In order to research the changing process of the pollution from the formation of Nansihu Lake, this study determined the isotope age and depositional rate and analyzed the organic geo-chem...In order to research the changing process of the pollution from the formation of Nansihu Lake, this study determined the isotope age and depositional rate and analyzed the organic geo-chemical quotas and heavy metal quotas of two sedimentary profiles of Weishan and Dushan lakes. Research results showed that from the formation of Nansihu Lake, the change of the pollution could be divided into four phrases. At the early phrase of the formation, the organic matters of the lake mainly derived from the exotic matters and had a close relation to the effect on the water and sands from the Huanghe (Yellow) River. At the middle and late phrases of the development, the endogenous matters of the lake became the main and stable source of the organic matters. The overflow of the Huanghe River, the excavation of the Grand Canal and the cut of trees caused the changes of the historic pollution. In recent 20 years, the modern industrial pollution from the organic matters and heavy metals has an increasingly heavy tendency.展开更多
Volatile hydrocarbons in urban environments pose significant risks to human and ecosystem health,resulting from wash-off into receiving waters during storm events.Effective mitigation strategies require understanding ...Volatile hydrocarbons in urban environments pose significant risks to human and ecosystem health,resulting from wash-off into receiving waters during storm events.Effective mitigation strategies require understanding of the significance of contributing factors to pollutant generation and their processes.This study employed Bayesian Network modelling to investigate how anthropogenic and environmental factors influence volatile hydrocarbons build-up.The volatile hydrocarbons investigated were,benzene,toluene,ethylbenzene and xylene and styrene.Most volatile hydrocarbons showed statistically significant relationships with environmental factors rather than with anthropogenic factors.Additionally,the research study found that anthropogenic factors could largely contribute to releasing volatile hydrocarbon into the urban environment,while environmental factors are likely to determine their prevalence.The research outcomes will contribute to improving stormwater quality modelling approaches and strengthen the assessment of risk associated with stormwater pollutants in order to enhance stormwater reuse.展开更多
This study focused on the manufacture of microcrystalline cellulose(MCC)from wheat straw using environmentally-friendly solvents.Raw cellulose was separated from wheat straw after thermal decomposition of lignin follo...This study focused on the manufacture of microcrystalline cellulose(MCC)from wheat straw using environmentally-friendly solvents.Raw cellulose was separated from wheat straw after thermal decomposition of lignin followed by dissolution of lignin using a recyclable ethanol/acetic acid/water solvent system.Then,pure cellulose was produced using a four-step refining process,including chelating,O_(3),H_(2)O_(2),and xylanase treatments.Finally,MCC was obtained through hydrolysis,drying,and mechanical treatments.The effects of acetic acid,O_(3),H_(2)O_(2),NaOH,pretreatment time,and temperature on the properties of wheat straw cellulose(including Kappa number,yield,α-cellulose content,crystallinity,KMnO4 value,degree of polymerization(DP),and brightness)were investigated.The results showed that the addition of acetic acid enhanced lignin removal and hemicellulose degradation,improving the purity of the raw cellulose.The optimized acetic acid dosage in the wheat straw thermal decomposition step was 2%(w/w).The optimized O_(3)dosage was 1.2%(w/w).The optimized conditions for H_(2)O_(2)treatment were found to be 3%(w/w)H_(2)O_(2)and 1.8%(w/w)NaOH at 70°C for 120 min.The KMnO4 value was 2.0,brightness was 84.1%ISO,the viscosity was 934 mL/g,and the DP was 626 for refined cellulose.Xylanase effectively improved theα-cellulose content of wheat straw cellulose.With an optimized xylanase dosage of 1.5 IU/g,theα-cellulose content was 94.7%,the brightness was 85.6%ISO,and the DP was 615 for wheat straw cellulose.展开更多
文摘In order to research the changing process of the pollution from the formation of Nansihu Lake, this study determined the isotope age and depositional rate and analyzed the organic geo-chemical quotas and heavy metal quotas of two sedimentary profiles of Weishan and Dushan lakes. Research results showed that from the formation of Nansihu Lake, the change of the pollution could be divided into four phrases. At the early phrase of the formation, the organic matters of the lake mainly derived from the exotic matters and had a close relation to the effect on the water and sands from the Huanghe (Yellow) River. At the middle and late phrases of the development, the endogenous matters of the lake became the main and stable source of the organic matters. The overflow of the Huanghe River, the excavation of the Grand Canal and the cut of trees caused the changes of the historic pollution. In recent 20 years, the modern industrial pollution from the organic matters and heavy metals has an increasingly heavy tendency.
基金We thank the National Natural Science Foundation of China(4160151021806110)+1 种基金China Postdoctoral Science Foundation(2018M643194),Key Field Research Project of Guangdong(2019B110205003)the Development and Reform Commission of Shenzhen Municipality(urban water recycling and environment safety program)to support this research study.
文摘Volatile hydrocarbons in urban environments pose significant risks to human and ecosystem health,resulting from wash-off into receiving waters during storm events.Effective mitigation strategies require understanding of the significance of contributing factors to pollutant generation and their processes.This study employed Bayesian Network modelling to investigate how anthropogenic and environmental factors influence volatile hydrocarbons build-up.The volatile hydrocarbons investigated were,benzene,toluene,ethylbenzene and xylene and styrene.Most volatile hydrocarbons showed statistically significant relationships with environmental factors rather than with anthropogenic factors.Additionally,the research study found that anthropogenic factors could largely contribute to releasing volatile hydrocarbon into the urban environment,while environmental factors are likely to determine their prevalence.The research outcomes will contribute to improving stormwater quality modelling approaches and strengthen the assessment of risk associated with stormwater pollutants in order to enhance stormwater reuse.
基金the Doctoral Program of Higher Education Projects(for the priority development areas)by Ministry of Education of China(Grant No.20126125130001)State Key Laboratory of Pulp and Paper Engineering open foundation(Grant No.201505)the Doctoral Scientific Research Foundation(Grant No.BJ13-02)by Shaanxi University of Science and Technology.
文摘This study focused on the manufacture of microcrystalline cellulose(MCC)from wheat straw using environmentally-friendly solvents.Raw cellulose was separated from wheat straw after thermal decomposition of lignin followed by dissolution of lignin using a recyclable ethanol/acetic acid/water solvent system.Then,pure cellulose was produced using a four-step refining process,including chelating,O_(3),H_(2)O_(2),and xylanase treatments.Finally,MCC was obtained through hydrolysis,drying,and mechanical treatments.The effects of acetic acid,O_(3),H_(2)O_(2),NaOH,pretreatment time,and temperature on the properties of wheat straw cellulose(including Kappa number,yield,α-cellulose content,crystallinity,KMnO4 value,degree of polymerization(DP),and brightness)were investigated.The results showed that the addition of acetic acid enhanced lignin removal and hemicellulose degradation,improving the purity of the raw cellulose.The optimized acetic acid dosage in the wheat straw thermal decomposition step was 2%(w/w).The optimized O_(3)dosage was 1.2%(w/w).The optimized conditions for H_(2)O_(2)treatment were found to be 3%(w/w)H_(2)O_(2)and 1.8%(w/w)NaOH at 70°C for 120 min.The KMnO4 value was 2.0,brightness was 84.1%ISO,the viscosity was 934 mL/g,and the DP was 626 for refined cellulose.Xylanase effectively improved theα-cellulose content of wheat straw cellulose.With an optimized xylanase dosage of 1.5 IU/g,theα-cellulose content was 94.7%,the brightness was 85.6%ISO,and the DP was 615 for wheat straw cellulose.