Effect of Strain Ratio on Fatigue Model of Ultra-fine Grained Pure Titanium

The ultra-fine grained(UFG)pure titanium was prepared by equal channel angular pressing(ECAP)and rotary swaging(RS).The strain controlled low cycle fatigue(LCF)test was carried out at room temperature.The fatigue life prediction model and mean stress relaxation model under asymmetrical stress load were discussed.The results show that the strain ratio has a significant effect on the low cycle fatigue performance of the UFG pure titanium,and the traditional Manson-coffin model can not accurately predict the fatigue life under asymmetric stress load.Therefore,the SWT mean stress correction model and three-parameter power curve model are proposed,and the test results are verified.The final research shows that the threeparameter power surface model has better representation.By studying the mean stress relaxation phenomenon under the condition of R≠-1,it is revealed that the stress ratio and the strain amplitude are the factors that significantly afiect the mean stress relaxation rate,and the mean stress relaxation model with the two variables is calculated to describe the mean stress relaxation phenomenon of the UFG pure titanium under different strain ratios.The fracture morphology of the samples was observed by SEM,and it was concluded that the final fracture zone of the fatigue fracture of the UFG pure titanium was a mixture of ductile fracture and quasi cleavage fracture.The toughness of the material increases with the increase of strain ratio at the same strain amplitude.

Microstructure and texture of commercially pure titanium in cold deep drawing

The development of microstructure and texture during cold deep drawing of commercially pure titanium（CP-Ti） was investigated.Three parts,stretching region,drawing region and flange region,were sequentially formed in the deep drawing process of the hemispheric surface part,with reference to deformation modes and strain regimes.Results show that the plastic strain is accommodated by dislocation slip and deformation twinning in the whole deep drawing process.The texture of the CP-Ti sheet and its drawn part consists of rolling texture component and recrystallization texture component.The intensity and type of the initial texture varied during the drawing process are related to the production of deformation twinning and dislocation slip.Twinning weakens the initial texture by randomizing the orientations of crystals,especially for the recrystallization texture.The recrystallization texture in the drawing region disappears due to the significant forming of twinning.Furthermore,over drawing would result in the predominance of dislocation slip and the texture is strengthened.

Deformation and fracture behavior of commercially pure titanium with gradient nano-to-micron-grained surface layer

Titanium with gradient nano-to-micron scale grains from surface to matrix was fabricated by surface mechanical grinding treatment(SMGT) at room temperature.The SMGT-treated titanium shows higher strength than that of as-received one,but moderate ductility between those of ultra-fine grained(UFG) and coarse-grained titanium.Tensile stress-strain curves of SMGT-treated titanium show double strain hardening regimes.The strain hardening rate(dσ/dε) decreases with increasing strain in tensile deformation.The high strain hardening rate at initial yielding is attributed to nano-to-micron-grained surface layer.The low strain hardening rate at large plastic strain regime primarily results from coarse-grained matrix.The SMGT-treated titanium shows a ductile fracture mode with a large number of dimples.The small size of dimples in the treated surface layer is due to the combination of the high strength and strain hardening exponent.The difference between dimple size in nano-to-micron-grained surface layer and coarse-grained matrix is discussed in terms of plastic zone size at the tip of crack in the SMGT-treated titanium.

Comparison of microstructures and mechanical properties between forging and rolling processes for commercially pure titanium

In order to reveal the differences caused by forging and rolling process for titanium ingots, hot compression behavior, mechanical properties and the microstructures of forged billets and rolled ones were investigated in detail using Gleeble-1500 thermal mechanical simulator, universal testing machine and optical microscope （OM）. The compression deformation experimental data of commercially pure titanium （CP-Ti） were mapped to be a T vs lg diagram in which data fall into three distinct regions, i.e., three-stage work hardening, two-stage work hardening and flow softening, which can be separated by border lines at 17.5 and 15.4 for lg Z, where Z represents the Zener-Hollomon parameter. The deformation twin is found to have higher Z-value corresponding to the work hardening region. The differences in microstructures and mechanical properties for two kinds of billets indicate that forged billet consists of deformation twins and some twin intersections, and many twins cross the grain boundaries. However, nearly no twins can be seen in the microstructure of billet formed by rolling under optical microscope （OM）, but there are equiaxed and platelike grains. Tensile tests and Vickers hardness test indicate that yield strength, tensile strength and microhardness of the samples after forging are higher than those after rolling.

