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Analysis of radiometer effect on proof mass in purely gravitational orbit
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作者 刘红卫 王兆魁 张育林 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2012年第5期583-592,共10页
Spacecrafts with the pure gravity environment are of great significance in precision navigation, gravity field measurement for celestial bodies, and basic physics ex- periments. The radiometer effect is one of the imp... Spacecrafts with the pure gravity environment are of great significance in precision navigation, gravity field measurement for celestial bodies, and basic physics ex- periments. The radiometer effect is one of the important interfering factors on the proof mass in a purely gravitational orbit. For the gravity field measurement system based on the inner-formation flying, the relationship between the radiometer effect on the inner- satellite and the system parameters is studied by analytical and numerical methods. An approximate function of the radiometer effect suitable for the engineering computation and the correction factor are obtained. The analytic results show that the radiometer effect on the inner-satellite is proportional to the average pressure while inversely pro- portional to the average temperature in the outer-satellite cavity. The radiometer effect increases with the temperature difference in the cavity, and its minimum exists when the cavity radius increases. When the minimum of the radiometer effect arrives, the ratio of the cavity radius to the inner-satellite radius is 1.189 4. This constant is determined by the spherical cavity configuration and independent of the temperature and pressure distributions. When the ratio of the cavity radius to the inner-satellite radius is more than 10, it is believed that the cavity is large enough, the radiometer effect is approxi- mately proportional to the square of the inner-satellite radius, and the influence of the outer-satellite cavity radius on the radiometer effect can be ignored. 展开更多
关键词 purely gravitational orbit proof mass inner-formation flying system ra-diometer effect cavity radius
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Restrictions on Purely Kinetic K-Essence
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作者 YANG Rong-Jia QI Jing-Zhao YANG Bao-Zhu 《Chinese Physics Letters》 SCIE CAS CSCD 2011年第10期296-298,共3页
We restrict purely kinetic k-essence.Assuming that the equation of state is a power law of the kinetic energy,i.e.w=w0Xα,we find thatαmust be positive to obtain accelerated phases,constrained from the conditions for... We restrict purely kinetic k-essence.Assuming that the equation of state is a power law of the kinetic energy,i.e.w=w0Xα,we find thatαmust be positive to obtain accelerated phases,constrained from the conditions for stability and causality.In this case the k-essence behaves like a phantom.We also study the evolutions of the equation of state and the speed of sound with numerical simulations. 展开更多
关键词 KINETIC purely restrict
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Existence of Localized Modes in a Purely Anharmonic Chain
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作者 WANG Shaofeng 《Chinese Physics Letters》 SCIE CAS CSCD 1995年第2期95-97,共3页
For a monatomic one-dimensional chain of particles interacting via a nearest-neighbor purely anharmonic potential of any even order(such a chain is called purely anharmonic chain),it is proved that there really exist ... For a monatomic one-dimensional chain of particles interacting via a nearest-neighbor purely anharmonic potential of any even order(such a chain is called purely anharmonic chain),it is proved that there really exist exact localized modes. 展开更多
关键词 HARMONIC purely EXISTENCE
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In Situ Observation of KB_(5) Crystal Growth Under Purely Diffusion Gel Systems by Holographic Interferometry
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作者 CHEN Wanchun SHEN Yunxue +2 位作者 MA Wenyi LI Ming CHEN Yansong 《Chinese Physics Letters》 SCIE CAS CSCD 1991年第9期469-471,共3页
KB_(5)O_(8).4H_(2)O(KB_(5))crystals have been grown in an agar-agar gel by temperature decrease method for simulating crystal growth in space.Nucleation and growth have been followed by interferometric holography.A co... KB_(5)O_(8).4H_(2)O(KB_(5))crystals have been grown in an agar-agar gel by temperature decrease method for simulating crystal growth in space.Nucleation and growth have been followed by interferometric holography.A concentration field surrounding the growing crystals was obtained and a Liesegang ring was observed.The pattern are visualized directly to reveal physical phenomena of purely diffusion crystal growth kinetics. 展开更多
