The effects of the addition of 0.6%Ca（mass fraction） on the as-cast microstructure and mechanical properties of the Mg-3Ce-1.2Mn-0.9Sc and Mg-4Y-1.2Mn-0.9Sc magnesium alloys were investigated and compared by optical...The effects of the addition of 0.6%Ca（mass fraction） on the as-cast microstructure and mechanical properties of the Mg-3Ce-1.2Mn-0.9Sc and Mg-4Y-1.2Mn-0.9Sc magnesium alloys were investigated and compared by optical microscopy and scanning electron microscopy,differential scanning calorimetry analysis,and tensile and creep tests.The results indicate that the addition of 0.6%Ca to the Mg-3Ce-1.2Mn-0.9Sc and Mg-4Y-1.2Mn-0.9Sc alloys can refine the grains of the two alloys.At the same time,the addition of 0.6%Ca to the Mg-3Ce-1.2Mn-0.9Sc and Mg-4Y-1.2Mn-0.9Sc alloys can effectively improve the tensile properties of the two alloys.In addition,the addition of 0.6%Ca can also improve the creep properties of the Mg-3Ce-1.2Mn-0.9Sc alloy but is not beneficial to the creep properties of the Mg-4Y-1.2Mn-0.9Sc alloy.The different effects of minor Ca on the creep properties of the Mg-3Ce-1.2Mn-0.9Sc and Mg-4Y-1.2Mn-0.9Sc alloys are possibly related to the difference in the solid solubilities of Ce and Y in Mg.展开更多
Due to the ferro-philic and rock-philic geochemical properties, dispersion of resources as well as itscomplicated composition, the properties of scandium are similar to those of the lanthanide. Hence, its separa-tion ...Due to the ferro-philic and rock-philic geochemical properties, dispersion of resources as well as itscomplicated composition, the properties of scandium are similar to those of the lanthanide. Hence, its separa-tion from the lanthanides and iron is an important subject which has been studied extensively.1,10-bis(1’-phenyl-3’-methyl-5’-oxopyrazole-4’-yl)decane-1, 10-dione(BPMDD, HA)is a β-diketone chelating agent, and has a strong extracting power. The extraction of Sc with this chelating agenthas not been reported so far. In this communication, we attempt to separate scandium from the lanthanidesand some other elements by the extraction with BPMDD under suitable conditions.展开更多
基金Projects (CSTC2013jcyjC60001) supported by the Chongqing Science and Technology Commission of ChinaProject (KJ120834) supported by the Chongqing Education Commission of ChinaProject (CQUT1205) supported by the Open Funds from Key Laboratory of Manufacture and Test Techniques for Automobile Parts(Chongqing University of Technology),Ministry of Education,China
文摘The effects of the addition of 0.6%Ca（mass fraction） on the as-cast microstructure and mechanical properties of the Mg-3Ce-1.2Mn-0.9Sc and Mg-4Y-1.2Mn-0.9Sc magnesium alloys were investigated and compared by optical microscopy and scanning electron microscopy,differential scanning calorimetry analysis,and tensile and creep tests.The results indicate that the addition of 0.6%Ca to the Mg-3Ce-1.2Mn-0.9Sc and Mg-4Y-1.2Mn-0.9Sc alloys can refine the grains of the two alloys.At the same time,the addition of 0.6%Ca to the Mg-3Ce-1.2Mn-0.9Sc and Mg-4Y-1.2Mn-0.9Sc alloys can effectively improve the tensile properties of the two alloys.In addition,the addition of 0.6%Ca can also improve the creep properties of the Mg-3Ce-1.2Mn-0.9Sc alloy but is not beneficial to the creep properties of the Mg-4Y-1.2Mn-0.9Sc alloy.The different effects of minor Ca on the creep properties of the Mg-3Ce-1.2Mn-0.9Sc and Mg-4Y-1.2Mn-0.9Sc alloys are possibly related to the difference in the solid solubilities of Ce and Y in Mg.
文摘Due to the ferro-philic and rock-philic geochemical properties, dispersion of resources as well as itscomplicated composition, the properties of scandium are similar to those of the lanthanide. Hence, its separa-tion from the lanthanides and iron is an important subject which has been studied extensively.1,10-bis(1’-phenyl-3’-methyl-5’-oxopyrazole-4’-yl)decane-1, 10-dione(BPMDD, HA)is a β-diketone chelating agent, and has a strong extracting power. The extraction of Sc with this chelating agenthas not been reported so far. In this communication, we attempt to separate scandium from the lanthanidesand some other elements by the extraction with BPMDD under suitable conditions.
