Across two phylogeographic breaks: Quaternary evolutionary history of a mountain aspen (Populus rotundifolia) in the Hengduan Mountains

Biogeographical barriers to gene flow are central to plant phylogeography.In East Asia,plant distribution is greatly influenced by two phylogeographic breaks,the Mekong-Salween Divide and Tanaka-Kaiyong Line,however,few studies have investigated how these barriers affect the genetic diversity of species that are distributed across both.Here we used 14 microsatellite loci and four chloroplast DNA fragments to examine genetic diversity and distribution patterns of 49 populations of Populus rotundifolia,a species that spans both the Mekong-Salween Divide and the Tanaka-Kaiyong Line in southwestern China.Demographic and migration hypotheses were tested using coalescent-based approaches.Limited historical gene flow was observed between the western and eastern groups of P.rotundifolia,but substantial flow occurred across both the Mekong-Salween Divide and Tanaka-Kaiyong Line,manifesting in clear admixture and high genetic diversity in the central group.Wind-borne pollen and seeds may have facilitated the dispersal of P.rotundifolia following prevalent northwest winds in the spring.We also found that the Hengduan Mountains,where multiple genetic barriers were detected,acted on the whole as a barrier between the western and eastern groups of P.rotundifolia.Ecological niche modeling suggested that P.rotundifolia has undergone range expansion since the last glacial maximum,and demographic reconstruction indicated an earlier population expansion around 600 Ka.The phylogeographic pattern of P.rotundifolia reflects the interplay of biological traits,wind patterns,barriers,niche differentiation,and Quaternary climate history.This study emphasizes the need for multiple lines of evidence in understanding the Quaternary evolution of plants in topographically complex areas.

Wettability alteration of organo-vermiculites induced by layer charge and tailored bis-N-heterocyclic quaternary ammonium salts

Wettability is an important surface property that deserves to further explore the factors on its alteration.Series of bis-N-heterocyclic quaternary ammonium salts with different spacer length and N-heterocyclic headgroups(morpholinium(BMMB,BMMD and BMMH),piperidinium(BPMH)and piperazinium(BMPMH))have been synthesized and employed for altering the wettability of vermiculite and its derivates(Vts)treated by Li^(+)-saturated heating method.The results of X-ray diffraction(XRD),Fourier transform infrared spectroscopy(FT-IR),thermogravimetric analysis(TG-DTG),scanning electron microscopy(SEM)and N_(2)adsorption/desorption isotherms indicate that all of the bis-N-heterocyclic quaternary ammonium salts have been successfully inserted into the vermiculite layers,leading to the organic monolayer.The results of capillary rise tests combined with Lipophilic to Hydrophilic Ratio(LHR)values unveil the wettability alteration of the organo-Vts.As the layer charge decreases,the hydrophilicity of the organo-Vts gradually increases,which is probably caused by the decline in binding sites.As the result of the change in spacer length of modifier,the wetting properties of morpholinium-based organo-Vts change in order of BMMD-Vts>BMMH-Vts>BMMB-Vts,and difference in N-heterocyclic headgroups leads to the sequence of wettability:BMPMH-Vts>BPMH-Vts>BMMH-Vts.Layer charge of Vt,spacer length and the type of the N-heterocyclic headgroup of modifier have the synergistic effect on the regulation of the wettability.

Discovery of new potential magnetic semiconductors in quaternary Heusler compounds by addition of lanthanides

Magnetic semiconductors have attracted a lot of attention by having both electronic charge and spin degrees of freedom. In this paper, we obtained twenty magnetic semiconductors such as FeVLaSb, FeVPrSb, FeCrTbSi, CoVDySi, and CoVHoSi by adding lanthanides to quaternary Heusler compounds based on the Slater-Pauling law and orbital hybridization theory. The relationship between the lattice constants and energy gaps of the magnetic semiconductors with lanthanide elements is investigated by in-depth analysis. These magnetic semiconductors of quaternary Heusler compounds are promising candidates to find applications as spin filtering materials in spintronics devices.

