Poly(p-phenylene terephthalamide)(PPTA)pulp was prepared by polycondensation of the p-phenylene diamine(PPDA)with terephthaloyl chloride(TPC)in the completely anhydrous solvent system of N-methyl pyrrolidone(NMP)havin...Poly(p-phenylene terephthalamide)(PPTA)pulp was prepared by polycondensation of the p-phenylene diamine(PPDA)with terephthaloyl chloride(TPC)in the completely anhydrous solvent system of N-methyl pyrrolidone(NMP)having calcium chloride,in the presence of poly(vinyl pyrrolidone)(PVP)having a viscosity average molecular weight lower than 40 000.It was confirmed that the polycondensation could be accelerated,the inherent viscosity of the polymer could be increased,and the polymers could be fibrillated more easily by the addition of the PVP.FTIR and X-ray spectra proved that PVP had not combined into molecular chains of the resultant PPTA pulps.The morphology of the resultant pulps,the effect of viscosity average molecular weight,amount and adding mode of PVP on inherent viscosity,specific surface area,and mean length of the resultant pulps were discussed in detail.And the friction and wear properties of the compound reinforced by the resultant pulps were simply investigated.展开更多
The effect of N,N,N＇,N＇-tetraalkyl terephthalamide （TATA） on the non-isothermal crystallization and melting characteristics ofpolypropylene （PP） was studied. The addition of TATA can lead to the formation ofβ-c...The effect of N,N,N＇,N＇-tetraalkyl terephthalamide （TATA） on the non-isothermal crystallization and melting characteristics ofpolypropylene （PP） was studied. The addition of TATA can lead to the formation ofβ-crystal PP. With the increase in TATA concentration the degree of crystallinity for β-crystal PP increased significantly, and that for a-crystal PP decreased, which indicated that TATA effectively induced the formation of β-crystal PP. WAXD also revealed the existence of β-crystal PP after the introduction of TATA into PP. PP containing TATA crystallized at a temperature range of 5-10℃ higher than that of pure PP, and the half-crystallization time （t1/2） and Avrami exponent （n） of PP at the same cooling rate were decreased by the addition of TATA, indicating that TATA influenced the crystallization rate and crystallization growth mode of PP. The rate constant of crystallization of PP containing TATA （Zc） was larger than that of pure PP, which further indicated that the crystallization of PP was accelerated by the addition of TATA.展开更多
The relationship between property and structure of poly( p-phenylene terephthalamide)( PPTA) was investigated for the purpose of obtaining products with better performance. PPTA fiber subjected to heat treatment under...The relationship between property and structure of poly( p-phenylene terephthalamide)( PPTA) was investigated for the purpose of obtaining products with better performance. PPTA fiber subjected to heat treatment under different conditions was intensively studied. Simultaneous wide-angle X-ray diffraction( WAXD) technique was introduced to study the changes of crystal structure. It was found that the tensile modulus was strongly sensitive to the levels of temperature and tension. The structure parameters including crystal size and crystal orientation after heat treatment evolve similarly to the tensile modulus,indicating a direct structure-property relationship. The lattic c-dimension increases after heat treatment and is greatly affected by the tension. An optimal temperature can be found around 400 ℃,where big change can happen in the crystal structure due to α-relaxation in the crystal region as supported in dynamic mechanical analysis( DMA).展开更多
The preparation of PPy/PPTA conductive composite films by electrochemical method is presented.The first step is to cast a thin layer of poly (p-phenylene-terephthalamide) (PPTA) on a slice of Pt working electrode. The...The preparation of PPy/PPTA conductive composite films by electrochemical method is presented.The first step is to cast a thin layer of poly (p-phenylene-terephthalamide) (PPTA) on a slice of Pt working electrode. The second step is to electrochemically polymerize pyrrole on the PPTA/Pt working electrode. Both of the electrical conductivity and the mechanical properties of the PPy/PPTA composite film are better than those of the pure PPy film, and the film has excellent flexibility at low temperature, even in liquid nitrogen.The SEM picture of the cross-section of PPy,/PPTA composite film showed that the two components were well mixed.Cyclic voltammograms of PPy,/PPTA film in aqueous solution showed that the conductive films could be reduced and reoxidized.展开更多
为研究对位芳纶沉析纤维这种新型纤维及其复合纸的结构与性能,文中采用光学显微镜、扫描电镜、原子力显微镜表征了纤维的表观形貌;通过纤维质量分析仪分析了纤维的形态参数;利用压汞仪定量表征了复合纸的结构特征,并综合研究了其力学性...为研究对位芳纶沉析纤维这种新型纤维及其复合纸的结构与性能,文中采用光学显微镜、扫描电镜、原子力显微镜表征了纤维的表观形貌;通过纤维质量分析仪分析了纤维的形态参数;利用压汞仪定量表征了复合纸的结构特征,并综合研究了其力学性能、介电性能和热学性能。结果表明,沉析纤维呈薄膜褶皱状,形态柔顺,表面粗糙,在水相介质中分散均匀;重均长度0.552mm,细小纤维含量71.9%,纤维均一性好,细碎化程度高,有利于成纸的增强;芳纶复合纸的孔隙率为18.33%,孔径为14.64μm,成纸结合相对紧密,类似于钢筋混凝土结构;其拉伸指数为38.8 N·m/g,撕裂指数为18.4 m N·m2/g,耐压强度达到21.8 k V/mm;初始分解温度535℃,t10%为560℃,热学稳定性优异。展开更多
文摘Poly(p-phenylene terephthalamide)(PPTA)pulp was prepared by polycondensation of the p-phenylene diamine(PPDA)with terephthaloyl chloride(TPC)in the completely anhydrous solvent system of N-methyl pyrrolidone(NMP)having calcium chloride,in the presence of poly(vinyl pyrrolidone)(PVP)having a viscosity average molecular weight lower than 40 000.It was confirmed that the polycondensation could be accelerated,the inherent viscosity of the polymer could be increased,and the polymers could be fibrillated more easily by the addition of the PVP.FTIR and X-ray spectra proved that PVP had not combined into molecular chains of the resultant PPTA pulps.The morphology of the resultant pulps,the effect of viscosity average molecular weight,amount and adding mode of PVP on inherent viscosity,specific surface area,and mean length of the resultant pulps were discussed in detail.And the friction and wear properties of the compound reinforced by the resultant pulps were simply investigated.
