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Efficient and selective removal of Pb(Ⅱ) from landfill leachate using L-serine-modified polyethylene/polypropylene nonwoven fabric synthesized via radiation grafting technique
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作者 Xin-Xin Feng Cheng Li +6 位作者 Xuan-Zhi Mao Wan-Ning Ren Yang Gao Yu-Long He Zhe Xing Rong Li Guo-Zhong Wu 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2024年第4期144-155,共12页
In this study,to efficiently remove Pb(Ⅱ) from aqueous environments,a novel L-serine-modified polyethylene/polypropylene nonwoven fabric sorbent(NWF-serine)was fabricated through the radiation grafting of glycidyl me... In this study,to efficiently remove Pb(Ⅱ) from aqueous environments,a novel L-serine-modified polyethylene/polypropylene nonwoven fabric sorbent(NWF-serine)was fabricated through the radiation grafting of glycidyl methacrylate and subsequent L-serine modification.The effect of the absorbed dose was investigated in the range of 5–50 kGy.NWF-serine was characterized by Fourier transform infrared spectroscopy,thermogravimetric analysis,and scanning electron microscopy.Batch adsorption tests were conducted to investigate the influences of pH,adsorption time,temperature,initial concentration,and sorbent dosage on the Pb(Ⅱ) adsorption performance of NWF-serine.The results indicated that Pb(Ⅱ) adsorption onto NWF-serine was an endothermic process,following the pseudo-second-order kinetic model and Langmuir isotherm model.The saturated adsorption capacity was 198.1 mg/g.NWF-serine exhibited Pb(Ⅱ) removal rates of 99.8% for aqueous solutions with initial concentrations of 100 mg/L and 82.1% for landfill leachate containing competitive metal ions such as Cd,Cu,Ni,Mn,and Zn.Furthermore,NWF-serine maintained 86% of its Pb(Ⅱ) uptake after five use cycles.The coordination of the carboxyl and amino groups with Pb(Ⅱ) was confirmed using X-ray photoelectron spectroscopy and extended X-ray absorption fine structure analysis. 展开更多
关键词 Landfill leachate Radiation grafting polyethylene/polypropylene nonwoven fabric Pb(Ⅱ)removal
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Temperature Effect on the Conformation Transition of Ultra-high Molecular Weight Polyethylene/Polypropylene Blends Undergoing Continuous Volume Extensional Flow:A Mesoscopic Simulation
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作者 王军霞 YAN Shilin 余丁山 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2022年第3期540-545,共6页
Due to the multiformity and complexity of chain conformation under external flow and the challenge of systematically investigating the transient conformation and dynamic evolution process of polymer chains at the mole... Due to the multiformity and complexity of chain conformation under external flow and the challenge of systematically investigating the transient conformation and dynamic evolution process of polymer chains at the molecular level by means of present experimental techniques,a universal description of both chain conformation and dynamics with respect to continuous volume extensional flow(CVEF)is still absent.Taking into account the temperature effect,we performed dissipative particle dynamics(DPD)simulations with the particles corresponding to the repeat units of polymers over a wide temperature range and analyzed the correlation with the conformational properties of ultra-high molecular weight polyethylene/polypropylene(UHMWPE/PP)blend in response to the CVEF.With time evolution,the polymer chains become highly oriented parallel to the flow direction instead of the initial random coiling and self-aggregation.It is found that a high temperature is necessary for more substantial compactness to take place than low temperature.The low-k plateau and low-k peak in structure factor S(k)curves suggest a low degree of conformational diversity and a high degree of chain stretching.It is also concluded that the intra-molecular C-C bond interaction is the main driving force for the dynamics process of the chain conformations undergoing CVEF,where the motion of the alkyl chains is seriously restricted owing to the increase in bond interaction potential,resulting in a reduction of the difference in diffusion rates among alkyl chains. 展开更多
关键词 temperature effect dissipative particle dynamics ultra-high molecular weight polyethylene polypropylene volume extensional flow chain conformation BLENDS
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Vertically aligned montmorillonite aerogel-encapsulated polyethylene glycol with directional heat transfer paths for efficient solar thermal energy harvesting and storage
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作者 Qijing Guo Cong Guo +2 位作者 Hao Yi Feifei Jia Shaoxian Song 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第5期907-916,共10页
