Investigation of Refractory Bricks and Oxide Materials Heated in Hydrogen Reduction Conditions

This study aims to provide the basic knowledge for furnace refractory design by investigating refractory property changes occurred in a hydrogen atmosphere.Since refractory bricks are thermodynamically stable in a hydrogen atmosphere at 1100°C,we tried to find out the minute changes.In this experiment,a refractory brick was prepared by andalusite,mullite chamotte,and clay as raw materials and heated to 1100°C in a 100%hydrogen atmosphere for 72 h.It was found that the strength of the brick was decreased and the color was changed to black by the reduction of impurities.And in addition,this study covered research on the slaking risk of MgO raw materials because the minimum temperature is expected to 400°C in fluidized reduction furnaces unlike shaft furnaces.

Effects of Al_(2)O_(3)-SiO_(2) Raw Material Types on Properties of Anorthite Based Insulation Refractories

To optimize their Al_(2)O_(3)-SiO_(2) raw materials,anorthite based insulation refractories were prepared by the in-situ sintering process combined with the foaming method after sintering at 1350℃for 3 h,using green and pollution-free kaolin,kyanite,andalusite and sillimanite as Al_(2)O_(3)-SiO_(2) raw materials,respectively,and industrial CaCO_(3) as the CaO source.Effects of Al_(2)O_(3)-SiO_(2) raw material types on the physical properties,phase composition and microstructure were investigated.The results are as follows.All samples prepared by different Al_(2)O_(3)-SiO_(2) raw materials have hexagonal flake anorthite and a small amount of mullite and corundum.Their bulk density and thermal conductivity decrease in the order of using kaolin,andalusite,kyanite and sillimanite as the Al_(2)O_(3)-SiO_(2) raw material,but their apparent porosity increases.Moreover,in the sample with kaolin,the bonding between anorthite crystals on the pore walls is closer than that of the other samples,which is conducive to increasing the cold crushing strength.The bonding between anorthite crystals on pore walls gradually decreases in the order of using kyanite,andalusite and sillimanite as the Al_(2)O_(3)-SiO_(2) raw material,thus their cold crushing strength decreases accordingly.In comprehensive consideration,the properties of the sample from kyanite are the optimal.Its apparent porosity,thermal conductivity and cold crushing strength are 84.6%,0.141 W·m^(-1)·K^(-1) and 1.89 MPa,respectively.

Raw Materials of Chinese Traditional Handmade paper

Chinese traditional handmade papers,due to their numerous names,have been misunderstood by the public about raw materials for a long time.This manuscript aims to introduce the raw materials of traditional Chinese handmade paper in a botanical aspect in chronological order.Chinese handmade paper’s raw materials are divided into two groups,bast fiber and grass fiber.Bast fiber paper includes ramie-made rag paper,mulberry and paper mulberry paper,Thymelaeaceae paper,and vine paper.Stalk and grass fiber paper includes bamboo paper,grass paper,and stalk paper.

On "China-measures related to the exportation of various raw materials" case in terms of DSB's interpretations

The Appellate Body report in January 2012 had supported the decision of Panel in the"China-measures related to the exportation of various raw materials"case(WT/DS394,395,398)and affirmed that China's restrictions(such as tariffs and quota measures)on the exportation of raw materials violated rules put forth by the WTO,which were required to be modified.In this case China's right to invoke Article 20 of GATT1994("general exception")to justify its exemption from the guidelines in Article 11.3 of the WTO Accession Protocol was denied by the Panel and the Appellate Body.This was due to the fact that the phrasing in Article 11.3 of Protocol failed to mention"GATT."This was the consequence of the two interpretation approaches the Dispute Settlement Body(DSB)adopted-a narrow textual interpretation and a subjective presumption of"legislative silence."The inappropriate use of the two methods of interpretation lead to an imbalance between the right and obligation of China under the additional obligations that were imposed upon China by the WTO,which create a negative impact on China's rare earth case and the protection of domestic natural resources.

Development and Markets of China's Refractory Raw Materials

The distribution of refractory raw material resources , its throughput capacity, product varieties and quality as well as market situation in China were investigated.

