According to the factors that confirm the shape of surface, it is classified into two categories: arc surface and curve surface The method to confirm the category of surfaces and the plotting methods are discussed in...According to the factors that confirm the shape of surface, it is classified into two categories: arc surface and curve surface The method to confirm the category of surfaces and the plotting methods are discussed in this paper, which provide guidance for parts plotting.展开更多
The non-isothermal kinetics of mechanochemical reduction of Ag2O with graphite was studied by DSC and TGA with a model of fitting Malek approach and a model-free advanced isoconversional method of Vyazovkin. To evalua...The non-isothermal kinetics of mechanochemical reduction of Ag2O with graphite was studied by DSC and TGA with a model of fitting Malek approach and a model-free advanced isoconversional method of Vyazovkin. To evaluate the kinetics parameters, Ag2O–graphite mixture of as-received and milled for 2 and 4 h samples were selected. Based on the results obtained by Vyazovkin method calculation, however, the difference between the maximum and minimum values of activation energy is less than 20%-30%of the average activation energy ((99.38±2.36) kJ/mol) and thermal decomposition of mechanically activated Ag2O for 2 h is a multi-step process. Moreover, the thermal decomposition of mechanically activated Ag2O–graphite powder activated for 4 h is a single-step process (the average activation energy=(93.68±2.26) kJ/mol). The kinetics modeling shows that the complexity of thermal decomposition of as-received Ag2O–graphite mixture is higher than that of the others. While, the autocatalytic tendency of as-received Ag2O–graphite mixture is lower than that of the others.展开更多
In this paper,nitrogen dielectric barrier discharge(DBD) plasma was generated in a quartz tube with coaxial wire-cylinder electrodes at atmospheric pressure.By varying the nitrogen gas flow(FN) in the range of 0-1...In this paper,nitrogen dielectric barrier discharge(DBD) plasma was generated in a quartz tube with coaxial wire-cylinder electrodes at atmospheric pressure.By varying the nitrogen gas flow(FN) in the range of 0-1 m3/h,the plasma optical emission spectra(OES) were measured and studied.The vibration(T_(vib)) and rotation temperature(T_(rot)) of nitrogen were obtained,by fitting the rovibronic bands of N_2(C^3∏_u-B^3∏_g,0-1),and by the Boltzmann plot method for purposes of comparison.T_(vib) increased up to 2481 K with increasing nitrogen flow till0.2 m3/h,and then decreased with further increasing FN,while Trot decreased monotonously and approached to-350 K for FN ≥ 0.6 m^3/h.The intensity of N_2(C^3∏_u-B^3∏_g,0-0,1-0,0-3) and N_2~+(B^2∑_u~+-X^2Σ_g~+,0-0) exhibited similar evolution with increasing FN to those of the T_(vib) and Trot,respectively.The discharge photos revealed that the discharge filaments gradually decreased with increasing FN,and eventually disappeared,which implied that a discharge mode transition emerged with increasing FN.The possible mechanism for the discharge mode transition is studied in detail according to the vibration(T_(vib)) and rotation temperature(T_(rot)) of nitrogen.展开更多
A group of the stainless steel laser welding was performed using continuous wave (CW) laser and pulsed laser. During the welding process the laser induced plasma behavior was recorded by high-speed video camera, whi...A group of the stainless steel laser welding was performed using continuous wave (CW) laser and pulsed laser. During the welding process the laser induced plasma behavior was recorded by high-speed video camera, while the plasma spectrum was acquired by the spectrometer. The plasma temperature was calculated based on the spectroscopic analysis of the optical emission and the results show that different output mode of laser source led to big difference of plasma temperature. The high-speed video images showed that the plasma was very steady and kept certain strength in CW laser welding, while the plasma erupted a little later after the laser peak arising during the pulsed laser welding. During a period of time about 2 ms just after the laser peak arising during the pulsed laser welding, much more laser energy reached the workpiece. This made the workpicce fully penetrated with a lower average power.展开更多
