A joint international effort to improve solid propellant performance within the framework of a FP7European Project was described.Several metallized solid rocket propellants,of the broad family AP/HTPB/Metal in the rat...A joint international effort to improve solid propellant performance within the framework of a FP7European Project was described.Several metallized solid rocket propellants,of the broad family AP/HTPB/Metal in the ratio 68/14/18,were experimentally analyzed seeking to optimize the delivered specific impulse by identifying the most suitable high-energy fuel.Keeping the same nominal composition,different metallic fuels(including micrometric and nanometric Al,AlH3,and a variety of dual metal compositions)were characterized,tested,and contrasted to a conventional micrometric aluminum(30μm average grain size)certified for space flights.In order to overcome the intrinsic performance limitations of the matrix AP/HTPB,a new matrix consisting of ADN/GAP satisfying also the need for environmentally benign propellant formulation was considered as well.A comparative analysis between the two solid propellant systems in terms of ideal thermochemistry and experimental combustion properties reveals advantages and disadvantages of both.Overall,it is judged worthwhile to develop ADN/GAP propellants,with or without metallic fuels,to enhance the current status of solid rocket propulsion.Controlling morphology and mechanical properties of ADN/GAP compositions and understanding their flame structure and aggregation/agglomeration properties are the main issues still challenging industrial users.展开更多
Several metallized solid rocket propellants,AP/Metal/HTPB in the ratio 68/18/14,were experimentally analyzed at the Space Propulsion Laboratory of Politecnico di Milano.Effects of the metals(micrometric and nanometric...Several metallized solid rocket propellants,AP/Metal/HTPB in the ratio 68/18/14,were experimentally analyzed at the Space Propulsion Laboratory of Politecnico di Milano.Effects of the metals(micrometric and nanometric Al,B,Mg,and a variety of dual metals) on the performance of the propellant were studied and contrasted to a conventional micrometric aluminum(30 μm average grain size) taken as reference.It is shown that the propellant microstructure plays a fundamental role in controlling the critical aggregation/agglomeration phenomena occurring below and near the burning surface.Two specific effects of microstructure in terms of steady burning rate and average agglomerate size are illustrated.展开更多
基金supported by the HISP project(High performance solid propellants for In-Space Propulsion)of the European Community′s Seventh Framework Programme(FP7/2007-2013), under Grant Agreement No.262099,coordinated by FOI
文摘A joint international effort to improve solid propellant performance within the framework of a FP7European Project was described.Several metallized solid rocket propellants,of the broad family AP/HTPB/Metal in the ratio 68/14/18,were experimentally analyzed seeking to optimize the delivered specific impulse by identifying the most suitable high-energy fuel.Keeping the same nominal composition,different metallic fuels(including micrometric and nanometric Al,AlH3,and a variety of dual metal compositions)were characterized,tested,and contrasted to a conventional micrometric aluminum(30μm average grain size)certified for space flights.In order to overcome the intrinsic performance limitations of the matrix AP/HTPB,a new matrix consisting of ADN/GAP satisfying also the need for environmentally benign propellant formulation was considered as well.A comparative analysis between the two solid propellant systems in terms of ideal thermochemistry and experimental combustion properties reveals advantages and disadvantages of both.Overall,it is judged worthwhile to develop ADN/GAP propellants,with or without metallic fuels,to enhance the current status of solid rocket propulsion.Controlling morphology and mechanical properties of ADN/GAP compositions and understanding their flame structure and aggregation/agglomeration properties are the main issues still challenging industrial users.
基金supported by CNES(under Commande No.4700024752/DLA090 and No.4700028003/DLA094)
文摘Several metallized solid rocket propellants,AP/Metal/HTPB in the ratio 68/18/14,were experimentally analyzed at the Space Propulsion Laboratory of Politecnico di Milano.Effects of the metals(micrometric and nanometric Al,B,Mg,and a variety of dual metals) on the performance of the propellant were studied and contrasted to a conventional micrometric aluminum(30 μm average grain size) taken as reference.It is shown that the propellant microstructure plays a fundamental role in controlling the critical aggregation/agglomeration phenomena occurring below and near the burning surface.Two specific effects of microstructure in terms of steady burning rate and average agglomerate size are illustrated.
