Patterned silver nanowire(AgNW)networks have been widely used as transparent electrodes in many optoelectrical devices.However,obvious patterning visibility and poor thermostability of AgNW are still limiting its prac...Patterned silver nanowire(AgNW)networks have been widely used as transparent electrodes in many optoelectrical devices.However,obvious patterning visibility and poor thermostability of AgNW are still limiting its practical application.Herein,we report self-assembled monolayer(SAM)modulated Plateau-Rayleigh instability(PRI)of AgNW,which allows invisible patterning and superior stability of the AgNW network.Two opposite effects of different SAMs on the PRI are identified:the alkanethiol SAMs activate surface atom diffusion while the mercaptobenzoheterocyclic(MBH)SAMs suppress the diffusion.The degradation temperature of the AgNWs can be therefore,for the first time,tuned in the range of 193-381℃,so that the AgNW network can be patterned via PRI with a tiny optical difference between the insulative and conductive regions,i.e.,patterning invisible.Besides,the MBH SAMs provide AgNW with excellent durability under thermal annealing and oxidation,which enhances the maximum heating temperature of the AgNW transparent heater by over 120℃.Beyond the micro-patterning,we consider that the developed SAM strategy can be extended to other metal nanowires for stability improvement and has huge potential in nanoengineering of one-dimensional metal materials.展开更多
A shear-wave velocity model of the crust and uppermost mantle beneath the SE Tibetan plateau was derived by inverting Rayleigh-wave group-velocity measurements of periods between 10 and 70 s. Rayleigh-wave group-veloc...A shear-wave velocity model of the crust and uppermost mantle beneath the SE Tibetan plateau was derived by inverting Rayleigh-wave group-velocity measurements of periods between 10 and 70 s. Rayleigh-wave group-velocity dispersions along more than 3,000 interstation paths were measured based on analysis of teleseismic waveform data recorded by temporary seismic stations. These observations were then utilized to construct2 D group-velocity maps in the period range of 10–70 s.The new group-velocity maps have an enhanced resolution compared with previous global and regional group-velocity models in this region because of the denser and more uniform data coverage. The lateral resolution across the region is about 0.5° for the periods used in this study. Local dispersion curves were then inverted for a 3D shear-wave velocity model of the region by applying a linear inversion scheme. Our 3D shear-wave model confirms the presence of low-velocity zones(LVZs) in the crust beneath the northern part of this region. Our imaging shows that the upper-middle crustal LVZ beneath the Tengchong region is isolated from these LVZs beneath the eastern and northern part of this region. The upper–middle crustal LVZ may be regarded as evidence of a magma chamber in the crust beneath the Tengchong Volcanoes. Our model also reveals a slow lithospheric structure beneath Tengchong and a fast shield-like mantle beneath the stable Yangtze block.展开更多
In this paper,218 long period Rayleigh wave records from 7 seismic station of CDSN are selected.We applied a partitioned waveform inversion to these data in order to construct a 3\|D model of shear velocity down to 40...In this paper,218 long period Rayleigh wave records from 7 seismic station of CDSN are selected.We applied a partitioned waveform inversion to these data in order to construct a 3\|D model of shear velocity down to 400km depth in the crust and upper mantle of Qinghai\|Tibet plateau and Its Adjacent Regions (22°～44°N,70°～110°E).The first step of the waveform inversion used involved the matching of the waveforms of fundamental and highermost Ravleigh waves with waveforms synthesized from stratified models;in the second stage,the 3\|D model was constructed by solve linear constrains equation. The major structural features inferred from the surface waveform inversions can be summarized as follows:(1) There is a great contrast between surface waveform through Qinghai—Thibet plateau and the others.Main frequency of the former is lower than the latter, which indicate the crust depth of Qinghai—Tibet plateau is deeper than the others. In addition,the amplitude of about 30s period and 50s period is lower than both sides,which implied these exist lower velocity layer at about 25km depth and about 50km depth in Qinghai—Tibet plateau Crust.The former is common,the latter was argued because resolution of most method can not prove it.展开更多
基金The work is supported by the National Natural Science Foundation of China(Nos.61904067,62175094,61805108,and 62075088)Science and Technology Projects in Guangzhou(No.202102020758)+3 种基金Guangdong Basic and Applied Basic Research Foundation(No.2020A1515011498)Scientific and Technological Projection of Guangdong province(No.2020B1212060030)KeyArea Research and Development Program of Guangdong Province(No.2019B010934001)Fundamental Research Funds for the Central Universities(Nos.21621405 and 21620328).
