氧化铝水合物在聚苯乙烯上的覆盖

The prerequisite of covering of aluminum hydrous oxide, obtained by the hydrolysis of acldic alumimum salts in the present of urea, on pre-existing spheric polystyrene particles is that surface of pre-existing particles must be modified by anionic surfactants. Meanwhile, modifiers also accelerate the hydrolysis of aluminum salt, which will induce independent nucleation of aluminum hydrous oxide. Therefore, in order to prevent the formation of aluminum hydrous oxide particles, the amount of surf hce modifier should be correctly contolled.

铝合金表面改性对有机涂层附着力的影响及腐蚀防护性能研究

利用电化学阻抗(EIS)、扫描微参比技术(SRET)、接触角、粗糙度、附着力、盐雾等测试方法,研究了铝合金阳极氧化与贻贝黏附蛋白(MAP)/CeO_(2)/硅烷γ-APS(MCA)表面复合修饰的腐蚀防护性能以及对改性聚氨酯涂层附着力和耐蚀性的影响。结果表明,MCA复合膜可抑制铝合金的腐蚀,并具有一定的自修复功能;阳极氧化和MCA表面复合修饰可为铝合金提供有效的早期腐蚀防护作用,且能提高铝合金表面粗糙度和润湿性,显著提升改性聚氨酯涂层在铝合金表面的附着力和耐蚀性,因而结合改性聚氨酯涂层和表面复合修饰可实现对铝合金长期有效的腐蚀防护。