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Verification of Beam Models for Ionic Polymer-Metal Composite Actuator 被引量:3
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作者 Hoon Cheol Park Quoc Viet Nguyen +1 位作者 Jang Woo Lee Young Tai Yoo 《Journal of Bionic Engineering》 SCIE EI CSCD 2009年第3期232-238,共7页
Ionic Polymer-Metal Composite (IPMC) can work as an actuator by applying a few voltages.A thick IPMC actuator,where Nafion-117 membrane was synthesized with polypyrrole/alumina composite filler,was analyzed to verify ... Ionic Polymer-Metal Composite (IPMC) can work as an actuator by applying a few voltages.A thick IPMC actuator,where Nafion-117 membrane was synthesized with polypyrrole/alumina composite filler,was analyzed to verify the equivalent beam and equivalent bimorph beam models.The blocking force and tip displacement of the IPMC actuator were measured with a DC power supply and Young's modulus of the IPMC strip was measured by bending and tensile tests respectively.The calculated maximum tip displacement and the Young's modulus by the equivalent beam model were almost identical to the corresponding measured data.Finite element analysis with thermal analogy technique was utilized in the equivalent bimorph beam model to numerically reproduce the force-displacement relationship of the IPMC actuator.The results by the equivalent bimorph beam model agreed well with the force-displacement relationship acquired by the measured data.It is confirmed that the equivalent beam and equivalent bimorph beam models are practically and effectively suitable for predicting the tip displacement,blocking force and Young's modulus of IPMC actuators with different thickness and different composite of ionic polymer membrane. 展开更多
关键词 jonic polymer-metal composite BEAM model DISPLACEMENT FORCE
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Soft actuator based on ion-exchange polymer-metal composite
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作者 罗玉元 金健 +1 位作者 张国贤 李朝东 《Journal of Shanghai University(English Edition)》 CAS 2007年第1期88-90,共3页
Ion-exchange polymer-metal composite (IPMC) is a new electroactive material. It has large deformation and high force weight ratio in the presence of low voltage (〈1.5 V). In this study a soft actuator known as ar... Ion-exchange polymer-metal composite (IPMC) is a new electroactive material. It has large deformation and high force weight ratio in the presence of low voltage (〈1.5 V). In this study a soft actuator known as artificial muscle based on IPMC was prepared. The IPMC actuator is composed of a perfluorinated ion-exchange membrane and platinum plated on both sides of the membrane by chemical means. Experiences and some key points are introduced in preparation of the IPMC. Electromechanical behaviors of the actuator are investigated, Factors related to the actuator performance are discussed. 展开更多
关键词 ion-exchange polymer-metal composite (IPMC) ACTUATOR artificial muscle
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Neural Network Approach to Modelling the Behaviour of Ionic Polymer-Metal Composites in Dry Environments
