A semi-analytical method is introduced to study kink instability in cylindrical plasma with line-tied boundary conditions. The method is based on an expansion for magnetohydrodynamics (MHD) equations in one-dimensio...A semi-analytical method is introduced to study kink instability in cylindrical plasma with line-tied boundary conditions. The method is based on an expansion for magnetohydrodynamics (MHD) equations in one-dimensional (1D) radial eigenvalue problems by using Fourier transforms. The MHD equations then become an ordinary differential equation. This method is applicable to both ideal and non-ideal MHD problem. The effect of plasma pressure (P0) on kink instability is studied in a cylindrical geometry. Complex discrete spectra are pre- sented. Two-dimensional (2D) eigenfunctions with the line-tied boundary conditions are obtained. The growth rate and radial eigenfunctions are different in the two cases of P0 = 0 and P0 ≠ 0, which indicate that the effect of plasma pressure can not be ignored if it is large enough. This method allows us to understand the role of individual radial eigenfunctions, and is also computationally efficient compared to direct solutions of the MHD equations by the finite difference method.展开更多
Pressure fluctuations in the plasma sheath from spacecraft reentry affect radiofrequency(RF) wave propagation.The influence of these fluctuations on wave propagation and wave properties is studied using methods deri...Pressure fluctuations in the plasma sheath from spacecraft reentry affect radiofrequency(RF) wave propagation.The influence of these fluctuations on wave propagation and wave properties is studied using methods derived by synthesizing the compressible turbulent flow theory,plasma theory,and electromagnetic wave theory.We study these influences on wave propagation at GPS and Ka frequencies during typical reentry by adopting stratified modeling.We analyzed the variations in reflection and transmission properties induced by pressure fluctuations.Our results show that,at the GPS frequency,if the waves are not totally reflected then the pressure fluctuations can remarkably affect reflection,transmission,and absorption properties.In extreme situations,the fluctuations can even cause blackout.At the Ka frequency,the influences are obvious when the waves are not totally transmitted.The influences are more pronounced at the GPS frequency than at the Ka frequency.This suggests that the latter can mitigate blackout by reducing both the reflection and the absorption of waves,as well as the influences of plasma fluctuations on wave propagation.Given that communication links with the reentry vehicles are susceptible to plasma pressure fluctuations,the influences on link budgets should be taken into consideration.展开更多
Acrylic polyurethane paint on the surface of 2A12 Al alloy was cleaned utilizing an atmospheric pressure plasma jet in this work.The dynamic evolution of the paint removal process during plasma treatment with time was...Acrylic polyurethane paint on the surface of 2A12 Al alloy was cleaned utilizing an atmospheric pressure plasma jet in this work.The dynamic evolution of the paint removal process during plasma treatment with time was explored through analysis of morphology and chemical states.The results showed that although the thickness of paint could be reduced effectively with an increase in cleaning time,the removal rate of paint gradually decreased with time.During the initial cleaning process range,its original smooth morphology of paint turned rugged quickly and was almost unchanged with further plasma treatment.Element and chemical state analysis showed that the content of C in the paint layer decreased obviously after plasma treatment.In contrast,the O content increased remarkably.The cleaning mechanism could be mainly attributed to the reaction between active O-containing species in air plasma and organic components in the paint.After removal of superficial organic matter,residue inorganic metal oxide substances aggregated on the base.The exposed metal oxides on the one hand elevated the superficial O content,but on the other hand hindered further plasma penetration,resulting in a gradual decrease in cleaning rate with cleaning time.Therefore,physical wiping was proposed to be incorporated with the plasma method and effective removal of paint was realized.展开更多
Atmospheric pressure plasma jet shows great potential for polymer film processing. The electrode geometry is the key factor to determine discharge characteristics and film modification of jets. In this paper, we compa...Atmospheric pressure plasma jet shows great potential for polymer film processing. The electrode geometry is the key factor to determine discharge characteristics and film modification of jets. In this paper, we compared the discharge characteristics and the film modifications of atmospheric pressure plasma jets with needle-ring electrode(NRE) and doublering electrode(DRE). The results show that jet with NRE has stronger electric field intensity and higher discharge power,making it present more reactive oxygen particles and higher electron temperature, but its discharge stability is insufficient.In contrast, the jet with DRE has uniform electric field distribution of lower field intensity, which allows it to maintain stable discharge over a wide range of applied voltages. Besides, the modification results show that the treatment efficiency of PET film by NRE is higher than that by DRE. These results provide a suitable atmospheric pressure plasma jets device selection scheme for polymer film processing process.展开更多
Direct-current(DC)arc plasma has great application values in the field of the chemical industry,but it has the problem of low energy efficiency.Facing the requirement for improving the energy efficiency of the arc,thi...Direct-current(DC)arc plasma has great application values in the field of the chemical industry,but it has the problem of low energy efficiency.Facing the requirement for improving the energy efficiency of the arc,this paper proposes a unique method of pulsed modulated arc(PMA).This method uses high-frequency pulses and reduces the arc current to improve the control of electron temperature.The electrical characteristics,optical characteristics and products are tested.The test results show that during the PMA process,all of the experimental results which include voltage,current and light will significantly increase.These results are analyzed from the perspective of functionality,repeatability and energy conversion.The analysis results show that although the PMA method does not show good parameter consistency,it has potential application prospects because it increases the energy conversion rate by 4.5%and 8%from the perspective of light and products,respectively.展开更多
