The cathode material Pr0.7Sr0.3Co1-yCuyO3-δ (y=0.05～0.3) was synthesized by a sol-gel method. X-ray diffraction indicated that the samples with y≤0.2 were single phase orthorhombic perovskite structure, but in the ...The cathode material Pr0.7Sr0.3Co1-yCuyO3-δ (y=0.05～0.3) was synthesized by a sol-gel method. X-ray diffraction indicated that the samples with y≤0.2 were single phase orthorhombic perovskite structure, but in the case of y=0.3, traces of a second phase were observed. The unit cell volumes increased with increasing copper content. The electrical conductivity decreased gradually with increasing Cu addition. The investigation of the electrochemical performance suggested that the sample with y=0.1 exhibited the lowest overpotential in all prepared Pr0.7Sr0.3Co1-yCuyO3-δ. With Pr0.7Sr0.3Co0.9Cu0.1O3-δ cathode and porous NiO/Ce0.8Sm0.2O1.9 anode, the single cell based on SDC thin film electrolyte was obtained by a simple dry pressing process. Maximum power densities of the cell were 406 and 481 mW·cm-2 at 700 and 750 ℃, respectively.展开更多
基金the National Natural Science Foundation of China (10674034)
文摘The cathode material Pr0.7Sr0.3Co1-yCuyO3-δ (y=0.05～0.3) was synthesized by a sol-gel method. X-ray diffraction indicated that the samples with y≤0.2 were single phase orthorhombic perovskite structure, but in the case of y=0.3, traces of a second phase were observed. The unit cell volumes increased with increasing copper content. The electrical conductivity decreased gradually with increasing Cu addition. The investigation of the electrochemical performance suggested that the sample with y=0.1 exhibited the lowest overpotential in all prepared Pr0.7Sr0.3Co1-yCuyO3-δ. With Pr0.7Sr0.3Co0.9Cu0.1O3-δ cathode and porous NiO/Ce0.8Sm0.2O1.9 anode, the single cell based on SDC thin film electrolyte was obtained by a simple dry pressing process. Maximum power densities of the cell were 406 and 481 mW·cm-2 at 700 and 750 ℃, respectively.
