Two types of poly-porphyrin-based heterogeneous photocatalysts including insoluble polymer and water-soluble nanoparticles exhibited excellent photocatalytic activity in visible-light-induced dehydrogenation in water....Two types of poly-porphyrin-based heterogeneous photocatalysts including insoluble polymer and water-soluble nanoparticles exhibited excellent photocatalytic activity in visible-light-induced dehydrogenation in water.The extremely low catalyst loading(0.01 mol%)of water-soluble nanoparticles provided so far the highest turnover frequency(TOF)value(333 h^(-1))for such transformation among reported records.展开更多
基金supported by the National Science Foundation of China(No.21978039)Natural Science Foundation of Jiangsu Province(Nos.BK20211100 and BK20221265)Fundamental Research Funds for the Central Universities(Nos.DUT21YG133 and DUT22YG224).
文摘Two types of poly-porphyrin-based heterogeneous photocatalysts including insoluble polymer and water-soluble nanoparticles exhibited excellent photocatalytic activity in visible-light-induced dehydrogenation in water.The extremely low catalyst loading(0.01 mol%)of water-soluble nanoparticles provided so far the highest turnover frequency(TOF)value(333 h^(-1))for such transformation among reported records.