The conversion and storage of photothermal energy using phase change materials(PCMs)represent an optimal approach for harnessing clean and sustainable solar energy.Herein,we encapsulated polyethylene glycol(PEG)in mon... The conversion and storage of photothermal energy using phase change materials(PCMs)represent an optimal approach for harnessing clean and sustainable solar energy.Herein,we encapsulated polyethylene glycol(PEG)in montmorillonite aerogels(3D-Mt)through vacuum impregnation to prepare 3D-Mt/PEG composite PCMs.When used as a support matrix,3D-Mt can effectively prevent PEG leakage and act as a flame-retardant barrier to reduce the flammability of PEG.Simultaneously,3D-Mt/PEG demonstrates outstanding shape retention,increased thermal energy storage density,and commendable thermal and chemical stability.The phase transition enthalpy of 3D-Mt/PEG can reach 167.53 J/g and remains stable even after 50 heating-cooling cycles.Furthermore,the vertical sheet-like structure of 3D-Mt establishes directional heat transport channels,facilitating efficient phonon transfer.This configuration results in highly anisotropic thermal conductivities that ensure swift thermal responses and efficient heat conduction.This study addresses the shortcomings of PCMs,including the issues of leakage and inadequate flame retardancy.It achieves the development and design of 3D-Mt/PEG with ultrahigh strength,superior flame retardancy,and directional heat transfer.Therefore,this work offers a design strategy for the preparation of high-performance composite PCMs.The 3D-Mt/PEG with vertically aligned and well-ordered array structure developed in this research shows great potential for thermal management and photothermal conversion applications. 展开更多
关键词 montmorillonite aerogel polyethylene glycol phase change materials solar thermal energy storage flame retardant
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Detection of internal crack growth in polyethylene pipe using guided wave ultrasonic testing
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作者 Jay Kumar Shah Hao Wang Said El-Hawwat 《Earthquake Engineering and Engineering Vibration》 SCIE EI CSCD 2024年第2期319-329,共11页
Despite the success of guided wave ultrasonic inspection for internal defect detection in steel pipes,its application on polyethylene(PE)pipe remains relatively unexplored.The growth of internal cracks in PE pipe seve... Despite the success of guided wave ultrasonic inspection for internal defect detection in steel pipes,its application on polyethylene(PE)pipe remains relatively unexplored.The growth of internal cracks in PE pipe severely affects its pressure-holding capacity,hence the early detection of internal cracks is crucial for effective pipeline maintenance strategies.This study extends the scope of guided wave-based ultrasonic testing to detect the growth of internal cracks in a natural gas distribution PE pipe.Laboratory experiments and a finite element model were planned to study the wave-crack interaction at different stages of axially oriented internal crack growth with a piezoceramic transducer-based setup arranged in a pitch-catch configuration.Mode dispersion analysis supplemented with preliminary experiments was performed to isolate the optimal inspection frequency,leading to the selection of the T(0,1)mode at 50-kHz for the investigation.A transmission index based on the energy of the T(0,1)mode was developed to trace the extent of simulated crack growth.The findings revealed an inverse linear correlation between the transmission index and the crack depth for crack growth beyond 20%crack depth. 展开更多
关键词 polyethylene pipes internal cracks guided wave ultrasonic testing torsional modes finite element modeling
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Polyethylene glycol has immunoprotective effects on sciatic allografts, but behavioral recovery and graft tolerance require neurorrhaphy and axonal fusion
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作者 Tyler A.Smith Liwen Zhou +6 位作者 Cameron L.Ghergherehchi Michelle Mikesh Cathy Z.Yang Haley O.Tucker JuliAnne Allgood Jared S.Bushman George D.Bittner 《Neural Regeneration Research》 SCIE CAS 2025年第4期1192-1206,共15页
Behavioral recovery using(viable)peripheral nerve allografts to repair ablation-type(segmental-loss)peripheral nerve injuries is delayed or poor due to slow and inaccurate axonal regeneration.Furthermore,such peripher... Behavioral recovery using(viable)peripheral nerve allografts to repair ablation-type(segmental-loss)peripheral nerve injuries is delayed or poor due to slow and inaccurate axonal regeneration.Furthermore,such peripheral nerve allografts undergo immunological rejection by the host immune system.In contrast,peripheral nerve injuries repaired by polyethylene glycol fusion of peripheral nerve allografts exhibit excellent behavioral recovery within weeks,reduced immune responses,and many axons do not undergo Wallerian degeneration.The relative contribution of neurorrhaphy and polyethylene glycol-fusion of axons versus the effects of polyethylene glycol per se was unknown prior to this study.We hypothesized that polyethylene glycol might have some immune-protective effects,but polyethylene glycol-fusion was necessary to prevent Wallerian degeneration and functional/behavioral