for the superlattices with a specific thickness ratio of BTO and PTO layers, the piezoelectric response can be several times larger than that of bulk structure. The present work demonstrates a practical wast to design the piezoelectric superlattices with high piezoelectric coefficient by using the nonlocal effect at nanoscale.展开更多
This paper demonstrates the importance of three-dimensional(3-D)piezoelectric coupling in the electromechanical behavior of piezoelectric devices using three-dimensional finite element analyses based on weak and stron...This paper demonstrates the importance of three-dimensional(3-D)piezoelectric coupling in the electromechanical behavior of piezoelectric devices using three-dimensional finite element analyses based on weak and strong coupling models for a thin cantilevered piezoelectric bimorph actuator.It is found that there is a significant difference between the strong and weak coupling solutions given by coupling direct and inverse piezoelectric effects(i.e.,piezoelectric coupling effect).In addition,there is significant longitudinal bending caused by the constraint of the inverse piezoelectric effect in the width direction at the fixed end(i.e.,3-D effect).Hence,modeling of these effects or 3-D piezoelectric coupling modeling is an electromechanical basis for the piezoelectric devices,which contributes to the accurate prediction of their behavior.展开更多
The longitudinal wave propagating in one-dimensional periodic piezoelectric composite rod with inter-coupling between different piezoelectric segments is investigated. The analytical formulae for such a structure are ...The longitudinal wave propagating in one-dimensional periodic piezoelectric composite rod with inter-coupling between different piezoelectric segments is investigated. The analytical formulae for such a structure are shown and the dispersion relation is calculated. The results show that, by introducing the inter-coupling between the different piezoelectric segments, which is accomplished by serially connecting every n piezoelectric segment into supercells, some tunable Bragg band gaps can accordingly be opened in the low frequency region. The investigation could provide a new guideline for the tunable phononic crystal under passive control.展开更多
The paper is devoted to investigations on nanomechanical behaviors of biochips in label-free biodetections. The chip consists of Si-layer, Ti-layer, Au-layer and single-strand DNA (ssDNA) molecular brush biolayer im...The paper is devoted to investigations on nanomechanical behaviors of biochips in label-free biodetections. The chip consists of Si-layer, Ti-layer, Au-layer and single-strand DNA (ssDNA) molecular brush biolayer immobilized by self-assembly technology of thiol group. Unlike previous viewpoints, such as force-bending, entropy-bending and curvature electricity effect, etc., the piezoelectric effect of the biopolymer brush layer is viewed as the main factor that induces nanomechanical bending of biochips, and a classical macroscopic piezoelectric constitutive relation is used to describe the piezoelectric effect. A new laminated cantilever beam model with a piezoelectric biolayer in continuum mechanics, the linearized Poisson-Boltzmann equation in statistical mechanics and the scaling method in polyelectrolyte brush theory are combined to es- tablish a relationship between the nanomechanical deflection of DNA chips and the factors such as nanoscopic structural features of ssDNA molecules, buffer salt concentration, macroscopic mechanical/piezoelectric parameters of DNA chips etc. Curve fitting of experimental data shows that the sign of the piezoelectric constant of the biolayer may control the deflection direction of DNA chips during the packaging process.展开更多
Piezoelectric materials have been analyzed for over 100 years,due to their ability to convert mechanical vibrations into electric charge or electric fields into a mechanical strain for sensor,energy harvesting,and act...Piezoelectric materials have been analyzed for over 100 years,due to their ability to convert mechanical vibrations into electric charge or electric fields into a mechanical strain for sensor,energy harvesting,and actuator applications.A more recent development is the coupling of piezoelectricity and electro-chemistry,termed piezo-electro-chemistry,whereby the piezoelectrically induced electric charge or voltage under a mechanical stress can influence electro-chemical reactions.There is growing interest in such coupled systems,with a corresponding growth in the number of associated publications and patents.This review focuses on recent development of the piezo-electro-chemical coupling multiple systems