Bulk geochemistry,Sr,Nd,and O-H isotope systematics are reported for the first time on banded iron formation(BIF)-hosted high-grade iron ore at the northwestern segment of Congo Craton(CC).Located in Mbalam iron ore d...Bulk geochemistry,Sr,Nd,and O-H isotope systematics are reported for the first time on banded iron formation(BIF)-hosted high-grade iron ore at the northwestern segment of Congo Craton(CC).Located in Mbalam iron ore district,Southern Cameroon,Metzimevin iron ore deposit is a hematite-magnetite BIF system,dominated by SiO_(2)+Fe_(2)O_(3)(97.1 to 99.84 wt%),with low concentrations of clastic elements e.g.,Al_(2)O_(3),TiO_(2),and HFSE,depicting a nearly pure chemical precipitate.The REE+Y signature of the iron deposit displays strong positive Eu anomaly,strong negative Ce anomaly,and chondritic to superchondritic Y/Ho ratios,suggestive of formation by mixed seawater-high temperature hydrothermal fluids in oxidising environment.The^(87)Sr/^(86)Sr ratios of the BIF are higher than the maximum^(87)Sr/^(86)Sr evolution curves for all Archean reservoirs(bulk silicate earth,Archean crust and Archean seawater),indicating involvement of continentally-derived components during BIF formation and alteration.TheƐ_(Nd)(t)(+2.26 to+3.77)and Nd model age indicate that chemical constituents for the BIF were derived from undifferentiated crustal source,between 3.002 and 2.88 Ga.The variable and diverse O and H isotope data(−1.9‰to 17.3‰and−57‰to 136‰respectively)indicate that the Metzimevin iron ore formed initially from magmatic plumes and later enriched by magmatic-metamorphic-modified meteoric fluids.Mass balance calculations indicate mineralisation by combined leaching and precipitation,with an average iron enrichment factor of>2.67 and SiO_(2)depletion factor of>0.99.This is associated with an overall volume reduction of 28.27%,reflecting net leaching and volume collapse of the BIF protholith.展开更多
Located along the southern part of the West Qinling orogenic belt,the Yangshan gold deposit is one of the largest in China.The major gold ores of Yangshan are disseminated in metasedimentary host rocks with minor nati...Located along the southern part of the West Qinling orogenic belt,the Yangshan gold deposit is one of the largest in China.The major gold ores of Yangshan are disseminated in metasedimentary host rocks with minor native gold amounts in stibnite-gold quartz veins.Pyrite and arsenopyrite are the major Au-bearing minerals.Hydrothermal muscovite from gold-bearing quartz veins was dated using the in situ Rb-Sr method to determine the formation age of the Yangshan gold deposit.The Rb-Sr isochron date of the muscovite yielded 210.1±5.6 Ma(MSWD=1.2).This date is near the lower end of the period of the mineralized granitic dykes(210.49-213.10 Ma).Two stages of gold enriching process are recognized in the gold-bearing pyrite:the first is incorporated with the Co,Cu,As,Ni enrichment;and the second is accompanied by Bi,Co,Ni,Pb,Cu,Sb concentration.The in-situ sulfur isotopic values of pyrites show a restrictedΔ34s range of-1.43‰to 2.86‰with a mean value of 0.43‰.Trace-element mapping and in-situ sulfur isotopic analysis of pyrite suggest that the sulfur deposits are likely derived from a magmatic source and likely assimilated by sulfur from the sedimentary bedrock.Thus,magmatism plays a critical role in the formation of the Yangshan gold deposit.展开更多
文摘Bulk geochemistry,Sr,Nd,and O-H isotope systematics are reported for the first time on banded iron formation(BIF)-hosted high-grade iron ore at the northwestern segment of Congo Craton(CC).Located in Mbalam iron ore district,Southern Cameroon,Metzimevin iron ore deposit is a hematite-magnetite BIF system,dominated by SiO_(2)+Fe_(2)O_(3)(97.1 to 99.84 wt%),with low concentrations of clastic elements e.g.,Al_(2)O_(3),TiO_(2),and HFSE,depicting a nearly pure chemical precipitate.The REE+Y signature of the iron deposit displays strong positive Eu anomaly,strong negative Ce anomaly,and chondritic to superchondritic Y/Ho ratios,suggestive of formation by mixed seawater-high temperature hydrothermal fluids in oxidising environment.The^(87)Sr/^(86)Sr ratios of the BIF are higher than the maximum^(87)Sr/^(86)Sr evolution curves for all Archean reservoirs(bulk silicate earth,Archean crust and Archean seawater),indicating involvement of continentally-derived components during BIF formation and alteration.TheƐ_(Nd)(t)(+2.26 to+3.77)and Nd model age indicate that chemical constituents for the BIF were derived from undifferentiated crustal source,between 3.002 and 2.88 Ga.The variable and diverse O and H isotope data(−1.9‰to 17.3‰and−57‰to 136‰respectively)indicate that the Metzimevin iron ore formed initially from magmatic plumes and later enriched by magmatic-metamorphic-modified meteoric fluids.Mass balance calculations indicate mineralisation by combined leaching and precipitation,with an average iron enrichment factor of>2.67 and SiO_(2)depletion factor of>0.99.This is associated with an overall volume reduction of 28.27%,reflecting net leaching and volume collapse of the BIF protholith.
基金financially supported by China Geological Survey Project(Grant No.DD20220971)。
文摘Located along the southern part of the West Qinling orogenic belt,the Yangshan gold deposit is one of the largest in China.The major gold ores of Yangshan are disseminated in metasedimentary host rocks with minor native gold amounts in stibnite-gold quartz veins.Pyrite and arsenopyrite are the major Au-bearing minerals.Hydrothermal muscovite from gold-bearing quartz veins was dated using the in situ Rb-Sr method to determine the formation age of the Yangshan gold deposit.The Rb-Sr isochron date of the muscovite yielded 210.1±5.6 Ma(MSWD=1.2).This date is near the lower end of the period of the mineralized granitic dykes(210.49-213.10 Ma).Two stages of gold enriching process are recognized in the gold-bearing pyrite:the first is incorporated with the Co,Cu,As,Ni enrichment;and the second is accompanied by Bi,Co,Ni,Pb,Cu,Sb concentration.The in-situ sulfur isotopic values of pyrites show a restrictedΔ34s range of-1.43‰to 2.86‰with a mean value of 0.43‰.Trace-element mapping and in-situ sulfur isotopic analysis of pyrite suggest that the sulfur deposits are likely derived from a magmatic source and likely assimilated by sulfur from the sedimentary bedrock.Thus,magmatism plays a critical role in the formation of the Yangshan gold deposit.