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作者 Andrés Díaz Lantada Pilar Lafont Morgado +2 位作者 José Luis Munoz Sanz Juan Manuel Munoz Guijosa Javier Echávarri Otero 《Journal of Signal and Information Processing》 2012年第2期137-145,共9页
Ionic polymer-metal composites (IPMCs) are especially interesting electroactive polymers because they show large a deformation in the presence of a very low driving voltage (around 1 - 2 V) and several applications ha... Ionic polymer-metal composites (IPMCs) are especially interesting electroactive polymers because they show large a deformation in the presence of a very low driving voltage (around 1 - 2 V) and several applications have recently been proposed. Normally a humid environment is required for the best operation, although some IPMCs can operate in a dry environment, after proper encapsulation or if a solid electrolyte is used in the manufacturing process. However, such solutions usually lead to increasing mechanical stiffness and to a reduction of actuation capabilities. In this study we focus on the behaviour of non-encapsulated IPMCs as actuators in dry environments, in order to obtain relevant information for design tasks linked to the development of active devices based on this kind of smart material. The non-linear response obtained in the characterisation tests is especially well-suited to modelling these actuators with the help of artificial neural networks (ANNs). Once trained with the help of characterisation data, such neural networks prove to be a precise simulation tool for describing IPMC response in dry environments. 展开更多
关键词 IONIC polymer-metal Composites (IPMCs) Artificial Neural Networks (ANNs) Smart Materials MODELLING and Simulation
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Bio-inspired robotic manta ray powered by ionic polymer-metal composite artificial muscles 被引量:4
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作者 Zheng Chen Tae I.Um Hilary Bart-Smith 《International Journal of Smart and Nano Materials》 SCIE EI 2012年第4期296-308,共13页
The manta ray(Manta birostris)is the largest species of rays that demonstrates excellent swimming capabilities via large-amplitude flapping of its pectoral fins.In this article,we present a bio-inspired robotic manta ... The manta ray(Manta birostris)is the largest species of rays that demonstrates excellent swimming capabilities via large-amplitude flapping of its pectoral fins.In this article,we present a bio-inspired robotic manta ray using ionic polymer–metal composite(IPMC)as artificial muscles to mimic the swimming behavior of the manta ray.The robot utilizes two artificial pectoral fins to generate undulatory flapping motions,which produce thrust for the robot.Each pectoral fin consists of an IPMC muscle in the leading edge and a passive polydimethylsiloxane membrane in the trailing edge.When the IPMC is actuated,the passive polydimethylsiloxane membrane follows the bending of the leading edge with a phase delay,which leads to an undulatory flapping motion on the fin.Characterization of the pectoral fin has shown that the fin can generate flapping motions with up to 100%tip deflection and 40◦twist angle.To test the free-swimming performance of the robot,a light and compact on-board control unit with a lithium ion polymer battery has been developed.The experimental results have shown that the robot can swim at 0.067 BL/s with portable power consumption of under 2.5 W. 展开更多