based on various piezoelectric materials.It provides an overview of the basic characteristics of piezoelectric materials and comparison of operating conditions and their overall electro-chemical performance.The reported piezo-electro-chemical mechanisms are examined in detail.Comparisons are made between the ranges of material morphologies employed,and typical operating conditions are discussed.In addition,potential future directions and applications for the development of piezo-electro-chemical hybrid systems are described.This review provides a comprehensive overview of recent studies on how piezoelectric materials and devices have been applied to control electro-chemical processes,with an aim to inspire and direct future efforts in this emerging research field.展开更多
Two problems of a one-dimensional(1D)piezoelectric quasicrystal(QC)wedge are investigated,i.e.,the two sides of the wedge subject to uniform tractions and the wedge apex subject to the concentrated force.By virtue of ...Two problems of a one-dimensional(1D)piezoelectric quasicrystal(QC)wedge are investigated,i.e.,the two sides of the wedge subject to uniform tractions and the wedge apex subject to the concentrated force.By virtue of the Stroh formalism and Barnett-Lothe matrices,the analytical expressions of the displacements and stresses are derived,and the generalized solutions for the critical wedge angles are discussed.Numerical examples are given to present the mechanical behaviors of the wedge in each field.The results indicate that the effects of the uniform tractions and the concentrated force on the phonon field displacement are larger than those on the phason field.展开更多
The finite element equations considering the geometrical nonlinearity of piezoelectric smart structures are derived based on the total Lagrange method under the assumption of weak coupling between electricity and mech...The finite element equations considering the geometrical nonlinearity of piezoelectric smart structures are derived based on the total Lagrange method under the assumption of weak coupling between electricity and mechanics. Buckling and post-buckling of piezoelectric-plate with various boundary conditions are investigated. The calculated results show that piezoelectric effects and external voltage can hardly affect the buckling and post-bucking characteristics of piezoelectric-plate under uniaxial pressure while the buckling caused by displacement in-plane has much to do with the electric field.展开更多
A system of Mathieu–Hill equations have been obtained for the dynamic stability analysis of electrical graded piezoelectric circular cylindrical shells subjected to the combined loading of periodic axial compressio...A system of Mathieu–Hill equations have been obtained for the dynamic stability analysis of electrical graded piezoelectric circular cylindrical shells subjected to the combined loading of periodic axial compression and radial pressure and electric ?eld. Bolotin’s method is then employed to obtain the dynamic instability regions. It is revealed that the piezoelectric e?ect, the piezoelectric graded e?ect and the electric ?eld only have minor e?ect on the unstable region. In contrast, the geometric parameters, the rigidity of constituent materials and the external loading play a dominant role in determining the unstable region.展开更多
Considering mass and stiffness of piezoelectric layers and damage effects of composite layers, nonlinear dynamic equations of damaged piezoelectric smart laminated plates are derived. The derivation is based on the Ha...Considering mass and stiffness of piezoelectric layers and damage effects of composite layers, nonlinear dynamic equations of damaged piezoelectric smart laminated plates are derived. The derivation is based on the Hamilton's principle, the higher- order shear deformation plate theory, von Karman type geometrically nonlinear straindisplacement relations, and the strain energy equivalence theory. A negative velocity feedback control algorithm coupling the direct and converse piezoelectric effects is used to realize the active control and damage detection with a closed control loop. Simply supported rectangular laminated plates with immovable edges are used in numerical computation. Influence of the piezoelectric layers' location on the vibration control is in- vestigated. In addition, effects of the degree and location of damage on the sensor output voltage are discussed. A method for damage detection is introduced.展开更多