Petrography, Geochemistry and Relative Chronology of Quaternary Volcanic Formations in the Mermoz and Fann Sectors, West Senegal

Detailed work on Quaternary volcanism has been carried out in the Mermoz and Fann sectors of western Senegal. In the Mermoz sector, the main emission zone is a collapsed crater located at the intersection of three major fractures: NE-SW, NW-SE and N-S. The lithological succession in this Mermoz sector comprises, from bottom to top: 1) a substratum with at its base Eocene limestones on which lie Quaternary sands surmounted by stratified tuffs;2) a vesicular ball dolerite which deforms the stratified tuffs;3) a dark early breccia;4) two generations of basanites: the first is vesicular, the second non-vesicular;5) a clear intermediate breccia and finally 6) a late breccia. The Fann sector contains several emission zones, most of which are currently located in the ocean. The lavas may have reached the coast through E-W and NE-SW faults. The lithological succession includes from bottom to top: 1) scoria-rich early volcanic breccias;2) a first generation of non-vesicular mesocrate dolerite (D1);3) a second generation of melanocrate vesicular dolerite (D2);4) basanites and finally 5) a late breccia. The geochemical characteristics of the lavas studied are compatible with a very enriched and very deep magmatic source of the garnet lherzolite type located in the lower mantle. The magma from this source would have risen in the form of mantle plumes through major NE-SW and E-W faults in a continental intraplate context.

Physical and Mechanical Features of the Quaternary Basanites of the Cap-Vert Peninsula of Dakar (Senegal, West Africa)

This work presents the results of geotechnical tests carried out in the laboratory on specimens of Quaternary olivine basanites from the Cap-Vert peninsula of Dakar. The samples were taken following geotechnical investigations in the Fann-PE, Mermoz-Ouakam, Yoff and Ngor areas respectively. The results obtained show a dry density between 20.45 and 29.30 kN/m3 which corresponds to medium to high density basanites. The porosity varies between 0.33% and 4.20%. For microlitic basanites, the porosity remains low, on the other hand, for micrograined basanites;a slight increase in porosity is noticed. As for the methylene blue adsorption test value measured, it is between 0.25 and 1.10. The uniaxial compression strength (Rc) and Young’s modulus (E) vary respectively from 12.19 MPa to 41.748 MPa and from 1477.6 MPa to 7699.1 MPa. The low strength values are recorded in altered and vesicular basanites. Also, a correlation was made between uniaxial compression strength and porosity and showed a gradual decrease in strength with increasing porosity.

基于Quaternary编码的球面三角格网邻近搜索算法

分析了球面Quaternary编码的特点,给出了三角格网方向判断的规则,并对该算法与Bartholdi邻近搜索算法的时间复杂度进行了对比。结果表明,分解算法的平均时间耗时量约是Bartholdi邻近搜索算法的23.66%。

Palaeoclihlatic Indicators of China's Quaternary Saline Lake Sediments and Hydrochemistry

In this paper the authors classify saline lake sediments into the cold, warm and eurythermal phases, reveal the consistency between the zoning of hydrochemical types of modern saline lake water and climatic zoning and give climatic parameters under the conditions of typical cold phase (mirabilite and natron), warm phase (thenar-dite) and slightly warm phase (bloedite) saline lake deposition.

Studies on a Cationically Modified Quaternary Ammonium Salt of Lignin

A new quaternary ammonium salt monomer was synthesized and a quaternary amination of lignin（ noted as QL）, with the monomer was carried out by grafting copolymerization. The products were characterized by Fourier Transform Infrared spectroscopy（ FTIR）. The experimental results indicate that the yield of the monomer was 99.06%, and the conversion of the monomer and the grafting yield of QL were 93.69% and 185.78%, respectively. The feasibility of QL as the flocculant to be applied in color removal of five artificial dyes, erioehrome black T（dye A）, gongo red（dye B ）, direct fast black G （dye C ）, cuprofix blue green B （dye D ）, and acid black ATT （dye E ） was examined. Results show that OL exhihits the favorable flocculation nerformance and high stability.

Effects of quaternary ammonium chain length on the antibacterial and remineralizing effects of a calcium phosphate nanocomposite

Composites containing nanoparticles of amorphous calcium phosphate （NACP） remineralize tooth lesions and inhibit caries. A recent study synthesized quaternary ammonium methacrylates （QAMs） with chain lengths （CLs） of 3-18 and determined their effects on a bonding agent. This study aimed to incorporate these QAMs into NACP nanocomposites for the first time to simultaneously endow the material with antibacterial and remineralizing capabilities and to investigate the effects of the CL on the mechanical and biofilm properties. Five QAMs were synthesized： DMAPM （CL3）, DMAHM （CL6）, DMADDM （CL12）, DMAHDM （CL16）, and DMAODM （CL18）. Each QAM was incorporated into a composite containing 20% NACP and 50% glass fillers. A dental plaque microcosm biofilm model was used to evaluate the antibacterial activity. The flexural strength and elastic modulus of nanocomposites with QAMs matched those of a commercial control composite （n = 6; P 〉 0.1）. Increasing the CL from 3 to 16 greatly enhanced the antibacterial activity of the NACP nanocomposite （P 〈 0.05）; further increasing the CL to 18 decreased the antibacterial potency. The NACP nanocomposite with a CL of 16 exhibited biofilm metabolic activity and acid production that were 10-fold lesser than those of the control composite. The NACP nanocomposite with a CL of 16 produced 2-log decreases in the colony-forming units （CFU） of total microorganisms, total streptococci, and mutans streptococci. In conclusion, QAMs with CLs of 3-18 were synthesized and incorporated into an NACP nanocomposite for the first time to simultaneously endow the material with antibacterial and remineralization capabilities. Increasing the C/reduced the metabolic activity and acid production of biofilms and caused a 2-log decrease in CFU without compromising the mechanical properties. Nanocomposites exhibiting strong anti-biofilm activity, remineralization effects, and mechanical properties are promising materials for tooth restorations that inhibit caries.

