Ethylene-methacrylate-glycidyl(EMG)copolymer is employed to strengthen polyethylene terephthalate(PET)/glass fiber(GF)blends.This paper starts from investigating the effects of various EMG contents on mechanical prope...Ethylene-methacrylate-glycidyl(EMG)copolymer is employed to strengthen polyethylene terephthalate(PET)/glass fiber(GF)blends.This paper starts from investigating the effects of various EMG contents on mechanical properties,thermal properties and fractured surface morphology of PET/GF blends.All of the above-mentioned properties own extreme limits of EMG concentration.The crystallization ability of the blends increases with an increment in EMG content,whereas the crystallinity keeps stable at a relatively high level of 0-20 wt.%EMG loading.The tension,bending and impact properties of PET blends are enhanced with the addition of a self-made three-dimensional hierarchical porous carbon sponge(3DC)based on an optimal additive amount.Results indicate that EMG possesses the capabilities of increasing the toughness of PET/GF blends remarkably and transforming the blends from brittle fracture to tough fracture.According to the results,the blends exhibit the best overall properties as the content of EMG reaches 10-15 wt.%.展开更多
In this work,polyethylene terephthalate(PET) fibers were continuously treated by atmospheric dielectric barrier discharge(DBD) in Ar mixed O2 plasma,and the discharge was characterized by electrical function and optic...In this work,polyethylene terephthalate(PET) fibers were continuously treated by atmospheric dielectric barrier discharge(DBD) in Ar mixed O2 plasma,and the discharge was characterized by electrical function and optical diagnostics.It is found that the interfacial adhesion strength between treated PET fiber and resorcinol formaldehyde latex(RFL)(little)-rubber was improved(about 50%) by the measurement of interfacial shear strength(IFSS) and peel test.The wettability was improved rapidly in the initial treatment time.It is considered that oxidation chemical reaction as the major role of PET fiber surface modification is ahead of the physical etching effect.The high density of atomic oxygen in the plasma by optical emission spectroscopy supports the purpose.According to the scanning electron micrograph(SEM) image in the work,the longer treatment time obviously caused physical etching effect,which shall be less responsible for the improvement of the wettability.展开更多
A group of grafted PET fibers with different graft yield are formed by grafting acrylamide onto the PET main chains. The structure of grafted fibers are studied by scanning electronic microscope ( SEM ), infra-red spe...A group of grafted PET fibers with different graft yield are formed by grafting acrylamide onto the PET main chains. The structure of grafted fibers are studied by scanning electronic microscope ( SEM ), infra-red spectrophotometer ( IR ), and differential scanning calorimetry(DSC). At the same time, the moisture regain, dyeability, strength, and elongation at break of the samples are measured and their relations with structural changes are discussed. Compared with ungrafted fiber, shape of the fiber cross-section, IR characteristic absorption peaks, and melting behavior of the grafted fibers have been changed, causing the fiber dyeability and moisture regain to be increased, and mechanical properties to be changed.展开更多
Glass fiber reinforced plastics geogrid has a wide application in the field of soil reinforcement because of its high strength, good toughness, and resistance to environmental stress, creep resistance and strong stabi...Glass fiber reinforced plastics geogrid has a wide application in the field of soil reinforcement because of its high strength, good toughness, and resistance to environmental stress, creep resistance and strong stability. In order to get high-powered glass fiber reinforced plastics geogrid and its mechanical characteristics, the properties and physical mechanical index of geogrid have been got through the study of its raw material, production process and important quality index. The analysis and study have been made to the geogrid＇s mechanical properties with loading speed, three-axial compression, temperature tensile test and FLAC3D numerical simulation, thus obtain the mechanical parameters of its displacement time curve, breaking strength and elongation at break. Some conclusions can be drawn as follows： （a） Using glass fiber materials, knurling and coated projection process, the f^acture strength and corrosion resistance of geogrid are greatly improved and the interlocking bite capability of soil is enhanced. （b） The fracture strength of geogrid is related to temperature and loading rate. When the surrounding rock pressure is fixed, the strength and anti-deformation ability of reinforced soil are significantly enhanced with increasing reinforced layers. （c） The pullout test shows the positive correlation between geogrid displacement and action time. （d） As a new reinforced material, the glass fiber reinforced plastics geogrid is not mature enough in theoretical research and practical experience, so it has become an urgent problem both in theoretical study and practical innovation.展开更多