The resonant flow of an incompressible, inviscid fluid with surface tension on varying bottoms was researched. The effects of different bottoms on the nonlinear surface waves were analyzed. The waterfall plots of the ...The resonant flow of an incompressible, inviscid fluid with surface tension on varying bottoms was researched. The effects of different bottoms on the nonlinear surface waves were analyzed. The waterfall plots of the wave were drawn with Matlab according to the numerical simulation of the fKdV equation with the pseudo-spectral method. From the waterfall plots, the results are obtained as follows: for the convex bottom, the waves system can be viewed as a combination of the effects of forward-step forcing and backwardstep forcing, and these two wave systems respectively radiate upstream and downstream without mutual interaction. Nevertheless, the result for the concave bottom is contrary to the convex one. For some combined bottoms, the wave systems can be considered as the combination of positive forcing and negative forcing.展开更多
Thermal degradation of vegetable-tanned leather fiber(VLF)was investigated by thermogravimetric analysis aiming to know the exact kinetics and degradation mechanism.The thermogravimetric(TG)and differential thermograv...Thermal degradation of vegetable-tanned leather fiber(VLF)was investigated by thermogravimetric analysis aiming to know the exact kinetics and degradation mechanism.The thermogravimetric(TG)and differential thermogravimetric(DTG)curves showed that decomposition of the VLF occurs mainly in the range of 150-600℃,and the latter exhibits asymmetrical peak with a pronounced shoulder.The decomposition process was first analyzed by deconvolution of the experimental DTG curves,followed by reconstruction of the weight loss profiles of two individual processes.Several common isoconversional approaches were applied to calculate the activation energy over a wide range of conversion for the sample,including modified Kissinger-Akahira-Sunose(MKAS),Friedman,and Flynn-Wall-Ozawa.The average activation energy of vegetable-tanned leather fiber was found to be 241.9 kJ mol^(−1) by MKAS method.The activation energy values obtained for the pseudocomponents representing highly-crosslinked and low-crosslinked collagen in VLF were given as 190.6 and 124.8 kJ mol^(−1),respectively.Generalized master plots results suggested that the reaction mechanism for highly-crosslinked collagen follows the random nucleation and growth process at conversion values lower than 0.5.When the conversion is higher than 0.5,the mechanism tends to random scission model.For low-crosslinked collagen,the degradation is mainly governed by random nucleation and nuclei growth.The gaseous products of VLF thermal degradation were analyzed with an online-coupled TG-Fourier transform infrared spectroscopy system.展开更多
文摘According to the factors that confirm the shape of surface, it is classified into two categories: arc surface and curve surface The method to confirm the category of surfaces and the plotting methods are discussed in this paper, which provide guidance for parts plotting.
文摘The non-isothermal kinetics of mechanochemical reduction of Ag2O with graphite was studied by DSC and TGA with a model of fitting Malek approach and a model-free advanced isoconversional method of Vyazovkin. To evaluate the kinetics parameters, Ag2O–graphite mixture of as-received and milled for 2 and 4 h samples were selected. Based on the results obtained by Vyazovkin method calculation, however, the difference between the maximum and minimum values of activation energy is less than 20%-30%of the average activation energy ((99.38±2.36) kJ/mol) and thermal decomposition of mechanically activated Ag2O for 2 h is a multi-step process. Moreover, the thermal decomposition of mechanically activated Ag2O–graphite powder activated for 4 h is a single-step process (the average activation energy=(93.68±2.26) kJ/mol). The kinetics modeling shows that the complexity of thermal decomposition of as-received Ag2O–graphite mixture is higher than that of the others. While, the autocatalytic tendency of as-received Ag2O–graphite mixture is lower than that of the others.