Quaternary glacio-erosional landforms in Laoshan Mountain and their constraints on the origin of Jiaozhou Bay, Qingdao, east of China

A field investigation on Quaternary glacial landforms in Laoshan Motmtain has discovered many glacial potholes, scouring grooves on top of granite ridges, and large boulders. These erosional landforms were formed by the meltwater from the overlying ice cap, suggesting that there was at least an ice cap covering Laoshan Mountain and the surrounding areas or even a continental ice sheet over the vast area of Shandong Province in the Late Pleistocene. The ice sheet was obstructed by the Laoshan Mountain, Dazhu Mountain and Xiaozhu Mountain in the coastal areas as it moved toward the Yellow Sea. The ice flows eroded the bedrock and carved the weak intersection of the fault systems in the NE and NW directions into a deep channel, which gradually formed a fjord in the area of the Jiaozhou Bay basin by 20.00 ka BE The seawater gradually invaded the fjord from the beginning of the Holocene （11.00 ka BP） and Jiaozhou Bay was eventually formed. Similar fjords are easily found along the east of China and they share a similar origin because of the Quaternary glaciation in the region.

Synthesis of isosorbide-based polycarbonates via melt polycondensation catalyzed by quaternary ammonium ionic liquids

A series of quaternary ammonium ionic liquids(ILs)were synthesized and employed as catalysts for the production of poly(isosorbide carbonate)(PIC)from diphenyl carbonate and isosorbide via a melt polycondensation process.The relationship between the anions of the ILs and the catalytic activities was investigated,and the readily‐prepared IL tetraethylammonium imidazolate(TEAI)was found to exhibit the highest catalytic activity.After optimizing the reaction conditions,a PIC with a weight‐average molecular weight(Mw)of25600g/mol was obtained,in conjunction with an isosorbide conversion of92%.As a means of modifying the molecular flexibility and thermal properties of the PIC,poly(aliphatic diol‐co‐isosorbide carbonate)s(PAIC)s were successfully synthesized,again using TEAI,and polymers with Mw values ranging from29000to112000g/mol were obtained.13C NMR analyses determined that the PAIC specimens had random microstructures,while differential scanning calorimetry demonstrated that each of the PAICs were amorphous and had glass transition temperatures ranging from50to115°C.Thermogravimetric analyses found Td‐5%values ranging from316to332°C for these polymers.Based on these data,it is evident that the incorporation of linear or cyclohexane‐based diol repeating units changed the thermal properties of the PIC.

A "Yellow Cap" on Quaternary Red Clay in Jiujiang,Jiangxi Province

A thin layer of yellow-brown-colored earth was generally found on Quaternary red clay in Jiujiang,Jiangxi Province. A typical profile was established. Both particle size distribution and REE (rare earthelements) characteristics of the yellow-brown-colored earth of the profile fully suggested its aeolian origin andclose similarity to Naming Xiashu loess. The study also implied aeolian origin of the underlying Quaternaryred clap Compared with the red clay, the yellow- brown- colored earth was less weathered because of its lowercontent of free iron and higher mole ratios of SiO2/A12O3 and SiO2/(Fe2O3+A12O3 ) as well as its lessdeveloped chemical microtextures of quartz grains.In order to study the aged of the two deposits comparatively, the thermoluminescent dating method wasused. As a result, the bottom of the yellow-brown-colored esrth was dated to 6015 ka B. P. and the upperpart of the red clay 38854 ka B. P. It was suggested that the yellow- browm- colored earth was formed inthe Late Pleistocene and was probably the aeolian deposit of the Last Glacial, which corresponded with theMalan loess in the Loess Plateau of the northwestern part of China; while the underlying red clay was formedin the Middle Pleistocene.A "yellow cap" on Quaternary red clay in Jiujiang implied a great climatic and environmental varistionin the beginning of the Late Pleistocene in the southern pot of China, especially in the middle and lowerreaches of the Yangtze River. The eveal not only halted the rubification, once dominating the region, butalso produced a widespread covering of aeolian deposit, as only occurred in the cold and dry environment.

