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The reform of mode idea of "separation of powers" for China's rural land property system
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作者 Xilong Deng Juan Chen 《International Journal of Technology Management》 2015年第8期136-139,共4页
By briefly reviewing the history of farmland property right in China, it puts forwards the conception of separation of three powers, which is to divide it into ownership, fight of contract, right of use, of farmland p... By briefly reviewing the history of farmland property right in China, it puts forwards the conception of separation of three powers, which is to divide it into ownership, fight of contract, right of use, of farmland property right. In addition, it specifies the practical operational methods to realize the reform that make peasants become the only owner of land in the category of public ownership. It expects to promote the communication and concentration of farmland, so that we can realize the industrialization of agriculture to promote the agricultural productivity level. 展开更多
关键词 FARMLAND property RIGHT separation of three POWERS REFORM CONCEPTION
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On the Function, Subject, and Capacity of the Religious Property System in China
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作者 Hou Shuiping Wang Mingcheng Cao Jinghao 《Contemporary Social Sciences》 2017年第4期1-23,共23页
To construct our religious property system, we must first define its purpose and function, and then clarify the connotation, subject, and capacity of religious property, the premise of which is to scientifically under... To construct our religious property system, we must first define its purpose and function, and then clarify the connotation, subject, and capacity of religious property, the premise of which is to scientifically understand the nature, purpose and function of religions. The"religious purpose"of the religious property system is different in its appeal to different subjects: The state, religious groups and believers. For different types of property, religious purposes differ in directness and indirectness, but they are unified in the realization of the basic religious policy of the Party and the state. 展开更多
关键词 RELIGION Religious property Institutional Norm Religious Organization Religious Group Religious Policy
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Reform Paths of Rural Land Property Rights System in the Context of Agricultural Modernization
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作者 Mingyi DU 《Asian Agricultural Research》 2023年第2期15-20,共6页
The reform of rural land property rights system can promote large-scale and intensive agricultural production,improve the quality of laborers,improve agricultural production efficiency,increase farmers'income,and ... The reform of rural land property rights system can promote large-scale and intensive agricultural production,improve the quality of laborers,improve agricultural production efficiency,increase farmers'income,and effectively promote the development of agricultural modernization.In the context of the reform of the"separation of three powers",the rural land property rights system still has problems in terms of ownership,use rights,disposal rights,and income rights,which affect the healthy development of agricultural modernization.In this situation,it is necessary to further clarify the subject of rural land ownership,thoroughly improve the right to use rural land,vigorously improve the right to dispose of rural land,effectively protect the right to benefit from rural land,and deeply promote the reform of the rural land property rights system in order to effectively promote the development of agricultural modernization. 展开更多
关键词 Reform of rural land property rights system Agricultural modernization Moderate scale operation
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Mechanical Property and Microstructure of Cement Mortar with Carbonated Recycled Powder
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作者 丁亚红 张美香 +3 位作者 YANG Xiaolin XU Ping SUN Bo GUO Shuqi 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第3期689-697,共9页
