Detailed geochemistry studies were conducted to investigate the origin of solid bitumens and hydrocarbon gases in the giant Puguang gas field. Two types of solid bitumens were recognized： low sulfur content, low refl...Detailed geochemistry studies were conducted to investigate the origin of solid bitumens and hydrocarbon gases in the giant Puguang gas field. Two types of solid bitumens were recognized： low sulfur content, low reflectance （LSLR） solid bitumens in sandstone reservoirs in the Xujiahe Formation and high sulfur content, high reflectance （HSHR） solid bitumens in the carbonate reservoirs in the Lower Triassic Feixianguan and Upper Permian Changxing formations. Solid bitumens in the Upper Triassic Xujiahe Formation correlate well with extracts from the Upper Triassic to Jurassic nonmarine source rocks in isotopic composition of the saturated and aromatic fractions and biomarker distribution. Solid bitumens in the Feixianguan and Changxing formations are distinctly different from extracts from the Cambrian and Silurian rocks but display reasonable correlation with extracts from the Upper Permian source rocks both in isotopic composition of the saturated and aromatic fractions and in biomarker distribution, suggesting that the Permian especially the Upper Permian Longtan Formation was the main source of solid bitumens in the carbonate reservoirs in the Feixianguan and Changxing formations in the Puguang gas field. Chemical and isotopic composition of natural gases indicates that the majority of hydrocarbon gases originated from sapropelic organic matter and was the products of thermal cracking of accumulated oils. This study indicates that source rock dominated by sapropelic organic matter existed in the Upper Permian and had made major contribution to the giant Puguang gas field, which has important implication for petroleum exploration in marine sequences in South China.展开更多
Solid bitumens were found throughout the carbonate reservoirs in the Puguang gas field, the largest gas field so far found in marine carbonates in China, confirming that the Puguang gas field evolved from a paleo-oil ...Solid bitumens were found throughout the carbonate reservoirs in the Puguang gas field, the largest gas field so far found in marine carbonates in China, confirming that the Puguang gas field evolved from a paleo-oil reservoir. The fluid conduit system at the time of intensive oil accumulation in the field was reconstructed, and petroleum migration pathways were modeled using a 3-D model and traced by geochemical parameters. The forward modeling and inversion tracing coincided with each other and both indicated that oils accumulated in the Puguang-Dongyuezhai structure originated from a generative kitchen to the northwest of the Puguang gas field. The deposition of organic-rich Upper Permian source rocks dominated by sapropelic organic matter in the Northeast Sichuan Basin, the development of fluid conduit system that was vertically near-source rock and laterally near-generative kitchen, and the focusing of oils originated from a large area of the generative kitchen, were the three requirements for the formation of the giant paleo-oil reservoir from which the giant Puguang gas field evolved. The Puguang gas field had experienced a three-stage evolution. The post-accumulation processes, especially the organic-inorganic interaction in the hydrocarbon-water-rock system, had not only profoundly altered the composition and characteristics of the petroleum fluids, but also obviously changed the physicochemical conditions in the reservoir and resulted in complicated precipitation and solution of carbonate minerals.展开更多
Based on the technology of balanced cross-section and physical simulation experiments associated with natural gas geochemical characteristic analyses, core and thin section observations, it has been proven that the Pu...Based on the technology of balanced cross-section and physical simulation experiments associated with natural gas geochemical characteristic analyses, core and thin section observations, it has been proven that the Puguang gas reservoir has experienced two periods of diagenesis and restructuring since the Late Indo-Chinese epoch. One is the fluid transfer controlled by the tectonic movement and the other is geochemical reconstruction controlled by thermochemical sulfate reduction （TSR）. The middle Yanshan epoch was the main period that the Puguang gas reservoir experienced the geochemical reaction of TSR. TSR can recreate the fluid in the gas reservoir, which makes the gas drying index higher and carbon isotope heavier because C2＋ （ethane and heavy hydrocarbon） and 12C （carbon 12 isotope） is first consumed relative to CH4 and 13C （carbon 13 isotope）. However, the reciprocity between fluid regarding TSR （hydrocarbon, sulfureted hydrogen （H2S）, and water） and reservoir rock results in reservoir rock erosion and anhydrite alteration, which increases porosity in reservoir, thereby improving the petrophysical properties. Superimposed by later tectonic movement, the fluid in Puguang reservoir has twice experienced adjustment, one in the late Yanshan epoch to the early Himalayan epoch and the other time in late Himalayan epoch, after which Puguang gas reservoir is finally developed.展开更多
The deeply buried shoal dolomite reservoirs of the Lower Triassic Feixianguan Formation, giant Puguang Gas Field, NE Sichuan Basin, are exceptionally porous. The influences of diageneses on pore evolution are studied....The deeply buried shoal dolomite reservoirs of the Lower Triassic Feixianguan Formation, giant Puguang Gas Field, NE Sichuan Basin, are exceptionally porous. The influences of diageneses on pore evolution are studied. Through petrologic investigation, diagenetic phases are divided into four stages, i.e., near-surface, pre-oil window, oil window, and gas window. The Adobe Photoshop system is used to quantify the rock texture components, porosity constitutions and the influences of diageneses on reservoir porosity. Porosity evolution curves are quantitatively recovered. The Feixianguan reservoir porosities are mainly created by early meteoric dissolution, dolomitization, and organic acids dissolution. Dissolution during deep burial is insignificant. Pores are formed in near-surface and pre-oil window stages and effectively preserved till present. This result may be of great significance to the further exploration of deeply buried carbonate reservoirs not only in NE Sichuan Basin, but also around the world.展开更多
