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除草剂pyrasulfotole的合成 被引量:3
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作者 赵全刚 英君伍 +4 位作者 刘鹏飞 杨辉斌 梁爽 李斌 孙克 《农药》 CAS CSCD 北大核心 2017年第5期324-325,338,共3页
[目的]Pyrasulfotole是拜耳公司于1999年开发的羟基苯基丙酮酸双氧化酶(HPPD)抑制剂类除草剂,用于苗后防除禾谷类作物田的阔叶杂草,主要探索其合成方法。[方法]以2-甲磺酰基-4-三氟甲基苯甲酸为起始原料经缩合、氯代、酯化、转位4步反... [目的]Pyrasulfotole是拜耳公司于1999年开发的羟基苯基丙酮酸双氧化酶(HPPD)抑制剂类除草剂,用于苗后防除禾谷类作物田的阔叶杂草,主要探索其合成方法。[方法]以2-甲磺酰基-4-三氟甲基苯甲酸为起始原料经缩合、氯代、酯化、转位4步反应合成pyrasulfotole。[结果]总收率36.4%,纯度97%,目标化合物结构经MS和~1H NMR确证。 展开更多
关键词 pyrasulfotole 合成 除草剂
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Tolerance of Winter Wheat (<i>Triticum aestivum</i>L.) and Under Seeded Red Clover (<i>Trifolium pretense</i>L.) to Fall Applied Post-Emergent Broadleaf Herbicides
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作者 Kristen E. McNaughton Lynette R. Brown Peter H. Sikkema 《American Journal of Plant Sciences》 2014年第9期1265-1271,共7页
The fall application of post-emergent (POST) herbicides on winter wheat provided effective control of emerged winter annual, biennial, and perennial broadleaf weeds. In recent years, wheat producers have seen a shift ... The fall application of post-emergent (POST) herbicides on winter wheat provided effective control of emerged winter annual, biennial, and perennial broadleaf weeds. In recent years, wheat producers have seen a shift to these weeds, due in part, to the adoption of reduced-and no-tillage practices and the use of non-residual herbicides such as glyphosate in the preceding soybean and corn crops. The tolerance of winter wheat to ten herbicides, applied POST in the fall, was evaluated between 2008 and 2011 at Exeter and Ridgetown, Ontario. Winter wheat yield was not reduced by applications of MCPA ester, dicamba/ MCPA/ mecoprop, clopyralid, bromoxynil/ MCPA, thifensulfuron /tribenuron +MCPA ester, fluroxypyr +MCPA ester, and pyrasulfotole/ bromoxynil. In contrast, 2,4-D ester and dichlorprop/2,4-D, caused visible injury in June and July of the following year and consistently decreased winter wheat yield by at least 10%. Applications of 100 g a.i. ha-1 saflufenacil also decreased winter wheat yield in two of the four harvest years examined. None of the herbicide options examined were safe on red clover when it was under seeded the spring following winter wheat planting. All herbicides significantly decreased red clover dry biomass one month after wheat harvest. 展开更多
关键词 2 4-D CLOPYRALID pyrasulfotole Saflufenacil Winter Wheat
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