关键词 ionic polymer-metal composite artificial muscle bio-inspired robot
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Novel Strategies for Preparation and Characterization of Functional Polymer-metal Nanocomposites for Electrochemical Applications
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作者 D.N.Muraviev 《复旦学报(自然科学版)》 CAS CSCD 北大核心 2007年第5期630-631,共2页
1 Introduction The synthesis and characterization of Metal NanoParticles (MNPs) has attracted great interest of scientists and technologists within the last years due their unique physical and chemical properties,whic... 1 Introduction The synthesis and characterization of Metal NanoParticles (MNPs) has attracted great interest of scientists and technologists within the last years due their unique physical and chemical properties,which substantially differ from those of both bulk material and single atoms.These properties provide various practical applications of MNPs including catalysis-and electrocatalysis-based processes,which occur in,for example,fuel cells of different types or in various sensing devices (e.g.amper... 展开更多
关键词 novel strategies polymer-metal NANOCOMPOSITES
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Wireless actuation and control of ionic polymer-metal composite actuator using a microwave link
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作者 J.S.Lee W.Yim +1 位作者 C.Bae K.J.Kim 《International Journal of Smart and Nano Materials》 SCIE EI 2012年第4期244-262,共19页
The ionic polymer–metal composite(IPMC),a type of electroactive polymer(EAP)actuator,has created a unique opportunity to design robots that mimic the motion of biological systems due to its soft structure and operati... The ionic polymer–metal composite(IPMC),a type of electroactive polymer(EAP)actuator,has created a unique opportunity to design robots that mimic the motion of biological systems due to its soft structure and operation at a low voltage.Although this polymer actuator has strong potential for a next-generation artificial muscle actuator,it has been observed by many researchers that supplying actuation voltages in multiple locations is challenging.In robotic applications,a tethered operation is prohibited and the battery weight can be critical for actual implementation.In this research,the remote unit can provide necessary power and control signals to the target mobile robot units actuated by IPMCs.This research addresses a novel approach of using a wireless power link between the IPMC and a remote unit using microstrip patch antennas designed on the electrode surface of the IPMC for transmitting the power.Frequency modulation of the microwave is proposed to selectively actuate a particular portion of the IPMC where the matching patch antenna pattern is located.This approach can be especially useful for long-term operation of small-scale locomotion units and avoids problems caused by complex internal wiring often observed in various types of biologically inspired robots. 展开更多