A Study on the Radioactivity Level in Raw Materials, Final Products and Wastes of the Phosphate Fertilizer Industries in Bangladesh

A study on the detection of probable radionuclides and their activity concentrations in the raw material (phosphate rock), final product (fertilizer) and waste samples collected from all the phosphate fertilizer factories (total two factories—A Diammonium Phosphate, DAP and a Triple Super Phosphate, TSP factory) in Bangladesh were carried out. A total of seven types of samples (grossly divided into solid and liquid types);liquid waste, waste-mixed river water, normal river water, phosphate rock, phosphate fertilizer, solid waste and normal soil;were analyzed under this study. Raw material samples were collected only from the TSP fertilizer factory. Fertilizer, solid and liquid waste samples were collected from both the factories under study. Moreover, normal soil and natural surface water samples from the suitable areas adjacent to the factories were also collected for the comparison purpose. The samples were analyzed by gamma ray spectrometry technique using a Hyper-Pure Germanium (HPGe) detector of 40% relative efficiency. The analysis of the samples showed that only natural radionuclides such as 226Ra, 232Th and 40K were present in the samples and no traces of artificial radioactivity were found in any of the samples. 40K was found below the detection limit in some samples. The analysis of the samples in the case of TSP fertilizer factory showed that the average activity concentrations of 226Ra and 232Th and 40K in raw materials were 851.27 ± 7.10, 19.63 ± 6.57 and 54.06 ± 5.93 Bq/kg, respectively, in final product 211.90 ± 4.74, 42.48 ± 10.56 Bq/kg and ND (Not Detected), respectively, in solid waste 187.49 ± 4.88, 70.06 ± 11.76 and 289.27 ± 40.24 Bq/kg, respectively and in liquid waste 6.26 ± 0.63, 10.01 ± 1.39 Bq/L and ND, respectively. The measured results in the case of samples collected from DAP fertilizer factory showed that the average activity concentrations of 226Ra and 232Th and 40K in the final product were 17.31 ± 3.92, 69.74 ± 9.88 and 48.46 ± 17.22 Bq/kg, respectively, in solid waste 24.47 ± 4.15, 164.62 ± 11.08, 191.52 ± 33.74 Bq/kg, respectively and in liquid waste 3.59 ± 1.05, 37.08 ± 3.30 Bq/L and ND, respectively. Considering the stored raw materials and wastes the part of the ambient environment of the factory, radium equivalent activity, radiation hazard index and external annual effective dose to the workers and public due to these materials were also calculated and compared with world average values.

Studies on Fragrance Raw Materials of α-Terpineol Analogues

Thirty four α-substituted or α, α-disubstituted-( 1-methylcyclohexen-4-yl )methanols and α-substituted or α,α-disubstituted-(4-methylcyclohexyl) methanols weresynthesized. Thirty two of them are new compounds. 1H NMR and IR spectra of allthe compounds were determined, MS spectra of some of them were obtained as well.The characteristic odors were evaluated.Keywords Fragrance raw materials,α-Terpineol analogues, Synthesis, Structuredetermination

Development and Application of Hydrocracking Catalysts RHC-1/RHC-5 for Maximizing High Quality Chemical Raw Materials Yield

To adapt to the change in the demand of the oil refining market,two hydrocracking catalysts,RHC-1 and RHC-5,were developed to improve the quality of tail oil.The catalysts were designed based on the theory of selective ring-opening.By selecting more acidic molecular sieves,the problem of poor selectivity of conventional materials can be solved to properly match up to the hydrogenation performance of catalysts.Compared with the performance of previous catalysts,the quality of the tail oil achieved by the said catalysts is better,and the BMCI is reduced by 1—2 units.In the long cycle operation of the petroleum industry,the good quality of the tail oil has been verified and the adaptability of the process conditions is good.When the RHC-1 catalyst is used to process heavy feed under medium pressure,a BMCI value of about12 can be obtained along with a nearly 60%yield of tail oil.The total yield of chemical raw material(steaming cracking feed+catalytic reforming feed)can exceed 80%,and the hydrogen consumption has dropped by nearly 50%as compared to the conventional hydrocracking conversion rate.When processing a mixed CGO and VGO feed with the full conversion mode under a hydrogen pressure of 13.0 MPa,the RHC-5 catalyst can yield about 68.4%of heavy naphtha with a potential aromatic content of up to 50.6,while the total yield of chemical raw materials can reach more than 98%.The results of industrial application of these catalysts show that more than 30%of high quality tail oil can be obtained via processing of inferior quality feed,and its BMCI value can reach 10.7.The total yield of chemical raw materials can reach more than65%.The industrial operation process has implemented two operating cycles totaling 8 years.

Carboxyethylated Microfibrillated Cellulose Fibers Prepared from Different Raw Materials

Carboxyethylation pretreatment was used to prepare microfibrillated cellulose(MFC)in this study.In order to evaluate the adaptability of this pretreatment method,carboxyethylated MFC was prepared from six different cellulosic materials.The carboxyl content,degree of polymerization,water retention value,charge density,chemical structure,size distribution,and micromorphology of the materials before and after pretreatment and grinding were studied and compared.The viscosity,ultraviolet(UV)transmittance,and thermal stability of the MFC samples at a certain concentration were determined.The results showed that the carboxyl content,water retention value,charge density,degree of polymerization,size distribution,and micromorphology of the pretreated and ground samples varied with those of the raw materials.The initial viscosity varied based on the type of raw material used.The MFC suspension prepared from cotton linter pulp had the highest UV transmittance,while the MFC prepared from bleached softwood kraft pulp had the highest viscosity at a low shear rate.After thermal degradation,the amount of residual char from the MFC prepared with the thermo-mechanical pulp was slightly higher than that of the other MFCs.This study demonstrates that carboxyethylation is an effective pretreatment method for different cellulosic materials.