recovery.We examined how polyethylene glycol solutions per se affect functional and behavioral recovery and peripheral nerve allograft morphological and immunological responses in the absence of polyethylene glycol-induced axonal fusion.Ablation-type sciatic nerve injuries in outbred Sprague–Dawley rats were repaired according to a modified protocol using the same solutions as polyethylene glycol-fused peripheral nerve allografts,but peripheral nerve allografts were loose-sutured(loose-sutured polyethylene glycol)with an intentional gap of 1–2 mm to prevent fusion by polyethylene glycol of peripheral nerve allograft axons with host axons.Similar to negative control peripheral nerve allografts not treated by polyethylene glycol and in contrast to polyethylene glycol-fused peripheral nerve allografts,animals with loose-sutured polyethylene glycol peripheral nerve allografts exhibited Wallerian degeneration for all axons and myelin degeneration by 7 days postoperatively and did not recover sciatic-mediated behavioral functions by 42 days postoperatively.Other morphological signs of rejection,such as collapsed Schwann cell basal lamina tubes,were absent in polyethylene glycol-fused peripheral nerve allografts but commonly observed in negative control and loose-sutured polyethylene glycol peripheral nerve allografts at 21 days postoperatively.Loose-sutured polyethylene glycol peripheral nerve allografts had more pro-inflammatory and less anti-inflammatory macrophages than negative control peripheral nerve allografts.While T cell counts were similarly high in loose-sutured-polyethylene glycol and negative control peripheral nerve allografts,loose-sutured polyethylene glycol peripheral nerve allografts expressed some cytokines/chemokines important for T cell activation at much lower levels at 14 days postoperatively.MHCI expression was elevated in loose-sutured polyethylene glycol peripheral nerve allografts,but MHCII expression was modestly lower compared to negative control at 21 days postoperatively.We conclude that,while polyethylene glycol per se reduces some immune responses of peripheral nerve allografts,successful polyethylene glycol-fusion repair of some axons is necessary to prevent Wallerian degeneration of those axons and immune rejection of peripheral nerve allografts,and produce recovery of sensory/motor functions and voluntary behaviors.Translation of polyethylene glycol-fusion technologies would produce a paradigm shift from the current clinical practice of waiting days to months to repair ablation peripheral nerve injuries. 展开更多
关键词 allograft rejection AXOTOMY macrophage MYELIN nerve repair polyethylene glycol(PEG) sciatic nerve T cell transplantation Wallerian degeneration
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Enhancing performance of low-temperature processed CsPbI2Br all-inorganic perovskite solar cells using polyethylene oxide-modified TiO_(2)
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作者 Xu Zhao Naitao Gao +2 位作者 Shengcheng Wu Shaozhen Li Sujuan Wu 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第4期786-794,共9页
CsPbX_(3)-based(X=I,Br,Cl)inorganic perovskite solar cells(PSCs)prepared by low-temperature process have attracted much attention because of their low cost and excellent thermal stability.However,the high trap state d... CsPbX_(3)-based(X=I,Br,Cl)inorganic perovskite solar cells(PSCs)prepared by low-temperature process have attracted much attention because of their low cost and excellent thermal stability.However,the high trap state density and serious charge recombination between low-temperature processed TiO_(2)film and inorganic perovskite layer interface seriously restrict the performance of all-inorganic PSCs.Here a thin polyethylene oxide(PEO)layer is employed to modify TiO_(2)film to passivate traps and promote carrier collection.The impacts of PEO layer on microstructure and photoelectric characteristics of TiO_(2)film and related devices are systematically studied.Characterization results suggest that PEO modification can reduce the surface roughness of TiO_(2)film,decrease its average surface potential,and passivate trap states.At optimal conditions,the champion efficiency of CsPbI_(2)Br PSCs with PEO-modified TiO_(2)(PEO-PSCs)has been improved to 11.24%from 9.03%of reference PSCs.Moreover,the hysteresis behavior and charge recombination have been suppressed in PEO-PSCs. 展开更多
关键词 polyethylene oxide-modified TiO_(2) film low-temperature process CsPbI_(2)Br-based all-inorganic perovskite solar cells photo-voltaic performance
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Experimental Study of the Influence of Intrinsic Parameters on the Thermal Reactivity of Sawdust, Polyethylene Terephthalate and Composite
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作者 Ange Brel Boukongou Timoléon Andzi Barhé 《Journal of Materials Science and Chemical Engineering》 2024年第3期9-20,共12页