In this study the effects of surface modification of Polyethylene Terephthalates （PET） fibers with 58S bioactive glasses on osteoblasts proliferation and osseointegration in the tibia-articular tendon-bone healing m...In this study the effects of surface modification of Polyethylene Terephthalates （PET） fibers with 58S bioactive glasses on osteoblasts proliferation and osseointegration in the tibia-articular tendon-bone healing model were investigated. PET sheets were coated with 58S bioactive glass and uncoated PET sheets were used as a control. Scanning Electron Microscope （SEM） and X-ray photoelectron spectrometer were adopted to analyze the surface characteristics of the fibers. MT3T3-E 1 cells were cultured with the PET fibers and the MTT and ALP were tested at 1, 3, 5 days. Twenty-four skeletally mature male New Zealand white rabbits were randomly divided into two groups, the 58S-PET group and the PET group. Both groups underwent a surgical procedure to establish a tibia-articular tendon-bone healing model. Mechanical examinations and histological assays were taken to verify the coating effects in vivo. Results of both MTT and ALP tests show significant differences （P 〈 0.01） between the 58S-PET group and the PET group. At 6 weeks and 12 weeks, the max load-to-failure was significantly higher in the 58S-PET group. In the histological assays, distinct new bone formation was observed only in the 58S-PET group and stronger osseoin- tegration was seen in the 58S-PET group than that in the control group. The 58S-coating on PET could enhance the proliferation and activity of the osteoblasts and therefore promote the new bone formation and tendon-bone healing.展开更多
The dynamic observation of the fracture processes of PET(polyethylene terephthalate)andPAN(polyacrylonitrile)fibers in tension was carried out under a scanning electron microscope.Thestepwisc micrographs taken reveale...The dynamic observation of the fracture processes of PET(polyethylene terephthalate)andPAN(polyacrylonitrile)fibers in tension was carried out under a scanning electron microscope.Thestepwisc micrographs taken revealed the features of crack initiation and crack growth and of thefailure of the fibers.The fracture behaviour of PET fibers in tension is characterized by theoccurence of shear bands,which initiate a crack whose development leads to the final failure of afiber.For tensile PAN fibers,a high concentration of cracks are initiate in the skin of a fiber,andthen a few or one of them develop themselves by way of pulse and lead to the final failure of the fi-ber.展开更多
Polyethylene terephthalate(PET)and polyethylene(PE)fibers were surface photo-grafted with acrylic acid(AA)by using UV irradiation photochemical initiationduring a continuous winding process within 1-2 min-utes.The gra...Polyethylene terephthalate(PET)and polyethylene(PE)fibers were surface photo-grafted with acrylic acid(AA)by using UV irradiation photochemical initiationduring a continuous winding process within 1-2 min-utes.The grafted fibers were characterized by measure-ments of dye uptaking,moisture regain,pull-out forcesof monofilament from cured matrix,as well as by analy-sis of ESCA and ATR-FTIR spectra.All these resultsconfirm that the surface behavior of the UV-irradiationgrafted fibers was greatly improved.It was also provedthat the original excellent mechanical properties of the fi-bers were well-retained after the surface grafting treat-ment.展开更多
基金supported by the Special Support Plan for High-Level Talents of Guangdong Province(No.2017TQ04N840)Science and Technology Planning Project of Guangdong Province(No.2017A030313081).
文摘Ethylene-methacrylate-glycidyl(EMG)copolymer is employed to strengthen polyethylene terephthalate(PET)/glass fiber(GF)blends.This paper starts from investigating the effects of various EMG contents on mechanical properties,thermal properties and fractured surface morphology of PET/GF blends.All of the above-mentioned properties own extreme limits of EMG concentration.The crystallization ability of the blends increases with an increment in EMG content,whereas the crystallinity keeps stable at a relatively high level of 0-20 wt.%EMG loading.The tension,bending and impact properties of PET blends are enhanced with the addition of a self-made three-dimensional hierarchical porous carbon sponge(3DC)based on an optimal additive amount.Results indicate that EMG possesses the capabilities of increasing the toughness of PET/GF blends remarkably and transforming the blends from brittle fracture to tough fracture.According to the results,the blends exhibit the best overall properties as the content of EMG reaches 10-15 wt.%.
文摘In this work,polyethylene terephthalate(PET) fibers were continuously treated by atmospheric dielectric barrier discharge(DBD) in Ar mixed O2 plasma,and the discharge was characterized by electrical function and optical diagnostics.It is found that the interfacial adhesion strength between treated PET fiber and resorcinol formaldehyde latex(RFL)(little)-rubber was improved(about 50%) by the measurement of interfacial shear strength(IFSS) and peel test.The wettability was improved rapidly in the initial treatment time.It is considered that oxidation chemical reaction as the major role of PET fiber surface modification is ahead of the physical etching effect.The high density of atomic oxygen in the plasma by optical emission spectroscopy supports the purpose.According to the scanning electron micrograph(SEM) image in the work,the longer treatment time obviously caused physical etching effect,which shall be less responsible for the improvement of the wettability.