Generation of atmospheric pressure homogeneous air plasma in a large gap(>4 mm)is a challenge.In this study,an atmospheric pressure homogeneous air plasma generated in a gap up to 10 mm is reported,which is based o...Generation of atmospheric pressure homogeneous air plasma in a large gap(>4 mm)is a challenge.In this study,an atmospheric pressure homogeneous air plasma generated in a gap up to 10 mm is reported,which is based on a three-electrode configuration,where a high-voltage(HV)electrode and a middle electrode form a surface dielectric barrier discharge(S-DBD),and together with the ground electrode form the main volume discharge.High-speed photographs confirm that the discharge in the main gap is homogeneous.The gas temperature of the plasma estimated from the N_(2)(C^(3)∏_(u)-B^(3)∏_(g))(Δv=-2)emission is about 320 K,which is close to room temperature.A detailed analysis shows that the discharge ignited between the HV electrode and the middle electrode is serving as an electron source,and the electrons deposited on the dielectric plate are due to the S-DBD along with the applied voltage generating a driving force,which results in a high concentration of seed electrons in the main gap and induces the homogeneous plasma.Further analysis shows that the electric field in the main gap is only about18.45 k V·cm^(-1),which is much lower than the typical breakdown electric field of 30 k V·cm^(-1)for atmospheric pressure air discharge.展开更多
In this work,the antibacterial activity of cotton containing silver nanocapsules prepared by atmospheric pressure plasma(APP)deposition is investigated.The nanocapsules consist of a shell and a silver nanoparticle(Ag ...In this work,the antibacterial activity of cotton containing silver nanocapsules prepared by atmospheric pressure plasma(APP)deposition is investigated.The nanocapsules consist of a shell and a silver nanoparticle(Ag NP)core,where the core is used to bring antibacterial activity,and the shell is utilized to suppress the potential toxicity of Ag NPs.The surface morphology and the elements of the samples are analyzed by scanning electron microscopy(SEM),energy dispersive x-ray and x-ray photoelectron spectroscopy(XPS).The SEM results show that the skin of the cotton fibers will fall off gradually after APP treatment over 3 min,and the XPS results show that the Ag content will rise to 1.6%after APP deposition for 10 min.Furthermore,the antimicrobial activity tests show that the reduction rates of Escherichia coli and Staphylococcus aureus can achieve 100%when the sample is treated for 10 min,which exhibits excellent antibacterial activity.In addition,the UV absorption properties of the cotton will also be correspondingly improved,which brings a broader application prospect for antibacterial cotton.展开更多
The effects of radio frequency(RF)atmospheric pressure(AP)He/H_(2)plasma and thermal treatment on the hydrogenation of TiO_(2)thin films were investigated and compared in this work.The color of the original TiO_(2)fil...The effects of radio frequency(RF)atmospheric pressure(AP)He/H_(2)plasma and thermal treatment on the hydrogenation of TiO_(2)thin films were investigated and compared in this work.The color of the original TiO_(2)film changes from white to black after being hydrogenated in He/H_(2)plasma at160 W(gas temperature~381℃)within 5 min,while the color of the thermally treated TiO_(2)film did not change significantly even in pure H_(2)or He/H_(2)atmosphere with higher temperature(470℃)and longer time(30 min).This indicated that a more effective hydrogenation reaction happened through RF AP He/H_(2)plasma treatment than through pure H_(2)or He/H_(2)thermal treatment.The color change of TiO_(2)film was measured based on the Commission Internationale d’Eclairage L*a*b*color space system.Hydrogenated TiO_(2)film displayed improved visible light absorption with increased plasma power.The morphology of the cauliflower-like nanoparticles of the TiO_(2)film surface remained unchanged after plasma processing.X-ray photoelectron spectroscopy results showed that the contents of Ti3+species and Ti-OH bonds in the plasma-hydrogenated black TiO_(2)increased compared with those in the thermally treated TiO_(2).X-ray diffraction(XRD)patterns and Raman spectra indicated that plasma would destroy the crystal structure of the TiO_(2)surface layer,while thermal annealing would increase the overall crystallinity.The different trends of XRD and Raman spectra results suggested that plasma modification on the TiO_(2)surface layer is more drastic than on its inner layer,which was also consistent with transmission electron microscopy results.Optical emission spectra results suggest that numerous active species were generated during RF AP He/H_(2)plasma processing,while there were no peaks detected from thermal processing.A possible mechanism for the TiO_(2)hydrogenation process by plasma has been proposed.Numerous active species were generated in the bulk plasma region,accelerated in the sheath region,and bumped toward the TiO_(2)film,which will react with the TiO_(2)surface to form OVs and disordered layers.This leads to the tailoring of the band gap of black TiO_(2)and causes its light absorption to extend into the visible region.展开更多
An atmospheric microwave plasma argon was used for the inactivation of bacteria E. coli. The employed device, called Axial Injection Torch (or TIA for Torche à Injection Axiale), consisted of a microwave power so...An atmospheric microwave plasma argon was used for the inactivation of bacteria E. coli. The employed device, called Axial Injection Torch (or TIA for Torche à Injection Axiale), consisted of a microwave power source, a waveguide and a gas supply system. Using this argon plasma source, we studied the effects of the exposure time, the exposure distance, the input power, and the gas flow rate on the reduction rate of Escherichia coli cells. The first part of the study was carried out with a static sample exposed to the plasma and then in the second part the sample was set in motion relative to the plasma jet. A log reduction number of E. coli of 4 (10<sup>-4 </sup>CFU/mL) was obtained with UV and active species, for UV only a log of 1 (10<sup>-1</sup> CFU/mL) was obtained.展开更多
Hydrogen is an alternative energy source that has the potential to replace fossil fuels.One of the hydrogen applications is as a material for Polymer Electrolyte Membrane Fuel Cells(PEMFC)in fuel cell vehicles.High-pu...Hydrogen is an alternative energy source that has the potential to replace fossil fuels.One of the hydrogen applications is as a material for Polymer Electrolyte Membrane Fuel Cells(PEMFC)in fuel cell vehicles.High-purity hydrogen can be obtained using a hydrogen separation membrane to prevent unwanted contaminants from potentially harming the PEMFC components.In this study,we fabricated a plasma membrane reactor and investigated the permeation performance of a hydrogen separation membrane in a plasma membrane reactor utilizing atmospheric pressure plasma.The result showed the hydrogen permeation rate increasing with time as reactor temperature is increased through joule heating.By decreasing the gap length of the reactor from 2 to 1 mm,the hydrogen permeation rate increases by up to 40%.The hydrogen permeation rate increases by 30%when pressure is applied to the plasma membrane reactor by up to 100 kPa.展开更多