关键词 ionic polymer-metal composite actuator microwave link wireless actuation robotic application biomimetic robot
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Ionic polymer-metal composite mechanoelectric transduction:effect of impedance
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作者 Rashi Tiwari 《International Journal of Smart and Nano Materials》 SCIE EI 2012年第4期275-295,共21页
Ionic polymer–metal composites(IPMCs)are commonly used as soft actuators due to their electromechanical response.However,the reverse phenomenon,i.e.IPMC’s ability to generate charge on application of mechanical stra... Ionic polymer–metal composites(IPMCs)are commonly used as soft actuators due to their electromechanical response.However,the reverse phenomenon,i.e.IPMC’s ability to generate charge on application of mechanical strain(mechanoelectric response),is not very well understood.The concept of mechanoelectric transduction and its dependence on complex IPMC architecture comprising of electrode,polymer and composite layer is illustrated with a phenomenological model.The impedance model takes into account the charge transport inside the polymer and layer properties in terms of their impedances.The model lucidly indicates the significance of capacitance in IPMC transduction.The impedance model is used for studying IPMC step and frequency response and the effect of IPMC capacitance on its application as energy harvester. 展开更多
关键词 ionic polymer-metal composite CAPACITANCE IMPEDANCE mechanoelectric response
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Development of an ionic polymer-metal composite stepper motor using a novel actuator model
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作者 A.J.McDaid K.C.Aw +2 位作者 K.Patel S.Q.Xie E.Haemmerle 《International Journal of Smart and Nano Materials》 SCIE EI 2010年第4期261-277,共17页
A novel ionic polymer–metal composite(IPMC)actuated stepper motor was developed in order to demonstrate an innovative design process for complete IPMC systems.The motor was developed by utilizing a novel model for IP... A novel ionic polymer–metal composite(IPMC)actuated stepper motor was developed in order to demonstrate an innovative design process for complete IPMC systems.The motor was developed by utilizing a novel model for IPMC actuators integrated with the complete mechanical model of the motor.The dynamic,nonlinear IPMC model can accurately predict the displacement and force actuation in air for a large range of input voltages as well as accounting for interactions with mechanical systems and external loads.By integrating this geometrically scalable IPMC model with a mechanical model of the motor mechanism an appropriate size IPMC strip has been chosen to achieve the required motor specifications.The entire integrated system has been simulated and its performance verified.The system has been built and the experimental results validated to show that the motor works as simulated and can indeed achieve continuous 360rotation,similar to conventional motors.This has proven that the model is an indispensable design tool for integrated IPMC actuators into real systems.This newly developed system has demonstrated the complete design process for smart material actuator systems,representing a large step forward and aiding in the progression of IPMCs towards wide acceptance as replacements for traditional actuators. 展开更多