Evaluation of the Phosphate Raw Materials Potential of Amur Region

The Amur region,far east of Russia,is well endowed with phosphate in the forms of phosphorite, apatite,and vivianite.The 500-km2 Selitkansky phosphorite district has a proven reserve of ca.14.7 million tons（Mt） of P2O5.The Minsky phosphorite district contains ca.100 Mt phosphor ores at 6%P2O5.

Influence of Characteristics of Alumina-silicate Raw Materials on the Formation Process of Clinker

The traditional alumina-silicate raw materials, for example, clays, in the precalcining technique of cement production, have been replaced by low grade and high silica content sandstones, shales, and industrial waste residues, including fly ashes, slag, and others. The results are the change of compositions and characteristics of raw materials applied and a great effect on cement calcination process and clinker formation. In this work, the cement clinker formation process of different alumina-silicate raw materials to replace clay raw material was studied by chemical analysis, X-ray diffraction, differential thermal analysis, and high temperature microscope based on the characteristics of the alumina-silicate raw materials. The formation heat of the clinker was determined by the acid dissolution method. Influence of different alumina-silicate raw materials on the clinker burnability and formation process was studied. The results show that the changing of alumina- silicate raw materials, especially using industrial waste residues, can reduce the formation temperature of high temperature liquid phases, improve the burnability of raw materials, reduce the formation temperature and formation heat of clinker. And this study also observed the formation temperature and transformation of high temperature liquid phases in the heating process of raw materials by high temperature microscope.

Impact of Alternative Raw Materials on the Profitability of a Large-Scale Bio-Coal Pellet Plant in Finland

The aim of this paper was to compare the annual economic impact of a large-scale bio-coal pellet plant by raw material specifically for the Finnish Lakeland region. In this study, the total production volume of the theoretical plant was 200,000 tons per year and the raw wood materials used were birch pulpwood, spruce pulpwood, pine pulpwood, and energy wood. These wood materials were young delimbed wood from early thinnings. The main goal of the paper was to illustrate that the energy content differences of raw wood materials affect the economic profitability of a bio-coal pellet plant at regional level. In this case, wood type also has a regional economic impact, which the pellet plant can influence through its raw wood material choices. The raw material comparison was based on measured data and not computational or literary data alone. The study found that lower solid wood energy densities caused higher relative costs for the total supply chain. A parallel phenomenon occurred with the required gross margin of the pellets, where lower energy content caused higher required gross margin for pellet sales. The gross margin was also sensitivity analyzed at different discount rates from 5% to 20%. At each required discount rate, the highest annual economic impact on the region was found for birch pellets, with values of 36.95 - 42.66 million €. Spruce pellets had the smallest annual economic impact, although it had the highest final pellet price in the same cases. The different economic effects were caused by the energy volumes sold.

Studies on Silicon-Containing Fragrance Raw Materials( Ⅱ )——Syntheses and Odors of 4-Trimethylsilylcyclohex-3-enol and 4-Trimethylsilylcyclohexanol Derivatives

1-Substituted- 4-trimethylsilylcyclohex- 3-enol and 1-substituted- 4-trimetnylsilyl-cyclohexanol, 4-trimethylsilylcyclohex-3-enol and 4-trimethylsilylcyclohexanol, and some of their esters and carbon counterparts were synthesized. Structures of the nineteen new compounds were determined by 1H NMR, IR and MS. Their odors are evaluated.

Countermeasures for dealing with the change of blast furnace raw materials

Following the dramatic increase of iron and steel output ,iron ore is increasingly in short supply ,and the quality of blast furnace （BF） raw materials is increasingly inferior. All these factors have a strong impact on the BF operation. According to the analysis of the raw material properties at Baosteel and the combination of the BF smelting mechanism and its operational practice, this study probes into the operational countermeasures for dealing with the change of raw materials and puts forward optimized BF control technology to ensure the operation of BFs is stable and smooth.

Mapping of the Use of Waste as Raw Materials for Biogas Production

Anthropic methane emissions can largely be prevented or minimized using technologies that are already available. One such technology is anaerobic digestion (AD), which is used commercially around the world, especially in Europe and the United States, where some challenging targets have been set to diversify the energy mix with more renewable energy. This foresight study was designed to identify which technological solutions out of the many options available for biogas production are attracting most interest, for which purpose patent documents and scientific publications were analyzed. The aim is to identify which raw materials are most attractive for AD and biogas production. It was found that the raw materials that have attracted most research and patenting activity are sludge, sewage, and wastewater, livestock waste, and agriculture waste, which together account for 62% of all the patents filed and 74% of all the scientific publications. The countries most engaged in producing biogas from AD plants are China, Germany, and the United States. We also identified a rising trend in the use of biogas around the world, and a steady increase in the number of patents filed on the subject, especially in Japan and South Korea. This growth is driven, amongst other things, by strategic governmental actions, global environmental pacts, and the realization on the part of industry that anaerobic digestion can be used as an efficient method for treating waste and effluents.