文摘A group of grafted PET fibers with different graft yield are formed by grafting acrylamide onto the PET main chains. The structure of grafted fibers are studied by scanning electronic microscope ( SEM ), infra-red spectrophotometer ( IR ), and differential scanning calorimetry(DSC). At the same time, the moisture regain, dyeability, strength, and elongation at break of the samples are measured and their relations with structural changes are discussed. Compared with ungrafted fiber, shape of the fiber cross-section, IR characteristic absorption peaks, and melting behavior of the grafted fibers have been changed, causing the fiber dyeability and moisture regain to be increased, and mechanical properties to be changed.
基金Funded by National Natural Science Foundation of China(No.41372289)the Shandong Province Higher Educational Science and Technology Program(No.12LH03)+1 种基金the China's Post-doctoral Science Fund(No.2012M521365)the SDUST Research Fund
文摘Glass fiber reinforced plastics geogrid has a wide application in the field of soil reinforcement because of its high strength, good toughness, and resistance to environmental stress, creep resistance and strong stability. In order to get high-powered glass fiber reinforced plastics geogrid and its mechanical characteristics, the properties and physical mechanical index of geogrid have been got through the study of its raw material, production process and important quality index. The analysis and study have been made to the geogrid＇s mechanical properties with loading speed, three-axial compression, temperature tensile test and FLAC3D numerical simulation, thus obtain the mechanical parameters of its displacement time curve, breaking strength and elongation at break. Some conclusions can be drawn as follows： （a） Using glass fiber materials, knurling and coated projection process, the f^acture strength and corrosion resistance of geogrid are greatly improved and the interlocking bite capability of soil is enhanced. （b） The fracture strength of geogrid is related to temperature and loading rate. When the surrounding rock pressure is fixed, the strength and anti-deformation ability of reinforced soil are significantly enhanced with increasing reinforced layers. （c） The pullout test shows the positive correlation between geogrid displacement and action time. （d） As a new reinforced material, the glass fiber reinforced plastics geogrid is not mature enough in theoretical research and practical experience, so it has become an urgent problem both in theoretical study and practical innovation.
基金This project was financially supported by the 973 Project，The Ministry of Science and Technology of China，The Nano Project of the Shanghai Municipal Science and Technology Commission，The National Natural Science Foundation
文摘In this study the effects of surface modification of Polyethylene Terephthalates （PET） fibers with 58S bioactive glasses on osteoblasts proliferation and osseointegration in the tibia-articular tendon-bone healing model were investigated. PET sheets were coated with 58S bioactive glass and uncoated PET sheets were used as a control. Scanning Electron Microscope （SEM） and X-ray photoelectron spectrometer were adopted to analyze the surface characteristics of the fibers. MT3T3-E 1 cells were cultured with the PET fibers and the MTT and ALP were tested at 1, 3, 5 days. Twenty-four skeletally mature male New Zealand white rabbits were randomly divided into two groups, the 58S-PET group and the PET group. Both groups underwent a surgical procedure to establish a tibia-articular tendon-bone healing model. Mechanical examinations and histological assays were taken to verify the coating effects in vivo. Results of both MTT and ALP tests show significant differences （P 〈 0.01） between the 58S-PET group and the PET group. At 6 weeks and 12 weeks, the max load-to-failure was significantly higher in the 58S-PET group. In the histological assays, distinct new bone formation was observed only in the 58S-PET group and stronger osseoin- tegration was seen in the 58S-PET group than that in the control group. The 58S-coating on PET could enhance the proliferation and activity of the osteoblasts and therefore promote the new bone formation and tendon-bone healing.
文摘The dynamic observation of the fracture processes of PET(polyethylene terephthalate)andPAN(polyacrylonitrile)fibers in tension was carried out under a scanning electron microscope.Thestepwisc micrographs taken revealed the features of crack initiation and crack growth and of thefailure of the fibers.The fracture behaviour of PET fibers in tension is characterized by theoccurence of shear bands,which initiate a crack whose development leads to the final failure of afiber.For tensile PAN fibers,a high concentration of cracks are initiate in the skin of a fiber,andthen a few or one of them develop themselves by way of pulse and lead to the final failure of the fi-ber.
文摘Polyethylene terephthalate(PET)and polyethylene(PE)fibers were surface photo-grafted with acrylic acid(AA)by using UV irradiation photochemical initiationduring a continuous winding process within 1-2 min-utes.The grafted fibers were characterized by measure-ments of dye uptaking,moisture regain,pull-out forcesof monofilament from cured matrix,as well as by analy-sis of ESCA and ATR-FTIR spectra.All these resultsconfirm that the surface behavior of the UV-irradiationgrafted fibers was greatly improved.It was also provedthat the original excellent mechanical properties of the fi-bers were well-retained after the surface grafting treat-ment.