Carbonated recycled powder as cementitious auxiliary material can reduce carbon emissions and realize high-quality recycling of recycled concrete.In this paper,microscopic property of recycled powder with three carbon... Carbonated recycled powder as cementitious auxiliary material can reduce carbon emissions and realize high-quality recycling of recycled concrete.In this paper,microscopic property of recycled powder with three carbonation methods was tested through XRD and SEM,the mechanical property and microstructure of recycled powder mortar with three replacement rates were studied by ISO method and SEM,and the strengthening mechanism was analyzed.The results showed that the mechanical property of recycled powder mortar decreased with the increasing of replacement rate.It is suggested that the replacement rate of recycled powder should not exceed 20%.The strength index and activity index of carbonated recycled powder mortar were improved,in which the flexural strength was increased by 27.85%and compressive strength was increased by 20%at the maximum.Recycled powder can be quickly and completely carbonated,and the improvement effect of CH pre-soaking carbonation was the best.The activity index of carbonated recycled powder can meet the requirements of Grade II technical standard for recycled powder.Microscopic results revealed the activation mechanism of carbonated recycled powder such as surplus calcium source effect,alkaline polycondensation effect and carbonation enhancement effect. 展开更多
关键词 recycled powder carbonation activation compound carbonation activity index mechanical property MICROSTRUCTURE
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Formation and ecological response of sand patches in the protection system of Shapotou section of the Baotou-Lanzhou railway,China
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作者 DUN Yaoquan QU Jianjun +4 位作者 KANG Wenyan LI Minlan LIU Bin WANG Tao SHAO Mei 《Journal of Arid Land》 SCIE CSCD 2024年第2期298-313,共16页
The development of bare patches typically signifies a process of ecosystem degradation.Within the protection system of Shapotou section of the Baotou-Lanzhou railway,the extensive emergence of bare sand patches poses ... The development of bare patches typically signifies a process of ecosystem degradation.Within the protection system of Shapotou section of the Baotou-Lanzhou railway,the extensive emergence of bare sand patches poses a threat to both stability and sustainability.However,there is limited knowledge regarding the morphology,dynamic changes,and ecological responses associated with these sand patches.Therefore,we analyzed the formation and development process of sand patches within the protection system and its effects on herbaceous vegetation growth and soil nutrients through field observation,survey,and indoor analysis methods.The results showed that sand patch development can be divided into three stages,i.e.,formation,expansion,and stabilization,which correspond to the initial,actively developing,and semi-fixed sand patches,respectively.The average dimensions of all sand patch erosional areas were found to be 7.72 m in length,3.91 m in width,and 0.32 m in depth.The actively developing sand patches were the largest,and the initial sand patches were the smallest.Throughout the stage of formation and expansion,the herbaceous community composition changed,and the plant density decreased by more than 50.95%.Moreover,the coverage and height of herbaceous plants decreased in the erosional area and slightly increased in the depositional lobe;and the fine particles and nutrients of soils in the erosional area and depositional lobe showed a decreasing trend.In the stabilization phases of sand patches,the area from the inlet to the bottom of sand patches becomes initially covered with crusts.Vegetation and 0-2 cm surface soil condition improved in the erosional area,but this improvement was not yet evident in the depositional lobe.Factors such as disturbance,climate change,and surface resistance to erosion exert notable influences on the formation and dynamics of sand patches.The results can provide evidence for the future treatment of sand patches and the management of the protection system of Shapotou section of the Baotou-Lanzhou railway. 展开更多
关键词 railway protection system sand patch MORPHOLOGY vegetation characteristic soil property
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Study of hybrid nanofluid flow in a stationary cone-disk system with temperature-dependent fluid properties
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作者 A.S.JOHN B.MAHANTHESH G.LORENZINI 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2024年第4期677-694,共18页
Cone-disk systems find frequent use such as conical diffusers,medical devices,various rheometric,and viscosimetry applications.In this study,we investigate the three-dimensional flow of a water-based Ag-Mg O hybrid na... Cone-disk systems find frequent use such as conical diffusers,medical devices,various rheometric,and viscosimetry applications.In this study,we investigate the three-dimensional flow of a water-based Ag-Mg O hybrid nanofluid in a static cone-disk system while considering temperature-dependent fluid properties.How the variable fluid properties affect the dynamics and heat transfer features is studied by Reynolds's linearized model for variable viscosity and Chiam's model for variable thermal conductivity.The single-phase nanofluid model is utilized to describe convective heat transfer in hybrid nanofluids,incorporating the experimental data.This model is developed as a coupled system of convective-diffusion equations,encompassing the conservation of momentum and the conservation of thermal energy,in conjunction with an incompressibility condition.A self-similar model is developed by the Lie-group scaling transformations,and the subsequent self-similar equations are then solved numerically.The influence of variable fluid parameters on both swirling and non-swirling flow cases is analyzed.Additionally,the Nusselt number for the disk surface is calculated.It is found that an increase in the temperature-dependent viscosity parameter enhances heat transfer characteristics in the static cone-disk system,while the thermal conductivity parameter has the opposite effect. 