2019 Nationwide Conference on Raw Materials for Refractories Successfully Held in Tianjin

2019 Nationwide Conference on Raw Materials for Refractories,organized by Refractories Committee of The Chinese Society for Metals,Sinosteel Luoyang Institute of Refractories Research Co.,Ltd.(LIRR),State Key Laboratory of Advanced Refractories,Sinosteel Technology Incubator(Tianjin)Co.,Ltd.,and Refractories Press,sponsored by Imerys Aluminates Technology Co., Ltd.

Evaluation of physicochemical properties as supporting information on quality control of raw materials and veterinary pharmaceutical formulations

This study aimed to show that the physicochemical proprieties obtained by Fourier transform infrared spectroscopy （FTIR）, thermogravimetry （TG）, and scanning electronic microscopy （SEM） can be useful tools for evaluating the quality of active pharmaceutical ingredients （APIs） and pharmaceutical products. In addition, a simple, sensitive, and efficient method employing HPLC-DAD was developed for simulta- neous determination of lidocaine （LID）, ciprofloxacin （CFX） and enrofloxacin （EFX） in raw materials and in veterinary pharmaceutical formulations. Compounds were separated using a Gemini Cm （250 mm×4.6 mm, 5μm） Phenomenex column, at a temperature of 25℃, with a mobile phase containing 10 mM of phosphoric acid （pH 3.29）： acetonitrile （85.7：14.3, v/v） and a flow rate of 1.5 mL/min. Physicochemical characterization by TG, FTIR, and SEM of raw materials of LID, CFX, and EFX provided information useful for the evaluation, differentiation, and qualification of raw materials. Finally, the HPLC method was proved to be useful for evaluation of raw material and finished products, besides satisfying the need for an analytical method that allows simultaneous determination of EFX, CFX, and LID, which can also be extended to other matrices and applications.

Preliminary Study on Raw Materials Exploitation at Donggutuo Site,Nihewan Basin,North China

The present study examines material quarrying, utilization, and exploitation strategy with respect to availability, quality and distribution at Donggutuo, a Lower Pleistocene archeological site in the Nihewan Basin of North China. Through identification of the bedrocks in the vicinity, the analysis reveals that raw materials available at the Donggutuo site are mainly chert, dolomicrite, siliceous dolomite, siliceous limestone, tectonic breccia, quartzite and intermediate lava. Related documents and a geological survey of the area demonstrate that the chert was quarried from dolomite within the Gaoyuzhuang Formation of the Mesoproterozoic Changcheng Group, and the quartzite from the Yousuopu Formation of the Archeozoic Qianxi Group, as well as from Jurassic volcanic lava. Fractures formed by tectonic movements of the Yanshan Stage and the Himalaya Stage made it convenient to quarry these materials. It is observed that fragmentary rock pieces were directly collected and quarried from local fracture belts and that this became the principal strategy of raw material exploitation adopted by the Donggutuo toolmakers. In general, raw materials were not efficiently used, and many of them could have been reduced, retouched and used again. Some suggestions are also proposed to improve the understanding of earlyhumans’ tool complex in the Nihewan Basin.

Refractory Raw Materials and Products

Shandong Shengquan Chemical Co., Ltd Add： Shengquan Industrial Park, Zhangqiu 250204, Shandong Tel： ＋086-531-83502307 Fax： ＋086-531-83513019 E-mail ： april, tang@ shengquan, com Web： www. shengquanchem, corn

Refractory Raw Materials and Products

Shandong Shengquan Chemical Co. ,Ltd. Add: Shengquan Industrial Park,Zhangqiu 250204,Shandong Tel: + 086-531-83502307 Fax: + 086-531-83513019 E-mail: april. tang@ shengquan. com Web: www. shengquanchem. com Henan Ruishi Investment Croup Co. ,Ltd. Add: Huayuan Caifu Square A-1403,No. 1 Luopu Road,Luoyang 471000,Henan Tel: + 86-379-65286183 Fax: + 86-379-65285889 E-mail: duzude521@ rs-abrasive. com Web: www. rs-abrasive. com Jingzhou Huaxin Mullite Co. ,Ltd. Add: Gantai Industrial Park,Jingzhou County, Huaihua 418403,Hunan,China Tel: + 86-745-8310998 Fax: + 86-745-83109993