Unraveling the hydraulic properties of loess for landslide prediction:A study on variations in loess landslides in Lanzhou,Dingxi,and Tianshui,China

Loess has distinctive characteristics,leading to frequent landslide disasters and posing serious threats to the lives and properties of local re sidents.The involvement of water repre sents a critical factor in inducing loess landslides.This study focuses on three neighboring cities sequentially situated on the Loess Plateau along the direction of aeolian deposition of loess,namely Lanzhou,Dingxi,and Tianshui,which are densely populated and prone to landslide disasters.The variations in hydraulic properties,including water retention capacity and permeability,are investigated through Soil Water Characteristic Curve(SWCC)test and hydraulic conductivity test.The experimental findings revealed that Tianshui loess exhibited the highest water retention capacity,followed by Dingxi loess,while Lanzhou loess demonstrated the lowest water retention capacity.Contrastingly,the results for the saturated permeability coefficient were found to be the opposite:Tianshui loess showed the lowest permeability,whereas Lanzhou loess displayed the highest permeability.These results are supported and analyzed by scanning electron microscopy(SEM)observation.In addition,the water retention capacity is mathematically expressed using the van Genuchten model and extended to predict unsaturated hydraulic properties of loess.The experimental results exhibit a strong accordance with one another and align with the regional distribution patterns of disasters.

PRELIMINARY STUDIES ON STRUCTURES AND PROPERTIES OF WATER-RETENTIVE, FLAME-RETARDANT ACRYLIC FIBERS

The blend fibers of acrylonitrile-vinylidene chloride-sodium methallysulfonate copolymer(AN-VDC-SMAS) and cellulose acetate (CA) with various blend ratios were investigated bymeans of SEM, DDV, WAXD, etc. The results show that AN-VDC-SMAS and CA areincompatibale; the numerous microvoids in the blend fiber resulted from the phase seperationcan remarkably improve the water absorbability and the dyeing behavior but hardly influencethe mechanical properties. On the other hand, the crystal structure of the continuous phaseAN-VDC-SMAS is not influnced by the dispersed phase CA.

Effects of water on the structure and transport properties of room temperature ionic liquids and concentrated electrolyte solutions

Transport properties and the associated structural heterogeneity of room temperature aqueous ionic liquids and especially of super-concentrated electrolyte aqueous solutions have received increasing attention,due to their potential application in ionic battery.This paper briefly reviews the results reported mainly since 2010 about the liquid-liquid separation,aggregation of polar and apolar domains in neat RTILs,and solvent clusters and 3D networks chiefly constructed by anions in super-concentrated electrolyte solutions.At the same time,the dominating effect of desolvation process of metal ions at electrode/electrolyte interface upon the transport of metal ions is stressed.This paper also presents the current understanding of how water affects the anion-cation interaction,structural heterogeneities,the structure of primary coordination sheath of metal ions and consequently their transport properties in free water-poor electrolytes.

Mutual optimization of water utilization structure and industrial structure in arid inland river basins of Northwest China

Water is a key restricting factor of the economic development and eco-environmental protection in arid inland river basins of Northwest China. Although water supplies are short, the water utilization structure and the corresponding industrial structure are unbalanced. We constructed a System Dynamic Model for mutual optimization based on the mechanism of their interaction. This model is applied to the Heihe River Basin where the share of limited water resources among ecosystem, production and human living is optimized. Results show that, by mutual optimization, the water utilization structure and the industrial structures fit in with each other. And the relationships between the upper, middle and lower reaches of the Heihe River Basin can be harmonized. Mutual benefits of ecology, society and economy can be reached, and a sustainable ecology-production-living system can be obtained. This study gives a new insight and method for the sustainable utilization of water resources in arid inland river basins.