Several works have been based on the study of thermal variations in biomass to derive more valuable products such as fuels capable of replacing oil in the event of a crisis or activated carbon used as an adsorbent mat... Several works have been based on the study of thermal variations in biomass to derive more valuable products such as fuels capable of replacing oil in the event of a crisis or activated carbon used as an adsorbent material, widely used in industry for the elimination of unwanted materials, both in liquid and gaseous environments. A study of thermal parameters such as: heating speed, retention time, drying temperature, carbonization temperature, particle size, was carried out with the aim of determining the characteristic factors of the carbonization of Polyethylene terephthalate (PET), sawdust (SC) and sawdust/polyethylene terephthalate (CPS) mixture. The results of the immediate analysis revealed a very low level of ash in PET (0.013%) compared to the level of ash in sawdust (2.9%), as well as a high level of fixed carbon (82.960%), which suggests the presence of mineral oxides and a significant carbon matrix unlike PET, which indicates a very significant organic matrix (essentially made up of organic matter) with the absence of mineral oxides. The study of thermal parameters showed the water loss from Sawdust (SC) and the Sawdust/Polyethylene terephthalate (CPS) mixture, an increase with temperature, unlike that of PET whose variation is essentially zero. Without heat treatment, sawdust alone contains approximately 7% water. The optimal drying temperature for this study is 110˚C for a stay of 24 hours. It appears that the largest mass losses for the PET samples are between 87.19% and 96.05%, followed by that of the mixture, between 47.33% and 64.37%. And the lowest are observed, those of sawdust (from 24.02% to 62.6%). However, here we can say that the influence of the mass is not great, given the slight difference between the losses by temperature. The results of the study of the influence of grain size showed that the differences are insignificant, even if we vary the diameter of the grains from simple to triple. To better minimize physical constraints such as the intragranular diffusibility of the volatile matter and the homogeneity of the temperature in the grains, 75 μm particles are found to be optimal for our study. It can be noted when studying the heating rate that the mass loss at the end of the reaction is approximately the same depending on each precursor material. However, it has been demonstrated that the heating rate strongly influences the nature of the reaction products both for volatile materials and for the solid residue as well as on the kinetic parameters of the chemical reaction. Furthermore, the variation in apparent density shows a decrease as a function of the increase in the residence time of the materials in the reactor. As the carbonization time increases, the apparent density decreases. We note, for the lignocellulosic material, that the apparent density stabilizes after 60 minutes. 展开更多
关键词 Intrinsic Parameters Thermal Reactivity SAWDUST polyethylene Terephthalate COMPOSITE
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The Impact of the Inclusion of MgO Nano-Fillers in a Polyethylene Matrix on Dielectric Strength and Resistance to Partial Discharges
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作者 Virginie Griseri Dominique Mary +1 位作者 David Malec Eric David 《Open Journal of Applied Sciences》 2024年第3期626-634,共9页
One commonly used strategy to enhance polymers specific properties such as the resistance to partial discharges erosion is the incorporation into the polymeric matrix of inorganic micro or nanoparticles. This study fo... One commonly used strategy to enhance polymers specific properties such as the resistance to partial discharges erosion is the incorporation into the polymeric matrix of inorganic micro or nanoparticles. This study focused on the dielectric properties of Low-Density Polyethylene (LDPE) filled with nano-sized Magnesium Oxide (MgO) particles compounded by thermo-mechanical process and one of the purposes was to establish appropriate processing parameters in order to reach the desired dielectric properties. LDPE was used as a matrix and was reinforced by MgO particles having a nominal average size of 30 nm. The MgO nanoparticles were treated with a silane coupling agent (3-Glycidyloxypropyl Trimethoxysilane). The samples were initially prepared in a melt-mixing chamber with a MgO content of 1% wt. These pre-mixed samples were further treated by the means of thermo-mechanical mixing in a conical co-rotating twin-screw extruder in order to improve the dispersion and distribution of the MgO particles. In this report, both lifetime under a PD activity and AC dielectric strength of pure and nano-filled LDPE samples have been measured and compared. Nano-filled LDPE samples were found to exhibit an improve lifetime, without any detrimental impact on their short-term dielectric strength. This suggests that nano-filled LDPE may be for electric applications for which the dielectric materials may be exposed to partial discharge activities. This is significant result for the use of MgO-reinforced PE as an insulating material for HV cables since the resistance to PD is closely related to treeing resistance which is the main electrical degradation mechanism that leads to failure for shielded extruded power cables. 展开更多
