In this paper, polyurethane resins were synthesized from liquefied benzylated wood and TD1 (toluene diisocyanate)-TMP (trihydromethylene propane) prepolymer. And the relation between microphase structure and propertie...In this paper, polyurethane resins were synthesized from liquefied benzylated wood and TD1 (toluene diisocyanate)-TMP (trihydromethylene propane) prepolymer. And the relation between microphase structure and properties of PU samples were also studied. The results indicated that coatings obtained had good mechanical and thermal properties. The amount of the curing agent has great effect on the degree of phase segregation. In addition, with increased the curing agent amount, the thermal stabilities were also improved.展开更多
基金The author thanks the Tianjin Natural Science Foundation for the financial support(Project No.013801411) the help ofTianjin Beacon Paint＆Coatings Co．，Ltd．
文摘In this paper, polyurethane resins were synthesized from liquefied benzylated wood and TD1 (toluene diisocyanate)-TMP (trihydromethylene propane) prepolymer. And the relation between microphase structure and properties of PU samples were also studied. The results indicated that coatings obtained had good mechanical and thermal properties. The amount of the curing agent has great effect on the degree of phase segregation. In addition, with increased the curing agent amount, the thermal stabilities were also improved.