Interaction among deformation, recrystallization and phase transformation of TA2 pure titanium during hot compression

TA2 pure titanium was chosen to research the interaction among deformation, recrystallization and phase transformation during hot compression. The samples were hot compressed by thermal simulation method with different processing parameters. Variant selection induced by stress during cooling after compression was found. The prismatical texture component which featured that the [0001] direction perpendicular to the compressing direction produced preferentially under the compressing stress. As a result, the transformedα phase possesses strong prismatical texture which is different with the basal texture of compressed αphase. The minimum elastic strain energy is demonstrated to be the main reason that causes the variant selection. Dynamic recrystallization behavior and microstructure evolution during hot compression were also studied.

Characterization of microarc oxidation coatings on pure titanium

Key Laboratory for Beam Technology and Materials Modification, Institute ofLow Energy Nuclear Physics, Beijing Normal UniversityThe morphology, composition, and phase structure of the oxide coatings produced on the surface ofpure titanium by alternating-current microarc discharge in aluminate solution were investigated byX-ray diffraction and scanning electron microscopy. The profiles of the hardness H and the elasticmodulus E in the coatings were determined using a nanoindentation method. The concentrationdistributions of Ti, Al, and O in the coating show that this coating over 30 mu m thick contains twolayers: an outer layer and an inner layer. The oxide coating is mainly composed of TiO_2 rutile andAl_2TiO_5 compounds. During oxidation, the temperature in the microarc discharge channel was veryhigh to make the local coating molten. From the surface to the interior of the coating, H and Eincrease gradually, and then reach maximum values of 9.78 GPa and 176 GPa respectively at a distanceof 7 mu m from the coating/titanium interface. They are also rather high near the interface.

Microstructure and textural evolution during cold rolling and annealing of commercially pure titanium sheet

The effects of cold rolling and annealing on the microstructure and textural evolution of a commercially pure titanium（CP-Ti） sheet were investigated. Electron backscatter diffractometry demonstrates that the deformation during rolling is accommodated by twinning and slip. Additionally, twinning is the dominant deformation mechanism when the cold rolling reduction is less than 40%. During rolling, {11ˉ22}11ˉ2ˉ3contraction twinning（CT） and {10ˉ12}10ˉ11 extension twinning（ET） are activated. And, the intensity of the（0002） pole along the ND gradually increases with increasing deformation. During annealing, the fraction of low angle grain boundaries（LAGBs） and the intensity of the（0002） pole along the ND gradually decrease slightly with increasing annealing time, while twinning lamellae disappear rapidly. When the annealing time reaches 60 min, 20% cold-rolled sheet recrystallizes almost completely.

Mechanical properties,corrosion behavior and biocompatibility of orthopedic pure titanium−magnesium alloy screw prepared by friction welding

The dissimilar joining of biodegradable magnesium alloy to pure commercial titanium by rotational friction welding with rotational speeds of 1100,1200 and 1300 r/min for the production of bio-screw was investigated.The metallographic analysis revealed that a good joining was obtained at the Ti/Mg alloy joint.On the magnesium alloy side,various regions such as the weld center zone(WCZ),dynamic recrystallization zone(DRX),thermo-mechanically affected zone(TMAZ)and partially deformed zone(PDZ)were observed.The highest tensile and shear strengths were 173 and 103.2 MPa,respectively at a rotational speed of 1300 r/min.The Ti/Mg alloy dissimilar friction welded joint failed at the vicinity of the intermetallic zone containing Ti3Al phase.The hardness values from the base metal magnesium alloy to the joining point increased mainly due to grain refinement(8.57μm in diameter)and the presence of titanium particles,while the hardness values were constant on the titanium side.It was also found that the corrosion rate of the Ti/Mg alloy joint was higher compared with that of the Ti and Mg alloy from the immersion studies.Additionally,the sample with a rotational speed of 1300 r/min showed better biocompatibility and a cell viability of 98.12%due to better corrosion resistance.