关键词 DIFFUSION purely
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An Investigation of Purely Azimuthal Passive Localization and Position Adjustment in Attempted UAV Formation Flights
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作者 Qi Zhang Keren Sun Qiaozhen Zhang 《Journal of Applied Mathematics and Physics》 2023年第10期3075-3098,共24页
When a cluster of unmanned aerial vehicles (UAVs) is flying in formation, it is crucial to maintain the formation and not to be interfered by external electromagnetic wave signals. In order to maintain the formation, ... When a cluster of unmanned aerial vehicles (UAVs) is flying in formation, it is crucial to maintain the formation and not to be interfered by external electromagnetic wave signals. In order to maintain the formation, this paper proposes to use pure azimuth passive positioning to adjust the position of UAVs, i.e., certain UAVs in the formation transmit signals, the rest of the UAVs receive the signals passively, and extract the orientation information from them to adjust the position of the UAVs [1] [2] [3]. In this paper, the position adjustment problem of UAVs in “circular” formation flight under three models is investigated. To address the problem of “how to obtain the position of the receiving UAV when there are two UAVs with known numbers and evenly distributed on the circumference in addition to the UAV transmitting at the known center of the circle, and the rest of the UAVs with slight deviations in their positions are receiving the signals”, two purely mathematical geometric methods, namely, triangular localization method and polar co-ordinate method, are proposed respectively. We have determined the position of the receiving UAV;we have used the exhaustive method and the construction and disproof method to solve the problem of “how many UAVs are needed to transmit signals in order to realize the effective positioning of the UAVs when it is known that a certain UAV with a slight deviation in its position receives the signals emitted by two UAVs at the same time”, and the results show that: in addition to the known signals emitted by two UAVs, it is also necessary to transmit the signals emitted by two UAVs. The results show that in addition to the known two UAVs transmitting signals, two additional UAVs are required to transmit signals for precise po-sitioning. When the position of UAVs has deviation at the initial moment, the ideal approximation method and the target delimitation method are pro-posed, and the target of nine UAVs uniformly distributed on a circle of a spe-cific radius is achieved through several adjustments, after which the ad-vantages and disadvantages of each model are analyzed, and suggestions for improvement are put forward. The purely azimuthal passive localization method and the constructed model approach proposed in this paper can be extended to other fields, such as spacecraft formations in space and battle-ship formations at sea, as well as other formation flight position adjustment problems. 展开更多
关键词 Pure Azimuth Passive Positioning Unmanned Aerial Vehicle (UAV) Position Adjustment Electromagnetic Silence
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Blastoids generated purely from embryonic stem cells both in mice and humans 被引量:2
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作者 Baojiang Wu Yanqiu Wang +4 位作者 Jia Yan Mengya Liu Xihe Li Fuchou Tang Siqin Bao 《Science China(Life Sciences)》 SCIE CAS CSCD 2024年第2期418-420,共3页
Dear Editor,Embryonic stem cells(ESCs)and trophoblast stem cells(TSCs)are derived from blastocysts(Lu et al.,2001).Blastocyst-like structures(blastoids)are self-assembled structures formed by a combination of ESCs and... Dear Editor,Embryonic stem cells(ESCs)and trophoblast stem cells(TSCs)are derived from blastocysts(Lu et al.,2001).Blastocyst-like structures(blastoids)are self-assembled structures formed by a combination of ESCs and TSCs(Rivron et al.,2018).To increase the success rate of blastoid formation and its similarity with the features of blastocysts,some reports showed that blastoid could also be derived from a combination of three cell lines,ESCs,TSCs,and extraembryonic endoderm cells(XENs),or novel type of stem cells(Sozen et al.,2018;Weatherbee et al.,2023:Wu et al.,2023;Zhang et al.,2023;Zhang et al.,2019). 展开更多
