The fully oxidized state of polyaniline (PANI), pernigraniline (PN), was synthesized by oxidation of the emeraldine base form of PAM dissolved in NMP solvent with m-chloroperoxybenzoic acid. The resulted PN was charac...The fully oxidized state of polyaniline (PANI), pernigraniline (PN), was synthesized by oxidation of the emeraldine base form of PAM dissolved in NMP solvent with m-chloroperoxybenzoic acid. The resulted PN was characterized by FTIR and UV-Visible spectra. The third-order nonlinear optical properties of PN in concentrated sulfuric acid (PN/H2SO4) were measured by a degenerated four wave mixing (DFWM) method. The results obtained suggest that the soliton-pair intermediate state associated with the degenerated state does not play a major role in the third order nonlinear optical properties of PANI.展开更多
Water surface wave turbulence is one of the factors afecting the performances of underwater optical wireless communication(UOWC)systems.In our research,a phase-conjugate beam was used to correct the beam distortion an...Water surface wave turbulence is one of the factors afecting the performances of underwater optical wireless communication(UOWC)systems.In our research,a phase-conjugate beam was used to correct the beam distortion and enhance the communication performances when a system is subject to surface wave turbulence.The phase-conjugate beam was generated by a phase-conjugate mirror(PCM),and a turbulence generator was used to generate surface wave turbulence in the experiment.We calculated the beam centroid distribution and the results showed that the phase-conjugate beam had a better propagation performance than the distorted beam at the diferent water depths.The root mean square(RMS)of the beam centroid for the phase-conjugate beam was 11 times less than that for the distorted beam,which meant that the phase-conjugate beam could efectively correct the beam drift.We further investigated the scintillation index and the signal-to-noise ratio(SNR);the results showed that the phase-conjugate beam was able to reduce the scintillation and an obvious improvement in SNR could be obtained.This research has the potential to be applied in UWC.展开更多
基金This work was partly supported by NNSFC,Chinese Academy of Sciences and Director Foundation of the Institute of Chemistry,Academia Sinica
文摘The fully oxidized state of polyaniline (PANI), pernigraniline (PN), was synthesized by oxidation of the emeraldine base form of PAM dissolved in NMP solvent with m-chloroperoxybenzoic acid. The resulted PN was characterized by FTIR and UV-Visible spectra. The third-order nonlinear optical properties of PN in concentrated sulfuric acid (PN/H2SO4) were measured by a degenerated four wave mixing (DFWM) method. The results obtained suggest that the soliton-pair intermediate state associated with the degenerated state does not play a major role in the third order nonlinear optical properties of PANI.
基金supported by the National Natural Science Foundation of China(Grant No.62005088)Foundation for Young Scientists of the Education Ministry of China(No.18B352)+1 种基金Hunan Provincial Natural Science Foundation of China(No.2020JJ4331)the project supported by the Science and Technology Program of Hunan Province,China(No.2019TP1014).
文摘Water surface wave turbulence is one of the factors afecting the performances of underwater optical wireless communication(UOWC)systems.In our research,a phase-conjugate beam was used to correct the beam distortion and enhance the communication performances when a system is subject to surface wave turbulence.The phase-conjugate beam was generated by a phase-conjugate mirror(PCM),and a turbulence generator was used to generate surface wave turbulence in the experiment.We calculated the beam centroid distribution and the results showed that the phase-conjugate beam had a better propagation performance than the distorted beam at the diferent water depths.The root mean square(RMS)of the beam centroid for the phase-conjugate beam was 11 times less than that for the distorted beam,which meant that the phase-conjugate beam could efectively correct the beam drift.We further investigated the scintillation index and the signal-to-noise ratio(SNR);the results showed that the phase-conjugate beam was able to reduce the scintillation and an obvious improvement in SNR could be obtained.This research has the potential to be applied in UWC.