Transformation mechanism and mechanical properties of commercially pure titanium

In order to establish the rolling process parameters of grade-2 commercially pure titanium （CP-Ti）, it is necessary to understand the transformation mechanism and mechanical properties of this material. The β→α transformation kinetics of the grade-2 CP-Ti during continuous cooling was measured and its hot compression behavior was investigated using Gleeble-1500 thermal mechanical simulator. Dynamic CCT diagram confirms that cooling rate has an obvious effect on the start and finishing transformation and microstructures at room temperature. The critical cooling rate for γ-phase transforms to a phase is about 15℃/s. When the cooling rate is higher than 15 ℃/s, some β phases with fine granular shape remain residually into plate-like structure. The plate-like a phase forms at cooling rate lower than 2 ℃/s, serrate a phase forms at medium cooling rates, about 5-15℃/s. The flow stress behavior of grade-2 CP-Ti was investigated in a temperature range of 700-900℃ and strain rate of 3.6-40 mm/min. The results show that dynamic recrystallization, dynamic recovery and work-hardening obviously occur during hot deformation. Constitutive equation of grade-2 CP-Ti was established by analyzing the relationship of the deformation temperature, strain rate, deformation degree and deformation resistance.

Static mechanical properties and ductility of biomedical ultrafine-grained commercially pure titanium produced by ECAP process

Equal channel angular pressing(ECAP)is one of the most effective processes to produce ultra-fine grain(UFG)and nanocrystalline(NC)materials.Because the commercially pure titanium exhibits excellent biocompatibility properties,it has a significant potential to be utilized as an implant material.The low static and dynamic strengths of the pure titanium are one of the weaknesses of this material.This defect can be removed by applying the ECAP process on the pure titanium.In this work,the commercially pure titanium Grade2(CP-Ti of Grade2)was pressed at room temperature by the ECAP process via a channel angle of135°for3passes.The microstructural analysis and mechanical tests such as tensile test,hardness test,three-point bending test and Charpy impact test were all carried out on the ECAPed CP-Ti through3passes.The microstructural evolution reveals that by applying the ECAP process,coarse grain(CG)structure develops to UFG/NC structure.Moreover,the results of the mechanical tests show that the process significantly increases the yield and ultimate tensile strengths,bending strength,hardness and fracture toughness of the commercially pure titanium so that it can be used as a replacement for metallic alloys used as biomaterials.

Effect of electropulsing on anisotropy behaviour of cold-rolled commercially pure titanium sheet

The specimens cut from the cold-rolled pure titanium sheet at 0°,45°and 90°to the rolling direction were treated by high density electropulsing(maximum current density J=(7.22-7.96)×10^(3)A/mm^(2),pulse period t_(p)=110μs).The mechanical properties and microstructures of the cold-rolled,electropulsed and conventional annealed commercially pure titanium sheet were examined by using uniaxial tension test machine and optical microscope(OM),respectively.The results show that the deformation behavior of the electropulsed pure titanium sheet is significantly different from that of conventional annealed pure titanium sheet.The difference of the mechanical properties between the 0°,45°and 90°direction specimens is almost diminished.It is mainly due to the increase in dislocation mobility and formation of lamellar microstructure after the electropulsing.