展开更多
关键词 hybrid nanofluid cone-disk system laminar flow variable fluid property Nusselt number
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Effect of Cryogenic Treatment on Microstructure and Tribological Property Evolution of Electron Beam Melted Ti6Al4V
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作者 黄西娜 MA Xiaowen XU Tianyi 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第4期1010-1017,共8页
Cryogenic treatment was used to improve the tribological properties of Ti6Al4V artificial hip joint implants.Cryogenic treatment at-196℃with different holding time were carried out on Ti6Al4V specimens fabricated usi... Cryogenic treatment was used to improve the tribological properties of Ti6Al4V artificial hip joint implants.Cryogenic treatment at-196℃with different holding time were carried out on Ti6Al4V specimens fabricated using electron beam melting(EBM),and their microstructure and tribological properties evolution were systematically analyzed by scanning electron microscopy(SEM),vickers hardness,and wear tests.The experimental results show that the as-fabricated specimen consists of lamellarαphase andβcolumnar crystal.While,the thickness of lamellarαphase decreased after cryogenic treatment.In addition,it can be found that the fineαphase was precipitated and dispersed between the lamellarαphase with the holding time increase.Vickers hardness shows a trend of first increasing and then decreasing.The wear rate of the specimen cryogenic treated for 24 h is the minimum and the average friction coefficient is 0.50,which is reduced by 14.61%compared with the as-fabricated.The wear mechanism of the as-fabricated specimen is severe exfoliation,adhesive,abrasive,and slight fatigue wear.However,the specimen cryogenic treated for 24 h shows slight adhesive and abrasive wear.It can be concluded that it is feasibility of utilizing cryogenic treatment to reduce the wear of EBMed Ti6Al4V. 展开更多
关键词 electron beam melting(EBM) cryogenic treatment MICROSTRUCTURE vickers hardness tribological property
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Capillary Property of Entangled Porous Metallic Wire materials and Its Application in Fluid Buffers:Theoretical Analysis and Experimental Study
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作者 Yu Tang Yiwan Wu +1 位作者 Hu Cheng Rong Liu 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第1期400-416,共17页
Strong impact does serious harm to the military industries so it is necessary to choose reasonable cushioning material and design effective buffers to prevent the impact of equipment.Based on the capillary property en... Strong impact does serious harm to the military industries so it is necessary to choose reasonable cushioning material and design effective buffers to prevent the impact of equipment.Based on the capillary property entangled porous metallic wire materials(EPMWM),this paper designed a composite buffer which uses EPMWM and viscous fluid as cushioning materials under the low-speed impact of the recoil force device of weapon equipment(such as artillery,mortar,etc.).Combined with the capillary model,porosity,hydraulic diameter,maximum pore diameter and pore distribution were used to characterize the pore structure characteristics of EPMWM.The calculation model of the damping force of the composite buffer was established.The low-speed impact test of the composite buffer was conducted.The parameters of the buffer under low-speed impact were identified according to the model,and the nonlinear model of damping force was obtained.The test results show that the composite buffer with EPMWM and viscous fluid can absorb the impact energy from the recoil movement effectively,and provide a new method for the buffer design of weapon equipment(such as artillery,mortar,etc.). 展开更多
关键词 Entangled porous metallic wire materials Capillary property Viscousfluid Low-speed impact Damping force
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Passivity-Based Stabilization for Switched Stochastic Nonlinear Systems
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作者 Yaowei Sun Jun Zhao 《IEEE/CAA Journal of Automatica Sinica》 SCIE EI CSCD 2024年第5期1307-1309,共3页