关键词 Low Density polyethylene MgO Nanofillers Dielectric Strength Partial Discharges Resistance
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Industrial-Scale Polypropylene–Polyethylene Physical Alloying Toward Recycling 被引量:2
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作者 Jinping Qu Zhaoxia Huang +8 位作者 Zhitao Yang Guizhen Zhang Xiaochun Yin Yanhong Feng Hezhi He Gang Jin Ting Wu Guangjian He Xianwu Cao 《Engineering》 SCIE EI 2022年第2期95-100,共6页
Polypropylene(PP)and polyethylene(PE)play central roles in our daily life.However,their immiscibility presents a major hurdle in both industry and academia when recycling them into alloys with favorable mechanical pro... Polypropylene(PP)and polyethylene(PE)play central roles in our daily life.However,their immiscibility presents a major hurdle in both industry and academia when recycling them into alloys with favorable mechanical properties.Moreover,typical compatibilizer-enabled approaches are limited due to increased environmental concerns.Herein,inspired by a traditional Chinese technique,we report a facile,industry-scale methodology that produces a PP/PE binary blend with a highly ordered honeycomb nanostructure without any additives.Due to its nanostructure,the blend exhibits enhanced tensile properties in com-parison with the parent components or with a sample prepared using an internal mixer.This approach has potential for applications not only in immiscible polymer blending,but also in non-sorting,compatibilizer-free waste plastics recycling.Through this technique,we expect that an environmentally friendly and sustainable plastic wastes recycling avenue can be found,and great economic benefits can be gained. 展开更多
关键词 polypropylene polyethylene Physical alloying Honeycomb structure
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High Efficieney Synthesis of Isotaetie Polypropylene and Linear Polyethylene Using a New C_2-symmetric Carbon-bridged Zirconocene Catalyst 被引量:3
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作者 程正载 孙俊全 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2007年第4期667-672,共6页
Ansa-Cyclohexyl-bis(4,5,6,7-tertrahydro-l-indenyl) zirconium dichloride (5) was used as catalyst for propylene and ethylene polymerization together with methyl aluminoxane (MAO) as the cocatalyst. Isotactic poly... Ansa-Cyclohexyl-bis(4,5,6,7-tertrahydro-l-indenyl) zirconium dichloride (5) was used as catalyst for propylene and ethylene polymerization together with methyl aluminoxane (MAO) as the cocatalyst. Isotactic polypropylene (PP) was obtained with the highest activity of 6.37× 107g PP (molZr)^-1h^-1. The mesomeso (mmmmm) pentads sequence content of PP was determined by 13C NMR spectroscopy. The dependence of the microstructure on the reaction temperature and the AI/Zr molar ratio was examined and the catalytic activity of complex 5 was compared with that of the similar ansa-zirconocene 3. The high activity of the new zirconocene 5 for propylene isospectic polymerization at high temperature (60℃) is the result of its unique bridged-group structure. Complex 5/MAO displays also high catalytic activity of 0.46× 10^6 to 9.87× 10^6g PE(molZr)^-h^-in the homo-polymerization of ethylene, The visometric molecular weight of PE ranges from 0.97×10^4 to 11.16×10^4 g.mol^- under the given conditions.^13C NMR spectroscopy analysis proves the PE to be linear polyethylene (LPE). 展开更多
关键词 ANSA-ZIRCONOCENE propylene polymerization isotactic polypropylene ethylene polymerization
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Toughening wood/polypropylene composites with polyethylene octene elastomer (POE) 被引量:3
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作者 JIANG Feng QIN Te-fu 《Journal of Forestry Research》 SCIE CAS CSCD 2006年第4期312-314,共3页
Polyethylene octene elastomer (POE) as impact modifier was incorporated into wood/polypropylene composites (WPC) to enhance the impact strength of the composite. Two extruding routes, i.e. direct extruding route and t... Polyethylene octene elastomer (POE) as impact modifier was incorporated into wood/polypropylene composites (WPC) to enhance the impact strength of the composite. Two extruding routes, i.e. direct extruding route and two-stage extruding route, were adopted to produce Wood Powder/PP/POE ternary composites. The mechanical and dynamic mechanical analysis (DMA) properties of the composites were investigated. The results showed that the addition of POE can increase the impact strength of the composites, and the composites produced via two-stage extruding route showed superior mechanical properties. The results of the DMA confirmed the mechanical tests. 展开更多
关键词 木塑复合物 强化木/聚丙烯复合物 锯末 POE 冲击强度
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Mechanical, Thermal and Crystallization Properties of Polypropylene (PP) Reinforced Composites with High Density Polyethylene (HDPE) as Matrix 被引量:1