关键词 ionic polymer-metal composite(IPMC) stepper motor mechanical design model application
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Modeling Ionic Polymer-Metal Composites with Space-Time Adaptive Multimesh hp-FEM
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作者 David Pugal Pavel Solin +1 位作者 Kwang J.Kim Alvo Aabloo 《Communications in Computational Physics》 SCIE 2012年第1期249-270,共22页
We are concerned with a model of ionic polymer-metal composite(IPMC)materials that consists of a coupled system of the Poisson and Nernst-Planck equations,discretized by means of the finite element method(FEM).We show... We are concerned with a model of ionic polymer-metal composite(IPMC)materials that consists of a coupled system of the Poisson and Nernst-Planck equations,discretized by means of the finite element method(FEM).We show that due to the transient character of the problem it is efficient to use adaptive algorithms that are capable of changing the mesh dynamically in time.We also show that due to large qualitative and quantitative differences between the two solution components,it is efficient to approximate them on different meshes using a novel adaptive multimesh hp-FEM.The study is accompanied with numerous computations and comparisons of the adaptive multimesh hp-FEMwith several other adaptive FEM algorithms. 展开更多
关键词 Ionic polymer-metal composites IPMC Nernst-Planck equation Poisson equation finite element method FEM adaptive multi-mesh hp-FEM
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聚酯合成催化技术的研究进展
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作者 王翼嵩 王松林 +8 位作者 姜冰雪 李家旭 邓维 史胜斌 LIM Khak Ho 王青月 杨轩 刘平伟 王文俊 《高校化学工程学报》 EI CAS CSCD 北大核心 2024年第1期1-13,共13页
聚酯工业的进步离不开先进的催化技术。本文对聚酯合成催化体系的研究进展进行了评述。着眼于目前占主导的金属催化剂,对锑、钛、锡、锗、铝等催化剂在活性、副反应等方面所开展的金属复合、配体改性、载体负载等工作进行了总结,介绍了... 聚酯工业的进步离不开先进的催化技术。本文对聚酯合成催化体系的研究进展进行了评述。着眼于目前占主导的金属催化剂,对锑、钛、锡、锗、铝等催化剂在活性、副反应等方面所开展的金属复合、配体改性、载体负载等工作进行了总结,介绍了有机物、离子液体、酶等非金属催化体系的研究进展,并对促进聚酯合成的电、光、微波等催化辅助技术进行了评述。催化能力强、副反应少、聚合条件温和催化体系的开发有助于聚酯品质的提升,将先进的表征手段、模型研究以及聚酯构效关系规律探索结合到催化体系的研究中,可加速高效聚酯催化技术的研发。 展开更多
关键词 聚酯 金属催化剂 缩聚 开环聚合 非金属催化剂
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无金属光催化开环易位聚合
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作者 朱文雅 李邦森 +2 位作者 石建军 孙天一 史载锋 《广州化工》 CAS 2024年第4期1-4,共4页
随着无金属光催化原子转移自由基聚合的诞生,其绿色环保的优点受到众多学者的青睐,而无金属光催化剂介导的开环易位聚合反应也取得了重大进展。综述了无金属光催化开环易位聚合反应的机理及光催化剂的合成与开发,适用单体范围、引发剂... 随着无金属光催化原子转移自由基聚合的诞生,其绿色环保的优点受到众多学者的青睐,而无金属光催化剂介导的开环易位聚合反应也取得了重大进展。综述了无金属光催化开环易位聚合反应的机理及光催化剂的合成与开发,适用单体范围、引发剂和溶剂的选择对反应的引发效率、聚合单体的转化率、聚合产物空间构型的的影响。此外,介绍了该聚合方法合成嵌段共聚物、控制分子量以及同乙烯基单体共聚的研究进展。 展开更多
关键词 聚合 无金属光催化剂 合成 机理
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铋/锡催化L-丙交酯与乙交酯本体开环共聚
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作者 郑文 张建纲 +4 位作者 张跃胜 刘雄 包建娜 张先明 陈文兴 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2024年第2期39-51,共13页