关键词 purely SIMILARITY
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Coupled modeling and analysis of radiometer effect and residual gas damping on proof mass in purely gravitational orbit 被引量:9
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作者 LIU HongWei WANG ZhaoKui ZHANG YuLin 《Science China(Technological Sciences)》 SCIE EI CAS 2011年第4期894-902,共9页
Spacecrafts free of all but gravitational forces are important in precision navigation,gravity field measurement and basic scientific research.The Inner-formation Flying System,one kind of spacecrafts free of all but ... Spacecrafts free of all but gravitational forces are important in precision navigation,gravity field measurement and basic scientific research.The Inner-formation Flying System,one kind of spacecrafts free of all but gravitational forces,is used for gravitational field measurement with high precision.Restraining the interfering factors on the inner-satellite is one of the keys to gravitational field measurement.Radiometer effect and residual gas damping are both interfering forces on the inner-satellite caused by gas molecules.By analyzing the mechanism of the two forces,a coupled model for radiometer effect and residual gas damping was established,which contained the coupling term and reflected the actual force of gas molecules on the inner-satellite.The simulation results showed the coupling property of radiometer effect and residual gas damping:The actual force of gas molecules is directly proportional to the average pressure in the cavity and the largest cross-sectional area of the inner-satellite,but is inversely proportional to the square root of the average temperature in the cavity. 展开更多
关键词 purely gravitational orbit proof mass radiometer effect residual gas damping coupled modeling
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Negative refraction based on purely imaginary metamaterials 被引量:5
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作者 Yang-Yang Fu Ya-Dong Xu Huan-Yang Chen 《Frontiers of physics》 SCIE CSCD 2018年第4期237-245,共9页
By introducing a new mechanism based on purely imaginary metamaterials (PIMs), we reveal that bidirectional negative refraction and planar focusing can be obtained using a pair of PIM slabs, over- coming the unidire... By introducing a new mechanism based on purely imaginary metamaterials (PIMs), we reveal that bidirectional negative refraction and planar focusing can be obtained using a pair of PIM slabs, over- coming the unidirectional limit in parity-time (PT)-symmetric systems. Compared with PT-symmetric systems, which require two different types of materials, the proposed negative refraction can be realized using two identical media. In addition, asymmetric excitation with bidirectional total transmission is observed in our PIM system. Therefore, a new way to realize negative refraction with properties that are unavailable in PT-symmetrie systems is presented. 展开更多
关键词 negative refraction coherent perfect absorber LASER purely imaginary metamaterials
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Stimulus-responsive room temperature phosphorescence in purely organic luminogens 被引量:13
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作者 Jie Yang Manman Fang Zhen Li 《InfoMat》 SCIE CAS 2020年第5期791-806,共16页
Luminogens that exhibit stimulus-responsive room temperature phosphorescence(RTP)have attracted significant attention for their applications in a wide range of fields such as data storage,sensors,and bio-imaging.Howev... Luminogens that exhibit stimulus-responsive room temperature phosphorescence(RTP)have attracted significant attention for their applications in a wide range of fields such as data storage,sensors,and bio-imaging.However,very few such materials are known,partly because of the unclear internal mechanism.In this review,we summarize recent advances in the field of stimulusresponsive RTP in purely organic luminogens,focusing on their unique emission behaviors and internal mechanisms governing the phenomena.We also attempt to identify the relationship between the mechanism,luminogens,and possible applications. 展开更多
关键词 purely organic luminogens room temperature phosphorescence stimulus-responsive emission
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Purely Hom-Lie bialgebras 被引量:3
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作者 Liqiang Cai Yunhe Sheng 《Science China Mathematics》 SCIE CSCD 2018年第9期1553-1566,共14页
