Mechanism of ultrasonic-pulse electrochemical compound machining based on particles

The electric double layer with the transmission of particles was presented based on the principle of electrochemistry.In accordance with this theory,the cavitation catalysis removal mechanism of ultrasonic-pulse electrochemical compound machining(UPECM) based on particles was proposed.The removal mechanism was a particular focus and was thus validated by experiments.The principles and experiments of UPECM were introduced,and the removal model of the UPECM based on the principles of UPECM was established.Furthermore,the effects of the material removal rate for the main processing parameters,including the particles size,the ultrasonic vibration amplitude,the pulse voltage and the minimum machining gap between the tool and the workpiece,were also studied through UPECM.The results show that the particles promote ultrasonic-pulse electrochemical compound machining and thus act as the catalyzer of UPECM.The results also indicate that the processing speed,machining accuracy and surface quality can be improved under UPECM compound machining.

Pulse electrochemical synaptic transistor for supersensitive and ultrafast biosensors

High sensitivity and fast response are the figures of merit for benchmarking commercial sensors.Due to the advantages of intrinsic signal amplification,bionic ability,and mechanical flexibility,electrochemical transistors(ECTs)have recently gained increasing popularity in constructing various sensors.In the current work,we have proposed a pulse-driven synaptic ECT for supersensitive and ultrafast biosensors.By pulsing the presynaptic input(drain bias,VD)and setting the modulation potential(gate bias)near transconductance intersection(VG,i),the synaptic ECT-based pH sensor can achieve a record high sensitivity up to 124 mV pH^(-1)(almost twice the Nernstian limit,59.2 mV pH^(-1))and an ultrafast response time as low as 8.75 ms(7169 times faster than the potentiostatic sensors,62.73 s).The proposed synaptic sensing strategy can effectively eliminate the transconductance fluctuation issue during the calibration process of the pH sensor and significantly reduce power consumption.Besides,the most sensitive working point at VG,i has been elaborately figured out through a series of detailed mathematical derivations,which is of great significance to provide higher sensitivity with quasi-nonfluctuating amplification capability.The proposed electrochemical synaptic transistor paired with an optimized operating gate offers a new paradigm for standardizing and commercializing high-performance biosensors.

Electrochemical study and application on rutin at chitosan/graphene films modified glassy carbon electrode

Graphene（G） was dispersed into 0.5% chitosan（Chit） solution,then the composite films were coated on glassy carbon electrode（GCE）,the electrochemical behavior of rutin on a Chit/G modified GCE was investigated and the electrochemical parameters of rutin were calculated.Rutin effectively accumulated on the Chit/G/GCE and caused a pair of redox peaks at around 408 mV and 482 mV（vs.SCE） in 0.1M phosphate buffer solution（pH 4.0）.Under optimized conditions,the anodic peak current was linear to the rutin concentration in the range of 5×107-1.04×105M.The regression equation was：y 9.9219x-0.0025,r=0.9958.The proposed method was successfully used for the determination of rutin content in tablet samples with satisfactory results.

Pulsed electrochemistry:A pathway to enhanced electrocatalysis and sustainable electrosynthesis

This review delves into pulsed electrochemistry,a new technique that is becoming an essential tool in the field of electrocatalysis and electrosynthesis.Unlike traditional potentiostatic methods,pulsed electrochemical approaches provide dynamic control over catalytic reactions,leading to better selectivity,efficiency,and stability across a range of applications.We examine the underlying theory of pulsed electrocatalysis and explore how waveform characteristics,potential,and pulse time affect catalytic processes.The review pays special attention to its application in key areas such as organic electrosynthesis,CO_(2) reduction reactions,and water splitting,explaining how pulsed techniques improve reaction conditions to boost yields and selectivity.Meanwhile,we focus on the technique’s impact on catalyst surface modulation,managing local interface environments,and addressing issues like catalyst deactivation and mass transfer limitations.Ultimately,this review highlights the transformative potential of pulsed electrochemistry in driving various electrocatalysis and electrosynthesis applications and sets the stage for future exploration and optimization of these electrochemistry systems.