基金This work was supported by the Scientific Research Foundation for Returned Overseas Chinese Scholars, Ministry of Education.
文摘The effect of N,N,N＇,N＇-tetraalkyl terephthalamide （TATA） on the non-isothermal crystallization and melting characteristics ofpolypropylene （PP） was studied. The addition of TATA can lead to the formation ofβ-crystal PP. With the increase in TATA concentration the degree of crystallinity for β-crystal PP increased significantly, and that for a-crystal PP decreased, which indicated that TATA effectively induced the formation of β-crystal PP. WAXD also revealed the existence of β-crystal PP after the introduction of TATA into PP. PP containing TATA crystallized at a temperature range of 5-10℃ higher than that of pure PP, and the half-crystallization time （t1/2） and Avrami exponent （n） of PP at the same cooling rate were decreased by the addition of TATA, indicating that TATA influenced the crystallization rate and crystallization growth mode of PP. The rate constant of crystallization of PP containing TATA （Zc） was larger than that of pure PP, which further indicated that the crystallization of PP was accelerated by the addition of TATA.
基金National Basic Research Program of China(973 Program)(No.2011CB606103)National High-Tech Research and Development Program of China(863 Program)(No.2012AA03212)the Fundamental Research Funds for the Central Universities,China(No.11D10625)
文摘The relationship between property and structure of poly( p-phenylene terephthalamide)( PPTA) was investigated for the purpose of obtaining products with better performance. PPTA fiber subjected to heat treatment under different conditions was intensively studied. Simultaneous wide-angle X-ray diffraction( WAXD) technique was introduced to study the changes of crystal structure. It was found that the tensile modulus was strongly sensitive to the levels of temperature and tension. The structure parameters including crystal size and crystal orientation after heat treatment evolve similarly to the tensile modulus,indicating a direct structure-property relationship. The lattic c-dimension increases after heat treatment and is greatly affected by the tension. An optimal temperature can be found around 400 ℃,where big change can happen in the crystal structure due to α-relaxation in the crystal region as supported in dynamic mechanical analysis( DMA).
文摘The preparation of PPy/PPTA conductive composite films by electrochemical method is presented.The first step is to cast a thin layer of poly (p-phenylene-terephthalamide) (PPTA) on a slice of Pt working electrode. The second step is to electrochemically polymerize pyrrole on the PPTA/Pt working electrode. Both of the electrical conductivity and the mechanical properties of the PPy/PPTA composite film are better than those of the pure PPy film, and the film has excellent flexibility at low temperature, even in liquid nitrogen.The SEM picture of the cross-section of PPy,/PPTA composite film showed that the two components were well mixed.Cyclic voltammograms of PPy,/PPTA film in aqueous solution showed that the conductive films could be reduced and reoxidized.
文摘为研究对位芳纶沉析纤维这种新型纤维及其复合纸的结构与性能,文中采用光学显微镜、扫描电镜、原子力显微镜表征了纤维的表观形貌;通过纤维质量分析仪分析了纤维的形态参数;利用压汞仪定量表征了复合纸的结构特征,并综合研究了其力学性能、介电性能和热学性能。结果表明,沉析纤维呈薄膜褶皱状,形态柔顺,表面粗糙,在水相介质中分散均匀;重均长度0.552mm,细小纤维含量71.9%,纤维均一性好,细碎化程度高,有利于成纸的增强;芳纶复合纸的孔隙率为18.33%,孔径为14.64μm,成纸结合相对紧密,类似于钢筋混凝土结构;其拉伸指数为38.8 N·m/g,撕裂指数为18.4 m N·m2/g,耐压强度达到21.8 k V/mm;初始分解温度535℃,t10%为560℃,热学稳定性优异。