Acoustic wave propagation in piezoelectric crystals of classes 43m and 23 is studied. The crystals Tl3VS4 and Tl3TaSe4 (43m) of the Chalcogenide family and the crystal Bi12TiO20 (23) possess strong piezoelectric e...Acoustic wave propagation in piezoelectric crystals of classes 43m and 23 is studied. The crystals Tl3VS4 and Tl3TaSe4 (43m) of the Chalcogenide family and the crystal Bi12TiO20 (23) possess strong piezoelectric effect. Because the surface Bleustein-Gulyaev waves cannot exist in piezoelectric cubic crystals, it was concluded that new solutions for shear-horizontal surface acoustic waves (SH-SAWs) are found in the monocrystals using different electrical boundary conditions such as electrically "short" and "open" free-surfaces for the unique [ 101 ] direction of wave propagation. For the crystal Tl3TaSe4 with coefficient of electromechanical coupling (CEMC) Ke^2=e^2/(C×g)-1/3, the phase velocity Vph for the new SH-SAWs can be calculated with the following formula: Vph=(Vα+Vt)/2, where Vt is the speed of bulk SH-wave, Vt=Vt4(1+Ke^2)^1/2, Vα=αKVt4, αK=2[Ke(1+Ke^2)^1/2-Ke^2]^1/2, and Vt4=(C44/p)^1/2. It was found that the CEMC K2 evaluation for Tl3TaSe4 gave the value of K^2=2(Vf-Vm)/Vf-0.047 (-4.7%), where Vf-848 m/s and Vm-828 m/s are the new-SAW velocities for the free and metallized surfaces, respectively. This high value of KZ(Tl3TaSe4) is significantly greater than K2(Tl3VS4)-3% and about five times that of K2(Bi12YiO20).展开更多
Based on the new modified couple stress theory and considering the flexoelectric effect of the piezoelectric layers,the Euler Bernoulli nano-beam model of composite laminated materials driven by electrostatically fixe...Based on the new modified couple stress theory and considering the flexoelectric effect of the piezoelectric layers,the Euler Bernoulli nano-beam model of composite laminated materials driven by electrostatically fixed supports at both ends is established. The nonlinear differential governing equations and boundary conditions are derived by the Hamilton principle. The generalized differential quadrature method(GDQM) and the Newton Raphson method are used to numerically solve the differential governing equations. The influence of flexoelectric effect on the static and the dynamic pull-in characteristics of laminated nano-beams is analyzed. The results of the numerical calculation are in a good agreement with those in the literature when the model degenerated into a nanobeam model without flexoelectric effect. The stacking sequence,length scale parameter l and piezoelectric layer applied voltage V_(p) of the composite will affect the pull-in voltage,frequency and time-domain response of the structure. Given that the flexoelectric effect will reduce the pull-in voltage and dimensionless natural frequency of the structure,the maximum dimensionless displacement at the midpoint of the beam and the period of time-domain response should be increased.展开更多
The paper is concerned with the micro-flow self-sensing actuators,the work of which is based on the secondary piezoelectric effect. The piezoelectric ceramic stack can yield micro-displacement due to its first inverse...The paper is concerned with the micro-flow self-sensing actuators,the work of which is based on the secondary piezoelectric effect. The piezoelectric ceramic stack can yield micro-displacement due to its first inverse piezoelectric effect. Therefore,we apply this micro-displacement to cell micro-flow injection. Moreover, due to the charge of the secondary direct piezoelectric effect,the piezoelectric ceramic stack is able to detect the force and displacement in the injection by itself. The experiments of first inverse piezoelectric effect and secondary direct piezoelectric effect are conducted. The experiment results show that,subjected to 0- 60 V input,the piezoelectric ceramic stack can generate 13. 45 μm displacement,and control accuracy can achieve 2 nm. It can completely meet the needs of cell micro-flow injection. Also,the experiments demonstrate that the micro-displacement due to the first inverse piezoelectric effect can be well self-sensed by the electric charge due to the secondary direct piezoelectric effect.展开更多
基金Project supported by the National Natural Science Foundation of China(Nos.11962026,11462020,11862021,and 11502123)the Inner Mongolia Natural Science Foundation of China(Nos.2017MS0104 and NJZY18022)。
文摘The interaction between a screw dislocation and an elliptical hole with two asymmetrical cracks in a one-dimensional(1 D) hexagonal quasicrystal with piezoelectric effect is considered. A general formula of the generalized stress field, the field intensity factor, and the image force is derived, and the special cases are discussed. Several numerical examples are given to show the effects of the material properties and the dislocation position on the field intensity factors and the image forces.