In this paper, we first show that there is a Hom-Lie algebra structure on the set of(σ, σ)-derivations of an associative algebra. Then we construct the dual representation of a representation of a Hom-Lie algebra.We... In this paper, we first show that there is a Hom-Lie algebra structure on the set of(σ, σ)-derivations of an associative algebra. Then we construct the dual representation of a representation of a Hom-Lie algebra.We introduce the notions of a Manin triple for Hom-Lie algebras and a purely Hom-Lie bialgebra. Using the coadjoint representation, we show that there is a one-to-one correspondence between Manin triples for Hom-Lie algebras and purely Hom-Lie bialgebras. Finally, we study coboundary purely Hom-Lie bialgebras and construct solutions of the classical Hom-Yang-Baxter equations in some special Hom-Lie algebras using Hom-O-operators. 展开更多
关键词 Horn-Lie algebras Manin triples purely Horn-Lie bialgebras classical Hom-Yang-Baxter equations
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Room-temperature phosphorescence from purely organic materials 被引量:2
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作者 Yang Liu Ge Zhan +2 位作者 Zhi-Wei Liu Zu-Qiang Bian Chun-Hui Huang 《Chinese Chemical Letters》 SCIE CAS CSCD 2016年第8期1231-1240,1467,共10页
Room-temperature phosphorescence(RTP) materials have attracted great attention due to their involvement of excited triplet states and comparatively long decay lifetimes.In this short review,recent progress on enhanc... Room-temperature phosphorescence(RTP) materials have attracted great attention due to their involvement of excited triplet states and comparatively long decay lifetimes.In this short review,recent progress on enhancement of RTP from purely organic materials is summarized.According to the mechanism of phosphorescence emission,two principles are discussed to construct efficient RTP materials:one is promoting intersystem crossing(ISC) efficiency by using aromatic carbonyl,heavyatom,or/and heterocycle/heteroatom containing compounds;the other is suppressing intramolecular motion and intermolecular collision which can quench excited triplet states,including embedding phosphors into polymers and packing them tightly in crystals.With aforementioned strategies,RTP from purely organic materials was achieved both in fluid and rigid media. 展开更多
关键词 Room-temperature phosphorescence purely organic material Intersystem crossing Non-radiation transition
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Molecular uniting set identified characteristic(MUSIC): a promising strategy for purely organic RTP luminogens 被引量:1
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作者 Xiangfeng Shao 《Science China Chemistry》 SCIE EI CAS CSCD 2018年第8期975-976,共2页
The room temperature phosphorescences(RTP)are of growing interest owing to their promising applications in material science and bioimaging.To date,the lumiogens showing persistent RTP effect mainly contain the noble... The room temperature phosphorescences(RTP)are of growing interest owing to their promising applications in material science and bioimaging.To date,the lumiogens showing persistent RTP effect mainly contain the noble metals which have the shortcomings such as high cost,potential toxicity.The exploration of metal free luminogens,i.e.,purely organic RTP luminogens,is thus of great importance for the community. 展开更多
关键词 RTP Molecular uniting set identified characteristic a promising strategy for purely organic RTP luminogens MUSIC
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Error Bounds for Uniform Asymptotic Expansions-Modified Bessel Function of Purely Imaginary Order
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作者 Wei SHI Roderick WONG 《Chinese Annals of Mathematics,Series B》 SCIE CSCD 2010年第5期759-780,共22页
The authors modify a method of Olde Daalhuis and Temme for representing the remainder and coefficients in Airy-type expansions of integrals.By using a class of rational functions,they express these quantities in terms... The authors modify a method of Olde Daalhuis and Temme for representing the remainder and coefficients in Airy-type expansions of integrals.By using a class of rational functions,they express these quantities in terms of Cauchy-type integrals;these expressions are natural generalizations of integral representations of the coe?cients and the remainders in the Taylor expansions of analytic functions.By using the new representation,a computable error bound for the remainder in the uniform asymptotic expansion of the modified Bessel function of purely imaginary order is derived. 展开更多