Dear Editor,This letter addresses the passivity-based mean square exponential stabilization problem for switched stochastic nonlinear systems.A concept of generalized small-time norm-observability is presented and an ... Dear Editor,This letter addresses the passivity-based mean square exponential stabilization problem for switched stochastic nonlinear systems.A concept of generalized small-time norm-observability is presented and an appropriate test condition is also provided.For pre-given passivity rate and average dwell time,a set of feedback controllers is designed by use of the passivity property. 展开更多
关键词 property LETTER STABILIZATION
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Lyapunov Conditions for Finite-Time Input-to-State Stability of Impulsive Switched Systems
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作者 Taixiang Zhang Jinde Cao Xiaodi Li 《IEEE/CAA Journal of Automatica Sinica》 SCIE EI CSCD 2024年第4期1057-1059,共3页
Dear Editor,This letter studies finite-time input-to-state stability(FTISS)for impulsive switched systems.A set of Lyapunov-based conditions are established for guaranteeing FTISS property.When constituent modes gover... Dear Editor,This letter studies finite-time input-to-state stability(FTISS)for impulsive switched systems.A set of Lyapunov-based conditions are established for guaranteeing FTISS property.When constituent modes governing continuous dynamics are FTISS and discrete dynamics involving impulses are destabilizing,the FTISS can be retained if impulsive-switching signals satisfy an average dwell-time(ADT)condition. 展开更多
关键词 property IMPULSIVE satisfy
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Effect of slow shot speed on externally solidified crystal,porosity and tensile property in a newly developed high-pressure die-cast Al-Si alloy
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作者 Wen-ning Liu Wei Zhang +6 位作者 Peng-yue Wang Yi-xian Liu Xiang-yi Jiao Ao-xiang Wan Cheng-gang Wang Guo-dong Tong Shou-mei Xiong 《China Foundry》 SCIE EI CAS CSCD 2024年第1期11-19,共9页
The effect of slow shot speed on externally solidified crystal(ESC),porosity and tensile property in a newly developed high-pressure die-cast Al-Si alloy was investigated by optical microscopy(OM),scanning electron mi... The effect of slow shot speed on externally solidified crystal(ESC),porosity and tensile property in a newly developed high-pressure die-cast Al-Si alloy was investigated by optical microscopy(OM),scanning electron microscopy(SEM)and laboratory computed tomography(CT).Results showed that the newly developed AlSi9MnMoV alloy exhibited improved mechanical properties when compared to the AlSi10MnMg alloy.The AlSi9MnMoV alloy,which was designed with trace multicomponent additions,displays a notable grain refining effect in comparison to the AlSi10MnMg alloy.Refining elements Ti,Zr,V,Nb,B promote heterogeneous nucleation and reduce the grain size of primaryα-Al.At a lower slow shot speed,the large ESCs are easier to form and gather,developing into the dendrite net and net-shrinkage.With an increase in slow shot speed,the size and number of ESCs and porosities significantly reduce.In addition,the distribution of ESCs is more dispersed and the net-shrinkage disappears.The tensile property is greatly improved by adopting a higher slow shot speed.The ultimate tensile strength is enhanced from 260.31 MPa to 290.31 MPa(increased by 11.52%),and the elongation is enhanced from 3.72%to 6.34%(increased by 70.52%). 展开更多
关键词 hypoeutectic Al-Si alloy high pressure die casting POROSITY externally solidified crystal tensile property
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Foam rolling and stretching do not provide superior acute flexibility and stiffness improvements compared to any other warm-up intervention: A systematic review with meta-analysis
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作者 Konstantin Warneke Gerit Plöschberger +5 位作者 Lars H.Lohmann Eric Lichtenstein Daniel Jochum Stanislav D.Siegel Astrid Zech David G.Behm 《Journal of Sport and Health Science》 SCIE CAS CSCD 2024年第4期509-520,共12页
Background:Acute improvement in range of motion(ROM)is a widely reported effect of stretching and foam rolling,which is commonly explained by changes in pain threshold and/or musculotendinous stiffness.Interestingly,t... Background:Acute improvement in range of motion(ROM)is a widely reported effect of stretching and foam rolling,which is commonly explained by changes in pain threshold and/or musculotendinous stiffness.Interestingly,these effects were also reported in response to various other active and passive interventions that induce responses such as enhanced muscle temperature.Therefore,we hypothesized that acute ROM enhancements could be induced by a wide variety of interventions other than stretching or foam rolling that promote an increase in muscle