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作者 Harekrushna Sutar Prakash Chandra Sahoo +4 位作者 Prateekshya Suman Sahu Surajabala Sahoo Rabiranjan Murmu Sumit Swain Subash Chandra Mishra 《Materials Sciences and Applications》 2018年第5期502-515,共14页
Our work aims to evaluate a complete outlook of virgin high density polyethylene (HDPE) and polypropylene (PP) polyblends. Virgin PP of 20, 30 and 50 weight% is compounded with virgin HDPE. The properties like tensile... Our work aims to evaluate a complete outlook of virgin high density polyethylene (HDPE) and polypropylene (PP) polyblends. Virgin PP of 20, 30 and 50 weight% is compounded with virgin HDPE. The properties like tensile strength, flexural strength, Izod impact strength are examined. Scanning electron microscopy (SEM) and polarised light microscopy (PLM) are used to observe the surface and crystal morphology. X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) tests verify the non compatibility of both polymers. Differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) techniques are used to study the thermal behaviour of composites. The results manifest co-occurring spherulites for polyblends;indicating the composite to be a physical blend of continuous and dispersed phases, but on the other hand PP improves the tensile and flexural properties of HDPE. 展开更多
关键词 High Density Poly Ethylene (HDPE) polypropylene (PP) Polyblends MECHANICAL THERMAL CRYSTALLIZATION Properties
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TIME-DEPENDENT MORPHOLOGY OF POLYETHYLENE-POLYPROPYLENE BLENDS
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作者 Robert A. Shanks 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2002年第6期497-508,共12页
The effect of time-temperature treatment on morphology of polyethylene-polypropylene (PE-PP) blends wasstudied to establish a relationship between thermal history, morphology and mechanical properties. Polypropylene (... The effect of time-temperature treatment on morphology of polyethylene-polypropylene (PE-PP) blends wasstudied to establish a relationship between thermal history, morphology and mechanical properties. Polypropylene (PP)homopolymers were used to blend with various polyethylenes (PE), including high density polyethylene (HDPE), lowdensity polyethylene (LDPE), linear low density polyethylene (LLDPE), and very and ultra low density polyethylene(VLDPE and ULDPE). The majority of the blends were prepared at a ratio of PE:PP = 80:20, while blends of PP and LLDPEwere prepared at various compositions. Thermal treatment was carried out at temperatures between the crystallizationtemperatures of PP and PEs to allow PP to crystallize first from the blends. On cooling further, PE crystallized too. A verydiffuse PP spherulite morphology in the PE matrix was formed in some partially miscible blends when PP was less than 20%by mass. Droplet-matrix structures were developed in other blends with either PP or PE as dispersed domains in a continuousmatrix, depending on the composition ratio. The scanning electron microscopy (SEM) images displayed a fibrillar structureof PP spherulite in the LLDPE-PP (80:20) and large droplets of PP in the HDPE-PP (80:20) blend, providing larger surfacearea and better bonding in the LLDPE-PP (80:20) blends. This explains why the blends with diffuse spherulite morphologyshowed greater improvement in tensile properties than droplet-matrix morphology blends after time-temperature treatment. 展开更多
关键词 polypropylene and polyethylene blends Thermal history SPHERULITE MORPHOLOGY Mechanical properties
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Preparation and Mechanical and Thermal Properties of Chlorinated Polyethylene Reinforced Polypropylene Foam
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作者 张伟 夏茹 +5 位作者 苏丽芬 RUAN Fang ZHENG Zhengzhi MIAO Jibin YANG Bin QIAN Jiasheng 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2018年第2期500-504,共5页
The foamed polypropylene(PP) with excellent mechanical and thermal insulating properties was reinforced by blending chlorinated polyethylene(CPE), followed by compression molding foaming in cross-link. The effects... The foamed polypropylene(PP) with excellent mechanical and thermal insulating properties was reinforced by blending chlorinated polyethylene(CPE), followed by compression molding foaming in cross-link. The effects of CPE on the foaming behavior, thermal and mechanical properties of the foamed PP were studied by the measurements of density, thermal conductivity, Vicat softening temperature, tensile strength, impact strength and SEM. The results showed that the foamed PP got the best properties when the weight ratio of CPE/PP was 20 wt%. The density of the obtained foamed PP was as low as 0.37 g/cm^3, the impact strength was 16.5 kJ/m^2, the tensile strength was 17.7 MPa, the thermal conductivity was 0.035 W/(m·K), and the Vicat softening temperature was 112 ℃. 展开更多
关键词 chlorinated polyethylene mechanical thermal polypropylene foam