为探究金属催化剂辛酸亚锡(Sn(Oct)_(2))与次水杨酸铋(BiSS)对L-丙交酯(L-LA)与乙交酯(GA)本体开环聚合(ROP)反应过程及产物性能的影响,使用不同含量的Sn(Oct)_(2)或BiSS合成一系列聚丙交酯-乙交酯共聚物(PLGA)。通过核磁共振波谱仪、... 为探究金属催化剂辛酸亚锡(Sn(Oct)_(2))与次水杨酸铋(BiSS)对L-丙交酯(L-LA)与乙交酯(GA)本体开环聚合(ROP)反应过程及产物性能的影响,使用不同含量的Sn(Oct)_(2)或BiSS合成一系列聚丙交酯-乙交酯共聚物(PLGA)。通过核磁共振波谱仪、傅里叶变换红外光谱仪、凝胶渗透色谱仪对聚合物的微观结构、聚合反应动力学和相对分子质量进行了表征,借助热重分析仪和差示扫描量热仪对聚合物的热性能进行了分析。结果表明,BiSS是一种非常有吸引力的催化剂,在ROP制备PLGA共聚物中获得了与Sn(Oct)_(2)类似的结果,其催化性能可与Sn(Oct)_(2)相媲美。BiSS催化制备的PLGA的热稳定性显著提高,例如,1000×10^(-6)Bi催化制备的PLGA73在氮气氛围下的T_(5)%和T_(90)%分别为269.6℃和379.2℃,相较于Sn(Oct)_(2)分别升高了36℃和82.7℃。由BiSS催化制备的PLGA链段具有更高的随机性和更短的L-LA序列长度。BiSS可以替代商业使用的Sn(Oct)_(2)用于生产生物医学领域应用的低毒性PLGA。 展开更多
关键词 L-丙交酯 乙交酯 金属催化剂 开环聚合
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过渡金属配合物催化烯烃配位聚合综合实验的设计——催化剂构效关系的典型案例
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作者 李婷 罗明玲 +6 位作者 覃峰 陈伟强 李家兴 公培伟 刘鹏 郭丽华 冯媛媛 《化工高等教育》 2024年第1期141-148,共8页
文章介绍了一个涉及合成化学多领域的综合实验,要求学生利用合成的有机配体制备相应的过渡金属配合物,并作为催化剂均相催化烯烃配位聚合,同时对所得聚合物性能进行测试。该实验串联了有机配体合成、金属配合物合成、高分子催化合成和... 文章介绍了一个涉及合成化学多领域的综合实验,要求学生利用合成的有机配体制备相应的过渡金属配合物,并作为催化剂均相催化烯烃配位聚合,同时对所得聚合物性能进行测试。该实验串联了有机配体合成、金属配合物合成、高分子催化合成和高分子材料性能测试模块的内容,能让学生观察到烯烃配位聚合中的催化剂构效关系,有利于全面提高学生的学习兴趣、实验技能和独立思考能力。 展开更多
关键词 过渡金属配合物 配位聚合 构效关系 综合实验
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不同外源Cd(Ⅱ)对Pseudomonas aeruginosa EPS的胁迫效应--产量、组分、吸附特性变化及其机制
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作者 陈丽瑶 连泽阳 +5 位作者 宋卫锋 戴文灿 杨佐毅 孙梦格 黄祥武 白晓燕 《中国环境科学》 EI CAS CSCD 北大核心 2024年第1期537-547,共11页
以CdCl_(2)、CdSO_(4)和Cd(NO_(3))_(2)为胁迫因子,比较了不同阴离子在胁迫/诱导过程中对Pseudomonas aeruginosa(P.aeruginosa)胞外聚合物(EPS)的产量和特性的影响以及对Cd(II)吸附性能的变化.研究发现,当Cd(NO_(3))_(2)胁迫/诱导浓度... 以CdCl_(2)、CdSO_(4)和Cd(NO_(3))_(2)为胁迫因子,比较了不同阴离子在胁迫/诱导过程中对Pseudomonas aeruginosa(P.aeruginosa)胞外聚合物(EPS)的产量和特性的影响以及对Cd(II)吸附性能的变化.研究发现,当Cd(NO_(3))_(2)胁迫/诱导浓度为50mg/L时,EPS产量达到214.91mg/g VSS,其中蛋白质含量达到136.75mg/g VSS,较胁迫/诱导前增加了409.31%.此时EPS的吸附性能最好,对Cd(II)的平衡吸附量最大,较胁迫/诱导前增加了近一半.HPLC分析表明,EPS蛋白质中氨基酸的变化与EPS的吸附特性密切相关.3D-EEM、XPS和FTIR结果表明,EPS中C=O、C-N和N-H含量增加,有利于重金属的结合.竞争吸附实验发现,EPS对Cd(II)的亲和力高于Zn(II). 展开更多
关键词 革兰氏阴性菌 胞外聚合物 蛋白质 氨基酸 竞争吸附 重金属
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蒽基取代含酚单茂催化剂在乙烯聚合中的应用
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作者 郭钦生 韩书亮 +1 位作者 宋文波 董泽 《石油化工》 CAS CSCD 北大核心 2024年第6期802-809,共8页
以蒽基取代的含酚单茂催化剂为主催化剂,三苯甲基四(五氟苯基)硼酸盐为助催化剂进行了乙烯均聚和乙烯/α-烯烃共聚反应,利用DSC,GPC等方法考察了该催化体系在不同聚合条件下的聚合性能。实验结果表明,该催化体系催化乙烯均聚的活性最高... 以蒽基取代的含酚单茂催化剂为主催化剂,三苯甲基四(五氟苯基)硼酸盐为助催化剂进行了乙烯均聚和乙烯/α-烯烃共聚反应,利用DSC,GPC等方法考察了该催化体系在不同聚合条件下的聚合性能。实验结果表明,该催化体系催化乙烯均聚的活性最高可达到3.36×10^(6)g/(mol·h)。适宜的聚合条件为:催化剂用量10μmol,n(Al)∶n(Ti)=150,n(B)∶n(Ti)=1.5,反应温度20℃,反应压力0.4 MPa,聚合时间10 min,液体总体积200 mL。在该条件下还可催化乙烯与α-烯烃共聚,其中,与1-辛烯共聚时,聚合活性最高可达2.00×10^(6)g/(mol·h),共聚物密度在0.859~0.876 g/cm3之间,玻璃化转变温度均低于-52℃,符合乙烯共聚弹性体的结构性能特征,且通过调节共聚单体浓度能有效控制乙烯共聚物链结构。 展开更多
关键词 单茂金属配合物 苯酚配体 乙烯聚合 乙烯共聚物 聚烯烃弹性体
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原位聚合法负氧离子尼龙纤维的制备及应用
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作者 郑燕春 付文英 +3 位作者 蓝淼东 滕巧玲 孙珊珊 吕少微 《化工生产与技术》 CAS 2024年第1期4-6,15,I0002,共5页