The plasma arc pressure plays an important role in determining the keyhole formation and size. So it is of great significance to choose adaptive distribution mode of the plasma arc pressure for determining keyhole sha...The plasma arc pressure plays an important role in determining the keyhole formation and size. So it is of great significance to choose adaptive distribution mode of the plasma arc pressure for determining keyhole shape and size. In this study, through employing a double-elliptic distribution mode of plasma arc pressure, three-dimensional keyhole was numerically simulated. The unsymmetric feature of the keyhole inside the weld pool was described. The development of keyhole was demonstrated under different levels of welding current. The critical current required to form an open keyhole was obtained for the study cases .展开更多
In this study, we employed a nonthermal atmospheric pressure plasma(NTAPP) jet to evaluate the effect of plasma treatment on the durability of resin–dentin bonding under a thermocycling challenge. Furthermore, we ass...In this study, we employed a nonthermal atmospheric pressure plasma(NTAPP) jet to evaluate the effect of plasma treatment on the durability of resin–dentin bonding under a thermocycling challenge. Furthermore, we assessed the degradation resistance of plasma-treated collagen under a sodium hypochlorite(NaClO) challenge. We assessed the beneficial effect of NTAPP treatment on the acid-etched dentin–bonding interface by testing the micro-tensile bond strength and examining the morphology. We found that the immediate bonding strength of the dentin significantly increased after NTAPP treatment. Compared with the control group, NTAPP resulted in a more prominent effect on the bonding durability of the dentin–adhesive interface after treatment for 5 or 10 s. Simultaneously, the mechanical strength of dentin collagen under the NaClO challenge was improved. Our results indicate that, in optimal conditions, NTAPP could be a promising method to protect dentin collagen and to improve the bonding durability between dentin and etch-and-rinse adhesives.展开更多
An atmospheric pressure plasma jet generated in Ar and O2/Ar mixtures has been investigated by specially designed equipment with double power electrodes at 20~32 kHz, and their effects on the cleaning of surfaces have...An atmospheric pressure plasma jet generated in Ar and O2/Ar mixtures has been investigated by specially designed equipment with double power electrodes at 20~32 kHz, and their effects on the cleaning of surfaces have been studied. Properties of the jet discharge are studied by electrical diagnostics, including the waveform of discharge voltage, discharge current and the Q-V Lissajous figures. The optical emission spectroscopy is used to measure the plasma parameters, such as the excitation temperature and the gas temperature. It is found that the consumed power and the excitation temperature increase with increase of the discharge frequency. On the other hand, at the same discharge frequency, these parameters in O2/Ar mixture plasma are found to be much larger. The effect on surface cleaning is studied from the changes in the contact angle. For Ar plasma jet, the contact angle decreases with increase of the discharge frequency. For O2/Ar mixture plasma jet, the contact angle decreases with increase of discharge frequency up to 26 kHz, however, further increase of discharge frequency does not show further decrease in the contact angle. At the same discharge frequency, the contact angle after O2/Ar mixture plasma cleaning is found to be much lower compared to the case of pure Ar. From the results of quadrupole mass-spectrum analysis, we can identify more fragment molecules of CO and H2O in the emitted gases after O2/Ar plasma jet treatment compared with Ar plasma jet treatment, which are produced by the decomposition of surface organic contaminants during the cleaning process.展开更多
Atmospheric pressure cold plasma, with advantages such as high particle activity, no thermal damage, high efficiency and direct and friendly contact with human tissues, is considered to have great potential in biomedi...Atmospheric pressure cold plasma, with advantages such as high particle activity, no thermal damage, high efficiency and direct and friendly contact with human tissues, is considered to have great potential in biomedical applications. Therefore, 'plasma medicine' as a new interdiscipline has been developed in the past two decades. This review first briefly describes the development of typical plasma sources suitable for biomedical applications, and those with different discharge forms are simply compared, evaluated and summarized. Subsequently, measurement of the crucial gaseous reactive particles(e.g. OH and O) and their spatio-temporal distributions are introduced. Meanwhile, the generation and variation rules and the related critical macroscopic parameters of the plasma-induced aqueous reactive species are summarized. Finally, related studies in the last ten years on the mechanisms of the plasma-driven microbial inactivation and plasma-induced apoptosis of cancer cells are introduced. Moreover, some scientific problems that need to be urgently solved in the field of plasma medicine are also discussed. This review will provide useful guidance for future related research.展开更多
A unified numerical model is developed to couple the plasma arc, weld pool and keyhole in a self consistent way. The plasma arc/anode interface and the melt/solid interface are treated specially, the VOF method is use...A unified numerical model is developed to couple the plasma arc, weld pool and keyhole in a self consistent way. The plasma arc/anode interface and the melt/solid interface are treated specially, the VOF method is used to trace the moving keyhole wall, and the fluid flow and heat transfer in both the plasma arc and weld pool are numerically simulated. The distributions of current density and arc pressure on the weld pool surface during the keyhole formation process are analyzed using the coupled model. The predicted arc pressure and current density are compared with the experimentally measured results, and both are in good agreement.展开更多
Three different low-temperature plasma-based methods were used to improve the surface hydrophilicity of polyethy- lene (PE) films, and all the modification processes were carried out by employing an atmospheric pres...Three different low-temperature plasma-based methods were used to improve the surface hydrophilicity of polyethy- lene (PE) films, and all the modification processes were carried out by employing an atmospheric pressure plasma jet (APPJ) system. (a) PE films were directly modified by APPJ using a gas mixture of He and 02. (b) Acrylic acid (AA) was introduced into the system and a polymer acrylic acid (PAA) coating was deposited onto the PE films. (c) AA was grafted onto the PE surface activated by plasma pre-treatment. It was found that the hydrophilicity of the PE films was significantly improved for all the three methods. However, the samples modified by Process (a) showed hydrophobicity recovery after a storage time of 20 days while no significant change was found in samples modified by Process (b) and Process (c). The Fourier transform infrared spectroscopy (FTIR) results indicated that the most intensive C=O peak was detected on the PE surface modified by Process (c). According to the X-ray photoelectron spectroscopy (XPS) analysis, the ratios of oxygen-containing polar groups for samples modified by Process (b) and Process (c) were higher than that modified by Process (a).展开更多