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Catalytic Degradation of Mixed Polypropylene, Low and High Density Polyethylene into Environmental Friendly and Useful Products
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作者 Seyed Alireza Sakaki Mohamadreza Shishesaz Behrooz Roozbehani 《Journal of Environmental Science and Engineering(B)》 2012年第6期728-732,共5页
关键词 高密度聚乙烯 低密度聚乙烯 液体产品 混合塑料 催化降解 聚丙烯 催化转化反应 中间馏分油
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Influence ofβ-nucleating Compound Agents on the Mechanical Properties and Crystallization Behavior of Polypropylene Random Copolymer 被引量:1
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作者 谷亚新 LIU Yunxue +3 位作者 FAN Zhaorong GUI Jianfeng 刘鹏 WANG Hongmei 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2023年第1期237-243,共7页
A novel polypropylene random(PPR)composite materials with optimized properties was developed by addingβ-nucleating compound agents(rare earth complex WBG-2 and aryl amide derivative TMB-5)and ternary compound modifie... A novel polypropylene random(PPR)composite materials with optimized properties was developed by addingβ-nucleating compound agents(rare earth complex WBG-2 and aryl amide derivative TMB-5)and ternary compound modifier(TPE/WBG-2/CaCO_(3)).The effects of differentβ-nucleating agents and ternary compound modifier on the mechanical properties and crystallization behavior of PPR were analyzed.The results show that,compared with pure PPR materials,both WBG-2 and TMB-5 could significantly improve the impact strength of PPR.The crystallization temperature of PPR increased with the addition ofβ-nucleating agent.The modified PPR prepared with ternary compound modifier showed the most excellent comprehensive properties. 展开更多
关键词 polypropylene random copolymer β-nucleating agent impact strength crystallization behavior
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Hyponatremic encephalopathy due to polyethylene glycol-based bowel preparation for colonoscopy:A case report 被引量:1
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作者 Yuan Zhao Hai-Sheng Dong 《World Journal of Clinical Cases》 SCIE 2023年第1期187-192,共6页
BACKGROUND Adequate bowel preparation is critical for colonoscopy screening.At present,the most widely used intestinal cleaner recommended at home and abroad is Polyethylene glycol(PEG).Intestinal cleansers can cause ... BACKGROUND Adequate bowel preparation is critical for colonoscopy screening.At present,the most widely used intestinal cleaner recommended at home and abroad is Polyethylene glycol(PEG).Intestinal cleansers can cause electrolyte disturbances and hyponatremia.However,hyponatremic encephalopathy due to hyponatremia induced by PEG solution,although rare,can lead to serious irreversible sequelae and even death.CASE SUMMARY In this report,we discuss a case of neurological dysfunction due to hyponatremia,also known as hyponatremic encephalopathy,observed in a 63-year-old woman who underwent PEG-based bowel preparation for colonoscopy.She was eventually transferred to our intensive care unit for treatment due to her Glasgow Coma Scale score of 9/15(Eye opening 2;Verbal response 1;Motor response 6)and abnormal laboratory tests.CONCLUSION Physicians should be thoroughly familiarized with the patient’s history before prescribing PEG for bowel preparation,and timely identification of patients with hyponatremic encephalopathy is essential as delayed treatment is associated with poor neurological outcomes.An intravenous infusion of 3%sodium chloride is recommended at the onset of early symptoms.The goal of treatment is to adequately treat cerebral edema while avoiding serum sodium correction beyond 15 to 20 m Eq/L within 48 h of treatment to prevent osmotic demyelination syndrome. 展开更多
关键词 polyethylene glycol Intestinal preparation Hyponatremic encephalopathy HYPONATREMIA BRAIN Case report
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Emerging low-density polyethylene/paraffin wax/aluminum composite as a form-stable phase change thermal interface material 被引量:1
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作者 Chuanchang Li Weixuan Wang +2 位作者 Xiaoliang Zeng Chunxuan Liu Rong Sun 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2023年第4期772-781,共10页
Thermal interface materials(TIMs) play a vital role in the thermal management of electronic devices and can significantly reduce thermal contact resistance(TCR). The TCR between the solid–liquid contact surface is mu... Thermal interface materials(TIMs) play a vital role in the thermal management of electronic devices and can significantly reduce thermal contact resistance(TCR). The TCR between the solid–liquid contact surface is much smaller than that of the solid–solid contact surface, but conventional solid–liquid phase change materials are likely to cause serious leakage. Therefore, this work has prepared a new formstable phase change thermal interface material. Through the melt blending of paraffin wax(PW) and low-density polyethylene(LDPE), the stability is improved and it has an excellent coating effect on PW. The addition of aluminum(Al) powder improves the low thermal conductivity of PW/LDPE, and the addition of 15wt% Al powder improves the thermal conductivity of the internal structure of the matrix by 67%. In addition, the influence of the addition of Al powder on the internal structure, thermal properties, and phase change behavior of the PW/LDPE matrix was systematically studied. The results confirmed that the addition of Al powder improved the thermal conductivity of the material without a significant impact on other properties, and the thermal conductivity increased with the increase of Al addition. Therefore, morphologically stable PW/LDPE/Al is an important development direction for TIMs. 展开更多