关键词 Modified Bessel function of purely imaginary order Airy function Uniform asymptotic expansion Error bound
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Purely Inseparable Extensions and Ramification Filtrations
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作者 Hao Yu HU 《Acta Mathematica Sinica,English Series》 SCIE CSCD 2021年第1期35-58,共24页
In this article,we investigate the shift of Abbes and Saito’s ramification filtrations of the absolute Galois group of a complete discrete valuation field of positive characteristic under a purely inseparable extensi... In this article,we investigate the shift of Abbes and Saito’s ramification filtrations of the absolute Galois group of a complete discrete valuation field of positive characteristic under a purely inseparable extension.We also study a functoriality property for characteristic forms. 展开更多
关键词 Abbes and Saito’s ramification filtration purely inseparable extension characteristic form
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An in-situ study of static recrystallization in Mg using high temperature EBSD
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作者 Xu Ye Zhe Suo +5 位作者 Zhonghao Heng Biao Chen Qiuming Wei Junko Umeda Katsuyoshi Kondoh Jianghua Shen 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2024年第4期1419-1430,共12页
It has been a common method to improve the mechanical properties of metals by manipulating their microstructures via static recrystallization,i.e.,through heat treatment.Therefore,the knowledge of recrystallization an... It has been a common method to improve the mechanical properties of metals by manipulating their microstructures via static recrystallization,i.e.,through heat treatment.Therefore,the knowledge of recrystallization and grain growth is critical to the success of the technique.In the present work,by using in-situ high temperature EBSD,the mechanisms that control recrystallization and grain growth of an extruded pure Mg were studied.The experimental results revealed that the grains of priority for dynamic recrystallization exhibit fading competitiveness under static recrystallization.It is also found that grain boundary movement or grain growth is likely to show an inverse energy gradient effect,i.e.,low energy grains tend to swallow or grow into high energy grains,and grain boundaries of close to 30°exhibit superior growth advantage to others.Another finding is that{10-12}tensile twin boundaries are sites of hardly observed for recrystallization,and are finally swallowed by adjacent recrystallized grains.The above findings may give comprehensive insights of static recrystallization and grain growth of Mg,and may guide the design of advanced materials processing in microstructural engineering. 展开更多
关键词 Pure Mg IN-SITU HT-EBSD RECRYSTALLIZATION Grain growth
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The Early Mesozoic NE-SW Extensional Model and Exhumation Processes at the Southeastern Margin of the Central Asian Orogenic Belt:Insights from the Strain and Kinematic Vorticity Analysis of the Sonid Zuoqi Ductile Detachment Zone
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作者 LI Jianbo SONG Zhijie +1 位作者 LEI Hengcong ZENG Tao 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2024年第5期1141-1153,共13页
The Sonid Zuoqi ductile detachment zone is located at the southeastern margin of the Central Asian orogenic belt(CAOB),striking EW and dipping to the S.The major rock type of the Sonid Zuoqi ductile detachment zone is... The Sonid Zuoqi ductile detachment zone is located at the southeastern margin of the Central Asian orogenic belt(CAOB),striking EW and dipping to the S.The major rock type of the Sonid Zuoqi ductile detachment zone is mylonite derived from granite.The sequence of mylonite features is:(1)S and C foliations of mylonite,and(2)extensional crenulation cleavage(ecc)or C′and the kinematic vorticity(Wk)value changed from 0.70 to 0.95 and from 0.37 to 0.69,respectively;the strain type of the mylonites within the Sonid Zuoqi ductile detachment zone is compressional to planar strain.The strong deformation mylonite and Halatu plutons yielded a zircon U-Pb age of 244 Ma and a zircon(U-Th)/He age of 214 Ma,respectively.Based on the strain and kinematic vorticity analysis,together with the zircon U-Pb and zircon(U-Th)/He ages and the regional tectonic background,the study area experienced three stage evolution:tangential simpleshear(244 Ma),simple-shear-dominated general shear represented by upper crustal extension(224 Ma)and pure-shear-dominated general shear represented by the Halatu pluton doming(214 Ma),which constrained the early Mesozoic NE-SW crustal extension at the southeastern margin of the CAOB.This NE-SW extension probably originated from the postorogenic extensional collapse of the CAOB,subsequent exhumation being controlled by the far afield effects of the closure of the Mongol-Okhotsk belt. 展开更多