基金Project supported by the National Natural Science Foundation of China(Nos.11462020 and 11502123)the Natural Science Foundation of Inner Mongolia(Nos.2017MS0104 and 2017ZRYB003)
文摘An electro-elastic analysis is performed on an icosahedral quasicrystal with piezoelectric effects containing a straight dislocation. The closed-form expressions for the elastic and electric fields are obtained using the extended Stroh formalism. The effects of piezoelectric constant on the phonon displacement, phason displacement, and electric potential are discussed in detail.
文摘Direct piezoelectricity of electro-active papers (EAPap) is analysed in this paper. The test setups for direct effect are designed and determined. Different ambient factors impacting the piezoelectricity of EAPap, such as temperature, humidity, and strain rate, are applied and analyzed. Strong piezoelectricity of EAPap is found on the basis of the test results and in comparison with polyvinylidene fluoride (PVDF) and lead zirconate titanate (PZT)-5H. The maximum piezoelectric constant is achieved to be 504 pC/N. The reason of strong piezoelectricity of EAPap is discussed in this paper. The potential of EAPap as a biomimetic actuator and sensor is also investigated.
基金Project supported by the National High Technology Research and Development Program of China (Grant No.2009AA03Z405)the National Natural Science Foundation of China (Grant Nos.60908028 and 60971068)
文摘Piezoelectric effects and electronic structures of InAs/GaAs quantum dots grown along (111) and (011) directions are investigated in this paper. The finite element method is used. Electronic energy levels are calculated by solving the three-dimensional effective mass Schrodinger equation including a strain modified confinement potential and piezoelectric effects. The difference in electronic structure between quantum dots grown along the (111) direction and the (011) direction are compared. The cubic and truncated pyramidal shaped quantum dots are adopted.
基金Project supported by the National Natural Science Foundation of China(Nos.11502123 and11262012)the Natural Science Foundation of Inner Mongolia Autonomous Region of China(No.2015JQ01)
文摘Quasicrystals (QCs) are sensitive to the piezoelectric (PE) effect. This paper studies static deformation of a multilayered one-dimensional (1D) hexagonal QC plate with the PE effect. The exact closed-form solutions of the extended displacement and traction for a homogeneous piezoelectric quasicrystal (PQC)plate are derived from an eigensystem. The general solutions for multilayered PQC plates are then obtained using the propagator matrix method when mechanical and electrical loads are applied on the top surface of the plate. Numerical examples for several sandwich plates made up of PQC, PE, and QC materials are provided to show the effect of stacking sequence on phonon, phason, and electric fields under mechanical and electrical loads, which is useful in designing new composites for engineering structures.
文摘Piezoelectricity is pivotal for applications in micro/nanoelectromechanical systems(MEMS/NEMS).Inducing such a property in 2D systems via the reduction of the dimensionality of their corresponding 3D bulk is here explored.Based on DFT theory and Gaussian-type-localized basis sets,the structural,electronic,mechanical,and piezoelectric properties of both 3D and 2D rare earth monochalcogenides RmX(Rm=Tm,Yb,Lu,and X=S,Se,Te)are investigated using the CRYSTAL code.Most intriguingly,the 2D LuX compounds display a buckled structure,where the Lu and X atoms protrude from the monolayer surface leading to an additional out-of-plane piezoelectric effect;(e_(31)=2104.84,1770.28,1689.79 pC/m,and d31=56.37,49.76,and 147.90 pm/V for LuS,LuSe,and LuTe,respectively).Such piezoelectric response is two orders of magnitude larger than the one of recently reported 2D ferroelectric MXenes,and is nearly thirty times larger than the commonly used AlN and GaN bulk structures.Furthermore,the reduced elastic constants obtained,when compared to other 2D materials,confirm the flexibility and softness of the considered 2D systems.