Effect of annealing temperature on microstructure and mechanical properties of cold-rolled commercially pure titanium sheets

The strength of traditional commercially pure titanium(CP-Ti) alloys often fails to meet the demand of structural materials. In order to enhance their mechanical properties, the cold-rolled CP-Ti alloys were annealed at different temperatures, and the recrystallization behavior and texture evolution were investigated. It was found that the bimodal microstructure(equiaxed and elongated grains) was formed after partial recrystallization, and the corresponding sample exhibited an excellent combination of ultimate tensile strength(702 MPa) and total elongation(36.4%). The recrystallization nucleation of CP-Ti sheets occurred preferentially in the high strain and the high-angle grain boundaries(HAGBs) regions. Meanwhile, the internal misorientations of the deformed heterogeneous grains increased and transformed into HAGBs, which further promoted the recrystallization nucleation. The main recrystallization texture was basal TD-split texture transformed from cold-rolled basal RD-split texture, and the oriented nucleation played a dominated role during recrystallization.

Microstructural approach to equal channel angular processing of commercially pure titanium——A review

A review on severe plastic deformation（SPD） technique of equal channel angular pressing（ECAP） process of commercially pure titanium（CP-Ti） alloys was presented with a major emphasize on the influence of ECAP parameters that include channel and curvature angles, processing route, temperature of operation, pressing speed, internal heating, number of pass through the die and back pressure. Various ECAP characteristics such as microstructure, strain inhomogeneity and mechanical properties are considered to achieve the maximum homogeneity, equilibrium grain refinement and mechanical improvement of CP-Ti. Investigations show that a pressing speed of 1-3 mm/s at 450 °C with route BC along with channel and curvature angles of 90° and 20° respectively with backpressure can lead to the most homogeneous ultrafine microstructure.

Structure and properties of micro-arc calcium phosphate coatings on pure titanium and Ti-40Nb alloy

The microstructure, physical and mechanical, and chemical properties of micro-arc calcium phosphate （CAP） coatings deposited under different process voltages in the range of 150-400 V on the commercially pure titanium （Ti） and Ti-40%Nb （Ti-40Nb） （mass fraction） alloy were investigated by the SEM, TEM, XRD and EDX methods. The coating thickness, roughness, and sizes of structural elements were measured and showed similar linear character depending on the process voltage for the coatings on both substrates. SEM results showed the porous morphology with spherical shape structural elements and rough surface relief of the coatings. XRD and TEM studies exhibited the amorphous structure of the CaP coating. With increasing the process voltage to 300-400 V, the crystalline phases, such as CaHPO4 and β-Ca2P207, were formed onto the coatings. The annealing leads to the formation of complex poly-phase structure with crystalline phases： CaTi4（PO4）6, β-Ca2P2O7, TiP2O7, TiNb（PO4）3, TiO2, NbO2, and Nb2O5. The applied voltage and process duration in the ranges of 200-250 V and 5-10 min, respectively, revealed the coating formed on Ti and Ti-40Nb with optimal properties： thickness of 40-70μm, porosity of 20%-25%, roughness （Ra） of 2.5-5.0 μm, adhesion strength of 15-30 MPa, and Ca/P mole ratio of 0.5-0.7.

Surface nanocrystallization of commercial pure titanium by shot peening

The surface nanostructures of commercial pure titanium was realized by the modified shot peening equipment commonly used in industry through the special treatment process. The results show that high-energy-shot-peening(HESP) commonly used to prepare nanostructured surface layers can be achieved by the increase of pill size, pill speed, and treatment time in the commercial shot peening equipment. XRD, SEM and TEM were used to characterize the surface layer microstructure of treated specimens. The analytic results show that the main deformation mode of commercial pure Ti is twinning. At the beginning of deformation, the dislocations are formed and twins occur within or on plane, then twins in intersection plane appear, and at last the twin characteristics disappear in the surface layer after longer treatment time. The deformation layer depth increases with treatment time in a certain period when the pill size and speed are unchanged. And in the severe plastic deformation (SPD) layer in which the twins are not identified easily by using SEM, the nanocrystalline microstructures are found under TEM. The finest grain size in the surface layer is about 40 nm, and the depth of nanostructured layers is over 60 μm. The microhardness of the nanostructured surface layers is enhanced significantly after shot peening compared with that of the initial simple.