关键词 STRAIN simple shear pure shear kinematic vorticity ductile detachment zone
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Effects of cold rolling path on recrystallization behavior and mechanical properties of pure copper during annealing
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作者 Jing CHEN Wen-jie XU +8 位作者 Jia-hao YANG Zhi YANG Hong-li SHI Gao-yong LIN Zhu-min LI Xu SHEN Bo JIANG Hui-qun LIU Kai-xuan GUI 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2024年第10期3233-3250,共18页
The recrystallization behavior,grain boundary characteristic distribution,and mechanical properties of pure Cu sheets that were subjected to different cold rolling paths,and then annealed at 400°C for 10,30,60,an... The recrystallization behavior,grain boundary characteristic distribution,and mechanical properties of pure Cu sheets that were subjected to different cold rolling paths,and then annealed at 400°C for 10,30,60,and 420 min,were investigated.Different rolling paths changed the grain boundary orientations of cold-rolled copper,causing recrystallized grains to nucleate and grow in an oriented manner.However,the evolution of the texture indicated that cold-rolled copper with different rolling paths did not show an obvious preferred orientation after annealing.The RD-60 specimen exhibited the smallest grain size(6.6μm).The results indicated that the grain size and low-ΣCSL grain boundaries worked together to provide RD-60 samples with appropriate mechanical properties and high plasticity.The yield strength,ultimate tensile strength,and elongation of RD-60 sample were 81 MPa,230 MPa,and 49%,respectively.These results could provide guidance for tuning the microstructures and properties of pure Cu foils,as well as designing fabrication routes for pure Cu foils through processes such as rolling and drawing. 展开更多
关键词 rolling path grain boundary characteristic distribution pure copper mechanical properties
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Stable operation of highly loaded pure Si-Fe anode under ambient pressure via carboxy silane-directed robust solid electrolyte interphase
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作者 Guntae Lim Dong Guk Kang +6 位作者 Hyeon Gyu Lee Yen Hai Thi Tran Kihun An Junghyun Choi Kwang Chul Roh Do Youb Kim Seung-Wan Song 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第7期568-576,共9页
Incorporation of higher content Si anode material beyond 5 wt% to Li-ion batteries(LIBs)is challenging,owing to large volume change,swelling,and solid electrolyte interphase(SEI)instability issues.Herein,a strategy of... Incorporation of higher content Si anode material beyond 5 wt% to Li-ion batteries(LIBs)is challenging,owing to large volume change,swelling,and solid electrolyte interphase(SEI)instability issues.Herein,a strategy of diacetoxydimethylsilane(DAMS)additive-directed SEI stabilization is proposed for a stable operation of Si-0.33FeSi_(2)(named as Si-Fe)anode without graphite,which provides siloxane inorganics and organics enrichment that compensate insufficient passivation of fluoroethylene carbonate(FEC)additive and reduce a dependence on FEC.Unprecedented stable cycling performance of highly loaded(3.5 mA h cm^(-2))pure Si-Fe anode is achieved with 2 wt%DAMS combined with 9 wt%FEC additives under ambient pressure,yielding high capacity 1270 mA h g^(-1)at 0.5 C and significantly improved capacity retention of 81% after 100 cycles,whereas short circuit and rapid capacity fade occur with FEC only additive.DAMS-directed robust SEI layer dramatically suppresses swelling and particles crossover through separator,and therefore prevents short circuit,demonstrating a possible operation of pure Si or Sidominant anodes in the next-generation high-energy-density and safe LIBs. 展开更多
关键词 High-energy Li-ion battery Pure Si-Fe anode without graphite Silane additive SEI layer Suppressed swelling
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A low-frequency pure metal metamaterial absorber with continuously tunable stiffness