文摘Patterned silver nanowire(AgNW)networks have been widely used as transparent electrodes in many optoelectrical devices.However,obvious patterning visibility and poor thermostability of AgNW are still limiting its practical application.Herein,we report self-assembled monolayer(SAM)modulated Plateau-Rayleigh instability(PRI)of AgNW,which allows invisible patterning and superior stability of the AgNW network.Two opposite effects of different SAMs on the PRI are identified:the alkanethiol SAMs activate surface atom diffusion while the mercaptobenzoheterocyclic(MBH)SAMs suppress the diffusion.The degradation temperature of the AgNWs can be therefore,for the first time,tuned in the range of 193-381℃,so that the AgNW network can be patterned via PRI with a tiny optical difference between the insulative and conductive regions,i.e.,patterning invisible.Besides,the MBH SAMs provide AgNW with excellent durability under thermal annealing and oxidation,which enhances the maximum heating temperature of the AgNW transparent heater by over 120℃.Beyond the micro-patterning,we consider that the developed SAM strategy can be extended to other metal nanowires for stability improvement and has huge potential in nanoengineering of one-dimensional metal materials.
基金supported by the China National Special Fund for Earthquake Scientific Research in Public Interest(201008001)NSFC(41074067)
文摘A shear-wave velocity model of the crust and uppermost mantle beneath the SE Tibetan plateau was derived by inverting Rayleigh-wave group-velocity measurements of periods between 10 and 70 s. Rayleigh-wave group-velocity dispersions along more than 3,000 interstation paths were measured based on analysis of teleseismic waveform data recorded by temporary seismic stations. These observations were then utilized to construct2 D group-velocity maps in the period range of 10–70 s.The new group-velocity maps have an enhanced resolution compared with previous global and regional group-velocity models in this region because of the denser and more uniform data coverage. The lateral resolution across the region is about 0.5° for the periods used in this study. Local dispersion curves were then inverted for a 3D shear-wave velocity model of the region by applying a linear inversion scheme. Our 3D shear-wave model confirms the presence of low-velocity zones(LVZs) in the crust beneath the northern part of this region. Our imaging shows that the upper-middle crustal LVZ beneath the Tengchong region is isolated from these LVZs beneath the eastern and northern part of this region. The upper–middle crustal LVZ may be regarded as evidence of a magma chamber in the crust beneath the Tengchong Volcanoes. Our model also reveals a slow lithospheric structure beneath Tengchong and a fast shield-like mantle beneath the stable Yangtze block.
文摘In this paper,218 long period Rayleigh wave records from 7 seismic station of CDSN are selected.We applied a partitioned waveform inversion to these data in order to construct a 3\|D model of shear velocity down to 400km depth in the crust and upper mantle of Qinghai\|Tibet plateau and Its Adjacent Regions (22°～44°N,70°～110°E).The first step of the waveform inversion used involved the matching of the waveforms of fundamental and highermost Ravleigh waves with waveforms synthesized from stratified models;in the second stage,the 3\|D model was constructed by solve linear constrains equation. The major structural features inferred from the surface waveform inversions can be summarized as follows:(1) There is a great contrast between surface waveform through Qinghai—Thibet plateau and the others.Main frequency of the former is lower than the latter, which indicate the crust depth of Qinghai—Tibet plateau is deeper than the others. In addition,the amplitude of about 30s period and 50s period is lower than both sides,which implied these exist lower velocity layer at about 25km depth and about 50km depth in Qinghai—Tibet plateau Crust.The former is common,the latter was argued because resolution of most method can not prove it.