The new basic theory on Quaternary environmental research

On the basis of extensive survey to the Quaternary paleosols, soils and weathering layers in the vast northern China and the Loess Plateau, we found some unusually special phenomena of chemical components such as unsuccessive illuvium, twin illuviums, unusually thick illuvium and multi-illuviums etc. According to the analysis on the content of CaCO 3 and the data of penetrating experiment, a new theory of illuvial depth or removal depth of CaCO 3 in weathering and leaching belt was constructed, which indicates that the time of CaCO 3 removing to the illuvial depth is very short, and the effect of time factor on illuvial depth can be ignored. The theory can be taken as a credible foundation for studying many geological and geographical problems in weathering and leaching belt. When the illuvial depth of CaCO 3 is bigger than the thickness of developing belt of soil or paleosol, it can be determined that the paleosol has turned into weathering crust. When the illuvial depth of CaCO 3 is bigger than the thickness of paleosol, paleosol is leaching moderately acid soil. When two, three layers or unusually thick CaCO 3 illuviums exist in the same weathering section or at the bottom of the same paleosol, there were two or more periods forming paleosol and corresponding climatic stages at that time. On the basis of the equation of relationship between mean annual rainfall (y) and illuvial depth of CaCO 3 (x) (y = 305.5x + 168.5) determined in the paper, mean annual precipitation during the development of paleosol can be calculated.

Near surface velocity and Q_s structure of the Quaternary sediment in Bohai basin,China

Heavily populated by Beijing and Tianjin cities, Bohai basin is a seismically active Cenozoic basin suffering from huge lost by devastating earthquakes, such as Tangshan earthquake. The attenuation （Qp and Qs） of the surficial Quaternary sediment has not been studied at natural seismic frequency （1-10 Hz）, which is crucial to earthquake hazards study. Borehole seismic records of micro earthquake provide us a good way to study the velocity and attenuation of the surficial structure （0-500 m）. We found that there are two pulses well separated with simple waveforms on borehole seismic records from the 2006 Mw4.9 Wen＇an earthquake sequence. Then we performed waveform modeling with generalized ray theory （GRT） to confirm that the two pulses are direct wave and surface reflected wave, and found that the average vp and Vs of the top 300 m in this region are about 1.8 km/s and 0.42 km/s, leading to high ve/vs ratio of 4.3. We also modeled surface refleeted wave with propagating matrix method to constrain Qs and the near surface velocity structure. Our modeling indicates that Qs is at least 30, or probably up to 100, much larger than the typically assumed extremely low Q（-10）, but consistent with Qs modeling in Mississippi embayment. Also, the velocity gradient just beneath the free surface （0-50 m） is very large and velocity increases gradually at larger depth. Our modeling demonstrates the importance of borebole seismic records in resolving shallow velocity and attenuation structure, and hence may help in earthquake hazard simulation.

Synthesis of cyclic carbonates from epoxides or olefins and CO_2 catalyzed by metal-organic frameworks and quaternary ammonium salts

Catalytic properties of the metal-organic framework Cr-MIL-101 in solvent-free cycloaddition of CO2 to epoxides to produce cyclic carbon- ates using tetrabutylammonium bromide as co-catalyst have been explored under mild reaction conditions （8 bar CO2, 25 ~C）. Styrene and propylene carbonates were formed with high yields （95% and 82%, respectively）. Catalytic performance of Cr-MIL-101 was compared with other MOFs： Fe-MIL-101, Zn-MOF-5 and HKUST-1, The catalytic properties of different quaternary ammonium bromides, Cr-MIL-101 as well as PW12/Cr-MIL-101 composite material have been assessed in oxidative carboxylation of styrene in the presence of both tert-butyl hydroperoxide and H202 as oxidants at 8-100bar CO2 and 25-80 ~C with selectivity to styrene carbonate up to 44% at 57% substrate conversion.