An atmospheric-pressure air plasma is employed to treat C6 glioma cells in vitro. To elucidate on the mechanism causing cell death and role of reactive species (RS) in the medium produced by the plasma, the concentr...An atmospheric-pressure air plasma is employed to treat C6 glioma cells in vitro. To elucidate on the mechanism causing cell death and role of reactive species (RS) in the medium produced by the plasma, the concentration of the long-lived RS such as hydrogen peroxide, nitrate, and ozone in the plasma-treated liquid (phosphate-buffered saline solution) is measured. When vitamin C is added to the medium as a ROS quencher, the viability of C6 glioma cells after the plasma treatment is different from that without vitamin C. The results demonstrate that reactive oxygen species (ROS) such as H2O2, and O3 constitute the main factors for inactivation of C6 glioma cells and the reactive nitrogen species (RNS) may only play an auxiliary role in cell death.展开更多
A non-equilibrium atmospheric pressure argon(Ar)plasma excited by microsecond pulse is studied experimentally by laser scattering and optical emission spectroscopy(OES),and theoretically by collisional-radiative(CR)mo...A non-equilibrium atmospheric pressure argon(Ar)plasma excited by microsecond pulse is studied experimentally by laser scattering and optical emission spectroscopy(OES),and theoretically by collisional-radiative(CR)model.More specifically,the electron temperature and electron density of plasma are obtained directly by the laser Thomson scattering,the gas temperature is measured by laser Raman scattering,the optical emissions of excited Ar states of plasma are measured by OES.The laser scattering results show that the electron temperature is about 1 eV which is similar to that excited by 60 Hz AC power,but the gas temperature is as low as 300 K compared to about 700 K excited by 60 Hz AC power.It is shown that the microsecond pulsed power supply,rather than nanosecond ones,is short enough to reduce the gas temperature of atmospheric pressure plasma to near room temperature.The electron temperature and electron density are also obtained by CR model based on OES,and find that the intensities of the optical emission intensity lines of 727.41,811.73,841.08,842.83,852.44 and 912.86 nm of Ar can be used to characterize the behavior of electron density and electron temperature,it is very useful to quickly estimate the activity of the atmospheric pressure Ar plasma in many applications.展开更多
Enterococcus faecalis (E. faecalis) is a microorganism that can survive extreme challenges in obturated root canals. The aim of this study was to evaluate the efficacy of a non-thermal atmospheric pressure plasma pl...Enterococcus faecalis (E. faecalis) is a microorganism that can survive extreme challenges in obturated root canals. The aim of this study was to evaluate the efficacy of a non-thermal atmospheric pressure plasma plume against E. faecalis in vitro. A non-thermal atmospheric pressure plasma jet device which could generate a cold plasma plume carrying a peak current of 300 mA was used. The antibacterial efficacy of this device against E. faecalis and its biofihn un- der different conditions was detected. The antibacterial efficacy of the plasma against E. faecalis and Staphylococcus aureus (S. aureus) was also evaluated. After plasma treatment, the average diameter of inhibition zone on S. aureus and E. faecalis was 2.62±0.26 cm and 1.06±0.30 cm, respectively (P 〈 0.05). The diameter was increased with prolongation of the treatment dura- tion. The diameters of inhibition zone of the sealed Petri dishes were larger than those of the uncovered Petri dishes. There was significant difference in colony-forming units between plasma group and control group on E. faecalis biofilm (P 〈 0.01). The transmission electron microscopy revealed that the ultrastructural changes eytoderm of E. faecalis were observed after treatment for 2min. It is concluded that the non-thermal atmospheric pressure plasma could serve as an effective adjunct to standard endodontie microbial treatment.展开更多
This paper reports that a new plasma generator at atmospheric pressure, which is composed of two homocentric cylindrical all-metal tubes, successfully generates a cold plasma jet. The inside tube electrode is connecte...This paper reports that a new plasma generator at atmospheric pressure, which is composed of two homocentric cylindrical all-metal tubes, successfully generates a cold plasma jet. The inside tube electrode is connected to ground, the outside tube electrode is connected to a high-voltage power supply, and a dielectric layer is covered on the outside tube electrode. When the reactor is operated by low-frequency (6 kHz-20 kHz) AC supply in atmospheric pressure and argon is steadily fed as a discharge gas through inside tube electrode, a cold plasma jet is blown out into air and the plasma gas temperature is only 25-30℃. The electric character of the discharge is studied by using digital real-time oscilloscope (TDS 200-Series), and the discharge is capacitive. Preliminary results are presented on the decontamination of E.colis bacteria and Bacillus subtilis bacteria by this plasma jet, and an optical emission analysis of the plasma jet is presented in this paper. The ozone concentration generated by the plasma jet is 1.0× 10^16cm^-3 which is acquired by using the ultraviolet absorption spectroscopy.展开更多
基金supported by National Basic Research Program of China (No.2008CB717801)National Natural Science Foundation of China (No.10875024)Laboratory of College and University Program of Liaoning Province of China (No.2008S059)
文摘A semi-analytical method is introduced to study kink instability in cylindrical plasma with line-tied boundary conditions. The method is based on an expansion for magnetohydrodynamics (MHD) equations in one-dimensional (1D) radial eigenvalue problems by using Fourier transforms. The MHD equations then become an ordinary differential equation. This method is applicable to both ideal and non-ideal MHD problem. The effect of plasma pressure (P0) on kink instability is studied in a cylindrical geometry. Complex discrete spectra are pre- sented. Two-dimensional (2D) eigenfunctions with the line-tied boundary conditions are obtained. The growth rate and radial eigenfunctions are different in the two cases of P0 = 0 and P0 ≠ 0, which indicate that the effect of plasma pressure can not be ignored if it is large enough. This method allows us to understand the role of individual radial eigenfunctions, and is also computationally efficient compared to direct solutions of the MHD equations by the finite difference method.