文摘Detailed geochemistry studies were conducted to investigate the origin of solid bitumens and hydrocarbon gases in the giant Puguang gas field. Two types of solid bitumens were recognized： low sulfur content, low reflectance （LSLR） solid bitumens in sandstone reservoirs in the Xujiahe Formation and high sulfur content, high reflectance （HSHR） solid bitumens in the carbonate reservoirs in the Lower Triassic Feixianguan and Upper Permian Changxing formations. Solid bitumens in the Upper Triassic Xujiahe Formation correlate well with extracts from the Upper Triassic to Jurassic nonmarine source rocks in isotopic composition of the saturated and aromatic fractions and biomarker distribution. Solid bitumens in the Feixianguan and Changxing formations are distinctly different from extracts from the Cambrian and Silurian rocks but display reasonable correlation with extracts from the Upper Permian source rocks both in isotopic composition of the saturated and aromatic fractions and in biomarker distribution, suggesting that the Permian especially the Upper Permian Longtan Formation was the main source of solid bitumens in the carbonate reservoirs in the Feixianguan and Changxing formations in the Puguang gas field. Chemical and isotopic composition of natural gases indicates that the majority of hydrocarbon gases originated from sapropelic organic matter and was the products of thermal cracking of accumulated oils. This study indicates that source rock dominated by sapropelic organic matter existed in the Upper Permian and had made major contribution to the giant Puguang gas field, which has important implication for petroleum exploration in marine sequences in South China.
基金supported by the"973"Project (2005CB422105)the Program for Changjiang Scholars and Innovative Research Team at the University (PCSIRT IRT0658).
文摘Solid bitumens were found throughout the carbonate reservoirs in the Puguang gas field, the largest gas field so far found in marine carbonates in China, confirming that the Puguang gas field evolved from a paleo-oil reservoir. The fluid conduit system at the time of intensive oil accumulation in the field was reconstructed, and petroleum migration pathways were modeled using a 3-D model and traced by geochemical parameters. The forward modeling and inversion tracing coincided with each other and both indicated that oils accumulated in the Puguang-Dongyuezhai structure originated from a generative kitchen to the northwest of the Puguang gas field. The deposition of organic-rich Upper Permian source rocks dominated by sapropelic organic matter in the Northeast Sichuan Basin, the development of fluid conduit system that was vertically near-source rock and laterally near-generative kitchen, and the focusing of oils originated from a large area of the generative kitchen, were the three requirements for the formation of the giant paleo-oil reservoir from which the giant Puguang gas field evolved. The Puguang gas field had experienced a three-stage evolution. The post-accumulation processes, especially the organic-inorganic interaction in the hydrocarbon-water-rock system, had not only profoundly altered the composition and characteristics of the petroleum fluids, but also obviously changed the physicochemical conditions in the reservoir and resulted in complicated precipitation and solution of carbonate minerals.
基金supported by the 973 State Project (Project no.2005CB422105)
文摘Based on the technology of balanced cross-section and physical simulation experiments associated with natural gas geochemical characteristic analyses, core and thin section observations, it has been proven that the Puguang gas reservoir has experienced two periods of diagenesis and restructuring since the Late Indo-Chinese epoch. One is the fluid transfer controlled by the tectonic movement and the other is geochemical reconstruction controlled by thermochemical sulfate reduction （TSR）. The middle Yanshan epoch was the main period that the Puguang gas reservoir experienced the geochemical reaction of TSR. TSR can recreate the fluid in the gas reservoir, which makes the gas drying index higher and carbon isotope heavier because C2＋ （ethane and heavy hydrocarbon） and 12C （carbon 12 isotope） is first consumed relative to CH4 and 13C （carbon 13 isotope）. However, the reciprocity between fluid regarding TSR （hydrocarbon, sulfureted hydrogen （H2S）, and water） and reservoir rock results in reservoir rock erosion and anhydrite alteration, which increases porosity in reservoir, thereby improving the petrophysical properties. Superimposed by later tectonic movement, the fluid in Puguang reservoir has twice experienced adjustment, one in the late Yanshan epoch to the early Himalayan epoch and the other time in late Himalayan epoch, after which Puguang gas reservoir is finally developed.
文摘The deeply buried shoal dolomite reservoirs of the Lower Triassic Feixianguan Formation, giant Puguang Gas Field, NE Sichuan Basin, are exceptionally porous. The influences of diageneses on pore evolution are studied. Through petrologic investigation, diagenetic phases are divided into four stages, i.e., near-surface, pre-oil window, oil window, and gas window. The Adobe Photoshop system is used to quantify the rock texture components, porosity constitutions and the influences of diageneses on reservoir porosity. Porosity evolution curves are quantitatively recovered. The Feixianguan reservoir porosities are mainly created by early meteoric dissolution, dolomitization, and organic acids dissolution. Dissolution during deep burial is insignificant. Pores are formed in near-surface and pre-oil window stages and effectively preserved till present. This result may be of great significance to the further exploration of deeply buried carbonate reservoirs not only in NE Sichuan Basin, but also around the world.
