Sol-gel technology was employed to synthesize nanosized precursors of La-Mg hydrogen storage alloy at different pH values (0.5, 1.5, 8.0 and 9.0) of reaction solution. The effect of pH value on microstructure of the n...Sol-gel technology was employed to synthesize nanosized precursors of La-Mg hydrogen storage alloy at different pH values (0.5, 1.5, 8.0 and 9.0) of reaction solution. The effect of pH value on microstructure of the nano precursors of La-Mg hydrogen storage alloy was studied by infrared radiation (IR), thermo-gravimetric and differential thermal analysis (TG/DTA), X-ray diffraction analyzer (XRD) and transmission electron microscopy (TEM). IR results indicate that the chelating agent, citric acid, is not fully ionized, and carboxyl groups are not entirely used to complex metal ions in acidic solutions. The efficiency of complexing metal ions is enhanced in basic solutions. TG/DTA results show that the combustion may take place with low rate of the flame propagation that causes the longer combustion time when pH<1.5. On the contrary, the dry gel synthesized in basic solution combusts at low ignition temperature and combustion reaction is violent; it is easy to form fine particles. XRD and TEM results reveal that the precursor powders are mainly two-phase mixture of La 2 O 3 and MgO. The morphology of the particles is almost flake with the size of ~30 nm when pH is 8.0.展开更多
The sol-gel technology is applied for the preparation of solid-phase microextraction (SPME) fiber. The fiber demonstrates high thermal stability, efficient extraction rate and the selectivity for non-polar or low-pol...The sol-gel technology is applied for the preparation of solid-phase microextraction (SPME) fiber. The fiber demonstrates high thermal stability, efficient extraction rate and the selectivity for non-polar or low-polar analytes. Efficient SPME-GC-FID analyses of benzene- toluene-ethylbenzene-xylenes (BTEXs) and low-polar halocarbon were achieved by the sol-gel coated DSDA-DDBT-TiO2 fiber. Some parameters of the SPME fiber for the determination of halocarbon in aqueous sample were investigated.展开更多
Capillary column preparation using perpentylated (2,3,6-tri-O-pentyl)-β-cyclodextrin asstationary phase by sol-gel technology with simplicity and rapidity is described. Multiplepreparation steps in conventional colum...Capillary column preparation using perpentylated (2,3,6-tri-O-pentyl)-β-cyclodextrin asstationary phase by sol-gel technology with simplicity and rapidity is described. Multiplepreparation steps in conventional column technology were avoided. The prepared columns exhibitsatisfactory chromatographic performances and pronounced selectivity for a wide range of testsolutes, and have been successfully used for the separation of nitrotoluene, dimethoxybenzene,alcohols, alkanes, dimethylphenol and cresol isomers.展开更多
Heptakis(2, 3, 6-tri-O-octyl)-β-cyclodextrin was coated onto the fused silica capillary by sol-gel technology. Column efficiency and column selectivity were studied. The results indicated that high ability of separat...Heptakis(2, 3, 6-tri-O-octyl)-β-cyclodextrin was coated onto the fused silica capillary by sol-gel technology. Column efficiency and column selectivity were studied. The results indicated that high ability of separation was acquired . Positional isomers of aromatic compounds were well separated.展开更多
Coated capillary columns were prepared by sol-gel technology and used in the separation of basic proteins with capillary zone electrophoresis. The results indicated that a significant decrease in protein adsorption wa...Coated capillary columns were prepared by sol-gel technology and used in the separation of basic proteins with capillary zone electrophoresis. The results indicated that a significant decrease in protein adsorption was obtained and EOF was also diminished to zero in the pH range of 3-10.展开更多
The importance of foundry coating in improving the surface quality of castings cannot be over emphasized. The application of mould and core washes creates a high thermal integrity barrier between the metal and the mou...The importance of foundry coating in improving the surface quality of castings cannot be over emphasized. The application of mould and core washes creates a high thermal integrity barrier between the metal and the mould resulting in the reduction of the thermal shock experienced by the sand system. These thermal shock leads to series of surface defects such as veining/finning, metal penetration, burn-on/in, scab, rat tail, erosion etc. The use of coatings reduces the tendency of occurrence of these defects. However, the understanding of the coating, its components, characteristics and mechanism of action is important. In this review, a detailed description of these topics and examples are provided where necessary. A potential area of research in foundry coating development, using sol-gel process is suggested. The application of sol-gel technology in the development of foundry coatings is a novel approach.展开更多
3 - dimensional body measurement technology, the basis of developing high technology in industry, accelerates digital development of aplparel industry. This paper briefly introduces the history of 3 - dimensional body...3 - dimensional body measurement technology, the basis of developing high technology in industry, accelerates digital development of aplparel industry. This paper briefly introduces the history of 3 - dimensional body measurement technology, and recounts the principle and primary structure of some types of 3 - dimensional automatic body measurement system. With this understanding, it discusses prospect of 3- dimensional CAD and virtual technology used in apparel industry.展开更多