基金supported by the National Basic Research Program of China(No.2014CB340205)National Natural Science Foundation of China(No.61301173)
文摘Pressure fluctuations in the plasma sheath from spacecraft reentry affect radiofrequency(RF) wave propagation.The influence of these fluctuations on wave propagation and wave properties is studied using methods derived by synthesizing the compressible turbulent flow theory,plasma theory,and electromagnetic wave theory.We study these influences on wave propagation at GPS and Ka frequencies during typical reentry by adopting stratified modeling.We analyzed the variations in reflection and transmission properties induced by pressure fluctuations.Our results show that,at the GPS frequency,if the waves are not totally reflected then the pressure fluctuations can remarkably affect reflection,transmission,and absorption properties.In extreme situations,the fluctuations can even cause blackout.At the Ka frequency,the influences are obvious when the waves are not totally transmitted.The influences are more pronounced at the GPS frequency than at the Ka frequency.This suggests that the latter can mitigate blackout by reducing both the reflection and the absorption of waves,as well as the influences of plasma fluctuations on wave propagation.Given that communication links with the reentry vehicles are susceptible to plasma pressure fluctuations,the influences on link budgets should be taken into consideration.
基金supported by National Natural Science Foundation of China(No.U21A20438)the Foundation of Key Laboratory of Radiation Physics and Technology of the Ministry of Education(No.2021SCURPT03)。
文摘Acrylic polyurethane paint on the surface of 2A12 Al alloy was cleaned utilizing an atmospheric pressure plasma jet in this work.The dynamic evolution of the paint removal process during plasma treatment with time was explored through analysis of morphology and chemical states.The results showed that although the thickness of paint could be reduced effectively with an increase in cleaning time,the removal rate of paint gradually decreased with time.During the initial cleaning process range,its original smooth morphology of paint turned rugged quickly and was almost unchanged with further plasma treatment.Element and chemical state analysis showed that the content of C in the paint layer decreased obviously after plasma treatment.In contrast,the O content increased remarkably.The cleaning mechanism could be mainly attributed to the reaction between active O-containing species in air plasma and organic components in the paint.After removal of superficial organic matter,residue inorganic metal oxide substances aggregated on the base.The exposed metal oxides on the one hand elevated the superficial O content,but on the other hand hindered further plasma penetration,resulting in a gradual decrease in cleaning rate with cleaning time.Therefore,physical wiping was proposed to be incorporated with the plasma method and effective removal of paint was realized.
基金Project supported by the National Natural Science Foundation of China (Grant No. 11565003)the Jiangxi Province Academic Degree and Postgraduate Education and Teaching Reform Research Project (Grant No. JXYJG-2022-180)the Scientific Research Base Project of Gannan Normal University (Grant No. 22wdxt01)。
文摘Atmospheric pressure plasma jet shows great potential for polymer film processing. The electrode geometry is the key factor to determine discharge characteristics and film modification of jets. In this paper, we compared the discharge characteristics and the film modifications of atmospheric pressure plasma jets with needle-ring electrode(NRE) and doublering electrode(DRE). The results show that jet with NRE has stronger electric field intensity and higher discharge power,making it present more reactive oxygen particles and higher electron temperature, but its discharge stability is insufficient.In contrast, the jet with DRE has uniform electric field distribution of lower field intensity, which allows it to maintain stable discharge over a wide range of applied voltages. Besides, the modification results show that the treatment efficiency of PET film by NRE is higher than that by DRE. These results provide a suitable atmospheric pressure plasma jets device selection scheme for polymer film processing process.
基金supported by National Natural Science Foundation of China(No.52177135)the National Science and Technology Major Project of China(Nos.2017-Ⅲ-0007-0032,2019-Ⅲ-0013-0056)。
文摘Direct-current(DC)arc plasma has great application values in the field of the chemical industry,but it has the problem of low energy efficiency.Facing the requirement for improving the energy efficiency of the arc,this paper proposes a unique method of pulsed modulated arc(PMA).This method uses high-frequency pulses and reduces the arc current to improve the control of electron temperature.The electrical characteristics,optical characteristics and products are tested.The test results show that during the PMA process,all of the experimental results which include voltage,current and light will significantly increase.These results are analyzed from the perspective of functionality,repeatability and energy conversion.The analysis results show that although the PMA method does not show good parameter consistency,it has potential application prospects because it increases the energy conversion rate by 4.5%and 8%from the perspective of light and products,respectively.