temperature.Methods:After a systematic search in PubMed,Web of Science,and SPORTDiscus databases,38 studies comparing the effects of stretching and foam rolling with several other interventions on ROM and passive properties were included.These studies had 1134 participants in total,and the data analysis resulted in 140 effect sizes(ESs).ES calculations were performed using robust variance estimation model with R-package.Results:Study quality of the included studies was classified as fair(PEDro score=4.58)with low to moderate certainty of evidence.Results showed no significant differences in ROM(ES=0.01,p=0.88),stiffness(ES=0.09,p=0.67),or passive peak torque(ES=-0.30,p=0.14)between stretching or foam rolling and the other identified activities.Funnel plots revealed no publication bias.Conclusion:Based on current literature,our results challenge the established view on stretching and foam rolling as a recommended component of warm-up programs.The lack of significant difference between interventions suggests there is no need to emphasize stretching or foam rolling to induce acute ROM,passive peak torque increases,or stiffness reductions. 展开更多
关键词 Range of motion Passive properties Muscletendon unit Muscle tissue
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The Economics of Competing Water Uses under a FERC Licensing Agreement: Estimation of Property Value, Recreation, and Hydroelectric Impacts
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作者 Matthew Bingham Jason Kinnell 《Journal of Water Resource and Protection》 CAS 2024年第6期414-428,共15页
Reservoirs provide a variety of services with economic values across multiple sectors. As demands for reservoir services continue to grow and precipitation patterns evolve, it becomes ever more important to consider t... Reservoirs provide a variety of services with economic values across multiple sectors. As demands for reservoir services continue to grow and precipitation patterns evolve, it becomes ever more important to consider the integrated suite of values and tradeoffs that attend changes in water uses and availability. Section 316 (b) of the Clean Water Act requires that owners of certain water cooled power plants evaluate technologies and operational measures that can reduce their impacts to aquatic organisms. The studies must discuss the social costs and benefits of alternative technologies including cooling towers (79 Fed. Reg. 158, 48300 - 48439). Cooling towers achieve their effect through evaporation. This manuscript estimates the property value, recreation, and hydroelectric generation impacts that could result from the evaporative water loss associated with installing cooling towers at the McGuire Nuclear Generating Station (McGuire) located on Lake Norman, North Carolina. Although this study specifically evaluates the effects of evaporative water loss from cooling towers, its methods are applicable to estimating the economic benefits and costs of a new water user or reduced water input in any complex reservoir system that supports steam electric generation, hydroelectric generation, residential properties, recreation, irrigation, and municipal water use. 展开更多
关键词 property Value FERC Hydroelectric RECREATION Water Levels
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Preparation and property of seal coating for gas turbine compressor
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作者 余沛坰 刘中华 +2 位作者 郑健生 徐伏根 陈千宝 《China Welding》 CAS 2024年第1期60-64,共5页
Double-layer structure of seal coating which consisted of a Ni5Al bond coating and a Ni25 graphite top coating were prepared on steel substrate of gas turbine compressor cylinder block.Bond coating was prepared by atm... Double-layer structure of seal coating which consisted of a Ni5Al bond coating and a Ni25 graphite top coating were prepared on steel substrate of gas turbine compressor cylinder block.Bond coating was prepared by atmospheric plasma spraying and top coating was prepared by flame spraying.The microstructure,mechanical properties and abradability of the coating were characterized by scanning elec-tron microscope(SEM),hardness tester,universal testing machine,thermal shock testing machine and abradability testing machine.The res-ults show that the overall spraying structure of the seal coating is uniform,the nickel metal phase is the skeleton supporting the entire coat-ing,and the coating is well bonded without separation.The seal coating has a bonding strength of not less than 7.7 MPa,excellent thermal stability,and thermal shock resistance cycle numbers at 500℃more than 50;the scratch length,deepest invasion depth and wear amount of the coating increase with rise of test temperature,with almost no coating adhesion,indicating that the seal coating has excellent abradability. 展开更多
关键词 gas turbine compressor seal coating MICROSTRUCTURE mechanical property abradability