Prediction method for surface finishing of spiral bevel gear tooth based on least square support vector machine

The predictive model of surface roughness of the spiral bevel gear (SBG) tooth based on the least square support vector machine (LSSVM) was proposed.A nonlinear LSSVM model with radial basis function (RBF) kernel was presented and then the experimental setup of PECF system was established.The Taguchi method was introduced to assess the effect of finishing parameters on the gear tooth surface roughness,and the training data was also obtained through experiments.The comparison between the predicted values and the experimental values under the same conditions was carried out.The results show that the predicted values are found to be approximately consistent with the experimental values.The mean absolute percent error (MAPE) is 2.43% for the surface roughness and 2.61% for the applied voltage.

Optimizing the Quadruple-potential Waveform for the Determination of Gentamicin Sulfate by High Performance Liquid Chromatography with Pulsed Electrochemical Detection

In this paper, a quadruple-potential waveform was investigated and optimized for the determination of gentamicin by reversed phase ion-pair chromatography. Instead of a relatively high positive potential, a negative potential was adopted as a potential for the cleaning of gold working electrode. By this way, the formation of gold oxide resulting from the application of high positive potential during the analyte detection and electrode cleaning was greatly reduced, and therefore, the dissolution and recession of gold working electrode was also reduced. The good condition of gold working electrode achieved by this quadruple-potential waveform can help us to obtain a good reproducibility. In order to acquire signal-to-noise ratio as high as possible, several waveform parameters affecting the detection of gentamicin were carefully selected. The analytical method has been applied to the determination of two real gentamicin samples, and good results with low relative standard deviation not more than 4% were obtained.

Dependency of the pulsed electrochemical machining characteristics of Inconel 718 in NaNO_(3)solution on the pulse current

Pulsed electrochemical machining(PECM)has attracted increasing interest as a technique to improve material dissolution localization and surface quality.This work systematically investigates the effects of pulse current on the surface morphology,profile accuracy,and corrosion behavior of Inconel 718(IN718)in NaNO_(3)solution.Polarization behavior reveals that IN718 in NaNO_(3)solution during pulse current machining exhibited significant passive,transpassive,and re-passive characteristics.The passive film generated at the re-passive state contained some oxides and had a loose porous structure.The critical value for the quantity of electric charge to rupture the passive film was determined to be 26.88℃cm^(−2).The current efficiency indicates that the material removal rate of IN718 in NaNO_(3)solution during pulse current machining was nonlinear.The PECM experiments indicate that the loading process of the electrical double layer was prolonged with an increased workpiece scale,i.e.,the loading process of the electrical double layer lasted for the entire pulse-on time when the workpiece scale was 100 mm^(2)at a frequency of more than 10 kHz regardless of the duty cycle.A pulse current with a short pulse length and short pulse period improved the profile accuracy,as did the low applied voltage and small workpiece scale.The dissolution mechanism of IN718 in NaNO_(3)solution was also investigated based on the effective pulse current time.Finally,the leading-edge structure of a ruled blade with good dimensional accuracy and surface quality was successfully fabricated.The maximum deviations of the machined profile were effectively restricted within 0.057 mm,and the surface roughness was Ra=0.358μm.

Machining of circular micro holes by electrochemical micro-machining process

Machining of micro holes with micro electro- chemical machining （micro ECM） process has been carried out with an indigenously developed set up. This paper describes relevant problems and solutions for the circular micro holes machining process on 304 stainless steel sheets with 60 μm thickness using high speed steel cylindrical tool of diameter 500 ~tm and using dilute I-I2SO4 as elec- trolyte. The taper angle variation of the machined hole is analyzed and reported for different experimental setting parameters. The minimum value of the taper angle of machined holes is achieved at the parameter setting of 0.4 mol/L H2504, 700 kHz, 600 ns and 21 V, for stainless steel sheets and HSS tool.