The chemical reaction and dissolution processes of RE2 O3 in REF3-LiF（RE = La and Nd） molten salts were studied by X-ray diffraction, differential thermal analysis and chemical analysis. Firstly, RE2 O3 disperses in...The chemical reaction and dissolution processes of RE2 O3 in REF3-LiF（RE = La and Nd） molten salts were studied by X-ray diffraction, differential thermal analysis and chemical analysis. Firstly, RE2 O3 disperses in molten salts and reacts with REF3 and LiF, which lead to the generation of a new phase REOF, resulting in the dissociation or formation of complex ions by part of REOF, and the sedimentation of excessive REOF at the bottom. The RE contents in molten salts were used to determine the solubility of RE2 O3. The results show that with 20 mol%-40 mol% of REF3, the solubility ranges from 1.79 to 3.05 g RE2 O3 per100 g electrolyte and the corresponding mole concentration is 0.33%-0.87%. RE2 O3 solubility increases with increasing temperature and REF3 concentration. The natural logarithm of the RE2 O3 solubility is plotted against 1/T and can be interpreted by linear relationship. The fitting parameters can be used to estimate the solubility of RE2 O3 with minimized experimental efforts and difficult experiment conditions.展开更多
综述了稀土元素在镁合金溶液中去氧化夹杂、除氢和与熔剂的相互作用,以及稀土元素对镁及镁合金的组织、性能、起燃温度、耐蚀性等方面的影响。阐述了 RE 在镁合金显微组织中细化晶粒、强化晶粒和晶界、提高合金力学性能的机理,以及与氧...综述了稀土元素在镁合金溶液中去氧化夹杂、除氢和与熔剂的相互作用,以及稀土元素对镁及镁合金的组织、性能、起燃温度、耐蚀性等方面的影响。阐述了 RE 在镁合金显微组织中细化晶粒、强化晶粒和晶界、提高合金力学性能的机理,以及与氧等元素反应在镁合金表面生成 MgO、Al_2O_3、RE_2O_3、Mg_(17)Al_(12)组成的致密保护膜和由于Ce、Y、Le 等元素的加入形成稀土转化膜对镁合金起燃温度、耐蚀性的作用。并对含稀土镁合金进行了评价与展望。展开更多
基金supported by the National High Technology Research and Development Program(2011AA03A409)Fundamental Research Funds for the Central Universities(N110202002)
文摘The chemical reaction and dissolution processes of RE2 O3 in REF3-LiF（RE = La and Nd） molten salts were studied by X-ray diffraction, differential thermal analysis and chemical analysis. Firstly, RE2 O3 disperses in molten salts and reacts with REF3 and LiF, which lead to the generation of a new phase REOF, resulting in the dissociation or formation of complex ions by part of REOF, and the sedimentation of excessive REOF at the bottom. The RE contents in molten salts were used to determine the solubility of RE2 O3. The results show that with 20 mol%-40 mol% of REF3, the solubility ranges from 1.79 to 3.05 g RE2 O3 per100 g electrolyte and the corresponding mole concentration is 0.33%-0.87%. RE2 O3 solubility increases with increasing temperature and REF3 concentration. The natural logarithm of the RE2 O3 solubility is plotted against 1/T and can be interpreted by linear relationship. The fitting parameters can be used to estimate the solubility of RE2 O3 with minimized experimental efforts and difficult experiment conditions.
文摘综述了稀土元素在镁合金溶液中去氧化夹杂、除氢和与熔剂的相互作用,以及稀土元素对镁及镁合金的组织、性能、起燃温度、耐蚀性等方面的影响。阐述了 RE 在镁合金显微组织中细化晶粒、强化晶粒和晶界、提高合金力学性能的机理,以及与氧等元素反应在镁合金表面生成 MgO、Al_2O_3、RE_2O_3、Mg_(17)Al_(12)组成的致密保护膜和由于Ce、Y、Le 等元素的加入形成稀土转化膜对镁合金起燃温度、耐蚀性的作用。并对含稀土镁合金进行了评价与展望。