Viscoelasto-plastic properties of deep hard rocks under water environment

Using a circular incremental step load and unload method, a set of rheological experiments were performed to study the viscoelasto-plastic properties of amphibolite in Jinchuan No.2 diggings under different environments. Based on the scientific analysis on rheological experimental data, the viscoelasto-plastic properties of amphibolite under different environments were studied. The results show that the instantaneous elastic modulus and viscoplastic properties of amphibolite are affected little, the viscoelastic properties of amphibolite are significantly affected. Based on the experimental results and characteristics of recovered rock specimen, a generalized Kelvin model was chosen to simulate rheological properties of amphibolites and key parameters were obtained. It is found that the creep deformation modulus E1 is significantly influenced by the water, while the instant elastic modulus E2 is not significantly affected. The discreteness of the viscosity coefficient η is large, the influence of water on η is not clear and needs to be further studied.

Synthesis, Characterization and X-Ray Structure of a Ba(II)/Ag(I)/Cr(III)-Oxalate Salt with Water-Filled Nanochannels

A novel mixed barium(II)/silver(I)/chromium(III) oxalate salt, Ba0.5Ag2[Cr(C2O4)3]·5H2O (1), with open architecture has been synthesized in water and characterized by elemental analysis, vibrational and electronic spectra, and single crystal X-ray structure determination. Compound 1 crystallizes in a monoclinic space group C2/c, with unit cell parameters a = 18.179(3), b = 14.743(2), c = 12.278(2)Å, β = 113.821(3), V = 3010.34(90) Å3, Z = 8. The structure is characterized by a network of anionic [Cr(C2O4)3]3- units connected through the O atoms of the oxalates to Ba2+ and Ag+ sites, forming a three-dimensional coordination polymer with one-dimensional isolated nanochannels parallel to the c axis, and encapsulating hydrogen-bonded guest water molecules. The bulk structure is consolidated by O–H···O bridgings within the nanochannels and by coulombic interactions.

Suitability of Soil Water Retention Characteristic Models (SWRC) in Regions and Soil Depth

Soil Water Retention Characteristics (SWRC) models have been widely used in many applications. Presently, there are many models in the literature and many more still being developed so much so that it is confusing which model to prefer. The current choice of the appropriate model to use has not been well guided by any incisive research on the predictive performance of these models. Consequently, SWRC model applications have been largely moved by convenience. This study used a global dataset to evaluate 12 commonly used SWRC models. The measured data onto which the models were evaluated was grouped into different soil depths and different regions of the world. The evaluation used correlation, Nash-Sutcliffe efficiency, and residual standard error statistics to choose the best overall performing model and models for each category. It gives an indication of the type of SWRC models to use in different regions of the world and depths of sampling. The suitability of the models to regions showed that the Fredlund and Xing model had the best performance in subsoils in Africa;Omuto in Southern Asia;and van Genuchten in subsoils of the other regions. It is recommended that many more models be tested using the procedures in this study so that benchmarks can be established on SWRC model selection suitable for various regions.

Coordinated optimal allocation of water resources and industrial structure in the Beijing-Tianjin-Hebei regions of China

Optimizing the allocation of water resources is critical for promoting the optimization and upgrading of industrial structure and coordinated development in the Beijing-Tianjin-Hebei regions of China.Based on specific regional and water conditions,to strengthen the constraints on water resources,the“three-step”adaptive management approach of“scheme design-scheme diagnosis-scheme optimization”of water resource allocation are adopted to facilitate the coordinated optimal allocation of water resources and industrial structure in the Beijing-Tianjin-Hebei regions.First,from the level of overall industry,a water resource allocation scheme for the regions is designed by applying the master-slave hierarchical mode and a bi-level optimal model to determine the ideal amount of water resource allocation for the regions and respective industries.Second,the diagnostic criteria of spatial balance,structural matching,and coordinated development are constructed to determine the rationality of the water resource allocation scheme.Then a benefit compensation function with water market transactions is developed,to adaptively adjust the water resource allocation scheme.Finally,the optimization and upgrading of industrial structure are promoted to improve water consumption efficiency and the coordinated development of the Beijing-Tianjin-Hebei regions.The study can provide reference for the Beijing-Tianjin-Hebei regions to realize the comprehensive optimal allocation of water resources in the regions and improve the adaptability of water resources and industrial structure optimization.