基金supported by National Natural Science Foundation of China(Nos.52130701,51977096,52277150,and12005076)the National Key Research and Development Program of China(No.2021YFE0114700)。
文摘Generation of atmospheric pressure homogeneous air plasma in a large gap(>4 mm)is a challenge.In this study,an atmospheric pressure homogeneous air plasma generated in a gap up to 10 mm is reported,which is based on a three-electrode configuration,where a high-voltage(HV)electrode and a middle electrode form a surface dielectric barrier discharge(S-DBD),and together with the ground electrode form the main volume discharge.High-speed photographs confirm that the discharge in the main gap is homogeneous.The gas temperature of the plasma estimated from the N_(2)(C^(3)∏_(u)-B^(3)∏_(g))(Δv=-2)emission is about 320 K,which is close to room temperature.A detailed analysis shows that the discharge ignited between the HV electrode and the middle electrode is serving as an electron source,and the electrons deposited on the dielectric plate are due to the S-DBD along with the applied voltage generating a driving force,which results in a high concentration of seed electrons in the main gap and induces the homogeneous plasma.Further analysis shows that the electric field in the main gap is only about18.45 k V·cm^(-1),which is much lower than the typical breakdown electric field of 30 k V·cm^(-1)for atmospheric pressure air discharge.
基金supported by National Natural Science Foundation of China(Nos.11975163 and 12175160)together with a project funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)。
文摘In this work,the antibacterial activity of cotton containing silver nanocapsules prepared by atmospheric pressure plasma(APP)deposition is investigated.The nanocapsules consist of a shell and a silver nanoparticle(Ag NP)core,where the core is used to bring antibacterial activity,and the shell is utilized to suppress the potential toxicity of Ag NPs.The surface morphology and the elements of the samples are analyzed by scanning electron microscopy(SEM),energy dispersive x-ray and x-ray photoelectron spectroscopy(XPS).The SEM results show that the skin of the cotton fibers will fall off gradually after APP treatment over 3 min,and the XPS results show that the Ag content will rise to 1.6%after APP deposition for 10 min.Furthermore,the antimicrobial activity tests show that the reduction rates of Escherichia coli and Staphylococcus aureus can achieve 100%when the sample is treated for 10 min,which exhibits excellent antibacterial activity.In addition,the UV absorption properties of the cotton will also be correspondingly improved,which brings a broader application prospect for antibacterial cotton.
基金financially supported by National Natural Science Foundation of China(Nos.12075054,12205040,12175036,11875104)。
文摘The effects of radio frequency(RF)atmospheric pressure(AP)He/H_(2)plasma and thermal treatment on the hydrogenation of TiO_(2)thin films were investigated and compared in this work.The color of the original TiO_(2)film changes from white to black after being hydrogenated in He/H_(2)plasma at160 W(gas temperature~381℃)within 5 min,while the color of the thermally treated TiO_(2)film did not change significantly even in pure H_(2)or He/H_(2)atmosphere with higher temperature(470℃)and longer time(30 min).This indicated that a more effective hydrogenation reaction happened through RF AP He/H_(2)plasma treatment than through pure H_(2)or He/H_(2)thermal treatment.The color change of TiO_(2)film was measured based on the Commission Internationale d’Eclairage L*a*b*color space system.Hydrogenated TiO_(2)film displayed improved visible light absorption with increased plasma power.The morphology of the cauliflower-like nanoparticles of the TiO_(2)film surface remained unchanged after plasma processing.X-ray photoelectron spectroscopy results showed that the contents of Ti3+species and Ti-OH bonds in the plasma-hydrogenated black TiO_(2)increased compared with those in the thermally treated TiO_(2).X-ray diffraction(XRD)patterns and Raman spectra indicated that plasma would destroy the crystal structure of the TiO_(2)surface layer,while thermal annealing would increase the overall crystallinity.The different trends of XRD and Raman spectra results suggested that plasma modification on the TiO_(2)surface layer is more drastic than on its inner layer,which was also consistent with transmission electron microscopy results.Optical emission spectra results suggest that numerous active species were generated during RF AP He/H_(2)plasma processing,while there were no peaks detected from thermal processing.A possible mechanism for the TiO_(2)hydrogenation process by plasma has been proposed.Numerous active species were generated in the bulk plasma region,accelerated in the sheath region,and bumped toward the TiO_(2)film,which will react with the TiO_(2)surface to form OVs and disordered layers.This leads to the tailoring of the band gap of black TiO_(2)and causes its light absorption to extend into the visible region.
文摘An atmospheric microwave plasma argon was used for the inactivation of bacteria E. coli. The employed device, called Axial Injection Torch (or TIA for Torche à Injection Axiale), consisted of a microwave power source, a waveguide and a gas supply system. Using this argon plasma source, we studied the effects of the exposure time, the exposure distance, the input power, and the gas flow rate on the reduction rate of Escherichia coli cells. The first part of the study was carried out with a static sample exposed to the plasma and then in the second part the sample was set in motion relative to the plasma jet. A log reduction number of E. coli of 4 (10<sup>-4 </sup>CFU/mL) was obtained with UV and active species, for UV only a log of 1 (10<sup>-1</sup> CFU/mL) was obtained.
文摘Hydrogen is an alternative energy source that has the potential to replace fossil fuels.One of the hydrogen applications is as a material for Polymer Electrolyte Membrane Fuel Cells(PEMFC)in fuel cell vehicles.High-purity hydrogen can be obtained using a hydrogen separation membrane to prevent unwanted contaminants from potentially harming the PEMFC components.In this study,we fabricated a plasma membrane reactor and investigated the permeation performance of a hydrogen separation membrane in a plasma membrane reactor utilizing atmospheric pressure plasma.The result showed the hydrogen permeation rate increasing with time as reactor temperature is increased through joule heating.By decreasing the gap length of the reactor from 2 to 1 mm,the hydrogen permeation rate increases by up to 40%.The hydrogen permeation rate increases by 30%when pressure is applied to the plasma membrane reactor by up to 100 kPa.
