DyPt2 films were prepared by alternate deposition thin Dy and Pt layers on glass substrates by DC magneto controlled sputtering method. The XRD data indicated that for as-deposited Dy/Pt films, and the periodic layere...DyPt2 films were prepared by alternate deposition thin Dy and Pt layers on glass substrates by DC magneto controlled sputtering method. The XRD data indicated that for as-deposited Dy/Pt films, and the periodic layered structures along thickness direction were evidenced with low angle X-ray scattering. With increasing annealing temperature, the compounds of DyPt, DyPt2 and DyPt3 were formed successively at temperature ranging from 300 to 400 ℃. It was found that the composition reaction DyPt+DyPt3→2DyPt2 took place at 500 ℃. After annealing at 500 ℃ for 1 h, the compounds DyPt and DyPt3 transformed completely into the DyPt2 compound.展开更多
The preparation of PT/PEK c films is reported as well as their dielectric and optical properties. The c axis orientation ratio of the films is 68%. Dielectric constant and loss factor at 10 kHz is about 4.023 F/m and ...The preparation of PT/PEK c films is reported as well as their dielectric and optical properties. The c axis orientation ratio of the films is 68%. Dielectric constant and loss factor at 10 kHz is about 4.023 F/m and 0.003, respectively. The refractive indices of the films, n e and n o, are 1.657 3 and 1.627 8 at 0.63 μm wavelength, respectively. The optical band gap of the film with a thickness of 2.33 μm is found to be 3.06 eV.展开更多
A photoelectrochemical process in the degradation of an azodye (Acid Orange II) on a Pt/TiO 2 film electrode was investigated. By using the glass device and the voltage stabilized source of direct current, decoloriza...A photoelectrochemical process in the degradation of an azodye (Acid Orange II) on a Pt/TiO 2 film electrode was investigated. By using the glass device and the voltage stabilized source of direct current, decolorization ratios higher than 78% were observed during a period of 5h. Comparing this value with the sum of the decolorization ratios obtained by a sole application of electrochemical(lower than 3%) and photochemical(about 23%) procedures, a significant synergic effect between both processes was observed. The effects of adscititious voltage and pH value on the decolorization ratios were obvious while the effect of the amount of aeration was minor.展开更多
The thermal stability and separation characteristics of anti-sticking layers of Pt/Cr films are studied in this paper. Several types of adhesion layers were investigated： 10.0 nm Pt, 1.5 nm Cr ＋ 50.0 nm Pt, 2.5 nm ...The thermal stability and separation characteristics of anti-sticking layers of Pt/Cr films are studied in this paper. Several types of adhesion layers were investigated： 10.0 nm Pt, 1.5 nm Cr ＋ 50.0 nm Pt, 2.5 nm Cr ＋ 50.0 nm Pt and 3.5 nm Cr ＋ 50.0 nm Pt fabricated using direct current magnetron sputtering. The variation of layer thickness, roughness, crystallization and surface topography of Pt/Cr films were analyzed by grazing incidence X-ray reflectometry, large angle X-ray diffraction and optical profiler before and after heating. 2.5 nm Cr ＋ 50.0 nm Pt film exhibits the best thermal stability and separation characteristics according to the heating and hot slumping experiments. The film was also applied as an anti-sticking layer to optimize the maximum temperature of the hot slumping technique.展开更多
Aluminum-doped zinc oxide/platinum/fluorine-doped tin oxide（AZO/Pt/FTO） trilayer films were prepared by sputtering 5-nm-thick Pt layers and 150-nm-thick AZO layers in sequence on commercial FTO glass.The effects of ...Aluminum-doped zinc oxide/platinum/fluorine-doped tin oxide（AZO/Pt/FTO） trilayer films were prepared by sputtering 5-nm-thick Pt layers and 150-nm-thick AZO layers in sequence on commercial FTO glass.The effects of onestep annealing and layer-by-layer annealing on the morphology,structure and photoelectric properties of the AZO/Pt/FTO trilayer films were comparatively analyzed.It is found that the both annealing approaches increased the grain size and improved the crystallinity of the films,leading to enhancement in transmittance and conductivity.However,layer-by-layer annealing led to the formation of quasi-continuous or continuous AZO layers,different from the sparsely distributed AZO particles brought about by one-step annealing,resulting in excellent optical and electrical properties.Specifically,after layer-by-layer annealing at 400 ℃ for both Pt and AZO layers,the AZO/Pt/FTO trilayer film showed an increase in average transmittance from 71.3% to 85.3% and a decrease in sheet resistance from 7.5 to 5.6 Ω/□,leading to the highest figure of merit of 3.64 × 10^（-2） Ω^（-1）.展开更多
基金Project supported bythe National Natural Science Foundation of China (50261002 ,50661002)Natural Science Foundaion of Guangxi Province (0575093)
文摘DyPt2 films were prepared by alternate deposition thin Dy and Pt layers on glass substrates by DC magneto controlled sputtering method. The XRD data indicated that for as-deposited Dy/Pt films, and the periodic layered structures along thickness direction were evidenced with low angle X-ray scattering. With increasing annealing temperature, the compounds of DyPt, DyPt2 and DyPt3 were formed successively at temperature ranging from 300 to 400 ℃. It was found that the composition reaction DyPt+DyPt3→2DyPt2 took place at 500 ℃. After annealing at 500 ℃ for 1 h, the compounds DyPt and DyPt3 transformed completely into the DyPt2 compound.