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Scientific Data Intellectual Property Research by Literature Statistics
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作者 ZHANG Jia WANG Xirong 《Cultural and Religious Studies》 2024年第2期87-94,共8页
The main obstacle to the open sharing of scientific data is the lack of a legal protection system for intellectual property.This article analyzes the progress of research papers on intellectual property in scientific ... The main obstacle to the open sharing of scientific data is the lack of a legal protection system for intellectual property.This article analyzes the progress of research papers on intellectual property in scientific data in China through literature search and statistics.Currently,research subjects are unbalanced,research content is uneven,research methods are intellectual single,and research depth is insufficient.It is recommended that different stakeholders engage in deep cross disciplinary cooperation,further improve China’s legal and policy protection system for scientific data intellectual property,and promote the open sharing of scientific data. 展开更多
关键词 scientific data intellectual property BIBLIOMETRICS STAKEHOLDERS INTERDISCIPLINARY
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Study of Canada’s Economic System from a System Thinking Perspective
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作者 Wei Zhang Yuejun Cui 《Proceedings of Business and Economic Studies》 2024年第3期179-187,共9页
This article analyzes Canada’s economic system from a systems thinking perspective.The content includes patterns of public choice(party system and power distribution),organizational framework of decision-making arran... This article analyzes Canada’s economic system from a systems thinking perspective.The content includes patterns of public choice(party system and power distribution),organizational framework of decision-making arrangements,information provision and coordination mechanisms,property rights system,incentive system,and welfare system.Canada’s economic system significantly influences the development of the Canadian economy,and its economic system arrangements hold reference significance for other developed and developing countries. 展开更多
关键词 CANADA Economic system Party system Power distribution property rights system
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Abnormal electric transport property and magnetoresistance stability of La-Sr-K-Mn-O system 被引量:5
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作者 Yong-Gang Tang Gui-Ying Wang +3 位作者 Guo-Qing Yan Qi-Xiang Song Ming-Yu Zhang Zhen-Sheng Peng 《Rare Metals》 SCIE EI CAS CSCD 2013年第3期258-263,共6页
The perovskite samples La1-x(Sr1-yKy)xMnO3 (y = 0.0, 0.2, 04, 0.6, 0.8) were prepared by the solid-state reaction method with comparatively low sintering tem- perature and with comparatively short sintering time, ... The perovskite samples La1-x(Sr1-yKy)xMnO3 (y = 0.0, 0.2, 04, 0.6, 0.8) were prepared by the solid-state reaction method with comparatively low sintering tem- perature and with comparatively short sintering time, and the electric transport property and temperature stability of MR of this system were studied. The p-T curves show the abnormal phenomenon that with the increase of K doping amount, resistivity increases, and the insulator-metal transition temperature decreases, which is because the influence of the occupation disorder degree of A-site ions σ2 on the electric transport property of perovskite manga- nites is larger than that of the radius of A-site ions (rA). In the temperature range below 225 K, MR increases contin- uously with the decrease of temperature, which is the characteristic of low-field magnetoresistance; in the com- paratively wide temperature range near 250 K, the MR- T curves of all the samples are comparatively fiat, and the value of MR almost does not change with temperature, which shows the temperature stability of magnetoresis- tance, and can be explained by the competition between the low-field magnetoresistance induced by spin-dependent tunneling of surface phase and the intrinsic magnetoresis- tance of grain phase. The magnetoresistance value of the sample with y = 0.8 keeps at (7.92 ±0.36) % in the very wide temperature range of 225-275 K, and this is a goodreference for the preparation of this kind of sample with practical application value in the future. 展开更多
关键词 Keywords Magnetoresistance K doping Disorder degree σ2 Electric transport property
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Property Preservation of Petri Synthesis Net Based Representation for Embedded Systems 被引量:2
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作者 Chuanliang Xia Chengdong Li 《IEEE/CAA Journal of Automatica Sinica》 SCIE EI CSCD 2021年第4期905-915,共11页