基金supported by the National Natural Science Foundation of China(51572025,51627801,61435010 and 51702219)the State Key Research Development Program of China(2019YFB2203503)+3 种基金Guangdong Basic and Applied Basic Research Foundation(2019A1515110209)the Science and Technology Innovation Commission of Shenzhen(JCYJ20170818093453105,JCYJ20180305125345378)National Foundation of China(41422050303)Beijing Municipal Science&Technology Commission and the Fundamental Research Funds for Central Universities.
文摘The development of two-dimensional(2D)semiconductors has attracted widespread attentions in the scientific community and industry due to their ultra-thin thickness,unique structure,excellent optoelectronic properties and novel physics.The excellent flexibility and outstanding mechanical strength of 2D semiconductors provide opportunities for fabricated strain-sensitive devices and utilized strain tuning their electronic and optic–electric performance.The strain-engineered one-dimensional materials have been well investigated,while there is a long way to go for 2D semiconductors.In this review,starting with the fundamental theories of piezoelectric and piezoresistive effect resulted by strain,following we reviewed the recent simulation works of strain engineering in novel 2D semiconductors,such as Janus 2D and 2D-Xene structures.Moreover,recent advances in experimental observation of strain tuning PL spectra and transport behavior of 2D semiconductors are summarized.Furthermore,the applications of strain-engineered 2D semiconductors in sensors,photodetectors and nanogenerators are also highlighted.At last,we in-depth discussed future research directions of strain-engineered 2D semiconductor and related electronics and optoelectronics device applications.
基金The Technological Innovation R&D Program (S2848103) funded by the Small and Medium Business Administration (SMBA, Korea)The Technological Innovation R&D Program (No. S2849653) funded by the Small and Medium Business Administration (SMBA, Korea)supported by Korea Electric Power Corporation (No. R21XO01-5)。
文摘In this work, novel ZnO/SnS nanocomposites were successfully synthesized via a hydrothermal approach, which is developed for piezoelectric catalytic reduction of hexavalent chromium(Cr(VI)) in an aqueous solution. The constructed ZnO/SnS nanocomposites exhibited higher catalytic efficiency for Cr(VI) reduction under a mechanical force(e.g., ultrasonic vibration) compared to pristine ZnO and SnS. In particular, the ZnO/SnS(with 30 wt.% of SnS) heterojunctions revealed an optimal degradation activity among all the prepared samples, which completely removed the Cr(VI)(20 mg/L) solution within 35 min. Moreover, the piezoelectric catalytic activity of ZnO/SnS remained stable after four consecutive cycling experiments. The results of the morphology observations indicated that the SnS nanoparticles adhere to the surface of the ZnO nanorods. The improved piezoelectric catalytic performance of the ZnO/SnS heterojunctions can be attributed to the formation of an intimate interfacial between ZnO and SnS, which effectively inhibits the electron-hole recombination and speeds up the rate of charge transfer. The study reveals a new design of ZnO/SnS heterojunctions as a high-performance and eco-friendly piezoelectric catalyst and provides a promising strategy for addressing environmental problems and energy crises.