Synthesis, Crystal Structure and Spectral Property of a Water-bridged Co(Ⅱ) Coordination Polymer with 3-Flavonoxylacetic Acid Ligand

A new cobalt complex with flavonoid carboxylate ligand was synthesized and characterized. X-ray diffraction data revealed that the compound crystallizes in the monoclinic crystal system, space group P2_1/c with a = 7.936(3), b = 21.475(7), c = 20.010(7) ?, β = 102.856(14)o, V = 3325(2) ?~3, Z = 4, C_(34)H_(32)CoO_(15), M_r = 739.53, D_c = 1.477 g/cm^3, F(000) = 1532, μ = 0.591 mm^(-1), R = 0.1123 and w R = 0.1419. In the crystal structure, the Co(Ⅱ) shows 6 coordination geometry, and the flavonoid ligand coordinated with the Co(Ⅱ) ion in a monodentate mode. Hydrogen bonding interactions and π-π stacking interactions lead to the three-dimensional stacking of crystal and increase its stability. Moreover, the thermal stability and luminescent properties of the complex are also investigated. The fluorescence of the complex shows a great reduction of the intensity than that of the ligand.

Molecular Simulations of Water Transport Resistance in Polyamide RO Membranes: Interfacial and Interior Contributions

Understanding the transport resistance of water molecules in polyamide(PA)reverse osmosis(RO)membranes at the molecular level is of great importance in guiding the design,preparation,and applications of these membranes.In this work,we use molecular simulation to calculate the total transport resistance by dividing it into two contributions:the interior part and the interfacial part.The interior resistance is dependent on the thickness of the PA layer,while the interfacial resistance is not.Simulation based on the 5 nm PA layer reveals that interfacial resistance is the dominating contribution(>62%)to the total resistance.However,for real-world RO membranes with a 200 nm PA layer,interfacial resistance plays a minor role,with a contribution below 10%.This implies that there is a risk of inaccuracy when using the typical method to estimate the transport resistance of RO membranes,as this method involves simply multiplying the total transport resistance of the simulated value based on a membrane with a 5 nm PA layer.Furthermore,both the interfacial resistance and the interior resistance are dependent on the chemistry of the PA layer.Our simulation reveals that decreasing the number of residual carboxyl groups in the PA layer leads to decreased interior resistance;therefore,the water permeability can be improved at no cost of ion rejection,which is in excellent agreement with the experimental results.

Influence of interlayer water molecules in Ni-based catalysts for oxygen evolution reaction

Nickel-iron layered double hydroxides(NiFe LDHs) have been identified as one of the best promising electrocatalysts-candidates for oxygen evolution reaction(OER). However, the catalytic activity effected by interlayer water molecules is ignored and rarely reported. Herein, Ni(OH)_2, NiFe LDHs vertically aligned Ni foam are designed for OER. As a contrast, the corresponding electrocatalysts with the removal of the interlayer water molecules(Ni(OH)_2-AT, NiFe LDHs-AT) are developed to probe into the influence of the interlayer water molecules towards OER. As expected, NiFe LDH nanoplates exhibit excellent catalytic performance and durability for water electrolysis in alkaline conditions with lower overpotential and smaller Tafel slope compared to those of NiFe LDHs-AT, which are influenced mainly by stability of crystal structure due to the existence of interlayer water molecules. The discovery opens up a similar pathway by controlling the amount of water molecules to boost catalytic performance for studying other electrocatalysts with heteroatom dopant.

Parameterization of Longwave Optical Properties for Water Clouds

Based on relationships between cloud microphysical and optical properties, three different parameterization schemes for narrow and broad band optical properties in longwave region for water clouds have been presented. The effects of different parameterization schemes and different number of broad bands used on cloud radiative properties have been investigated. The effect of scattering role of cloud drops on longwave radiation fluxes and cooling rates in cloudy atmospheres has also been analyzed.

