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Effect of RRS on nitrogen transition and related bacteria in rhizosphere soil 被引量:11
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作者 LINing WANG Hongyan 《Journal of Northeast Agricultural University(English Edition)》 CAS 2007年第4期333-336,共4页
The biology safety of genetically modified organisms (GMO) has been a topic of considerable public debate in recent years. Parts of the international research on the safety of GMO focus on its effect on soil ecosyst... The biology safety of genetically modified organisms (GMO) has been a topic of considerable public debate in recent years. Parts of the international research on the safety of GMO focus on its effect on soil ecosystem, especially on microbial communities changing and process in soil that are essential to key terrestrial ecosystem functions. This paper studied the dynamic change of soil microbe after cultivating Roundup Ready soybean (RRS) and the effect on biochemical processing of nitrogen cycle. According to the variance analysis, the ammonifying bacteria and nitrifying bacteria quantities of RRS in the rhizosphere soil were much lower than that of other genotype soybeans. The effects of different genotype soybeans on ammoniation intensity and nitrification intensity were remarkable. The nitrification intensity and the nitrifying bacteria had the great positive correlation and sustainable development. 展开更多
关键词 rrs nitrogen transition bacteria
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氮掺杂石墨烯负载过渡金属催化CO_(2)RR的DFT研究
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作者 刘海龙 周震 程平 《广州化学》 CAS 2023年第5期62-66,I0004,共6页
设计了氮掺杂石墨烯负载四种过渡金属单原子催化剂用于CO_(2)RR(金属为Cu、Rh、Ir、Mn),考虑了5种氮配位(N_(1)、N_(2-1)、N_(2-2)、N_(3)和N_(4)),并通过第一性原理研究反应机理。自由能曲线显示Ir-N_(4)具有-0.323e V的低极限电位,通... 设计了氮掺杂石墨烯负载四种过渡金属单原子催化剂用于CO_(2)RR(金属为Cu、Rh、Ir、Mn),考虑了5种氮配位(N_(1)、N_(2-1)、N_(2-2)、N_(3)和N_(4)),并通过第一性原理研究反应机理。自由能曲线显示Ir-N_(4)具有-0.323e V的低极限电位,通过增加缺陷改性的Rh-N_(4)的CO_(2)RR性能也得到了改善。进一步通过Ir-N_(4)和Rh-N_(4)的差分电荷和态密度曲线分析吸附中间体COOH和金属原子之间的电荷转移和键合状态,发现金属原子和COOH之间的强烈相互作用形成了共价键,从而降低反应的总能量。本研究为设计高效的单原子CO_(2)RR催化剂提供了理论参考。 展开更多
关键词 氮掺杂石墨烯 CO_(2)RR 过渡金属 DFT 单原子催化剂
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