Environmental impact assessment of China’s primary aluminum based on life cycle assessment

Assessing and accounting for material consumption and environmental impact are necessary to measure environmental externalities of the aluminum industry and to construct an ecological civilization.In this research,life cycle assessment(LCA)theory was used to assess the environmental impact of primary aluminum based on the lime soda Bayer process and different power generation modes,and the sources and distributions of the four selected impact categories were analyzed.The results show that,(1)Negative environmental impact of aluminum industry generally occurs from alumina extraction,carbon anode fabrication and electrolysis,particularly electrolysis and alumina extraction.Primary energy demand(PED),water use(WU),global warming potential(GWP)and freshwater eutrophication potential(FEP)are main environmental impact categories.(2)The environmental load with thermal power is higher than that with hydropower,e.g.,for the former,the greenhouse gas emission coefficient of 21800 kg CO2 eq/t(Al)will be generated,while for the latter,4910 kg CO2 eq/t(Al)will be generated.(3)Both power mode methods reflect the energy structure,whereas direct emissions reflect the technical level,indicating the potential for large energy savings and emission reductions,and some policies,related to clean power,energy efficiency and technological progress,should be made for emission reduction.

Effect of barium on the refinement of primary aluminum and eutectics in a hypoeutectic Al-Si alloy

The effect of barium on the refinement of primary aluminum and on themodification of eutectics in a hypoeutectic aluminum-silicon alloy was investigated. The resultsindicate that barium not only modifies the eutectic silicon but also refines the primary aluminumand there is a relationship between the retained barium and the second spacing of primary aluminum.Experiments of barium-treated commercial Al-Si hypoeutectic alloy show that barium is a bettermodifier than sodium when there is a longer holding time.

Improvement in mechanical properties of hypereutectic Al-Si-Cu alloys through sonosolidified slurry

For the wider applications,it is necessary to improve the ductility as well as the strength and wear-resistance of hypereutectic AlSi-Cu alloys,which are typical light-weight wear-resistant materials.An increase in the amounts of primary silicon particles causes the modified wear-resistance of hypereutectic Al-Si-Cu alloys,but leads to the poor strength and ductility.It is known that dual phase steels composed of hetero-structure have succeeded in bringing contradictory mechanical properties of high strength and ductility concurrently.In order to apply the idea of hetero-structure to hypereutectic Al-Si-Cu alloys for the achievement of high strength and ductility along with wear resistance,ultrasonic irradiation of the molten metal during the solidification,which is called sono-solidification,was carried out from its molten state to just above the eutectic temperature.The sono-solidified Al-17Si-4Cu alloy is composed of hetero-structure,which are,hard primary silicon particles,soft non-equilibrium a-Al phase and the eutectic region.Rheo-casting was performed at just above the eutectic temperature with sono-solidified slurry to shape a disk specimen.After the rheo-casting with modified sonosolidified slurry held for 45 s at 570 oC,the quantitative optical microscope observation exhibits that the microstructure is composed of 18area%of hard primary silicon particles and 57area%of soft a-Al phase.In contrast,there exist only 5 area%of primary silicon particles and no a-Al phase in rheo-cast specimen with normally solidified slurry.Hence the tensile tests of T6 treated rheo-cast specimens with modified sono-solidified slurry exhibit improved strength and 5%of elongation,regardless of having more than 3 times higher amounts of primary silicon particles compared to that of rheo-cast specimen with normally solidified slurry.