基金Acknowledgement The authors are grateful to the financial support for this project from the National Natural Science Foundation of China under grant No. 50540420570.
文摘The plasma arc pressure plays an important role in determining the keyhole formation and size. So it is of great significance to choose adaptive distribution mode of the plasma arc pressure for determining keyhole shape and size. In this study, through employing a double-elliptic distribution mode of plasma arc pressure, three-dimensional keyhole was numerically simulated. The unsymmetric feature of the keyhole inside the weld pool was described. The development of keyhole was demonstrated under different levels of welding current. The critical current required to form an open keyhole was obtained for the study cases .
基金supported by grants from National Natural Science Foundation of China(Nos.81701014,81801310,31700076)the Basic Research of Natural Science Project funded by the Department of Science and Technology of Shaanxi Province(No.2017JM8038)the Science and Technology Project funded by the Science and Technology Bureau of Weiyang District,Xi’an city(No.201846)。
文摘In this study, we employed a nonthermal atmospheric pressure plasma(NTAPP) jet to evaluate the effect of plasma treatment on the durability of resin–dentin bonding under a thermocycling challenge. Furthermore, we assessed the degradation resistance of plasma-treated collagen under a sodium hypochlorite(NaClO) challenge. We assessed the beneficial effect of NTAPP treatment on the acid-etched dentin–bonding interface by testing the micro-tensile bond strength and examining the morphology. We found that the immediate bonding strength of the dentin significantly increased after NTAPP treatment. Compared with the control group, NTAPP resulted in a more prominent effect on the bonding durability of the dentin–adhesive interface after treatment for 5 or 10 s. Simultaneously, the mechanical strength of dentin collagen under the NaClO challenge was improved. Our results indicate that, in optimal conditions, NTAPP could be a promising method to protect dentin collagen and to improve the bonding durability between dentin and etch-and-rinse adhesives.
基金supported by National Natural Science Foundation of China(Nos.51077008 and 11247239)
文摘An atmospheric pressure plasma jet generated in Ar and O2/Ar mixtures has been investigated by specially designed equipment with double power electrodes at 20~32 kHz, and their effects on the cleaning of surfaces have been studied. Properties of the jet discharge are studied by electrical diagnostics, including the waveform of discharge voltage, discharge current and the Q-V Lissajous figures. The optical emission spectroscopy is used to measure the plasma parameters, such as the excitation temperature and the gas temperature. It is found that the consumed power and the excitation temperature increase with increase of the discharge frequency. On the other hand, at the same discharge frequency, these parameters in O2/Ar mixture plasma are found to be much larger. The effect on surface cleaning is studied from the changes in the contact angle. For Ar plasma jet, the contact angle decreases with increase of the discharge frequency. For O2/Ar mixture plasma jet, the contact angle decreases with increase of discharge frequency up to 26 kHz, however, further increase of discharge frequency does not show further decrease in the contact angle. At the same discharge frequency, the contact angle after O2/Ar mixture plasma cleaning is found to be much lower compared to the case of pure Ar. From the results of quadrupole mass-spectrum analysis, we can identify more fragment molecules of CO and H2O in the emitted gases after O2/Ar plasma jet treatment compared with Ar plasma jet treatment, which are produced by the decomposition of surface organic contaminants during the cleaning process.
基金financially supported by National Natural Science Foundation of China (Grant Nos. 51777206, 51807046 and 51877208)the Natural Science Foundation of Anhui Province (Grant Nos. 1908085MA29 and 1808085MA13)。
文摘Atmospheric pressure cold plasma, with advantages such as high particle activity, no thermal damage, high efficiency and direct and friendly contact with human tissues, is considered to have great potential in biomedical applications. Therefore, 'plasma medicine' as a new interdiscipline has been developed in the past two decades. This review first briefly describes the development of typical plasma sources suitable for biomedical applications, and those with different discharge forms are simply compared, evaluated and summarized. Subsequently, measurement of the crucial gaseous reactive particles(e.g. OH and O) and their spatio-temporal distributions are introduced. Meanwhile, the generation and variation rules and the related critical macroscopic parameters of the plasma-induced aqueous reactive species are summarized. Finally, related studies in the last ten years on the mechanisms of the plasma-driven microbial inactivation and plasma-induced apoptosis of cancer cells are introduced. Moreover, some scientific problems that need to be urgently solved in the field of plasma medicine are also discussed. This review will provide useful guidance for future related research.
基金The authors are grateful to the financial support for this project from the National Natural Science Foundation of China (No. 50936003 ).
文摘A unified numerical model is developed to couple the plasma arc, weld pool and keyhole in a self consistent way. The plasma arc/anode interface and the melt/solid interface are treated specially, the VOF method is used to trace the moving keyhole wall, and the fluid flow and heat transfer in both the plasma arc and weld pool are numerically simulated. The distributions of current density and arc pressure on the weld pool surface during the keyhole formation process are analyzed using the coupled model. The predicted arc pressure and current density are compared with the experimentally measured results, and both are in good agreement.