文摘The preparation of PT/PEK c films is reported as well as their dielectric and optical properties. The c axis orientation ratio of the films is 68%. Dielectric constant and loss factor at 10 kHz is about 4.023 F/m and 0.003, respectively. The refractive indices of the films, n e and n o, are 1.657 3 and 1.627 8 at 0.63 μm wavelength, respectively. The optical band gap of the film with a thickness of 2.33 μm is found to be 3.06 eV.
文摘A photoelectrochemical process in the degradation of an azodye (Acid Orange II) on a Pt/TiO 2 film electrode was investigated. By using the glass device and the voltage stabilized source of direct current, decolorization ratios higher than 78% were observed during a period of 5h. Comparing this value with the sum of the decolorization ratios obtained by a sole application of electrochemical(lower than 3%) and photochemical(about 23%) procedures, a significant synergic effect between both processes was observed. The effects of adscititious voltage and pH value on the decolorization ratios were obvious while the effect of the amount of aeration was minor.
文摘The thermal stability and separation characteristics of anti-sticking layers of Pt/Cr films are studied in this paper. Several types of adhesion layers were investigated： 10.0 nm Pt, 1.5 nm Cr ＋ 50.0 nm Pt, 2.5 nm Cr ＋ 50.0 nm Pt and 3.5 nm Cr ＋ 50.0 nm Pt fabricated using direct current magnetron sputtering. The variation of layer thickness, roughness, crystallization and surface topography of Pt/Cr films were analyzed by grazing incidence X-ray reflectometry, large angle X-ray diffraction and optical profiler before and after heating. 2.5 nm Cr ＋ 50.0 nm Pt film exhibits the best thermal stability and separation characteristics according to the heating and hot slumping experiments. The film was also applied as an anti-sticking layer to optimize the maximum temperature of the hot slumping technique.
基金supported by the National Key Basic Research Development Program of China(No. 2011CB013000)the Jiangsu Province Research Innovation Program of College Graduate(No.CXZZ13_0663)+1 种基金the Senior Talent Research Foundation of Jiangsu University(No.13JDG045)the Open Research Fund Program of Jiangsu Provincial Key Laboratory of Center for Photon Manufacturing Science and Technology(No. GZ201307)
文摘Aluminum-doped zinc oxide/platinum/fluorine-doped tin oxide（AZO/Pt/FTO） trilayer films were prepared by sputtering 5-nm-thick Pt layers and 150-nm-thick AZO layers in sequence on commercial FTO glass.The effects of onestep annealing and layer-by-layer annealing on the morphology,structure and photoelectric properties of the AZO/Pt/FTO trilayer films were comparatively analyzed.It is found that the both annealing approaches increased the grain size and improved the crystallinity of the films,leading to enhancement in transmittance and conductivity.However,layer-by-layer annealing led to the formation of quasi-continuous or continuous AZO layers,different from the sparsely distributed AZO particles brought about by one-step annealing,resulting in excellent optical and electrical properties.Specifically,after layer-by-layer annealing at 400 ℃ for both Pt and AZO layers,the AZO/Pt/FTO trilayer film showed an increase in average transmittance from 71.3% to 85.3% and a decrease in sheet resistance from 7.5 to 5.6 Ω/□,leading to the highest figure of merit of 3.64 × 10^（-2） Ω^（-1）.