Effect Mechanism of Structure-Changed Water on Heat Stability of Lysozyme

Based on the mechanism of the effect of hydration on the heat stability of lysozyme and the theory of water molecule clusters, the effect of structure-changed water on heat stability of lysozyme has been studied. The results obtained by differential scanning calorimetry (DSC) showed that the thermal denaturation temperature of lysozyme had been elevated 8.47 K through hydration of lysozyme with processed water whose structure had been changed so it was called "structured water" compared to ordinary water. The reason is that structured water changed the dipole moment of water molecules and easily formed cyclic water hexamer or cage-like water hexamer, so that the interacting force of maintaining three-dimensional conformation of lysozyme could be reinforced.

Analysis on the Structure of Influencing Factors of Sustainable Supply Chain Implementation of Water Diversion Project

The systematic analysis of the hierarchical relationship among the factors affecting the sustainable supply chain implementation of water diversion projects has theoretical value and practical significance for the sustainable development of large-scale water diversion projects. Through the investigation of relevant literature, books, web pages, materials, and discussions with relevant experts and scholars, a total of 23 factors influencing the sustainable supply chain implementation of water diversion projects were identified. Then using ISM (Interpretative Structural Modeling Method) to analyze the causality of each factor, a multi-level hierarchical structure model was obtained. The results showed that: 1) The surface-level influencing factors of the sustainable supply chain implementation of the water diversion project mainly included 8 factors such as water-saving awareness and water-saving intensity in the diversion area, water quality, water pollution and other disasters, effective incentive mechanisms, etc., and surface-level influencing factors were directly related to the sustainable supply chain implementation of water diversion projects. 2) The indirect influencing factors of the sustainable supply chain of water diversion projects included 12 factors such as the water quality and quantity guarantee rate of the supply chain, the government’s enforcement of laws and regulations, water distribution, ecological compensation, and compensation mechanisms for residents in the water source area. Indirect influencing factor scan acts directly on the direct influencing factors, and intervening in the factors that can be controlled by humans is one of the important ways to improve the sustainable operation of water diversion projects. 3) The fundamental influencing factors for the sustainable supply chain implementation of water diversion projects included three factors: Resettlement policy, government financial support, and sound laws and regulations. Deep influencing factors had multi-channel influence and controllability, and intervening in them was the main means to improve the sustainable operation of water diversion projects.

Experimental and QSPR Studies on n-Octanol/water Partition Coefficient (lgK_(ow)) of Substituted Aniline

The n-octanol/water partition coefficients （lgKow） of 18 substituted anilines were determined at 25 ℃ by shake-flask method. The geometrical optimization of substituted anilines has been performed at B3LYP/6-311G^＊＊ level with Gaussian98 program, and the molecular surface areas of substituted anilines were calculated using ChemOffice 2004 program. The calculated structural parameters of substituted anilines were used as theoretical descriptors and the two-parameter （molecular surface area （MA） and the energy of the highest occupied molecular orbital （EaoMo）） quantitative structure-property relationship （QSPR） model of lgKow for substituted aniline with molecular structural parameters was developed by multi-linear regression method. The regression coefficient square （r^2） is 0.990 and the standard deviation SE 0.109. The model was validated by variance inflation factors （VIF） and t-test, and the results show that there exists small self-correlation between variables of the model with perfect stability. The model gives results in good qualitative agreement with experimental data. At last, the model was applied to predict lgKow values of five substituted anilines whose lgKow values have not been determined experimentally.

DFT and Position of Cl Substitution (PCS) Methods Studies on n-Octanol/water Partition Coefficients (lgK_(ow)) and Aqueous Solubility (–lgS_w) of All PCDD Congeners

Optimized calculations of 75 PCDDs and their parent DD were carded out at the B3LYP/6-31G＊ level by density functional theory （DFT） method. The structural parameters were obtained and significant correlation between the C1 substitution position and some structural parameters was found. Consequently, the number of C1 substitution positions was taken as theoretical descriptors to establish two novel QSPR models for predicting lgKow and -lgSw of all PCDD congeners. The two models achieved in this work contain two variables （Na and Nβ）, of which r = 0.9312, 0.9965 and SD = 0.27, 0.12 respectively, and t values are all large. The variation inflation factors （VIF） of variables in the two models herein are both less than 5.0, suggesting high accuracy of the lgKow and -lgSw predicting models, and the results of cross-validation test also show that the two models exhibit optimum stability and good predictive power. By comparison, the correlation and predictive ability of the present work are more advantageous than those obtained using semi-empirical AM1 and GC-RI methods.