Revisiting Late Quaternary Slip-rate along the Maqu Segment of the Eastern Kunlun Fault, Northeast Tibet

The Late Quaternary slip rate along the Maqu segment of the eastern Kunlun Fault was estimated using a combination of high-resolution remote sensing imagery interpretation, field observations and differential Global Positioning System（GPS） measurements of offset river terraces, and 14 C dating of snail shells collected from offset risers. The results show that the left-slip rate along the segment is 3–5 mm/a, and that the vertical slip rate is 0.3–0.5 mm/a. Both the horizontal and vertical slips on the segment remain consistent over a distance of ~100 km. It means that no slip gradient as previously suggested occurred along the Maqu segment, and which thus might behave as an independent seismogenic fault. Judging from multiple relationships among young terrace offsets, we infer that co-seismic surface rupture produced by a characteristic earthquake with a magnitude of Ms7.0–7.5 on the Maqu fault could generate a horizontal slip of 4.5–5 m and a vertical slip of 0.45–0.5 m, with a corresponding ratio（Dh/Dv） of about 9. Two surface rupture events must have occurred over the past 3300 years, the latest one possibly between 1485 cal BP and 1730 cal BP.

Origin of Quaternary Red Clay of Southern Anhui Province

The particle size distribution, heavy mineral constituents and rare earth elements (REE) characteristics of the Quaternary red clay of southern Anhui Province were studied to explore the origin of the clay. The results showed that the clay had some properties of areolian deposits, which could be compared with those of the loess in North China; and its chondrite normalized curves of REE were similar to those of the Xiashu loess, implying that they shared the same origin. It was concluded in combination with the results reported by other researchers that the Quaternary red clay of southern Anhui Province originated from aeolian deposits, and this could reveal the cycles of warm and cold climates in the area during the Quaternary period.

Paleoenvironmental changes during the late Quaternary as inferred from foraminifera assemblages in the Laizhou Bay

Controlled by climate changes, there were three large-scale transgressions and regressions around the Bohai Sea during the late Quaternary, which were accepted by most geologists. However, a big controversy still exists about the time when the transgressions occurred separately. In order to find out the process of the paleoenvironmental changes around the Bohai Sea in the late Quaternary, the foraminifera assemblages from a new borehole Lz908 in the southern coast of the Laizhou Bay were studied, and then the transgressive strata were indentified. Combined with accelerator mass spectrometry radiocarbon 14C（AMS14C） and optically stimulated luminescence（OSL） ages, the occurrence time of these transgressions were re-determined. The result showed that three major large-scale transgressions occurred separately at the beginning of marine isotopic stage 7（MIS7）, the last interglacial period（MIS5） and the Holocene. In addition, a small-scale transgression occurred in the mid-MIS6, and the corresponding transgressive stratum was deposited. The transgressive deposition of MIS3 was also discovered in this study. However, the characteristics of the foraminifera indicated the environment during this period was colder than that in the MIS5. By comparison with the global sea-level changes, the paleoenvironmental changes around the Bohai Sea in the late Quaternary can be consistent with the global climate changes.

Synthesis and Characterization of Quaternary Complex of Sm-CH_3C(CH_2OH)_2COOH-Phen

A new quaternary complex with 2,2-dihydroxymethyl propionic acid and 1,10-phenanthroline, Sm(CH3C(CH2OH)2COO)(NO3)2(phen), was synthesized in ethanol solution and characterized by elemental analysis, IR and solid-state 13C NMR. The result of molar electrolytic conductivity of the complex indicates that it is non-electrolyte. Solution and thermal properties of the complex further verifies that the complex and ligant are different. In addition, the analytical results also imply that the two hydroxyl groups of 2,2-dihydroxymethyl propionic acid are not involved in the coordinate reaction. This will provide a new way for producing new multifunctional polymer materials with excellent fluorescent property. The fluorescence spectra of the complex were also studied. The main fluorescence emission peak of the complex appeared at 555, 604 and 646 nm. These fluorescent emission peaks correspond to transitions from 4G5/2 to 6H5/2, 6H7/2 and 6H9/2 energy levels of samarium(Ⅲ) ion, respectively. The most intense peak is at 646 nm, which lies in the range of absorption wavelength of chlorophyll a and chlorophyll b (600～680 nm), and it is beneficial to the crops to grow up.

Quaternary Climate and Environment in the Lop Nur,Xinjiang

Since the middle Early Pleistocene (1.20 Ma B.P.), the desert steppe climate and environment have predominated in the Lop Nur area, Xinjiang, characterized by warm humid epochs interrupted by dry cold intervals. The grain-size and magnetic susceptibility curves record 30 climatic oscillations, each with a ca. 40 ka cycle, in the area since 1.2 Ma B.P., which reflects the controlling effects exerted by the astronomic factor on the environment. The Quaternary sedimentary environment in the Lop Nur gradually changed from a fresh lake through a brackish lake to a saline lake, showing a spiral evolution, and finally it evolved into a playa.