Plasma Niobium Surface Alloying of Pure Titanium and its Oxidation at 900 ℃

A niobium-modified layer on pure titanium surface was obtained by means of double glow plasma surface alloying technique. The modified layer was uniform, continuous, compact and well adhered to the substrate. The niobium composition in the modified layer decreased gradually from the surface to the substrate. The oxidation behavior of the niobium-modified layer was investigated and com- pared with the untreated surface at 900 ~C for 100 h. Characterization of the layers was performed using X-ray diffraction and scanning electron microscope, respectively. The test results show that the oxidation behavior of pure titanium was improved by niobium alloying process. Niobium has a positive influence on the oxidation resistance.

Anisotropy of Mechanical Behavior in Commercially Pure Titanium Sheets

Commercially pure titanium( CP Ti) sheets show typical planar anisotropy due to inherently crystallographic texture and rolling process. To characterize the initial,planar,plastic anisotropy of CP Ti sheets in forming process,uniaxial tensile tests of cold-rolled TA1 sheets at 0°,45° and 90° to the rolling direction were performed at room temperature,corresponding stress-strain curves and Lankford coefficient( r value) were obtained. Based on Hill'48 and Barlat'89 yield criteria,the anisotropic behavior of TA1 sheets was investigated. In order to verify the accuracy of two models,the experimental values of yield stress and r were compared with predicted ones. It revealed that Barlat '89 criterion with M = 6 is the best agreement with experimental data,and the obtained model can be used in the simulation of forming process.

Mechanical Property Prediction of Commercially Pure Titanium Welds with Artificial Neural Network

Factors that affect weld mechanical properties of commercially pure titanium have been investigated using artificial neural networks. Input data were obtained from mechanical testing of single-pass, autogenous welds, and neural network models were used to predict the ultimate tensile strength, yield strength, elongation, reduction of area, Vickers hardness and Rockwell B hardness. The results show that both oxygen and nitrogen have the most significant effects on the strength while hydrogen has the least effect over the range investigated. Predictions of the mechanical properties are shown and agree well with those obtained using the 'oxygen equivalent' (OE) equations.

Planar anisotropy of commercially pure titanium sheets

Commercially pure titanium （CP Ti） sheets show typical planar anisotropy due to the inherently crys- tallographic texture and manufacturing process. To char- acterize the planar anisotropic behaviors of CP Ti sheets in the forming process, uniaxial tensile tests of TA0 sheets were performed along rolling, transverse, and diagonal directions at room temperature; corresponding stress-strain curves and Lankford coefficients were obtained. Based on Hi11＇48 and Barlat＇89 yield functions, the planar anisotropy of TA0 sheets was investigated. In order to verify the accuracy of two models, we compared the experimental and predicted values of yield stress and Lankford coeffi- cients. It reveals that Barlat＇89 criterion with M = 10 is good agreement with experimental data, and the obtained function can be used in simulation of forming process.

Effect of plane surface and wrinkly surface of pure Titanium on corrosion resistance and bacterium accumulation: an in vivo study

Objective: To study the effect of surface configuration on the corrosion resistance and bacterium accumulation of pure Titanium(Ti) when used in oral environment. Methods: Six edentulous volunteers with healthy oral mucosa participated in an in vivo study. Two kinds of pure Ti testing pieces with plane and wrinkly surface were fixed in the polished surface of upper complete dentures. After 6-month wearing, dynamic polarization curves were traced with electrochemical method and the amount and species of bacterium adhered on pure Ti were examined. Results: ① Ep and Ip of specimen in oral cavity was higher than that left in air, which meant corrosion resistance falling. Compared to plane one, Ecorr of wrinkly specimen was more positive and Ep and Ip were more higher, so its corrosion resistance reduced. ② Individual difference put a significant influence on amount of bacterium adhered on pure Titanium, but had no relation to species of bacterium. To the same patient, wrinkly samples collected more bacterium than plane ones, and exhibited G - coccus beside G + coccus. Conclusion: From the perspective of corrosion behavior and benefit to periodontal tissue, wrinkly surface should not be adopted when pure Ti prosthesis is made,especially on connector part of denture.