基金financial support from the National Natural Science Foundation of China(11472242,11672264,and 11621062)the Zhejiang Provincial Natural Science Foundation(LZ17A020001)the Fundamental Research Funds for the Central Universities
文摘Piezoelectric superlattice is a potential component for nanoelectromechanical systems. Due to the strong nonlocal effect such as flexoelectric effect at interfaces, classical piezoelectric theory is unable to accurately describe the electromechanical response of piezoelectric superlattice at nanoscale scale. Based on the previous nonlocal thermodynamics theory with flexoelectric effect Liu et al. (2016), the size- dependent electromechanical properties of piezoelectric superlattices made of BaTiO3 (BTO) and PbTiO3 (PRO) layers are investigated systematically in the present work. Giant strain gradient is found near the interface between BTO and PTO layers, which leads to the significant enhancement of polarization in the superlattice due to the flexoelectric effect. For the piezoelectric BTO-PTO superlattices with different unit- cell sizes, the thickness of interface with nontrivial strain gradient is almost constant. The influence of strain gradient at the interface becomes significant when the size of superlattice decreases, As a result, a strong size dependence of electromechanical properties is predicted for the piezoelectric BTO-PTO superlattices, In particular, for the superlattices with a specific thickness ratio of BTO and PTO layers, the piezoelectric response can be several times larger than that of bulk structure. The present work demonstrates a practical wast to design the piezoelectric superlattices with high piezoelectric coefficient by using the nonlocal effect at nanoscale.
基金supported by the Japan Society for the Promotion of Science under KAKENHI Grant Nos.19F19379 and 20H04199。
文摘This paper demonstrates the importance of three-dimensional(3-D)piezoelectric coupling in the electromechanical behavior of piezoelectric devices using three-dimensional finite element analyses based on weak and strong coupling models for a thin cantilevered piezoelectric bimorph actuator.It is found that there is a significant difference between the strong and weak coupling solutions given by coupling direct and inverse piezoelectric effects(i.e.,piezoelectric coupling effect).In addition,there is significant longitudinal bending caused by the constraint of the inverse piezoelectric effect in the width direction at the fixed end(i.e.,3-D effect).Hence,modeling of these effects or 3-D piezoelectric coupling modeling is an electromechanical basis for the piezoelectric devices,which contributes to the accurate prediction of their behavior.
基金Supported by the National Natural Science Foundation of China under Grant No 11274121
文摘The longitudinal wave propagating in one-dimensional periodic piezoelectric composite rod with inter-coupling between different piezoelectric segments is investigated. The analytical formulae for such a structure are shown and the dispersion relation is calculated. The results show that, by introducing the inter-coupling between the different piezoelectric segments, which is accomplished by serially connecting every n piezoelectric segment into supercells, some tunable Bragg band gaps can accordingly be opened in the low frequency region. The investigation could provide a new guideline for the tunable phononic crystal under passive control.
基金Project supported by the Outstanding Youth Program of Shanghai Municipal Commission of Education(No.04YQHB088)the Shanghai Leading Academic Discipline Project(No.Y0103).
文摘The paper is devoted to investigations on nanomechanical behaviors of biochips in label-free biodetections. The chip consists of Si-layer, Ti-layer, Au-layer and single-strand DNA (ssDNA) molecular brush biolayer immobilized by self-assembly technology of thiol group. Unlike previous viewpoints, such as force-bending, entropy-bending and curvature electricity effect, etc., the piezoelectric effect of the biopolymer brush layer is viewed as the main factor that induces nanomechanical bending of biochips, and a classical macroscopic piezoelectric constitutive relation is used to describe the piezoelectric effect. A new laminated cantilever beam model with a piezoelectric biolayer in continuum mechanics, the linearized Poisson-Boltzmann equation in statistical mechanics and the scaling method in polyelectrolyte brush theory are combined to es- tablish a relationship between the nanomechanical deflection of DNA chips and the factors such as nanoscopic structural features of ssDNA molecules, buffer salt concentration, macroscopic mechanical/piezoelectric parameters of DNA chips etc. Curve fitting of experimental data shows that the sign of the piezoelectric constant of the biolayer may control the deflection direction of DNA chips during the packaging process.
