Five compounds (1 - 5) were isolated from the rhizome of Beesia calthaefolia (Maxim.) Ulbr. Based on chemical and spectral evidence, their structures were determined as beesic acid (9-phenyl-2E, 4E, 6E, 8E-nontetraeno...Five compounds (1 - 5) were isolated from the rhizome of Beesia calthaefolia (Maxim.) Ulbr. Based on chemical and spectral evidence, their structures were determined as beesic acid (9-phenyl-2E, 4E, 6E, 8E-nontetraenoic acid, 1), vanillic acid (2), oleanolic acid-3-O-alpha.-L-arabinopyranosyl-28-O-alpha -L-rhanmopyranosyl-(1 --> 4)-beta -D-glucopyranosyl-(1 --> 6)-beta -D-glucopyranosyl ester (3), hederasaponin B (oleanolic acid-3-O-alpha -L-rhanmopyranosyl-(1-->2)-alpha -L-arabinopyranosyl-28-O-alpha -L-rhamnopyranosyl-(1-->4)beta -D-glucopyranosyl-(1-->6)-beta -D-glucopyranosyl ester, 4) and beesioside Q (oleanolic acid-3-O-beta -D-glucopyranosyl-(1-->3)-alpha -L-rhamnopyranosyl-(1-->2)-alpha -L-arabinopyranosyl-28-O-alpha -L-rhamnopyranosyl-(1--> 4)-beta -D-glucopyranosyl-(1-->6)-beta -D-glucopyranosyl ester, 5), respectively. Compound 1 was isolated from natural sources for the first time and compound 5 was a new compound.展开更多
Detrital minerals of 137 offshore and 22 river sediment samples collected from Qingdao coastal areas have been analyzed. Four mineral assemblage provinces can be classified by Q-mode cluster analysis. Factor analysis ...Detrital minerals of 137 offshore and 22 river sediment samples collected from Qingdao coastal areas have been analyzed. Four mineral assemblage provinces can be classified by Q-mode cluster analysis. Factor analysis identifies two major factors that account for the total variability in most common minerals: 1) based on the relationship of quartz, hornblende, actinolite, micas, and authigenic pyrite, 41.55% of the variability is related to sediment sources; 2) based on the relationship of epidote, garnet, sphere, and ilmenite, 23.21% can be related to strong hydrodynamic conditions that control transport and sedimentation. By comparing mineral compositions of river waters in the study area, the following four mineral provenances can be identified. The Qingdao-Laoshan nearshore area has a quartz-feldspar-epidote-hornblende-limenite-limonite-sphene assemblage, which is largely attributed to relict sediment and coastal erosion. The Jimo-Haiyang nearshore area has a quartz-feldspar-hornblende-epidote-limonite-mica-actinolite assemblage, derived largely from the Wulong River and Rushan River, and is also affected by the Huanghe River, while the Qianliyan Island area in the deeper offshore area separated by a mud belt has a similar assemblage. The Haiyang-Rushan nearshore area has a quartz-feldspar-hornblende-epidote-micas-limonite assemblage, indicating multiple sources from the Rushan River, the Wulong River, the Huanghe River, and coastal erosion. The central area, located in an eddy center, has a mica-authigenic pyrite-hornblende-quartz-feldspar assemblage, indicating multiple sources dominated by Huanghe River distal sediments.展开更多
文摘Five compounds (1 - 5) were isolated from the rhizome of Beesia calthaefolia (Maxim.) Ulbr. Based on chemical and spectral evidence, their structures were determined as beesic acid (9-phenyl-2E, 4E, 6E, 8E-nontetraenoic acid, 1), vanillic acid (2), oleanolic acid-3-O-alpha.-L-arabinopyranosyl-28-O-alpha -L-rhanmopyranosyl-(1 --> 4)-beta -D-glucopyranosyl-(1 --> 6)-beta -D-glucopyranosyl ester (3), hederasaponin B (oleanolic acid-3-O-alpha -L-rhanmopyranosyl-(1-->2)-alpha -L-arabinopyranosyl-28-O-alpha -L-rhamnopyranosyl-(1-->4)beta -D-glucopyranosyl-(1-->6)-beta -D-glucopyranosyl ester, 4) and beesioside Q (oleanolic acid-3-O-beta -D-glucopyranosyl-(1-->3)-alpha -L-rhamnopyranosyl-(1-->2)-alpha -L-arabinopyranosyl-28-O-alpha -L-rhamnopyranosyl-(1--> 4)-beta -D-glucopyranosyl-(1-->6)-beta -D-glucopyranosyl ester, 5), respectively. Compound 1 was isolated from natural sources for the first time and compound 5 was a new compound.
基金the National Natural Science Foundation of China (Nos. 41376079, 41406081 and 41506107)Marine Geology Survey Project (Nos. GZH200900501 and GZH201100203)the Basic Fund of Ministry of Science Foundation of China (No. 2013FY112200)
文摘Detrital minerals of 137 offshore and 22 river sediment samples collected from Qingdao coastal areas have been analyzed. Four mineral assemblage provinces can be classified by Q-mode cluster analysis. Factor analysis identifies two major factors that account for the total variability in most common minerals: 1) based on the relationship of quartz, hornblende, actinolite, micas, and authigenic pyrite, 41.55% of the variability is related to sediment sources; 2) based on the relationship of epidote, garnet, sphere, and ilmenite, 23.21% can be related to strong hydrodynamic conditions that control transport and sedimentation. By comparing mineral compositions of river waters in the study area, the following four mineral provenances can be identified. The Qingdao-Laoshan nearshore area has a quartz-feldspar-epidote-hornblende-limenite-limonite-sphene assemblage, which is largely attributed to relict sediment and coastal erosion. The Jimo-Haiyang nearshore area has a quartz-feldspar-hornblende-epidote-limonite-mica-actinolite assemblage, derived largely from the Wulong River and Rushan River, and is also affected by the Huanghe River, while the Qianliyan Island area in the deeper offshore area separated by a mud belt has a similar assemblage. The Haiyang-Rushan nearshore area has a quartz-feldspar-hornblende-epidote-micas-limonite assemblage, indicating multiple sources from the Rushan River, the Wulong River, the Huanghe River, and coastal erosion. The central area, located in an eddy center, has a mica-authigenic pyrite-hornblende-quartz-feldspar assemblage, indicating multiple sources dominated by Huanghe River distal sediments.