关键词 paraffin wax low-density polyethylene phase change materials thermal interface materials form stability
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Rotator cuff repair with an interposition polypropylene mesh:A biomechanical ovine study 被引量:1
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作者 Winston Shang Rong Lim Andy Khye Soon Yew +2 位作者 Hannah Lie Siaw Meng Chou Denny Tijauw Tjoen Lie 《World Journal of Orthopedics》 2023年第5期319-327,共9页
BACKGROUND Chronic large to massive rotator cuff tears are difficult to treat and re-tears are common even after surgical repair.We propose using a synthetic polypropylene mesh to increase the tensile strength of rota... BACKGROUND Chronic large to massive rotator cuff tears are difficult to treat and re-tears are common even after surgical repair.We propose using a synthetic polypropylene mesh to increase the tensile strength of rotator cuff repairs.We hypothesize that using a polypropylene mesh to bridge the repair of large rotator cuff tears will increase the ultimate failure load of the repair.AIM To investigate the mechanical properties of rotator cuff tears repaired with a polypropylene interposition graft in an ovine ex-vivo model.METHODS A 20 mm length of infraspinatus tendon was resected from fifteen fresh sheep shoulders to simulate a large tear.We used a polypropylene mesh as an interposition graft between the ends of the tendon for repair.In seven specimens,the mesh was secured to remnant tendon by continuous stitching while mattress stitches were used for eight specimens.Five specimens with an intact tendon were tested.The specimens underwent cyclic loading to determine the ultimate failure load and gap formation.RESULTS The mean gap formation after 3000 cycles was 1.67 mm in the continuous group,and 4.16 mm in the mattress group(P=0.001).The mean ultimate failure load was significantly higher at 549.2 N in the continuous group,426.4 N in the mattress group and 370 N in the intact group(P=0.003).CONCLUSION The use of a polypropylene mesh is biomechanically suitable as an interposition graft for large irreparable rotator cuff tears. 展开更多
关键词 Rotator cuff repair Massive tear Interposition graft BIOMECHANICS polypropylene mesh
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Natural aging mechanism of buried polyethylene pipelines during long-term service
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作者 Ying-Chun Chen Yan-Feng Li +3 位作者 Yan Xi Qiang Li Qi Lu Jie Yang 《Petroleum Science》 SCIE EI CSCD 2023年第5期3143-3156,共14页
Currently,accelerated aging tests are widely used to study the aging process of polyethylene pipelines.However,this approach can only simulate one or several main influencing factors in the natural environment,which a... Currently,accelerated aging tests are widely used to study the aging process of polyethylene pipelines.However,this approach can only simulate one or several main influencing factors in the natural environment,which are often quite different from the actual environment of the buried pipelines.In this study,five types of PE80 buried pipelines in service for 9e18 years were taken as the research object,while new PE80 pipelines were taken as the reference group.The aging process and mechanism of polyethylene buried pipelines were studied through mechanical and chemical property tests and microstructural analysis.The results showed that the pipeline exhibited cross-linking as the main aging mechanism after being in service for 0e18 years.The aging degree and law of the inner and outer surface of the pipeline were compared,and the observed mechanism of both surfaces was explained.After 18 years in service,the elongation at the break of the pipe decreased by 16.2%,and the toughness of the matrix in the main collapse area of the tensile sample was the fundamental reason responsible for changes in the mechanical properties.Finally,after 18 years in service,the oxidation induction time of the pipeline was 25.7 min,which was 28.5% higher than the national standard value.There were no potential safety hazards during continuous long-term service.The results of this paper provide reference data and theoretical guidance for the aging process study of buried polyethylene pipelines. 展开更多
关键词 polyethylene Buried pipelines Long-term service Natural aging
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