This paper briefly introduces the characteristics and structure of symbol QR two-dimensional code, a detailed analysis of the image processing method to identify QR code of the whole process, and the bilinear mapping ...This paper briefly introduces the characteristics and structure of symbol QR two-dimensional code, a detailed analysis of the image processing method to identify QR code of the whole process, and the bilinear mapping method is applied to image correction, the final steps of decoding are given. The actual test results show that, the design algorithm has theoretical and practical, this recognition system can correctly read QR code, and has high recognition rate and recognition speed, has practical value and application prospect.展开更多
基金supported by the Open Foundation of Key Laboratory of the Ministry of Educationof Nonferrous Metal Alloys and Processes(No.EKL09002)The Ph.D.Fund Project of Lanzhou University of Science and Technology(No.BS01200904)
文摘Sol-gel technology was employed to synthesize nanosized precursors of La-Mg hydrogen storage alloy at different pH values (0.5, 1.5, 8.0 and 9.0) of reaction solution. The effect of pH value on microstructure of the nano precursors of La-Mg hydrogen storage alloy was studied by infrared radiation (IR), thermo-gravimetric and differential thermal analysis (TG/DTA), X-ray diffraction analyzer (XRD) and transmission electron microscopy (TEM). IR results indicate that the chelating agent, citric acid, is not fully ionized, and carboxyl groups are not entirely used to complex metal ions in acidic solutions. The efficiency of complexing metal ions is enhanced in basic solutions. TG/DTA results show that the combustion may take place with low rate of the flame propagation that causes the longer combustion time when pH<1.5. On the contrary, the dry gel synthesized in basic solution combusts at low ignition temperature and combustion reaction is violent; it is easy to form fine particles. XRD and TEM results reveal that the precursor powders are mainly two-phase mixture of La 2 O 3 and MgO. The morphology of the particles is almost flake with the size of ~30 nm when pH is 8.0.
文摘The sol-gel technology is applied for the preparation of solid-phase microextraction (SPME) fiber. The fiber demonstrates high thermal stability, efficient extraction rate and the selectivity for non-polar or low-polar analytes. Efficient SPME-GC-FID analyses of benzene- toluene-ethylbenzene-xylenes (BTEXs) and low-polar halocarbon were achieved by the sol-gel coated DSDA-DDBT-TiO2 fiber. Some parameters of the SPME fiber for the determination of halocarbon in aqueous sample were investigated.
文摘Capillary column preparation using perpentylated (2,3,6-tri-O-pentyl)-β-cyclodextrin asstationary phase by sol-gel technology with simplicity and rapidity is described. Multiplepreparation steps in conventional column technology were avoided. The prepared columns exhibitsatisfactory chromatographic performances and pronounced selectivity for a wide range of testsolutes, and have been successfully used for the separation of nitrotoluene, dimethoxybenzene,alcohols, alkanes, dimethylphenol and cresol isomers.
文摘Heptakis(2, 3, 6-tri-O-octyl)-β-cyclodextrin was coated onto the fused silica capillary by sol-gel technology. Column efficiency and column selectivity were studied. The results indicated that high ability of separation was acquired . Positional isomers of aromatic compounds were well separated.
文摘Coated capillary columns were prepared by sol-gel technology and used in the separation of basic proteins with capillary zone electrophoresis. The results indicated that a significant decrease in protein adsorption was obtained and EOF was also diminished to zero in the pH range of 3-10.
文摘The importance of foundry coating in improving the surface quality of castings cannot be over emphasized. The application of mould and core washes creates a high thermal integrity barrier between the metal and the mould resulting in the reduction of the thermal shock experienced by the sand system. These thermal shock leads to series of surface defects such as veining/finning, metal penetration, burn-on/in, scab, rat tail, erosion etc. The use of coatings reduces the tendency of occurrence of these defects. However, the understanding of the coating, its components, characteristics and mechanism of action is important. In this review, a detailed description of these topics and examples are provided where necessary. A potential area of research in foundry coating development, using sol-gel process is suggested. The application of sol-gel technology in the development of foundry coatings is a novel approach.
基金item of significant subject construction in Shanghai
文摘3 - dimensional body measurement technology, the basis of developing high technology in industry, accelerates digital development of aplparel industry. This paper briefly introduces the history of 3 - dimensional body measurement technology, and recounts the principle and primary structure of some types of 3 - dimensional automatic body measurement system. With this understanding, it discusses prospect of 3- dimensional CAD and virtual technology used in apparel industry.
文摘This paper briefly introduces the characteristics and structure of symbol QR two-dimensional code, a detailed analysis of the image processing method to identify QR code of the whole process, and the bilinear mapping method is applied to image correction, the final steps of decoding are given. The actual test results show that, the design algorithm has theoretical and practical, this recognition system can correctly read QR code, and has high recognition rate and recognition speed, has practical value and application prospect.
