A series of random copolypeptides of poly(methoxy-diethylene glycol–L-glutamate)-co-poly(S-(onitrobenzyl)-L-cysteine)was synthesized by ring-open copolymerization of methoxydiethylene glycol-Lglutamate-N-carbox...A series of random copolypeptides of poly(methoxy-diethylene glycol–L-glutamate)-co-poly(S-(onitrobenzyl)-L-cysteine)was synthesized by ring-open copolymerization of methoxydiethylene glycol-Lglutamate-N-carboxyanhydride(EG2-Glu-NCA) and S-(o-nitrobenzyl)-L-cysteine-N-carboxyanhydride(NBC-NCA) in dried dimethylformamide solution, which presents quadruple thermo-photo-redox responsive self-assembly behavior and forms the related nanogel and hydrogel in water.展开更多
基金the financial support of the National Natural Science Foundation of China (No. 21474061)
文摘A series of random copolypeptides of poly(methoxy-diethylene glycol–L-glutamate)-co-poly(S-(onitrobenzyl)-L-cysteine)was synthesized by ring-open copolymerization of methoxydiethylene glycol-Lglutamate-N-carboxyanhydride(EG2-Glu-NCA) and S-(o-nitrobenzyl)-L-cysteine-N-carboxyanhydride(NBC-NCA) in dried dimethylformamide solution, which presents quadruple thermo-photo-redox responsive self-assembly behavior and forms the related nanogel and hydrogel in water.