Embedded systems have numerous applications in everyday life.Petri-net-based representation for embedded systems(PRES+)is an important methodology for the modeling and analysis of these embedded systems.For a large co... Embedded systems have numerous applications in everyday life.Petri-net-based representation for embedded systems(PRES+)is an important methodology for the modeling and analysis of these embedded systems.For a large complex embedded system,the state space explosion is a difficult problem for PRES+to model and analyze.The Petri net synthesis method allows one to bypass the state space explosion issue.To solve this problem,as well as model and analyze large complex systems,two synthesis methods for PRES+are presented in this paper.First,the property preservation of the synthesis shared transition set method is investigated.The property preservation of the synthesis shared transition subnet set method is then studied.An abstraction-synthesis-refinement representation method is proposed.Through this representation method,the synthesis shared transition set approach is used to investigate the property preservation of the synthesis shared transition subnet set operation.Under certain conditions,several important properties of these synthetic nets are preserved,namely reachability,timing,functionality,and liveness.An embedded control system model is used as an example to illustrate the effectiveness of these synthesis methods for PRES+. 展开更多
关键词 Modeling Petri nets property preservation SUBNET SYNTHESIS
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Structure and Luminescent Property of a Tetrahedral Silver(Ⅰ) Cluster Complex Based on Phosphor and Sulphur Mixed-ligand System 被引量:1
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作者 王跃 石永芳 +3 位作者 李晓波 邹晓川 何昱岑 王霞 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2019年第7期1216-1222,共7页
A tetrahedral silver(I) cluster complex {Ag4[HC(PPh2)3](S2PPh2)3}ClO4(1,HC(PPh2)3 = 1,1,1-tris(triphenylphosphino)methane, S2PPh2 = diphenyldithiophosphinate) was synthesized by assembling silver ion with phosphor and... A tetrahedral silver(I) cluster complex {Ag4[HC(PPh2)3](S2PPh2)3}ClO4(1,HC(PPh2)3 = 1,1,1-tris(triphenylphosphino)methane, S2PPh2 = diphenyldithiophosphinate) was synthesized by assembling silver ion with phosphor and sulphur mixed-ligand system. The complex was characterized by single-crystal X-ray crystallography, high-resolution mass spectroscopy and thermal analysis. In the crystal structure, an inverted tetrahedron was constructed from Ag4 metal skeleton. The Ag4 cage was stabilized by three diphenyldithiophosphinate ligands and one 1,1,1-tris(triphenylphosphino)methane ligand. 1 exhibits luminescent properties in solid state. A bright yellow-green emission centered at 533 nm has been observed in solid state. Large Stokes' shifts with long range of emissive lifetime indicate that the emission likely originates from a triplet state parentage. 展开更多
关键词 SILVER cluster crystal STRUCTURE luminescent property MIXED-LIGAND
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Measurement of Thermophysical Property of Energy Storage System (CaCl<sub>2</sub>&#46NH<sub>3</sub>System) 被引量:2
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作者 Yuki Sakamoto Hideki Yamamoto 《Natural Resources》 2014年第12期687-697,共11页
In order to measure the thermophysical properties of ammoniated salt (CaCl2.mNH3: m = 4, 8) as an energy storage system utilizing natural resources, the measurement unit was developed, and the thermophysical propertie... In order to measure the thermophysical properties of ammoniated salt (CaCl2.mNH3: m = 4, 8) as an energy storage system utilizing natural resources, the measurement unit was developed, and the thermophysical properties (effective thermal conductivity and thermal diffusivity) of CaCl2.mNH3 and CaCl2.mNH3 with heat transfer media (Ti: titanium) were measured by the any heating method. The effective thermal conductivities of CaCl2.4NH3 + Ti and CaCl2.8NH3 + Ti were 0.14 - 0.17 and 0.18 - 0.20 W/(m.K) in the measuring temperature range of 290 - 350 K, respectively, and these values were approximately 1.5 - 2.2 times larger than those of CaCl2.4NH3 and CaCl2.8NH3. The effective thermal diffusivities were 0.22 - 0.24 × 10-6 and 0.18 - 0.19 × 10-6 m2/sin the measuring temperature range of 290 - 350 K, respectively, and these values were approximately 1.3 - 1.5 times larger than those of CaCl2.4NH3 and CaCl2.8NH3. The obtained results show that the thermophysical properties have a dependence on the bulk densities and specific heats of CaCl2.mNH3 and CaCl2.mNH3 + Ti. It reveals that the thermophysical properties in this measurement would be the valuable design factors to develop energy and H2 storage systems utilizing natural resources such as solar energy. 展开更多
关键词 Energy Storage system Thermophysical property Calcium Chloride (CaCl2) AMMONIA (NH3) Ammoniated Salt AMMONIATION Heat Transfer Media
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