基金supported by the National Key R&D Project from Minister of Science and Technology in China (No. 2016YFA0202701)the National Natural Science Foundation of China (No. 51472055)+4 种基金External Cooperation Program of BIC, Chinese Academy of Sciences (No. 121411KYS820150028)the 2015 Annual Beijing Talents Fund (No. 2015000021223ZK32)Qingdao National Laboratory for Marine Science and Technology (No. 2017ASKJ01)the University of Chinese Academy of Sciences (Grant No. Y8540XX2D2)the ‘thousands talents’ program for the pioneer researcher and his innovation team, China。
文摘Piezoelectric materials have been analyzed for over 100 years,due to their ability to convert mechanical vibrations into electric charge or electric fields into a mechanical strain for sensor,energy harvesting,and actuator applications.A more recent development is the coupling of piezoelectricity and electro-chemistry,termed piezo-electro-chemistry,whereby the piezoelectrically induced electric charge or voltage under a mechanical stress can influence electro-chemical reactions.There is growing interest in such coupled systems,with a corresponding growth in the number of associated publications and patents.This review focuses on recent development of the piezo-electro-chemical coupling multiple systems based on various piezoelectric materials.It provides an overview of the basic characteristics of piezoelectric materials and comparison of operating conditions and their overall electro-chemical performance.The reported piezo-electro-chemical mechanisms are examined in detail.Comparisons are made between the ranges of material morphologies employed,and typical operating conditions are discussed.In addition,potential future directions and applications for the development of piezo-electro-chemical hybrid systems are described.This review provides a comprehensive overview of recent studies on how piezoelectric materials and devices have been applied to control electro-chemical processes,with an aim to inspire and direct future efforts in this emerging research field.
基金Project supported by the National Natural Science Foundation of China(Nos.11972365,12102458,11972354)the China Agricultural University Education Foundation(No.1101-2412001)。
文摘Two problems of a one-dimensional(1D)piezoelectric quasicrystal(QC)wedge are investigated,i.e.,the two sides of the wedge subject to uniform tractions and the wedge apex subject to the concentrated force.By virtue of the Stroh formalism and Barnett-Lothe matrices,the analytical expressions of the displacements and stresses are derived,and the generalized solutions for the critical wedge angles are discussed.Numerical examples are given to present the mechanical behaviors of the wedge in each field.The results indicate that the effects of the uniform tractions and the concentrated force on the phonon field displacement are larger than those on the phason field.
基金the National Natural Science Foundation of China(No.59635140)
文摘The finite element equations considering the geometrical nonlinearity of piezoelectric smart structures are derived based on the total Lagrange method under the assumption of weak coupling between electricity and mechanics. Buckling and post-buckling of piezoelectric-plate with various boundary conditions are investigated. The calculated results show that piezoelectric effects and external voltage can hardly affect the buckling and post-bucking characteristics of piezoelectric-plate under uniaxial pressure while the buckling caused by displacement in-plane has much to do with the electric field.
基金Project supported by the the Natural Science Foundation of China (Nos. 10132010 and 50135030).
文摘A system of Mathieu–Hill equations have been obtained for the dynamic stability analysis of electrical graded piezoelectric circular cylindrical shells subjected to the combined loading of periodic axial compression and radial pressure and electric ?eld. Bolotin’s method is then employed to obtain the dynamic instability regions. It is revealed that the piezoelectric e?ect, the piezoelectric graded e?ect and the electric ?eld only have minor e?ect on the unstable region. In contrast, the geometric parameters, the rigidity of constituent materials and the external loading play a dominant role in determining the unstable region.
基金Project supported by the National Natural Science Foundation of China(No.10572049)
文摘Considering mass and stiffness of piezoelectric layers and damage effects of composite layers, nonlinear dynamic equations of damaged piezoelectric smart laminated plates are derived. The derivation is based on the Hamilton's principle, the higher- order shear deformation plate theory, von Karman type geometrically nonlinear straindisplacement relations, and the strain energy equivalence theory. A negative velocity feedback control algorithm coupling the direct and converse piezoelectric effects is used to realize the active control and damage detection with a closed control loop. Simply supported rectangular laminated plates with immovable edges are used in numerical computation. Influence of the piezoelectric layers' location on the vibration control is in- vestigated. In addition, effects of the degree and location of damage on the sensor output voltage are discussed. A method for damage detection is introduced.