基金supported by National Natural Science Foundation of China(Nos.11475040,11375041)the Fundamental Research Funds for the Central Universities(No.DUT14ZD[G]04)
文摘In this paper,nitrogen dielectric barrier discharge(DBD) plasma was generated in a quartz tube with coaxial wire-cylinder electrodes at atmospheric pressure.By varying the nitrogen gas flow(FN) in the range of 0-1 m3/h,the plasma optical emission spectra(OES) were measured and studied.The vibration(T_(vib)) and rotation temperature(T_(rot)) of nitrogen were obtained,by fitting the rovibronic bands of N_2(C^3∏_u-B^3∏_g,0-1),and by the Boltzmann plot method for purposes of comparison.T_(vib) increased up to 2481 K with increasing nitrogen flow till0.2 m3/h,and then decreased with further increasing FN,while Trot decreased monotonously and approached to-350 K for FN ≥ 0.6 m^3/h.The intensity of N_2(C^3∏_u-B^3∏_g,0-0,1-0,0-3) and N_2~+(B^2∑_u~+-X^2Σ_g~+,0-0) exhibited similar evolution with increasing FN to those of the T_(vib) and Trot,respectively.The discharge photos revealed that the discharge filaments gradually decreased with increasing FN,and eventually disappeared,which implied that a discharge mode transition emerged with increasing FN.The possible mechanism for the discharge mode transition is studied in detail according to the vibration(T_(vib)) and rotation temperature(T_(rot)) of nitrogen.
基金This project is supported by Natural Science Foundation of Tianjin (11JCYBJC06100) and State Key Lab of Advanced Welding and Joining ( AWPT-M12-08 ).
文摘A group of the stainless steel laser welding was performed using continuous wave (CW) laser and pulsed laser. During the welding process the laser induced plasma behavior was recorded by high-speed video camera, while the plasma spectrum was acquired by the spectrometer. The plasma temperature was calculated based on the spectroscopic analysis of the optical emission and the results show that different output mode of laser source led to big difference of plasma temperature. The high-speed video images showed that the plasma was very steady and kept certain strength in CW laser welding, while the plasma erupted a little later after the laser peak arising during the pulsed laser welding. During a period of time about 2 ms just after the laser peak arising during the pulsed laser welding, much more laser energy reached the workpiece. This made the workpicce fully penetrated with a lower average power.
基金Project supported by the National Natural Science Foundation of China(No.10272044)the Ph. D. Programs Foundation of Ministry of Education of China(No.20040079004)
文摘The resonant flow of an incompressible, inviscid fluid with surface tension on varying bottoms was researched. The effects of different bottoms on the nonlinear surface waves were analyzed. The waterfall plots of the wave were drawn with Matlab according to the numerical simulation of the fKdV equation with the pseudo-spectral method. From the waterfall plots, the results are obtained as follows: for the convex bottom, the waves system can be viewed as a combination of the effects of forward-step forcing and backwardstep forcing, and these two wave systems respectively radiate upstream and downstream without mutual interaction. Nevertheless, the result for the concave bottom is contrary to the convex one. For some combined bottoms, the wave systems can be considered as the combination of positive forcing and negative forcing.
基金National Key Research and Development Program(2017YFB0308500)National Natural Science Foundation Commission of China(51673177,U1204504)Science and Technology Project of Henan Province(172102410022).
文摘Thermal degradation of vegetable-tanned leather fiber(VLF)was investigated by thermogravimetric analysis aiming to know the exact kinetics and degradation mechanism.The thermogravimetric(TG)and differential thermogravimetric(DTG)curves showed that decomposition of the VLF occurs mainly in the range of 150-600℃,and the latter exhibits asymmetrical peak with a pronounced shoulder.The decomposition process was first analyzed by deconvolution of the experimental DTG curves,followed by reconstruction of the weight loss profiles of two individual processes.Several common isoconversional approaches were applied to calculate the activation energy over a wide range of conversion for the sample,including modified Kissinger-Akahira-Sunose(MKAS),Friedman,and Flynn-Wall-Ozawa.The average activation energy of vegetable-tanned leather fiber was found to be 241.9 kJ mol^(−1) by MKAS method.The activation energy values obtained for the pseudocomponents representing highly-crosslinked and low-crosslinked collagen in VLF were given as 190.6 and 124.8 kJ mol^(−1),respectively.Generalized master plots results suggested that the reaction mechanism for highly-crosslinked collagen follows the random nucleation and growth process at conversion values lower than 0.5.When the conversion is higher than 0.5,the mechanism tends to random scission model.For low-crosslinked collagen,the degradation is mainly governed by random nucleation and nuclei growth.The gaseous products of VLF thermal degradation were analyzed with an online-coupled TG-Fourier transform infrared spectroscopy system.