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作者 Xingzhong WANG Shiteng RUI +2 位作者 Shaokun YANG Weiquan ZHANG Fuyin MA 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2024年第7期1209-1224,共16页
To address the incompatibility between high environmental adaptability and deep subwavelength characteristics in conventional local resonance metamaterials,and overcome the deficiencies in the stability of existing ac... To address the incompatibility between high environmental adaptability and deep subwavelength characteristics in conventional local resonance metamaterials,and overcome the deficiencies in the stability of existing active control techniques for band gaps,this paper proposes a design method of pure metal vibration damping metamaterial with continuously tunable stiffness for wideband elastic wave absorption.We design a dual-helix narrow-slit pure metal metamaterial unit,which possesses the triple advantage of high spatial compactness,low stiffness characteristics,and high structural stability,enabling the opening of elastic flexural band gaps in the low-frequency range.Similar to the principle of a sliding rheostat,the introduction of continuously sliding plug-ins into the helical slits enables the continuous variation of the stiffness of the metamaterial unit,achieving a continuously tunable band gap effect.This successfully extends the effective band gap by more than ten times.The experimental results indicate that this metamaterial unit can be used as an additional vibration absorber to absorb the low-frequency vibration energy effectively.Furthermore,it advances the metamaterial absorbers from a purely passive narrowband design to a wideband tunable one.The pure metal double-helix metamaterials retain the subwavelength properties of metamaterials and are suitable for deployment in harsh environments.Simultaneously,by adjusting its stiffness,it substantially broadens the effective band gap range,presenting promising potential applications in various mechanical equipment operating under adverse conditions. 展开更多
关键词 elastic metamaterial absorber continuously tunable stiffness low-frequency vibration damping variable stiffness design pure metal structure
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Strongly Coupled Ag/Sn-SnO_(2)Nanosheets Toward CO_(2)Electroreduction to Pure HCOOH Solutions at Ampere‑Level Current
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作者 Min Zhang Aihui Cao +5 位作者 Yucui Xiang Chaogang Ban Guang Han Junjie Ding Li‑Yong Gan Xiaoyuan Zhou 《Nano-Micro Letters》 SCIE EI CSCD 2024年第3期212-226,共15页
Electrocatalytic reduction of CO_(2) converts intermittent renewable electricity into value-added liquid products with an enticing prospect,but its practical application is hampered due to the lack of high-performance... Electrocatalytic reduction of CO_(2) converts intermittent renewable electricity into value-added liquid products with an enticing prospect,but its practical application is hampered due to the lack of high-performance electrocatalysts.Herein,we elaborately design and develop strongly coupled nanosheets composed of Ag nanoparticles and Sn-SnO_(2) grains,designated as Ag/Sn-SnO_(2) nanosheets(NSs),which possess optimized electronic structure,high electrical conductivity,and more accessible sites.As a result,such a catalyst exhibits unprecedented catalytic performance toward CO_(2)-to-formate conversion with near-unity faradaic efficiency(≥90%),ultrahigh partial current density(2,000 mA cm^(−2)),and superior long-term stability(200 mA cm^(−2),200 h),surpassing the reported catalysts of CO_(2) electroreduction to formate.Additionally,in situ attenuated total reflection-infrared spectra combined with theoretical calculations revealed that electron-enriched Sn sites on Ag/Sn-SnO_(2)NSs not only promote the formation of*OCHO and alleviate the energy barriers of*OCHO to*HCOOH,but also impede the desorption of H*.Notably,the Ag/Sn-SnO_(2)NSs as the cathode in a membrane electrode assembly with porous solid electrolyte layer reactor can continuously produce~0.12 M pure HCOOH solution at 100 mA cm^(−2)over 200 h.This work may inspire further development of advanced electrocatalysts and innovative device systems for promoting practical application of producing liquid fuels from CO_(2). 展开更多
关键词 Electrochemical CO_(2)reduction Coupled Ag/Sn-SnO_(2)nanosheets Electronic structure Porous solid electrolyte PURE
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