Analysis of Interf acial Zone Properties and Permeability of Concrete in Underground Structure

Chloride diffusion coefficient and water penetration depth of 3 types concrete were studied. The experimental results show that the concrete permeability decreases itself in the order as follow: pure portland cement concrete(CO), concrete added with fly ash(C1), concrete added with both fly ash and silica fume(C2). SEM and microhardness analyses show that the properties of interfacial zone are significantly influenced by silica fume. With the improvement of interfacial zone properties, the permeability especially the Chloride ion diffusivity of concrete significantly decreases.

Impact of forcing data and land surface properties on snow simulation in a regional climate model:a case study over the Tianshan Mountains,Central Asia

Snow is a key variable that influences hydrological and climatic cycles.Land surface models employing snow physics-modules can simulate the snow accumulation and ablation processes.However,there are still uncertainties in modeling snow resources over complex terrain such as mountains.This study employed the National Center for Atmospheric Research’s Weather Research and Forecasting(WRF)model coupled with the Noah-Multiparameterization(Noah-MP)land surface model to run one-year simulations to assess its ability to simulate snow across the Tianshan Mountains.Six tests were conducted based on different reanalysis forcing datasets and different land surface properties.The results indicated that the snow dynamics were reproduced in a snow hydrological year by the WRF/Noah-MP model for all of the tests.The model produced a low bias in snow depth and snow water equivalent(SWE)regardless of the forcing datasets.Additionally,the underestimation of snow depth and SWE could be relatively alleviated by modifying the land cover and vegetation parameters.However,no significant improvement in accuracy was found in the date of snow depth maximum and melt rate.The best performance was achieved using ERA5 with modified land cover and vegetation parameters(mean bias=−4.03 mm and−1.441 mm for snow depth and SWE,respectively).This study highlights the importance of selecting forcing data for snow simulation over the Tianshan Mountains.

Structural mechanism and construction method of mud and water inrush in Xiangyun tunnel of Guangtong-Dali railway

Mud and water inrush in tunnel is a common problem in the construction process. Nowadays, the research and classification on this are mostly focused on karst situations. According to the characteristics of the surrounding rock and damage forms of the tunnel in the studied area, the author analyzed the geological and structural characteristics of mud and water inrush in tunnel and obtained their construction type. Meanwhile, the advanced water detection under the complex geological conditions was studied by using induced polarization method, transient electromagnetic method and three-dimensional seismic method, it can be concluded that the water-rich fracture zone exists within the detection range with a risk of large mud and water inrush disaster. The concrete construction treatment measures are put forward:①cement-water glass binary slurry is selected as the material for ground and hole grouting, its advantage is that the gel time can be controlled, and it has certain grout ability in the strata with large permeability coeffcient, which is conducive to excavate construction immediately after grouting.②applying the mature retrograde grouting construction can reduce grouting time and improve the excavation efficiency.

AN INSTRUCTURAL SYSTEM MODEL OF COASTAL MANAGEMENT TO THE WATER RELATED HAZARDS IN CHINA

Coastal lowlands have large areas of hazard impact and relatively low capacity of prevention to the water related hazards,which have been indicated by the wide_spread flood hazards,high percentages of land with high flood vulnerability.Increasing population pressure and the shift of resources exploitation from land to sea will force more and more coastal lowlands to be developed in the future,further enhancing the danger of water_related hazards.In this paper,the coastal lowlands in the northern Jiangsu province,China,were selected as a case study.The Interpretation Structural Model (ISM) was employed to analyze the direct and indirect impacts among the elements within the system,and thereby,to identify the causal elements,middle linkages,their expressions,and relations.