文摘Acoustic wave propagation in piezoelectric crystals of classes 43m and 23 is studied. The crystals Tl3VS4 and Tl3TaSe4 (43m) of the Chalcogenide family and the crystal Bi12TiO20 (23) possess strong piezoelectric effect. Because the surface Bleustein-Gulyaev waves cannot exist in piezoelectric cubic crystals, it was concluded that new solutions for shear-horizontal surface acoustic waves (SH-SAWs) are found in the monocrystals using different electrical boundary conditions such as electrically "short" and "open" free-surfaces for the unique [ 101 ] direction of wave propagation. For the crystal Tl3TaSe4 with coefficient of electromechanical coupling (CEMC) Ke^2=e^2/(C×g)-1/3, the phase velocity Vph for the new SH-SAWs can be calculated with the following formula: Vph=(Vα+Vt)/2, where Vt is the speed of bulk SH-wave, Vt=Vt4(1+Ke^2)^1/2, Vα=αKVt4, αK=2[Ke(1+Ke^2)^1/2-Ke^2]^1/2, and Vt4=(C44/p)^1/2. It was found that the CEMC K2 evaluation for Tl3TaSe4 gave the value of K^2=2(Vf-Vm)/Vf-0.047 (-4.7%), where Vf-848 m/s and Vm-828 m/s are the new-SAW velocities for the free and metallized surfaces, respectively. This high value of KZ(Tl3TaSe4) is significantly greater than K2(Tl3VS4)-3% and about five times that of K2(Bi12YiO20).
文摘Based on the new modified couple stress theory and considering the flexoelectric effect of the piezoelectric layers,the Euler Bernoulli nano-beam model of composite laminated materials driven by electrostatically fixed supports at both ends is established. The nonlinear differential governing equations and boundary conditions are derived by the Hamilton principle. The generalized differential quadrature method(GDQM) and the Newton Raphson method are used to numerically solve the differential governing equations. The influence of flexoelectric effect on the static and the dynamic pull-in characteristics of laminated nano-beams is analyzed. The results of the numerical calculation are in a good agreement with those in the literature when the model degenerated into a nanobeam model without flexoelectric effect. The stacking sequence,length scale parameter l and piezoelectric layer applied voltage V_(p) of the composite will affect the pull-in voltage,frequency and time-domain response of the structure. Given that the flexoelectric effect will reduce the pull-in voltage and dimensionless natural frequency of the structure,the maximum dimensionless displacement at the midpoint of the beam and the period of time-domain response should be increased.
基金Sponsored by the Youths Science Foundation of Heilongjiang Province(Grant No.QC08C09)the Educational Committee Science Foundation of Heilongjiang Province(Grant No.11541272)
文摘The paper is concerned with the micro-flow self-sensing actuators,the work of which is based on the secondary piezoelectric effect. The piezoelectric ceramic stack can yield micro-displacement due to its first inverse piezoelectric effect. Therefore,we apply this micro-displacement to cell micro-flow injection. Moreover, due to the charge of the secondary direct piezoelectric effect,the piezoelectric ceramic stack is able to detect the force and displacement in the injection by itself. The experiments of first inverse piezoelectric effect and secondary direct piezoelectric effect are conducted. The experiment results show that,subjected to 0- 60 V input,the piezoelectric ceramic stack can generate 13. 45 μm displacement,and control accuracy can achieve 2 nm. It can completely meet the needs of cell micro-flow injection. Also,the experiments demonstrate that the micro-displacement due to the first inverse piezoelectric effect can be well self-sensed by the electric charge due to the secondary direct piezoelectric effect.