基金Project supported by the National Natural Science Foundation of China(Grant No.11175157)the Zhejiang Provincial Key Innovation Team,China(Grant No.2012R10038)the 521 Talent Project of Zhejiang Sci-Tech University,China
文摘Three different low-temperature plasma-based methods were used to improve the surface hydrophilicity of polyethy- lene (PE) films, and all the modification processes were carried out by employing an atmospheric pressure plasma jet (APPJ) system. (a) PE films were directly modified by APPJ using a gas mixture of He and 02. (b) Acrylic acid (AA) was introduced into the system and a polymer acrylic acid (PAA) coating was deposited onto the PE films. (c) AA was grafted onto the PE surface activated by plasma pre-treatment. It was found that the hydrophilicity of the PE films was significantly improved for all the three methods. However, the samples modified by Process (a) showed hydrophobicity recovery after a storage time of 20 days while no significant change was found in samples modified by Process (b) and Process (c). The Fourier transform infrared spectroscopy (FTIR) results indicated that the most intensive C=O peak was detected on the PE surface modified by Process (c). According to the X-ray photoelectron spectroscopy (XPS) analysis, the ratios of oxygen-containing polar groups for samples modified by Process (b) and Process (c) were higher than that modified by Process (a).
基金jointly supported by the Education and Research Foundation of Anhui Province(KJ2015A327)Science Foundation of Institute of Plasma Physics,Chinese Academy of Sciences No.DSJJ-14-YY02Hong Kong Research Grants Council(RGC)General Research Funds(GRF)No.CityU 11301215
文摘An atmospheric-pressure air plasma is employed to treat C6 glioma cells in vitro. To elucidate on the mechanism causing cell death and role of reactive species (RS) in the medium produced by the plasma, the concentration of the long-lived RS such as hydrogen peroxide, nitrate, and ozone in the plasma-treated liquid (phosphate-buffered saline solution) is measured. When vitamin C is added to the medium as a ROS quencher, the viability of C6 glioma cells after the plasma treatment is different from that without vitamin C. The results demonstrate that reactive oxygen species (ROS) such as H2O2, and O3 constitute the main factors for inactivation of C6 glioma cells and the reactive nitrogen species (RNS) may only play an auxiliary role in cell death.
基金supported by the National Key Research and Development Program of China(Nos.2017YFA0402300,2017YFA0304900 and 2016YFA0300600)National Natural Science Foundation of China(Nos.11604334,11575099,11474347 and 11874051)+1 种基金the Strategic Priority Research Program of Chinese Academy of Sciences(Nos.XDB28000000and XDB07030000)the Open Research Fund Program of the State Key Laboratory of Low-Dimensional Quantum Physics(KF201807)。
文摘A non-equilibrium atmospheric pressure argon(Ar)plasma excited by microsecond pulse is studied experimentally by laser scattering and optical emission spectroscopy(OES),and theoretically by collisional-radiative(CR)model.More specifically,the electron temperature and electron density of plasma are obtained directly by the laser Thomson scattering,the gas temperature is measured by laser Raman scattering,the optical emissions of excited Ar states of plasma are measured by OES.The laser scattering results show that the electron temperature is about 1 eV which is similar to that excited by 60 Hz AC power,but the gas temperature is as low as 300 K compared to about 700 K excited by 60 Hz AC power.It is shown that the microsecond pulsed power supply,rather than nanosecond ones,is short enough to reduce the gas temperature of atmospheric pressure plasma to near room temperature.The electron temperature and electron density are also obtained by CR model based on OES,and find that the intensities of the optical emission intensity lines of 727.41,811.73,841.08,842.83,852.44 and 912.86 nm of Ar can be used to characterize the behavior of electron density and electron temperature,it is very useful to quickly estimate the activity of the atmospheric pressure Ar plasma in many applications.
基金supported by National Natural Science Foundation of China (No. 10875048)
文摘Enterococcus faecalis (E. faecalis) is a microorganism that can survive extreme challenges in obturated root canals. The aim of this study was to evaluate the efficacy of a non-thermal atmospheric pressure plasma plume against E. faecalis in vitro. A non-thermal atmospheric pressure plasma jet device which could generate a cold plasma plume carrying a peak current of 300 mA was used. The antibacterial efficacy of this device against E. faecalis and its biofihn un- der different conditions was detected. The antibacterial efficacy of the plasma against E. faecalis and Staphylococcus aureus (S. aureus) was also evaluated. After plasma treatment, the average diameter of inhibition zone on S. aureus and E. faecalis was 2.62±0.26 cm and 1.06±0.30 cm, respectively (P 〈 0.05). The diameter was increased with prolongation of the treatment dura- tion. The diameters of inhibition zone of the sealed Petri dishes were larger than those of the uncovered Petri dishes. There was significant difference in colony-forming units between plasma group and control group on E. faecalis biofilm (P 〈 0.01). The transmission electron microscopy revealed that the ultrastructural changes eytoderm of E. faecalis were observed after treatment for 2min. It is concluded that the non-thermal atmospheric pressure plasma could serve as an effective adjunct to standard endodontie microbial treatment.
文摘This paper reports that a new plasma generator at atmospheric pressure, which is composed of two homocentric cylindrical all-metal tubes, successfully generates a cold plasma jet. The inside tube electrode is connected to ground, the outside tube electrode is connected to a high-voltage power supply, and a dielectric layer is covered on the outside tube electrode. When the reactor is operated by low-frequency (6 kHz-20 kHz) AC supply in atmospheric pressure and argon is steadily fed as a discharge gas through inside tube electrode, a cold plasma jet is blown out into air and the plasma gas temperature is only 25-30℃. The electric character of the discharge is studied by using digital real-time oscilloscope (TDS 200-Series), and the discharge is capacitive. Preliminary results are presented on the decontamination of E.colis bacteria and Bacillus subtilis bacteria by this plasma jet, and an optical emission analysis of the plasma jet is presented in this paper. The ozone concentration generated by the plasma jet is 1.0× 10^16cm^-3 which is acquired by using the ultraviolet absorption spectroscopy.