In this work, long-period waveguide grating-based tunable wavelength filters using organic–inorganic grafting poly(methyl methacrylate)(PMMA) materials are designed and fabricated by metal-cladding directly defin...In this work, long-period waveguide grating-based tunable wavelength filters using organic–inorganic grafting poly(methyl methacrylate)(PMMA) materials are designed and fabricated by metal-cladding directly defined technique.The thermal stabilities and optical properties of the organic–inorganic grafting PMMA core materials are analyzed. Structures and performance parameters of the waveguide gratings and self-electrode heaters are designed and simulated. The contrast of the filter is about 15 d B and the resonant wavelength can be tuned by different electric powers applied to the metal-cladding self-electrode heaters. The temperature sensitivity is 3.5 nm/℃ and the switching time is about 1 ms. The technique is very suitable for realizing the optoelectronic integrated wavelength-division-multiplexing systems.展开更多
Porous silica prepared by using an acrylic emulsion has been impregnated with bismuth ion resulting in Bi2Si05 species containing surface. The as-prepared materials have been characterized by X-ray diffraction spectro...Porous silica prepared by using an acrylic emulsion has been impregnated with bismuth ion resulting in Bi2Si05 species containing surface. The as-prepared materials have been characterized by X-ray diffraction spectroscopy (XRD), X-ray photoelectron spectroscopy (XPS), UV-Vis diffuse reflectance spectroscopy (UV-Vis DRS), scanning electron microscopy (SEM), energy dispersive analysis of X-ray (EDAX), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FTIR) and N2 adsorption/desorption techniques. EDAX analysis confirms the penetration of bismuth ions into the framework of silica to form Bi2SiO5, which is substantiated by XRD. The UV-Vis DRS shows that the catalysts are optically active and XPS confirms the inclusion of bismuth into the framework of silica. FTIR spectra illustrate the formation of Bi-O-Si linkages in the porous silica framework. SEM and TEM show the spherical morphology, whereas N2 adsorption/desorption study confirms the porosity of the prepared materials. The photocatalytic activity of the material is evaluated for the degradation of isoproturon herbicide and it is found that the material is active as compared to the commercial P-25 Degussa TiO2.展开更多
Sr- and Mg-doped lanthanum gallate powders with the composition of La0.55Sr0.15Ga0.85Mg0.15O2.85were synthesized by a glycine-nitrate combustion method. Powders prepared under different fuel combustion conditions were...Sr- and Mg-doped lanthanum gallate powders with the composition of La0.55Sr0.15Ga0.85Mg0.15O2.85were synthesized by a glycine-nitrate combustion method. Powders prepared under different fuel combustion conditions were investigated by XRD and TEM. The results show that, under slightly rich fuel condition, the product powders contain less impurity phases, and powders prepared by the glycine-nitrate combustion contain far less impurity phases and have smaller particle sizes than those prepared by solid-state reaction method or acrylamide polymerization technique.展开更多
基金Project supported by the National Natural Science Foundation of China(Grant Nos.61575076,61475061,and 61405070)the Fundamental Research Funds for the Central Universities,China(Grant No.JCKY-QKJC08)+1 种基金the Science and Technology Development Plan of Jilin Province,China(Grant Nos.20130522151JH,20140519006JH,and 20160520091JH)the China Postdoctoral Science Foundation(Grant No.2015M571362)
文摘In this work, long-period waveguide grating-based tunable wavelength filters using organic–inorganic grafting poly(methyl methacrylate)(PMMA) materials are designed and fabricated by metal-cladding directly defined technique.The thermal stabilities and optical properties of the organic–inorganic grafting PMMA core materials are analyzed. Structures and performance parameters of the waveguide gratings and self-electrode heaters are designed and simulated. The contrast of the filter is about 15 d B and the resonant wavelength can be tuned by different electric powers applied to the metal-cladding self-electrode heaters. The temperature sensitivity is 3.5 nm/℃ and the switching time is about 1 ms. The technique is very suitable for realizing the optoelectronic integrated wavelength-division-multiplexing systems.
基金PAKR and MS thank CSIR,New Delhi for funding this work under Emeritus Scientist Scheme
文摘Porous silica prepared by using an acrylic emulsion has been impregnated with bismuth ion resulting in Bi2Si05 species containing surface. The as-prepared materials have been characterized by X-ray diffraction spectroscopy (XRD), X-ray photoelectron spectroscopy (XPS), UV-Vis diffuse reflectance spectroscopy (UV-Vis DRS), scanning electron microscopy (SEM), energy dispersive analysis of X-ray (EDAX), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FTIR) and N2 adsorption/desorption techniques. EDAX analysis confirms the penetration of bismuth ions into the framework of silica to form Bi2SiO5, which is substantiated by XRD. The UV-Vis DRS shows that the catalysts are optically active and XPS confirms the inclusion of bismuth into the framework of silica. FTIR spectra illustrate the formation of Bi-O-Si linkages in the porous silica framework. SEM and TEM show the spherical morphology, whereas N2 adsorption/desorption study confirms the porosity of the prepared materials. The photocatalytic activity of the material is evaluated for the degradation of isoproturon herbicide and it is found that the material is active as compared to the commercial P-25 Degussa TiO2.
文摘Sr- and Mg-doped lanthanum gallate powders with the composition of La0.55Sr0.15Ga0.85Mg0.15O2.85were synthesized by a glycine-nitrate combustion method. Powders prepared under different fuel combustion conditions were investigated by XRD and TEM. The results show that, under slightly rich fuel condition, the product powders contain less impurity phases, and powders prepared by the glycine-nitrate combustion contain far less impurity phases and have smaller particle sizes than those prepared by solid-state reaction method or acrylamide polymerization technique.