针对尼龙纤维面料负氧离子释放/抗菌等问题,通过原位聚合法制备得到负氧离子尼龙纤维,研究了温度、湿度、光照及洗涤次数对负氧离子尼龙纤维负氧离子释放的影响。结果表明,原位聚合法负氧离子尼龙纤维安全性能达标,在温度为30℃,湿度达... 针对尼龙纤维面料负氧离子释放/抗菌等问题,通过原位聚合法制备得到负氧离子尼龙纤维,研究了温度、湿度、光照及洗涤次数对负氧离子尼龙纤维负氧离子释放的影响。结果表明,原位聚合法负氧离子尼龙纤维安全性能达标,在温度为30℃,湿度达到50%以上时,其负氧离子释放量趋于较大值(1 200~1 300个/cm^(3))。 展开更多
关键词 己内酰胺 原位聚合 无机纳米金属 负氧离子尼龙纤维
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冷冻界面聚合法制备聚吡咯@UIO-66复合织物电极及其电化学性能研究
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作者 孙艳 林秀玲 +2 位作者 田佳鑫 冯常奇 许杰 《化工新型材料》 CAS CSCD 北大核心 2024年第1期84-90,共7页
通过原位溶剂热反应将锆-金属有机框架(UIO-66)沉积在棉布上,并采用冷冻界面聚合法聚合聚吡咯(PPy)从而获得PPy@UIO-66@棉复合织物电极材料。通过扫描电镜、红外光谱、循环伏安、恒电流充放电、交流阻抗等手段对该复合织物电极的形貌结... 通过原位溶剂热反应将锆-金属有机框架(UIO-66)沉积在棉布上,并采用冷冻界面聚合法聚合聚吡咯(PPy)从而获得PPy@UIO-66@棉复合织物电极材料。通过扫描电镜、红外光谱、循环伏安、恒电流充放电、交流阻抗等手段对该复合织物电极的形貌结构和性能进行了表征。结果表明:利用该织物电极组装的超级电容器在电流密度为1.6mA/cm^(2)条件下面积比电容为3888mF/cm^(2)(相应的质量比容量为410.4F/g),经过1000个充放电循环后比电容保持率为73%。 展开更多
关键词 金属有机框架 超级电容器 聚吡咯 织物电极 冷冻界面聚合
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重金属镍对A^(2)/O-BAF系统运行效能的影响及作用机制探究
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作者 谢兴龙 徐松松 《水处理技术》 CAS CSCD 北大核心 2024年第1期116-121,共6页
针对重金属镍(Ni)对A^(2)/O-生物曝气滤池(BAF)双污泥系统污染物及营养盐去除影响不明确的现状,开展了重金属Ni对双污泥系统对污染物和营养盐去除规律的影响的研究,分析了重金属Ni暴露下双污泥系统内污泥特征的变化规律,解析了微生物群... 针对重金属镍(Ni)对A^(2)/O-生物曝气滤池(BAF)双污泥系统污染物及营养盐去除影响不明确的现状,开展了重金属Ni对双污泥系统对污染物和营养盐去除规律的影响的研究,分析了重金属Ni暴露下双污泥系统内污泥特征的变化规律,解析了微生物群落结构对重金属的响应特征。结果表明重金属镍浓度超过2.0 mg/L Ni降低了A^(2)/OBAF双污泥系统对污染物和营养盐的去除能力。重金属Ni刺激了胞外聚合物(EPS)尤其是SB-EPS的分泌,并降低了污泥浓度及有机质占比。微生物群落结果分析表明Ni能改变微生物的群落结构,高浓度Ni降低了Proteobacteria、Actinobacteriota和Bacteroidota的相对丰度,从而降低了双污泥系统对污染物和营养盐的去除。研究结果为双污泥系统处理含Ni废水提供了一定的数据支撑和理论指导。 展开更多
关键词 双污泥系统 重金属镍 胞外聚合物 微生物群落特征
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壳聚糖改性絮凝剂对含铅废水的强化絮凝处理
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作者 刘丽秀 何爱江 曾碧涛 《山东化工》 CAS 2023年第15期30-33,36,共5页
选用壳聚糖(CS)、丙烯酰胺(AM)和衣康酸(IA)作为接枝共聚单体,通过超声波-自由基引发聚合制备出富含羧酸基团的新型重金属絮凝剂CS-g-P(AM-IA),该絮凝剂兼具螯合配位与絮凝作用,用以高效去除重金属Pb^(2+)。FTIR和SEM的分析结果表明AM... 选用壳聚糖(CS)、丙烯酰胺(AM)和衣康酸(IA)作为接枝共聚单体,通过超声波-自由基引发聚合制备出富含羧酸基团的新型重金属絮凝剂CS-g-P(AM-IA),该絮凝剂兼具螯合配位与絮凝作用,用以高效去除重金属Pb^(2+)。FTIR和SEM的分析结果表明AM与IA成功接枝CS。絮凝实验结果表明:在pH值=5.0,絮凝时间为25 min,CS-g-P(AM-IA)和CS投加量为3.0 mg/L时,对Pb^(2+)的去除率分别达到了84.5%与64.3%。CS-g-P(AM-IA)对Pb^(2+)的去除效果明显优于CS。离子强度和共存阳离子对CS-g-P(AM-IA)和CS吸附絮凝性能有一定的影响,其中Ca^(2+)的影响最为明显。CS-g-P(AM-IA)主要通过其IA上的羧基基团螯合配位Pb^(2+)离子并将其固定住,然后在吸附架桥和网捕卷扫絮凝作用下,生成大而密实的重金属絮体结构(d_(50)=275.9μm,D_(f)=1.91),强化了Pb^(2+)的分离去除。 展开更多
关键词 壳聚糖 衣康酸 Pb 2+ 重金属废水 絮凝剂 接枝聚合
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含磺酸钠聚合物微凝胶的制备及对Cu(II)和Pb(II)的吸附
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作者 邓文谨 姚晨曦 +4 位作者 林文波 张家豪 彭学文 张春燕 罗建新 《塑料工业》 CAS CSCD 北大核心 2023年第11期170-179,共10页
采用回流-沉淀聚合制备了含磺酸钠聚合物微凝胶(SSPMg),通过扫描电子显微镜(SEM)、比表面及孔隙度分析(BET)、傅里叶变换红外光谱(FTIR)、X射线光电子能谱(XPS)等对其结构性能和化学组成进行了表征,并考察了SSPMg对Cu(II)和Pb(II)的吸... 采用回流-沉淀聚合制备了含磺酸钠聚合物微凝胶(SSPMg),通过扫描电子显微镜(SEM)、比表面及孔隙度分析(BET)、傅里叶变换红外光谱(FTIR)、X射线光电子能谱(XPS)等对其结构性能和化学组成进行了表征,并考察了SSPMg对Cu(II)和Pb(II)的吸附性能。结果表明,对苯乙烯磺酸钠占共聚单体总质量17.5%的微凝胶(SSPMg-4)在pH值=5时吸附效果最佳;吸附过程更符合准二级动力学和Langmuir等温吸附模型,以单分子层的化学吸附为主,包括络合、离子交换和静电吸附作用;吸附过程ΔG小于0、ΔH大于0,表现为常温下的自发吸热过程。298.15 K时,SSPMg-4对Cu(II)和Pb(II)的Langmuir理论最大吸附量分别达523.56 mg/g和568.18 mg/g。经过6次循环使用后,SSPMg-4对Cu(II)和Pb(II)的去除率保持在初始去除率的92%以上。 展开更多
关键词 微凝胶 磺酸钠 回流-沉淀聚合 重金属 吸附
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